Aluminium

This article is about the metallic element. For other uses, 1.1 Physical
see Aluminium (disambiguation).
Aluminium is a relatively soft, durable, lightweight,
ductile and malleable metal with appearance ranging
Aluminium (or aluminum; see spelling dierences) is
from silvery to dull gray, depending on the surface rougha chemical element in the boron group with symbol Al
ness. It is nonmagnetic and does not easily ignite. A
and atomic number 13. It is a silvery white, soft, nonfresh lm of aluminium serves as a good reector (apmagnetic, ductile metal. Aluminium is the third most
proximately 92%) of visible light and an excellent reecabundant element (after oxygen and silicon), and the most
tor (as much as 98%) of medium and far infrared radiaabundant metal in the Earth's crust. It makes up about 8%
tion. The yield strength of pure aluminium is 711 MPa,
by weight of the Earths solid surface. Aluminium metal
while aluminium alloys have yield strengths ranging from
is so chemically reactive that native specimens are rare
200 MPa to 600 MPa.[8] Aluminium has about one-third
and limited to extreme reducing environments. Instead,
the density and stiness of steel. It is easily machined,
it is found combined in over 270 dierent minerals.[6]
cast, drawn and extruded.
The chief ore of aluminium is bauxite.
Aluminium atoms are arranged in a face-centered cubic
Aluminium is remarkable for the metals low density and
(fcc) structure. Aluminium has a stacking-fault energy of
for its ability to resist corrosion due to the phenomenon
approximately 200 mJ/m2 .[9]
of passivation. Structural components made from aluminium and its alloys are vital to the aerospace indus- Aluminium is a good thermal and electrical conductor,
try and are important in other areas of transportation and having 59% the conductivity of copper, both thermal
structural materials. The most useful compounds of alu- and electrical, while having only 30% of coppers denminium, at least on a weight basis, are the oxides and sity. Aluminium is capable of being a superconductor,
with a superconducting critical temperature of 1.2 Kelvin
sulfates.
and a critical magnetic eld of about 100 gauss (10
Despite its prevalence in the environment, no known form
milliteslas).[10]
of life uses aluminium salts metabolically. In keeping
with its pervasiveness, aluminium is well tolerated by
plants and animals.[7] Owing to their prevalence, potential
1.2 Chemical
benecial (or otherwise) biological roles of aluminium
compounds are of continuing interest.
Corrosion resistance can be excellent due to a thin surface
layer of aluminium oxide that forms when the metal is exposed to air, eectively preventing further oxidation.[11]
The strongest aluminium alloys are less corrosion resis1 Characteristics
tant due to galvanic reactions with alloyed copper.[8] This
corrosion resistance is also often greatly reduced by aqueous salts, particularly in the presence of dissimilar metals.
In highly acidic solutions aluminium reacts with water
to form hydrogen, and in highly alkaline ones to form
aluminates protective passivation under these conditions is negligible. Also, chlorides such as common
sodium chloride are well-known sources of corrosion of
aluminium and are among the chief reasons that household plumbing is never made from this metal.[12]
However, owing to its resistance to corrosion generally,
aluminium is one of the few metals that retain silvery reectance in nely powdered form, making it an important component of silver-colored paints. Aluminium mirror nish has the highest reectance of any metal in the
200400 nm (UV) and the 3,00010,000 nm (far IR) regions; in the 400700 nm visible range it is slightly out-

"Red mud" storage facility in Stade Germany. The aluminium

industry generates about 70 million tons of this waste annually.

2 PRODUCTION AND REFINEMENT

performed by tin and silver and in the 7003000 (near found in the elemental state; instead it is found in oxIR) by silver, gold, and copper.[13]
ides or silicates. Feldspars, the most common group of
minerals
in the Earths crust, are aluminosilicates. Native
Aluminium is oxidized by water at temperatures below
aluminium
metal can only be found as a minor phase in
280C to produce hydrogen, aluminium hydroxide and
low
oxygen
fugacity environments, such as the interiors
heat:
of certain volcanoes.[19] Native aluminium has been reported in cold seeps in the northeastern continental slope
2 Al + 6 H2 O 2 Al(OH)3 + 3 H2
of the South China Sea and Chen et al. (2011)[20] have
proposed a theory of its origin as resulting by reduction

This conversion is of interest for the production of hydro- from tetrahydroxoaluminate Al(OH)4 to metallic alu[20]
gen. Challenges include circumventing the formed oxide minium by bacteria.
layer, which inhibits the reaction and the expenses asso- It also occurs in the minerals beryl, cryolite, garnet, spinel
ciated with the storage of energy by regeneration of the and turquoise. Impurities in Al2 O3 , such as chromium or
Al metal.[14]
iron yield the gemstones ruby and sapphire, respectively.
Although aluminium is an extremely common and
widespread element, the common aluminium minerals
1.3 Isotopes
are not economic sources of the metal. Almost all
metallic aluminium is produced from the ore bauxite
Main article: Isotopes of aluminium
(AlOx(OH)x). Bauxite occurs as a weathering product of low iron and silica bedrock in tropical climatic
Aluminium has many known isotopes, whose mass num- conditions.[21] Large deposits of bauxite occur in Ausbers range from 21 to 42; however, only 27 Al (stable tralia, Brazil, Guinea and Jamaica and the primary minisotope) and 26 Al (radioactive isotope, t = 7.2105 ing areas for the ore are in Australia, Brazil, China, India,
y) occur naturally. 27 Al has a natural abundance above Guinea, Indonesia, Jamaica, Russia and Suriname.
99.9%. 26 Al is produced from argon in the atmosphere
by spallation caused by cosmic-ray protons. Aluminium
isotopes have found practical application in dating marine
2 Production and renement
sediments, manganese nodules, glacial ice, quartz in rock
exposures, and meteorites. The ratio of 26 Al to 10 Be
has been used to study the role of transport, deposition, See also: Category:Aluminium minerals and List of
sediment storage, burial times, and erosion on 105 to 106 countries by aluminium production
year time scales.[15] Cosmogenic 26 Al was rst applied Bauxite is converted to aluminium oxide (Al2 O3 ) via the
in studies of the Moon and meteorites. Meteoroid fragments, after departure from their parent bodies, are exposed to intense cosmic-ray bombardment during their
travel through space, causing substantial 26 Al production. After falling to Earth, atmospheric shielding drastically reduces 26 Al production, and its decay can then
be used to determine the meteorites terrestrial age. Meteorite research has also shown that 26 Al was relatively
abundant at the time of formation of our planetary system. Most meteorite scientists believe that the energy released by the decay of 26 Al was responsible for the melting and dierentiation of some asteroids after their formation 4.55 billion years ago.[16]

1.4

Natural occurrence

See also: List of countries by bauxite production

Stable aluminium is created when hydrogen fuses with
magnesium either in large stars or in supernovae.[17]

Bauxite, a major aluminium ore. The red-brown color is due to

the presence of iron minerals.

Bayer process.[7] Relevant chemical equations are:

Al2 O3 + 2 NaOH 2 NaAlO2 + H2 O

2 H2 O + NaAlO2 Al(OH)3 + NaOH

In the Earths crust, aluminium is the most abundant
(8.3% by weight) metallic element and the third most
abundant of all elements (after oxygen and silicon).[18] The intermediate sodium aluminate, given the simplied
Because of its strong anity to oxygen, it is almost never formula NaAlO2 , is soluble in strongly alkaline water, and

2.1

Recycling

the other components of the ore are not. Depending on the Hoopes process. The process involves the electrolythe quality of the bauxite ore, twice as much waste ("red sis of molten aluminium with a sodium, barium and alumud") is generated compared to the amount of alumina. minium uoride electrolyte. The resulting aluminium has
[7][22]
The conversion of alumina to aluminium metal is a purity of 99.99%.
achieved by the Hall-Hroult process. In this energyintensive process, a solution of alumina in a molten (950
and 980 C (1,740 and 1,800 F)) mixture of cryolite
(Na3 AlF6 ) with calcium uoride is electrolyzed to give
the metal:
Al3+ + 3 e Al
At the anode, oxygen is formed:
2 O2 O2 + 4 e

Electric power represents about 20% to 40% of the cost

of producing aluminium, depending on the location of
the smelter. Aluminium production consumes roughly
5% of electricity generated in the U.S.[23] Aluminium
producers tend to locate smelters in places where electric power is both plentiful and inexpensivesuch as the
United Arab Emirates with its large natural gas supplies,
and Iceland and Norway with energy generated from
renewable sources. The worlds largest smelters of alumina are Peoples Republic of China, Russia, and Quebec
and British Columbia in Canada.[23][24][25]

3500

Aluminium Spot Price (USD) 1987 - 2012

2500
2000
1500

US Dollars tonne

3000

Upper quartile $2058

Mean price $1774
Lower quartile $1403

1000

The aluminium metal then sinks to the bottom of the solution and is tapped o, usually cast into large blocks
called aluminium billets for further processing. To some
extent, the carbon anode is consumed by subsequent reaction with oxygen to form carbon dioxide. The anodes
in a reduction cell must therefore be replaced regularly,
since they are consumed in the process. The cathodes do
erode, mainly due to electrochemical processes and metal
movement. After ve to ten years, depending on the current used in the electrolysis, a cell must be rebuilt because
of cathode wear.

Data: www.Indexmundi.com www.lme.com/aluminium.asp

http://www.indexmundi.com/commodities/?commodity=aluminum&months=300

1990

1995

2000

2005

2010

Production in 106 tons / year

Year

50
40
30
20
10
0
1900 1920 1940 1960 1980 2000 2020
Year

World production trend of aluminium

Aluminium electrolysis with the Hall-Hroult process

consumes a lot of energy. The worldwide average specic
energy consumption is approximately 150.5 kilowatthours per kilogram of aluminium produced (52 to 56
MJ/kg). The most modern smelters achieve approximately 12.8 kWh/kg (46.1 MJ/kg). (Compare this to
the heat of reaction, 31 MJ/kg, and the Gibbs free energy of reaction, 29 MJ/kg.) Reduction line currents for
older technologies are typically 100 to 200 kiloamperes;
state-of-the-art smelters operate at about 350 kA. Trials
have been reported with 500 kA cells.

Aluminium spot price 19872012

In 2005, the Peoples Republic of China was the top producer of aluminium with almost a one-fth world share,
followed by Russia, Canada, and the US, reports the
British Geological Survey.
Over the last 50 years, Australia has become the worlds
top producer of bauxite ore and a major producer and
exporter of alumina (before being overtaken by China
in 2007).[24][26] Australia produced 77 million tonnes of
bauxite in 2013.[27] The Australian deposits have some
rening problems, some being high in silica, but have the
advantage of being shallow and relatively easy to mine.[28]

2.1 Recycling
Main article: Aluminium recycling

Aluminium is theoretically 100% recyclable without any

loss of its natural qualities. According to the International
Resource Panel's Metal Stocks in Society report, the
global per capita stock of aluminium in use in society
(i.e. in cars, buildings, electronics etc.) is 80 kg (180 lb).
Much of this is in more-developed countries (350500
The Hall-Heroult process produces aluminium with a pu- kg (7701,100 lb) per capita) rather than less-developed
rity of above 99%. Further purication can be done by countries (35 kg (77 lb) per capita). Knowing the per

COMPOUNDS

3 Compounds
3.1 Oxidation state +3
The vast majority of compounds, including all Alcontaining minerals and all commercially signicant aluminium compounds, feature aluminium in the oxidation
state 3+. The coordination number of such compounds
varies, but generally Al3+ is six-coordinate or tetracoordinate. Almost all compounds of aluminium(III) are
colorless.[18]

3.1.1 Halides

Aluminium recycling code

capita stocks and their approximate lifespans is important

for planning recycling.
Recovery of the metal via recycling has become an important use of the aluminium industry. Recycling was a
low-prole activity until the late 1960s, when the growing
use of aluminium beverage cans brought it to the public
awareness.
Recycling involves melting the scrap, a process that requires only 5% of the energy used to produce aluminium
from ore, though a signicant part (up to 15% of the
input material) is lost as dross (ash-like oxide).[29] An
aluminium stack melter produces signicantly less dross,
with values reported below 1%.[30] The dross can undergo
a further process to extract aluminium.
In Europe aluminium experiences high rates of recycling,
ranging from 42% of beverage cans, 85% of construction
materials and 95% of transport vehicles.[31]

All four trihalides are well known. Unlike the structures of the three heavier trihalides, aluminium uoride
(AlF3 ) features six-coordinate Al. The octahedral coordination environment for AlF3 is related to the compactness of uoride ion, six of which can t around the small
Al3+ center. AlF3 sublimes (with cracking) at 1,291 C
(2,356 F). With heavier halides, the coordination numbers are lower. The other trihalides are dimeric or polymeric with tetrahedral Al centers. These materials are
prepared by treating aluminium metal with the halogen,
although other methods exist. Acidication of the oxides or hydroxides aords hydrates. In aqueous solution,
the halides often form mixtures, generally containing sixcoordinate Al centers, which are feature both halide and
aquo ligands. When aluminium and uoride are together
in aqueous solution, they readily form complex ions such
as [AlF(H
2O)
5]2+
, AlF
3(H
2O)
3, and [AlF
6]3
. In the case of chloride, polyaluminium clusters are
formed such as [Al13 O4 (OH)24 (H2 O)12 ]7+ .

Recycled aluminium is known as secondary aluminium,

but maintains the same physical properties as primary
aluminium. Secondary aluminium is produced in a wide
range of formats and is employed in 80% of alloy injections. Another important use is for extrusion.
3.1.2 Oxide and hydroxides
White dross from primary aluminium production and
from secondary recycling operations still contains use- Aluminium forms one stable oxide, known by its mineral
ful quantities of aluminium that can be extracted name corundum. Sapphire and ruby are impure corunindustrially.[32] The process produces aluminium billets, dum contaminated with trace amounts of other mettogether with a highly complex waste material. This als. The two oxide-hydroxides, AlO(OH), are boehmite
waste is dicult to manage. It reacts with water, releasing and diaspore. There are three trihydroxides: bayerite,
a mixture of gases (including, among others, hydrogen, gibbsite, and nordstrandite, which dier in their crysacetylene, and ammonia), which spontaneously ignites on talline structure (polymorphs). Most are produced from
contact with air;[33] contact with damp air results in the ores by a variety of wet processes using acid and base.
release of copious quantities of ammonia gas. Despite Heating the hydroxides leads to formation of corundum.
these diculties, the waste has found use as a ller in These materials are of central importance to the producasphalt and concrete.[34]
tion of aluminium and are themselves extremely useful.

3.3
3.1.3

Oxidation states +1 and +2

Carbide, nitride, and related materials

simplest hydride, aluminium hydride or alane, remains

a laboratory curiosity. It is a polymer with the formula
Aluminium carbide (Al4 C3 ) is made by heating a mix- (AlH3 )n, in contrast to the corresponding boron hydride
ture of the elements above 1,000 C (1,832 F). The pale with the formula (BH3 )2 .
yellow crystals consist of tetrahedral aluminium centers.
It reacts with water or dilute acids to give methane. The
acetylide, Al2 (C2 )3 , is made by passing acetylene over 3.3 Oxidation states +1 and +2
heated aluminium.
Although the great majority of aluminium compounds
Aluminium nitride (AlN) is the only nitride known for
feature Al3+ centers, compounds with lower oxidation
aluminium. Unlike the oxides it features tetrahedral Al
states are known and sometime of signicance as precenters. It can be made from the elements at 800 C
cursors to the Al3+ species.
(1,472 F). It is air-stable material with a usefully high
thermal conductivity. Aluminium phosphide (AlP) is
made similarly, and hydrolyses to give phosphine:
3.3.1 Aluminium(I)
AlP + 3 H2 O Al(OH)3 + PH3

3.2

AlF, AlCl and AlBr exist in the gaseous phase when the
trihalide is heated with aluminium. The composition
AlI is unstable at room temperature with respect to the
Organoaluminium compounds and re- triiodide:[36]

lated hydrides

Main article: Organoaluminium compound

A variety of compounds of empirical formula AlR3 and

3 AlI AlI3 + 2 Al
A stable derivative of aluminium monoiodide is the cyclic
adduct formed with triethylamine, Al4 I4 (NEt3 )4 . Also
of theoretical interest but only of eeting existence are
Al2 O and Al2 S. Al2 O is made by heating the normal
oxide, Al2 O3 , with silicon at 1,800 C (3,272 F) in a
vacuum.[36] Such materials quickly disproportionates to
the starting materials.
3.3.2 Aluminium(II)

Very simple Al(II) compounds are invoked or observed

in the reactions of Al metal with oxidants. For example, aluminium monoxide, AlO, has been detected in
the gas phase after explosion[37] and in stellar absorption
Structure of trimethylaluminium, a compound that features ve- spectra.[38] More thoroughly investigated are compounds
coordinate carbon.
of the formula R4 Al2 which contain an Al-Al bond and
[39]
[35]
AlR.Cl. exist.
These species usually feature tetra- where R is a large organic ligand.
hedral Al centers, e.g. "trimethylaluminium" has the formula Al2 (CH3 )6 (see gure). With large organic groups,
3.4 Analysis
triorganoaluminium exist as three-coordinate monomers,
such as triisobutylaluminium. Such compounds are
The presence of aluminium can be detected in qualitative
widely used in industrial chemistry, despite the fact that
analysis using aluminon.
they are often highly pyrophoric. Few analogues exist between organoaluminium and organoboron compounds except for large organic groups.

4 Applications

The important aluminium hydride is lithium aluminium

hydride (LiAlH4 ), which is used in as a reducing agent
in organic chemistry. It can be produced from lithium 4.1 General use
hydride and aluminium trichloride:
Aluminium is the most widely used non-ferrous metal.[40]
Global production of aluminium in 2005 was 31.9 mil4 LiH + AlCl3 LiAlH4 + 3 LiCl
lion tonnes. It exceeded that of any other metal except
Several useful derivatives of LiAlH4 are known, e.g. iron (837.5 million tonnes).[41] Forecast for 2012 is 42
sodium bis(2-methoxyethoxy)dihydridoaluminate. The 45 million tonnes, driven by rising Chinese output.[42]

Etched surface from a high purity (99.9998%) aluminium bar,

size 5537 mm

Aluminium is almost always alloyed, which markedly

improves its mechanical properties, especially when
tempered.
For example, the common aluminium
foils and beverage cans are alloys of 92% to 99%
aluminium.[43] The main alloying agents are copper, zinc,
magnesium, manganese, and silicon (e.g., duralumin) and
the levels of these other metals are in the range of a few
percent by weight.[44]

4 APPLICATIONS

Aluminium slabs being transported from a smelter

Transportation (automobiles, aircraft, trucks,

railway cars, marine vessels, bicycles, etc.) as sheet,
tube, castings, etc.
Packaging (cans, foil, frame of etc.)
Construction (windows, doors, siding, building wire,
etc.).[45]
A wide range of household items, from cooking
utensils to baseball bats, watches.[46]
Street lighting poles, sailing ship masts, walking
poles, etc.
Outer shells of consumer electronics, also cases for
equipment e.g. photographic equipment, MacBook
Pro's casing
Electrical transmission lines for power distribution
MKM steel and Alnico magnets
Super purity aluminium (SPA, 99.980% to 99.999%
Al), used in electronics and CDs, and also in
Wires/Cabling.

Household aluminium foil

Heat sinks for electronic appliances such as

transistors and CPUs.
Substrate material of metal-core copper clad laminates used in high brightness LED lighting.
Powdered aluminium is used in paint, and in
pyrotechnics such as solid rocket fuels and thermite.
Aluminium can be reacted with hydrochloric acid or
with sodium hydroxide to produce hydrogen gas.
Aluminium is used to make Food Containers, because of its characteristic - resistant to corrosion.

Aluminium-bodied Austin A40 Sports (c. 1951)

Some of the many uses for aluminium metal are in:

Aluminium with Magnesium [alloy] is used to make

body of Aircraft.
Aluminium with other metals, used to make Railway
tracks.

4.3

Aluminium alloys in structural applications

Aluminium is used to make Cooking Utensils, because it is resistant to corrosion, and light-weight.
A variety of countries, including France, Italy,
Poland, Finland, Romania, Israel, and the former
Yugoslavia, have issued coins struck in aluminium
or aluminium-copper alloys.[47][48]

7
the annual scale of several billions of kilograms. About
half of the production is consumed in water treatment.
The next major application is in the manufacture of
paper. It is also used as a mordant, in re extinguisher,
as a food additive, in reproong, and in leather tanning.
Aluminium ammonium sulfate, which is also called
ammonium alum, (NH4 )Al(SO4 )2 12H2 O, is used as a
mordant and in leather tanning.[7] Aluminium potassium
sulfate ([Al(K)](SO4 )2 )(H2 O)12 is used similarly. The
consumption of both alums is declining.

Some guitar models sport aluminium diamond

plates on the surface of the instruments, usually either chrome or black. Kramer Guitars and Travis
Bean are both known for having produced guitars
with necks made of aluminium, which gives the in- 4.2.3 Chlorides
strument a very distinct sound.
Aluminium chloride (AlCl3 ) is used in petroleum rening
Aluminium is usually alloyed it is used as pure metal and in the production of synthetic rubber and polymers.
only when corrosion resistance and/or workability is more Although it has a similar name, aluminium chlorohydrate
important than strength or hardness. A thin layer of alu- has fewer and very dierent applications, e.g. as a hardminium can be deposited onto a at surface by physical ening agent and an antiperspirant. It is an intermediate in
vapor deposition or (very infrequently) chemical vapor the production of aluminium metal.
deposition or other chemical means to form optical coatings and mirrors.
4.2.4 Niche compounds

4.2

Aluminium compounds

Because aluminium is abundant and most of its derivatives exhibit low toxicity, the compounds of aluminium
enjoy wide and sometimes large-scale applications.
4.2.1

Alumina

Main article: Aluminium oxide

Aluminium oxide (Al2 O3 ) and the associated oxyhydroxides and trihydroxides are produced or extracted
from minerals on a large scale. The great majority of
this material is converted to metallic aluminium. In 2013
about 10% of the domestic shipments in the Unitated
States were used for other applications.[49] A major use
is as an absorbent. For example, alumina removes water from hydrocarbons, which enables subsequent processes that are poisoned by moisture. Aluminium oxides
are common catalysts for industrial processes, e.g. the
Claus process for converting hydrogen sulde to sulfur in
reneries and for the alkylation of amines. Many industrial catalysts are supported, meaning generally that an
expensive catalyst (e.g., platinum) is dispersed over a high
surface area material such as alumina. Being a very hard
material (Mohs hardness 9), alumina is widely used as an
abrasive and the production of applications that exploit
its inertness, e.g., in high pressure sodium lamps.

Given the scale of aluminium compounds, a small scale

application could still involve thousands of tonnes. One
of the many compounds used at this intermediate level
include aluminium acetate, a salt used in solution as an
astringent. Aluminium borate (Al2 O3 B2 O3 ) is used in
the production of glass and ceramics. Aluminium uorosilicate (Al2 (SiF6 )3 ) is used in the production of synthetic gemstones, glass and ceramic. Aluminium phosphate (AlPO4 ) is used in the manufacture: of glass and
ceramic, pulp and paper products, cosmetics, paints and
varnishes and in making dental cement. Aluminium hydroxide (Al(OH)3 ) is used as an antacid, as a mordant,
in water purication, in the manufacture of glass and
ceramic and in the waterproong of fabrics. Lithium
aluminium hydride is a powerful reducing agent used in
organic chemistry. Organoaluminiums are used as Lewis
acids and cocatalysts. For example, methylaluminoxane
is a cocatalyst for Ziegler-Natta olen polymerization to
produce vinyl polymers such as polyethene.

4.3 Aluminium alloys in structural applications

Main article: Aluminium alloy
Aluminium alloys with a wide range of properties are
used in engineering structures. Alloy systems are classied by a number system (ANSI) or by names indicating
their main alloying constituents (DIN and ISO).

The strength and durability of aluminium alloys vary

widely, not only as a result of the components of the specic alloy, but also as a result of heat treatments and man4.2.2 Sulfates
ufacturing processes. A lack of knowledge of these asSeveral sulfates of aluminium nd applications. pects has from time to time led to improperly designed
Aluminium sulfate (Al2 (SO4 )3 (H2 O)18 ) is produced on structures and gained aluminium a bad reputation.

HISTORY

5 History

Aluminium foam

One important structural limitation of aluminium alloys

is their fatigue strength. Unlike steels, aluminium alloys
have no well-dened fatigue limit, meaning that fatigue The statue of the Anteros in Piccadilly Circus, London, was made
failure eventually occurs, under even very small cyclic in 1893 and is one of the rst statues cast in aluminium.
loadings. This implies that engineers must assess these
loads and design for a xed life rather than an innite life. Ancient Greeks and Romans used aluminium salts as
dyeing mordants and as astringents for dressing wounds;
Another important property of aluminium alloys is their alum is still used as a styptic. In 1761, Guyton de
sensitivity to heat. Workshop procedures involving heat- Morveau suggested calling the base alum alumine. In
ing are complicated by the fact that aluminium, unlike
1808, Humphry Davy identied the existence of a metal
steel, melts without rst glowing red. Forming operations base of alum, which he at rst termed alumium and later
where a blow torch is used therefore require some experaluminum (see etymology section, below).
tise, since no visual signs reveal how close the material is
to melting. Aluminium alloys, like all structural alloys, The metal was rst produced in 1825 in an impure form
also are subject to internal stresses following heating op- by Danish physicist and chemist Hans Christian rsted.
erations such as welding and casting. The problem with He reacted anhydrous aluminium chloride with potassium
aluminium alloys in this regard is their low melting point, amalgam, yielding a lump of metal looking similar to
[50]
which make them more susceptible to distortions from tin. Friedrich Whler was aware of these experiments
thermally induced stress relief. Controlled stress relief and cited them, but after redoing the experiments of
can be done during manufacturing by heat-treating the rsted he concluded that this metal was pure potasparts in an oven, followed by gradual coolingin eect sium. He conducted a similar experiment in 1827 by
mixing anhydrous aluminium chloride with potassium
annealing the stresses.
and yielded aluminium.[50] Whler is generally credited
The low melting point of aluminium alloys has not pre- with isolating aluminium (Latin alumen, alum). Furcluded their use in rocketry; even for use in constructing ther, Pierre Berthier discovered aluminium in bauxite
combustion chambers where gases can reach 3500 K. The ore. Henri Etienne Sainte-Claire Deville improved WhAgena upper stage engine used a regeneratively cooled lers method in 1846. As described in his 1859 book, alualuminium design for some parts of the nozzle, including minium trichloride could be reduced by sodium, which
the thermally critical throat region.
was more convenient and less expensive than potassium
Another alloy of some value is aluminium bronze (Cu-Al used by Whler.[51] In the mid 1880s, aluminium metal
alloy).
was exceedingly dicult to produce, which made pure

9
aluminium more valuable than gold.[52] So celebrated 6 Etymology
was the metal that bars of aluminium were exhibited at
the Exposition Universelle of 1855.[53] Napoleon III of
Two variants of the metals name are in current use, aluFrance is reputed to held a banquet where the most honminium (pronunciation: /l(j)mnim/) and aluminum
ored guests were given aluminium utensils, while the oth(/lumnm/)besides the obsolete alumium. The
ers made do with gold.[54][55]
International Union of Pure and Applied Chemistry (IUAluminium was selected as the material to use for the 100 PAC) adopted aluminium as the standard international
ounces (2.8 kg) capstone of the Washington Monument name for the element in 1990 but, three years later, recin 1884, a time when one ounce (30 grams) cost the daily ognized aluminum as an acceptable variant. Hence their
wage of a common worker on the project (in 1884 about periodic table includes both.[63] IUPAC internal publica$1 for 10 hours of labor; today, a construction worker tions use either spelling in nearly the same number.[64]
in the US working on such a project might earn $25-$35
Most countries use the spelling aluminium. In the
per hour and therefore around $300 in an equivalent sinUnited States and Canada, the spelling aluminum
gle 10-hour day).[56] The capstone, which was set in place
predominates.[18][65] The Canadian Oxford Dictionary
on 6 December 1884, in an elaborate dedication cereprefers aluminum, whereas the Australian Macquarie
mony, was the largest single piece of aluminium cast at
Dictionary
prefers aluminium. In 1926, the American
the time.[56]
Chemical Society ocially decided to use aluminum in
The Cowles companies supplied aluminium alloy in quan- its publications; American dictionaries typically label the
tity in the United States and England using smelters like spelling aluminium as chiey British.[66][67]
the furnace of Carl Wilhelm Siemens by 1886.[57][58][59]
The various names all derive from its status as a base of
alum. It is borrowed from Old French; its ultimate source,
alumen, in turn is a Latin word that literally means bitter
salt.[68]

5.1

Hall-Heroult process: availability of

cheap aluminium metal

Charles Martin Hall of Ohio in the U.S. and Paul Hroult

of France independently developed the Hall-Hroult electrolytic process that facilitated large-scale production
of metallic aluminium. This process remains in use
today.[60] In 1888 with the nancial backing of Alfred E.
Hunt, the Pittsburgh Reduction Company started, today
it is known as Alcoa. Hroults process was in production by 1889 in Switzerland at Aluminium Industrie, now
Alcan, and at British Aluminium, now Luxfer Group and
Alcoa, by 1896 in Scotland.[61]
By 1895, the metal was being used as a building material
as far away as Sydney, Australia in the dome of the Chief
Secretarys Building.
With the explosive expansion of the airplane industry during World War I (1914-1917), major governments demanded large shipments of aluminium for light, strong
airframes. They often subsidized factories and the necessary electrical supply systems.[62]

The earliest citation given in the Oxford English Dictionary for any word used as a name for this element is alumium, which British chemist and inventor Humphry Davy
employed in 1808 for the metal he was trying to isolate
electrolytically from the mineral alumina. The citation is
from the journal Philosophical Transactions of the Royal
Society of London: Had I been so fortunate as to have
obtained more certain evidences on this subject, and to
have procured the metallic substances I was in search of,
I should have proposed for them the names of silicium,
alumium, zirconium, and glucium.[69][70]
Davy settled on aluminum by the time he published his
1812 book Chemical Philosophy: This substance appears to contain a peculiar metal, but as yet Aluminum
has not been obtained in a perfectly free state, though
alloys of it with other metalline substances have been
procured suciently distinct to indicate the probable nature of alumina.[71] But the same year, an anonymous
contributor to the Quarterly Review, a British politicalliterary journal, in a review of Davys book, objected to
aluminum and proposed the name aluminium, for so we
shall take the liberty of writing the word, in preference to
aluminum, which has a less classical sound.[72]

The -ium sux conformed to the precedent set in other

newly discovered elements of the time: potassium,
sodium, magnesium, calcium, and strontium (all of which
Davy isolated himself). Nevertheless, -um spellings for
elements were not unknown at the time, as for example platinum, known to Europeans since the 16th century, molybdenum, discovered in 1778, and tantalum,
Aluminium wire was once widely used for domestic elec- discovered in 1802. The -um sux is consistent with
trical wiring. Owing to corrosion-induced failures, a the universal spelling alumina for the oxide (as opposed
to aluminia), as lanthana is the oxide of lanthanum, and
number of res resulted.
Many navies have used an aluminium superstructure for
their vessels; the 1975 re aboard USS Belknap that gutted her aluminium superstructure, as well as observation
of battle damage to British ships during the Falklands
War, led to many navies switching to all steel superstructures.

10

HEALTH CONCERNS

magnesia, ceria, and thoria are the oxides of magnesium, of 6207 mg/kg (oral, mouse), which corresponds to 500
cerium, and thorium respectively.
grams for an 80 kg (180 lb) person.[7] The extremely
The aluminum spelling is used in the Websters Dictio- low acute toxicity notwithstanding, the health eects of
nary of 1828. In his advertising handbill for his new elec- aluminium are of interest in view of the widespread octrolytic method of producing the metal in 1892, Charles currence of the element in the environment and in comMartin Hall used the -um spelling, despite his constant merce.
use of the -ium spelling in all the patents[60] he led between 1886 and 1903. Halls domination of production
of the metal ensured that aluminum became the standard
English spelling in North America.

Health concerns

Schematic of Al absorption by human skin.[73]

There are ve major Al forms absorbed by human body: the free

solvated trivalent cation (Al3+ (aq)); low-molecular-weight, neutral, soluble complexes (LMW-Al0 (aq)); high-molecular-weight,
neutral, soluble complexes (HMW-Al0 (aq)); low-molecularweight, charged, soluble complexes (LMW-Al(L)n+/ (aq)); nano
and micro-particulates (Al(L)n(s)). They are transported across
cell membranes or cell epi-/endothelia through ve major routes:
(1) paracellular; (2) transcellular; (3) active transport; (4) channels; (5) adsorptive or receptor-mediated endocytosis.[73]

Some toxicity can be traced to deposition in bone and the

central nervous system, which is particularly increased in
patients with reduced renal function. Because aluminium
competes with calcium for absorption, increased amounts
of dietary aluminium may contribute to the reduced
skeletal mineralization (osteopenia) observed in preterm
infants and infants with growth retardation. In very high
doses, aluminium can cause neurotoxicity,[74] and is associated with altered function of the bloodbrain barrier.[75]
A small percentage of people are allergic to aluminium
and experience contact dermatitis, digestive disorders,
vomiting or other symptoms upon contact or ingestion of
products containing aluminium, such as antiperspirants
and antacids. In those without allergies, aluminium is
not as toxic as heavy metals, but there is evidence of
some toxicity if it is consumed in amounts greater than
40 mg/day per kg of body mass.[76] Although the use
of aluminium cookware has not been shown to lead to
aluminium toxicity in general, excessive consumption of
antacids containing aluminium compounds and excessive use of aluminium-containing antiperspirants provide
more signicant exposure levels. Studies have shown
that consumption of acidic foods or liquids with aluminium signicantly increases aluminium absorption,[77]
and maltol has been shown to increase the accumulation of aluminium in nervous and osseus tissue.[78] Furthermore, aluminium increases estrogen-related gene expression in human breast cancer cells cultured in the
laboratory.[79] The estrogen-like eects of these salts
have led to their classication as a metalloestrogen.
The eects of aluminium in antiperspirants have been examined over the course of decades with little evidence
of skin irritation.[7] Nonetheless, its occurrence in antiperspirants, dyes (such as aluminium lake), and food
additives has caused concern.[80] Although there is little
evidence that normal exposure to aluminium presents a
risk to healthy adults,[81] some studies point to risks associated with increased exposure to the metal.[80] Aluminium in food may be absorbed more than aluminium
from water.[82] It is classied as a non-carcinogen by the
US Department of Health and Human Services.[76]
In case of suspected sudden intake of a large amount of
aluminium, deferoxamine mesylate may be given to help
eliminate it from the body by chelation.[83]

7.1 Alzheimers disease

Despite its widespread occurrence in nature, aluminium Aluminium has controversially been implicated as a fachas no known function in biology. Aluminium salts are tor in Alzheimers disease.[84] The Camelford water polremarkably nontoxic, aluminium sulfate having an LD50 lution incident involved a number of people consuming

11
aluminium sulfate. Investigations of the long-term health
eects are still ongoing, but elevated brain aluminium
concentrations have been found in post-mortem examinations of victims, and further research to determine if
there is a link with cerebral amyloid angiopathy has been
commissioned.[85]
According to the Alzheimers Society, the medical and
scientic opinion is that studies have not convincingly
demonstrated a causal relationship between aluminium
and Alzheimers disease.[86] Nevertheless, some studies,
such as those on the PAQUID cohort,[87] cite aluminium
exposure as a risk factor for Alzheimers disease. Some
brain plaques have been found to contain increased levels
of the metal.[88] Research in this area has been inconclusive; aluminium accumulation may be a consequence of
the disease rather than a causal agent. [89][90]

10 See also
Aluminium: The Thirteenth Element
Aluminiumair battery
Aluminium alloy
Aluminium foil
Aluminium granules
Aluminium hydroxide
Beverage can
Institute for the History of Aluminium
Panel edge staining
The Aluminum Association

Eect on plants

Aluminium is primary among the factors that reduce

plant growth on acid soils. Although it is generally harmless to plant growth in pH-neutral soils, the concentration
in acid soils of toxic Al3+ cations increases and disturbs
root growth and function.[91][92][93][94]
Most acid soils are saturated with aluminium rather than
hydrogen ions. The acidity of the soil is therefore a result of hydrolysis of aluminium compounds.[95] This concept of corrected lime potential[96] to dene the degree
of base saturation in soils became the basis for procedures now used in soil testing laboratories to determine
the "lime requirement[97] of soils.[98]
Wheat's adaptation to allow aluminium tolerance is such
that the aluminium induces a release of organic compounds that bind to the harmful aluminium cations.
Sorghum is believed to have the same tolerance mechanism. The rst gene for aluminium tolerance has been
identied in wheat. It was shown that sorghums aluminium tolerance is controlled by a single gene, as for
wheat.[99] This is not the case in all plants.

Biodegradation

Quantum clock
List of countries by aluminium production

11 References
[1] Aluminium monoxide
[2] Aluminium iodide
[3] Lide, D. R. (2000). Magnetic susceptibility of the elements and inorganic compounds. CRC Handbook of
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[4] Aluminum. Los Alamos National Laboratory. Retrieved 3 March 2013.
[5] 13 Aluminium. Elements.vanderkrogt.net. Retrieved
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[6] Shakhashiri, B. Z. (17 March 2008). Chemical of the
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[7] Frank, W. B. (2009).
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[8] Polmear, I. J. (1995). Light Alloys: Metallurgy of the Light
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Hill. ISBN 0-07-016893-8.
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[12] Roy E. Beal (1 January 1999). Engine Coolant Testing :

Fourth Volume. ASTM International. p. 90. ISBN 9780-8031-2610-7.
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[14] Reaction of Aluminum with Water to Produce Hydrogen. U.S. Department of Energy. 1 January 2008.

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12

EXTERNAL LINKS

[91] Belmonte Pereira, Luciane; Aimed Tabaldi, Luciane;

Fabbrin Gonalves, Jamile; Jucoski, Gladis Oliveira;
Pauletto, Mareni Maria; Nardin Weis, Simone; Texeira Nicoloso, Fernando; Brother, Denise; Batista
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ON THE KEROSENE FUNGUS CLADOSPORIUM
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12 External links
Aluminium at The Periodic Table of Videos (University of Nottingham)

15
CDC - NIOSH Pocket Guide to Chemical Hazards
- Aluminum
Electrolytic production
World production of primary aluminium, by country
Price history of aluminum, according to the IMF
History of Aluminium from the website of the International Aluminium Institute
Emedicine Aluminium
The short lm ALUMINUM (1941) is available for
free download at the Internet Archive

16

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TEXT AND IMAGE SOURCES, CONTRIBUTORS, AND LICENSES

Text and image sources, contributors, and licenses

Text

Aluminium Source: http://en.wikipedia.org/wiki/Aluminium?oldid=646580406 Contributors: AxelBoldt, Marj Tiefert, Sodium, CYD,

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Reddi, Stone, Stismail, David Latapie, Denni, Dysprosia, Vancouverguy, Grendelkhan, Vremya, Wernher, Topbanana, Bjarki S, Pakaran,
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File:41_ALU_Recycling_Code.svg Source: http://upload.wikimedia.org/wikipedia/commons/b/bb/41_ALU_Recycling_Code.svg License: CC-BY-SA-3.0 Contributors: Created in Adobe Illustrator CS3 based upon 'File:Recycling-Code-41.svg' by User:Moebius1. Original artist: Karl A Randall / User:k4rlR
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TEXT AND IMAGE SOURCES, CONTRIBUTORS, AND LICENSES

File:Aluminium_bar_surface_etched.jpg Source: http://upload.wikimedia.org/wikipedia/commons/e/e1/Aluminium_bar_surface_

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