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Exercise1: Group 1.
Elements
Atom No
lithium
3
sodium
11
potassium
19
rubidium
27
Table above shows a list of proton number of Group 1 element in the periodic table, using the
information above, answer this question.
a. Write the electron arrangement of lithium, sodium and potassium.
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b. State the electron valence of elements in group 1.
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c. Potassium atom will react to form potassium ion.
(i) Draw a diagrammatic atomic structure of potassium ion.
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(i) State the changes of melting an boiling point of elements down group 1.
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(i) State the changes of melting point and boiling point of elements down group 1.
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Element
Cl
Br
Atomic Number
______
______
______
______
Electron arrangement
______
______
a. Fill the table above by writing the atomic number and electron arrangement for fluorine
and chlorine in space provided.
(i) Draw the diagrammatic electron arrangement of fluoride ion.
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(ii) Write the half equation of the reaction of fluorine atom to fluoride ion.
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b.
c.
d.
If the formulae of bromide ion is Br , state the number of electron in bromide ion.
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(i) State the changes of atomic size of halogen atom down group 17.
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(ii) Explain your answer.
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(iii) This elements exists naturally as molecule, give the physical state of this
molecule fluorine, chlorine, bromine and iodine.
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(iv) Explain why the physical state of these elements changes down group 17.
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Electron
number
Neutron
number
11
11
12
17
17
20
Element
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(iii) Calculate the relative molecular mass for X oxide.
[Relative atomic mass: O, 16]
(ii) Y oxide can react with water. Write a balance chemical equation to show this reaction.
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(e) Sodium can burnt in a chlorine gas to produced sodium chloride as in chemical equation
below.
2Na + Cl2 2NaCl
(i) If 5.75 g of sodium burnt in chlorine gas, what is the mass of sodium chloride formed?
[Nucleon number: Na, 23, Cl, 35.5, 1 mole gas occupies 24 dm 3 at room temperature]
Answer: 14.625 g
(ii) What is the volume of chlorine gas that will react with sodium?
Answer: 3 dm3
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Proton number
11
12
13
14
15
16
17
18
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E
11
F
12
G
13
H
14
I
15
J
16
K
17
L
18
(iii) F2 +
(ii)
(iii)
(ii)
(iii)
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.
(e) E will react with element K in lab. Write a balance chemical equation happen
when E and K react.
.
(f) G reacts with oxygen to produced G oxide. Write these compound formulae.
.
2.
Mg2+
Cl -
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: ...
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3.
(d) Hydrocarbon molecule burnt in excess oxygen to produced carbon dioxide and
water. Write a balance chemical equation to represent this reaction.
.
(e) (i) How many electrons is there in this molecule?
..
(ii) How many chemical bonds formed between carbon atoms with the other
carbon atom?
.
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4.
_
2+
XX
XX
X
X
X X
X X
X X
X
XX
XX
Figure above shows a diagrammatic electron arrangement of compound formed
from elements X and Y.
(a) From the figure shown write the compound formula.
(ii) Y atom
..
.
(d) Do you expect that the melting point and freezing point of this compound is high
or low? Explain your answer.
(e) Write the half equation of the formation of X ion from X atom.
..
(f) What is the name of the bond exist between ions in this compound.
..
(g) Name one compound that can be indicated by this example.
(h) From the electron point of view, explain how the bond was formed
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.
MODULE 13: Periodic Table and Chemical Bonding
Answer all question.
Periodic Table 1
1.
1
13
Transition
Elements
14
15
16
17
E
L
18
G
M
T
Periodic Table above shows the position of eight elements which can be represent
by the symbol of E, G, J, L, M, Q, R and T. Based on the symbol of this elements,
answer the following questions.
(a) Give the other name for Group 2. : ..
(b) There are four metals and three non-metals in the periodic table. List these
elements.
Metal: .Non-Metal : :
(c) Which of the elements in the periodic table above has the biggest radius?
(d) (i)
(ii)
Explain why.
:
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(ii) L
: .
(ii)
(i) Write a balance chemical equation that happens with R and molecule Q.
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K+
Na+
Ca2+
Mg2+
Al3+
Zn2+
Fe2+
Sn2+
Pb2+
H+
Cu2+
Ag+
2.
NO3ClBrIOH-
If there is a competition for the following ions, ions with high concentration will be
discharge.
Example : If
(a) F- and OH(b) Br- and OH(c) I- and OHIons with high concentration (F-, Br- and I-) will be discharged during electrolysis.
3.
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Cu2+
Ag+
Ni2+
+
+
+
2e
e
2e
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Electrolysis of silver nitrate solution is conducted for a few minutes in a lab and the
observation is recorded.
A
Switch
Rheostat
Carbon electrode Y
Carbon
electrode X
Silver nitrate
aqueous
(a)
List the three factors that will determine ions that are selected to be discharged
during electrolysis.
(b)
(c)
Carbon electrode X and Y are labeled as in figure above, state which one is the
cathode and anode.
(d)
Cathode
(e)
(f)
What will happen to the concentration of silver ion, Ag+ if the experiment is
conducted for a few minutes? Explain why.
(g)
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2.
Electrolysis of copper (II) sulphate is conducted in laboratory with copper electrode for
a few minutes and the observations of this experiment are recorded.
Copper electrode
Copper
electrode
Copper (II)
sulphate solution
(a)
If copper (II) sulphate solution is replaced with a solid copper (II) sulphate, can
the experiment be done? Explain why.
(b)
Cathode
(c)
Cathode
(d)
(e)
(i) Is there any changes of the colour of copper (II) sulphate after the
experiment is conducted for a few hours?
(ii) The copper (II) ions are being discharged at cathode during electrolysis. Is there
any difference in the concentration of copper (II) ions during the experiment?
(iii) Explain why.
(f)
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(g)
If the copper anode is replaced with a carbon anode, what will you predict
happen at anode?
(h)
3.
A
Switch
Rheostat
Carbon electrode Q
Carbon
electrode P
Copper (II)
chloride aqueous
(a) Write all ions exist in copper (II) chloride solution.
(b) (i) Write the half equation of the reaction happened at anode.
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(b)
(c)
(d)
(ii) State what happen if a litmus paper is placed near the gas.
(iii) The anions discharged during electrolysis at anode is based on one factor. State
the factor.
(e)
If the acid is replaced with a more dilute acid, which is 0.01 M. What is the anion that
is selected to be discharged at anode during electrolysis?
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Carbon
Copper(II) sulphate
solutions
Cell 1
Copper
Cell 1
Copper(II) sulphate
solutions
Larutan
kuprum(II) sulfat
Copper(II) sulphate
solutions
Cell II
(a)
Cell II
Electricity is passed through Cell I and II. Based on observation state the corresponding
inferences.
Observation
Inference
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(b)
(i)
After 10 minutes;
In Cell A, the colour of the solution changes from dark blue to light blue.
In Cell B, there is no change of colour in the solution.
Explain the difference.
Cell A:
Cell B:
(ii)
After 10 minutes, state how the colour of copper(II) sulphate solution changes in
Cell A when the electrolysis process is keep proceed.
(c)
(d)
Draw a labelled diagram to show the electroplating of a iron ring with silver, using silver
nitrate solution as the electrolyte.
(d)
Classify all the ions that exist in copper(II) sulphate solution into cations and anions.
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Lead strip
Magnesium ribbon
Beaker
M Electrolyte
(d) Write a half equation of the reaction both magnesium ribbon and lead strip.
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(f) What happen to the concentration of lead (II) ion, Pb2+ after doing the experiment for a
few minutes? Explain why.
(g) What do you predict happen to the voltmeter reading if both electrodes are placed
nearer to each other in the ECS?
(h) At the figure above, mark the negative and positive terminal.
(i)
(j)
Lead strip is replaced with another metal strip which will produce a higher voltage
reading. Suggest the name for that metal strip.
(k) Lead strip is replaced with another metal strip which will produce a lower voltage
reading. Suggest the name for that metal strip.
2. A voltaic cell experiment has been set up in a laboratory as figure below for at least 30
minutes. The observation and the reading of the ammeter is recorded.
Ammeter
Porous pot
Copper strip
Zinc strip
Zinc sulphate
aqueous 1M
aqueous 1M
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(c) What is the function of using the porous pot in this experiment
(f)
What will happen to the concentration of copper (II), Cu 2+ after doing the experiment for
30 minute. Explain why?
(h) Write an overall ionic equation of the reaction happen in the voltaic cell.
(i)
(j)
How do you know that the reaction in voltaic cell had just begun?
(k) If the zinc and zinc sulphate aqueous is replaced with magnesium ribbon and
magnesium sulphate aqueous in other experiment.
(i) State the difference in reading of the ammeter.
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Copper
Zinc
Copper
Zinc
Copper(II)
sulphate
solution
(a)
Copper(II)
sulphate
solution
(b) Predict the change that you would see in the copper(II) sulphate solution during the
experiment.
(c)
The experiment is repeated by substituting the zinc metal with iron, magnesium and lead.
diagram below shows the reading of the voltmeter.
0
5
Iron
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5
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0
5
and copper
Manipulated variable.
Responding variable. .
Fixed variable.
Positive terminal
Zinc
Copper
Iron
Copper
Magnesium
Copper
Lead
Copper
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Reading of
voltmeter /V
(b) Name an apparatus used to measure exactly 20.0 cm3 of dilute sulphuric acid 0.2 M.
(c) Reactions happen in the conical flask between sulphuric acid and potassium hydroxide
solution.
(i)
Name this reaction.
(ii)
(iii)
(d) State the changes of color of the solution inside the conical flask when it reaches the
end point.
(e) How can you determine that the alkaline added to the acid is already excessive?
(f) (i) Calculate the number of mole for the sulphuric acid.
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Early Readings /
cm3
End Readings /
cm3
0.0
12.3
12.5
25.0
25.0
37.4
Volume of sodium
hydroxide / cm3
(a) Give the definition of weak acid and give one example
(e) State the changing of color in the conical flask while doing the experiment.
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(h) (i) Fill the table above and find the average volume of sodium hydroxide used.
(ii) Find the number of mole for sodium hydroxide.
(iii) From question (h) (ii), calculate the concentration of sulfuric acid used.
(i) Why does the conical flask always have to be shaking while doing the experiment?
(j) Dilute sulfuric acid are pour inside a test tube and add 8 g of calcium carbonate to the
test tube. Pass the gas released through another test tube fill with limewater.
[Relative atomic mass; Ca, 40; C, 12; O, 16; 1 mole of gas occupies 24 dm 3 at room
temperature]
(i) Draw a figure to shows an apparatus used in the experiment.
(iv) Find the volume of gas released at room temperature in this experiment.
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