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(b) [M2 L2 T1 ]
(d) [ML2 T1 ]
(b) hr = constant
h
(d) 2 = constant
r
is
(a) A+B
(b) (A 2 + B2 +
1/ 2
3 AB)
1/ 2
AB
(c) A 2 + B2 +
3
2
2
1/ 2
(d) (A + B + AB)
F
3
F
(d)
9
(b)
(a)
4
9
9
(d)
8
(b)
from A and B
2
2
(b) Wave C leads in phase by from A and B lags
behind by
by
2
(d) Wave C lags behind in phase by from A and B
leads by
leads by
(b) 70 J
(d) 150 J
(a) E
(b) B
(c) E B
(d) B E
(b) A/2
(d) A/
(a) X L = 0
(b) X L = XC
(c) XC = 0
(d) X
2
L
+ X C2 = 1
(b) 1
(c) A
(d) A
4 0 3
d
2 0 5
(c)
d
(a) XOR
(c) AND
3 0 5
d
5
(d) 0
d
(a)
(b)
(c) Q = R.
t
(a) Q =
10
1.4A
25
2
1.4A
20
(b) 40 m/s 2
(d) 640 m/s 2
R
1
(d) Q =
R t
(b) Q =
(a)
(b)
(c)
(d)
(b) OR
(d) NAND
of
electromagnetic
waves,
the
(a)
(b)
(c)
(d)
(b) 50 W, 20 W
(d) 200 W, 150 W
(b) 4 rad/s
(d) 21 rad/s
3
A
4
(b) 4.5 cm
(c) 5 cm
(d) 7 cm
(a) 2 p tan
(c) 2 p cos
1
A
4
4
(d)
A
3
(b)
(b) 62.5 cm
(d) 12.5 cm
Ee
C
=
EPh 2 v
P
2c
(d) e =
PPh
v
(b)
A
(a) 0
(b) 1
(c) 1
(d) 1
B
1
0
0
1
earth
(d) the length of the suspension
C
0
0
1
0
(a) v = Hr
H
(c) v = 2
r
(d) v = Hr 2
represents an area A = 05
. m2
situated in a uniform magnetic field
B = 20
. Wb /m 2 and making an angle of 60
with respect to magnetic field. The value of
magnetic flux through the area will be
38. Figure
60
(a) 0.5 Wb
3
(c) Wb
2
(b) 3 Wb
(d) 2.0 Wb
b
a
(a) ab
(c) cd
(a)
(b) bc
(d) be
10 V
+5 V
R
(b)
12 V
(a) B
(c)
(b) B
5 V
r
r
(d)
(c) B
(d) B
r
+5 V
+10 V
m
A
3 2
ml
2
(c) 2 ml 2
(a)
(a) parabola
(c) straight line
3 2
ml
4
5
(d) ml 2
4
01
. . If it is connected to a resistance of 3.9 ,
then the voltage across the cell will be (in
volts)
4
(b) circle
(d) ellipse
(b)
v
2
v
(c)
3
cos r
cos i
sin i
(d) v = C
sin r
(b) v = C
(a)
sin i
cos r
sin r
(c) v = C
sin i
(a) v = C
(b) blue
(d) red
(a) 2 V
(c) 195
. V
(b) 0.5 V
(d) 2.5 V
(b) 2R
(d) 5R
(b) F
(d) 2 F
Chemistry
CH 3 OH
HBr
1. CH 3 C CH CH 3
A (Predominant)
CH 3
Identify A.
(a)
(b)
(c)
(d)
(b) N
(d) All have same value
(a) I = II = III = IV
(c) II < III < I < IV
(b) HCHO
(d) (CH3 )3 C CHO
sodalime
(a) 2
(c) 5
(b) 4
(d) 6
copper corrodes to
(a) 1.20
(c) 3.55
4. C4H 6O4 A C3 H 6 O2 B C
(a)
(b)
(c)
(d)
(b) 96 amu
(d) 30 amu
III. CuSO4
IV. CuCO3
(a)
(b)
(c)
(d)
I and III
II and IV
I and IV
I and II
11. Mischmetal is
(a)
(b)
(c)
(d)
(a) 0
(c) + 2
(b) + 1
(d) + 3
NaBH 4
BCl 3 + NH4Cl ?
C 6 H 5 Cl
(a) B 3N3H6
(c) NaBCl 4
(b) B 2H6
(d) BN
(a) 2
(c) 6
(a) 0.76 cm
(c) 7.4 cm
(b) 4
(d) 8
(b) 0.70 cm
(d) 76 cm
I.
t = 2 min
t=0
II.
t = x min
t=0
(a) 2 min
(c) 6 min
(b) 4 min
(d) 8 min
f
f
(a) 1.8 10
(c) 1.8 10
H = 123.77 kJ mol 1
Substance
N2
H2
NH 3
P/ R
3.5
3.5
(b) 1.8 10
10
(d) 5.59 10
(b) 1.37
(d) 8.01
Column I
Column II
A.
Calomel
I.
B.
Glass
II.
Redox
C.
Hydrogen
III.
Membrane
D.
Quinhydrone
IV.
Gas
(a)
(b)
(c)
(d)
(a)
(b)
(c)
(d)
A
I
I
III
II
B
II
III
II
IV
C
III
IV
IV
III
Reference
D
IV
II
I
I
NaOH + I 2
ppt + B C CH 3COOH.
CO 2
(a) 44.8 L
(c) 11.2 L
yellow
(b) 22.4 L
(d) 5.6 L
Hence, A is
O
O
O
O
O
O
CH2CH3
O
I 2 / NaOH
I. CH 3 C CH 3
, H +
(a)
(b)
(c)
(d)
hv
H + Br2 X Y
D 2O
Br
D
(c) Br D
(a)
D
(d)
Cr2 O 27 / H +
II. CH 3 C CH 3
O
Ag(NH 3 ) +
2
III. CH 3 C CH 3
Which method are most effective?
(a) I, III
(c) I, II
(b)
Br
31. Relative
stabilities of the
carbocation will be in order
II. CH 3CHOHCHOHCH 3
III. (CH 3)2 COHCOH (CH 3)2
(b) II > I > III
(d) I > III = II
CH2
CH3O
I
I. HOCH2CH2OH,
III
(a) IV < III < II < I
(c) II < IV < III < I
CH2
II
CH2
CH3
following
CH3CH2
IV
(b) IV < II < III < I
(d) I < II < III < IV
570 K
(b) 11.5%
(c) 4.01%
p-bromoaniline
p-bromofluorobenzene
1, 3, 5-tri bromobenzene
2, 4, 6-tribromofluorobenzene
(b) Aluminium
(d) Sulphur
Krolls process
van Arkel process
Ellingham process
Goldschmidts aluminothermite process
(b) NaH
(d) HCOONa
precipitate of
NaOH
(a) (RCOO)2 Ca
(c) Both (a) and (b)
(b) (RCOO)2 Mg
(c) None of these
Compound
HO
( B)
(excess)
(a)
(b)
(c)
(d)
Sn(OH)2 , Na 2SnO 3
Sn(OH)2 , Na 2SnO 2
Sn(OH)2 , Na 2 [Sn(OH)6 ]
Sn(OH)2 , no effect
(b) basic
(d) cannot predict
OH
(b)
O (RCOO)2 Mg Coumarin
(d) 1.19%
MnO
(a) CH3CHO
(c) HCHO
Uracil
Thymine
Guanine
Adenine
(b) x cm 1
(a)
(d) 16 x cm 1
(b) 2 : 1
(c) 2 : 3
(d) 3 : 2
10
(b) 1.6
(d) 5.0
0.3010
log p
(b) 0.6
(d) 0.2
(b) BF3
(d) Al(CH3 )3
45
A
(a) 0.8
(c) 0.4
log x
m
sol.
is
x
49. Graph between log and log p is a
m
0.2 atm is
Biology
1. Pineapple (annanas) fruit develops from
tomato
fruits
can
be
produced by
(a) removing androecium of flowers before pollen grains
are released
(b) treating the plants with low concentrations of
gibberellic acid and auxins
(c) raising the plants from vernalized seeds
(d) treating the plants with phenylmercuric acetate
correct?
(a) Neurons regulate endocrine activity, but not vice versa
(b) Endocrine glands regulate neural activity and
nervous system regulates endocrine glands
(c) Neither hormones control neural activity nor the
neurons control endocrine activity
(d) Endocrine glands regulate neural activity, but not
vice versa
(b) dN / rN = dt
(d) dN / dt = rN
(b) cytochrome
(d) an iron-sulphur protein
11. Which
(a) Erythromycin
(b) Neomycin
(c) Streptomycin
(d) Tetracycline
11
(b) Plasmodium
(d) mycelium
(b) Axile
(d) Marginal
(b) styles
(d) hairs
(b) Four
(d) Two
(b) holoenzyme
(d) isoenzyme
12
of
polygenic inheritance?
(a) Flower colour in Mirabilis jalapa
(b) Production of male honey bee
(c) Pod shape in garden pea
(d) Skin colour in humans
neurotransmitter ?
(b) Epinephrine
(d) Cortisone
is
(a) Acetylcholine
(c) Nor epinephrine
segmentation
characteristic of
26. Metameric
(b) Ancestry
(d) Ontogeny
(a) salmon
(c) salamander
known as
(a) Phylogeny
(c) Paleontology
(b) cereals
(d) oilseed crops
(a) bacteria
(c) viruses
the
metabolism is
(a) cortisol
(b) corticosterone
(c) 11-deoxycorticosterone
(d) cortisone
means that
(a) one strand turns anti-clockwise
(b) the phosphate groups of two DNA strands, at their
ends, share the same position
(c) the phosphate groups at the start of two DNA strands
are in opposite position (pole)
(d) one strand turns clockwise
(b) steroids
(d) glycoproteins
(b) lipase
(d) invertase
cause
(a) Oestrogens
(b) FSH
(c) FSH-RH
(d) Progesterone
hormones is the
menstruation?
(a) coleorhiza
(c) prophyll
(b) 0.34 nm
(d) 2 nm
(a) hippurin
(c) histamine
13
of
Answers
Physics
1.
11.
21.
31.
41.
(c)
(c)
(b)
(c)
(b)
(d)
(c)
(b)
(c)
(c)
3.
13.
23.
33.
43.
(a)
(b)
(c)
(a)
(d)
4.
14.
24.
34.
44.
(d)
(b)
(d)
(b)
(c)
5.
15.
25.
35.
45.
(b)
(d)
(b)
(c)
(a)
6.
16.
26.
36.
46.
(a)
(b)
(c)
(d)
(c)
7.
17.
27.
37.
47.
(b)
(b)
(a)
(a)
(c)
8.
18.
28.
38.
48.
(c)
(d)
(d)
(a)
(d)
9.
19.
29.
39.
49.
(c)
(a)
(b)
(b)
(b)
10.
20.
30.
40.
50.
(d)
(a)
(c)
(d)
(c)
2.
12.
22.
32.
42.
(c)
(b)
(b)
(c)
(b)
3.
13.
23.
33.
43.
(b)
(a)
(a)
(a)
(b)
4.
14.
24.
34.
44.
(d)
(d)
(d)
(d)
(c)
5.
15.
25.
35.
45.
(c)
(c)
(c)
(c)
(d)
6.
16.
26.
36.
46.
(b)
(a)
(b)
(d)
(a)
7.
17.
27.
37.
47.
(c)
(b)
(a)
(a)
(a)
8.
18.
28.
38.
48.
(c)
(b)
(v)
(b)
(b)
9.
19.
29.
39.
49.
(a)
(c)
(a)
(c)
(a)
10.
20.
30.
40.
50.
(d)
(d)
(c)
(d)
(a)
2.
12.
22.
32.
42.
(b)
(c)
(a)
(a)
(d)
3.
13.
23.
33.
43.
(b)
(b)
(a)
(c)
(a)
4.
14.
24.
34.
44.
(a)
(d)
(c)
(d)
(c)
5.
15.
25.
35.
45.
(d)
(b)
(a)
(c)
(a)
6.
16.
26.
36.
46.
(c)
(d)
(c)
(c)
(b)
7.
17.
27.
37.
47.
(d)
(b)
(a)
(c)
(d)
8.
18.
28.
38.
48.
(d)
(a)
(a)
(d)
(d)
9.
19.
29.
39.
49.
(d)
(a)
(a)
(d)
(b)
10.
20.
30.
40.
50.
(c)
(b)
(d)
(b)
(b)
2.
12.
22.
32.
42.
Chemistry
1.
11.
21.
31.
41.
(a)
(c)
(a)
(b)
(b)
Biology
1.
11.
21.
31.
41.
(c)
(d)
(a)
(d)
(d)
15
Gm, m2
r2
Fr 2
[MLT 2 ][L2 ]
G=
=
m1m2
[M2 ]
2.
= [M1 L3 T 2 ]
Given, A B = 3 A . B
AB sin = 3 AB cos
A+ =i + e
We have,
i = A+
or
6 = ( i A)
Hence,
A+B =
A2 + B 2 + 2 AB cos
A2 + B 2 + 2 AB cos 60
1
A + B + 2 AB
2
2
= ( A2 + B 2 + AB)1/ 2
=
d water 8
(i A) = ( i )A
h. r = constant
Hence, B leads A by .
2
7. We have, Q = U + W
Here, Q = 110 J , U = 40 J
W = 70 J
i = A
I1 42 = 14
. 30
30
14
.
= 1 A.
42
2 cos
We have, h =
rg
...(ii)
tan = 3 or = 60
5.
and
I=
V
R
V
= ne A vd
R
or
V = ne A vd . R
= neA vd
V
= E = nelvd
l
E vd
16
E0 sin (t )
R 2 + ( XL XC )2
or
Current, I =
=
R R
So, charge Q = I . t =
17. We have, 2 = u 2 + 2 as
20
(80 )2 = 0 + 2 (a) 4
0.5v 2
+ 0.5 10
4
v = 16 m/ s
v 16
= =
= 4 rad/s
r
4
t =
R
R
mv 2
+ mg
r
37
. 10 =
XL XC = 0
XL = XC
16. We have, e =
g p = 8 10 = 80 m/s 2
or
is
= P 2 + P 2 + 2 P .P cos ( 2 )
= P 2 + 2( cos ) = P 2 (2 sin 2 )
= 2P sin
Ph = e
PPh = Pe
h
= mv
Ph
or
33. We have, v r
v = Hr
where, H is Hubble's" constant.
magnetic field at
distance r is
0 2I 0I
=
4 r 2 r
1
B
r
So, graph between B and r should be a
parabola as given in option (c).
I
36. Time period is given by, T = 2
MH
B=
37. We have, B = H
B
H
So, the permeability is defined as the ratio of
magnetic induction to the magnetising field.
38. As = B . A
ml 2
+ ml 2
4
5
= ml 2
4
2c
v
= 2 0.5 cos 60
1
= 2 0.5 , = 0.5 Wb
2
41. Given Rg = 50 ,
Ig = 25 4 10 4 A = 10 2 A
Range of
V = 25 volts
V
25
Resistance, R =
Rg = 2 50
10
Ig
= 2450
Thus, a resistance of 2450 is connected is
series to convert it into a voltmeter.
v + vs
42. We have, =
v vs
v + vs
or
2f =
f
v vs
or
or
2(v v s ) = v + v s
2v 2v s = v + v s
v = 3v s or v s =
v
3
R.D
1
= R . D 1
=
v sin r
sin r
v =c .
sin i
hence,
hence,
l
= 0 + m + ml 2
2
17
= 1000 80 cal
Heat produced in time t is, H = VIt
18
1
1
and
R.P v
(R . P )2 = (R . P ) 1
80kV
20kV
= 2(R . P )1
Chemistry
1.
CH 3 OH
H+
CH 3 C CH CH 3
CH 3
CH 3 O H 2
H2O
CH 3 C C H CH 3
CH 3
CH 3
1,2 methyl
CH 3 C C H CH 3
shift
CH 3
2 carbocation
CH 3
Br
CH 3 C C H CH 3
CH 3
3 carbocation
Br CH 3
CH 3 C C H CH 3
CH 3
2.
C y
4. C 4H 6O 4
C 3H 6O 2
A
B
From above equation, it is clear that CO 2 is
lost due to heating. Thus, A is a dibasic acid
with two COOH groups on same carbon
atom (gem position). Thus, A is
COOH
CH 3COH
CH 3CH 2COOH
'A'
'B'
COOH
propanoic acid
methyl malonic acid
Soda lime
CH 3CH 3
'C'
ethane
1 erg =
(n-1)
(n)
6. MS 2 2 D
100 40.06
or
or
or
R
mol K
8.314
1 kcal =
R
mol K
0.002
Cu 2 (OH)2 CO 3
M 160 64
M~
96
s
u
2
7. Formal charge, F = v
Fe 2+ + e Fe +
Thus, oxidation state of iron = + 1
C : 2
6 unshared electrons
unshared electrons
v
s
u
F
1
2
0
0
5
8
0
1
4
6
2
1
1 1
= 8.314 J mol K
2Cu 2 + H 2O + CO 2 + O 2
M + 64 160
H N
Cu 2 (OH)2 SO 4
or
10. 2Cu + H 2O + SO 3 + O 2
M + 64 64
100
40.06
=
M + 64
64
or
R
mol K
8.314 10 7
1J=
19
1 L atm =
R
mol K
0.0821
Fe+ = Ar 4s 3d7
Three unpaired electrons + 1oxidation state is
conirmed by magnetic moment of iron
= 3 (3 + 2 )
= 15 BM. and also by diamagnetic character
of NO (which is only possible when it has no
unpaired electron).
140 C
NaBH4
B3N 3H 6
borazine or
inorganic benzene
20
K =
+
4
2
2
Thus, greater the value of pK a of HA, greater
the pH.
Now
K =
K
=
K
NH+4
+ OH
Also,
or
[NH 4OH]
[NH+4 ] [H 2O]
= K w = 1 10 14
K = K 1 10 14
= 1.8 10 9 10 14 = 1.8 10 5
= 0.0072 76 cm of Hg
[OH ]
[NH 4OH]
[NH+4 ]
pK b (A , B , C ) | A < B < C
4
5
6
+ H 2O
Again,
NH 3 + H 2O NH 4OH
pH = 7 +
[NH+4 ] [H 2O]
= 1.8 10 9
[NH 4OH] [H+ ]
[NH+4 ]
0 .01
= 474
.
0 .01
j NH
[CH 3COO]
[CH 3COOH]
= 474
. + log
16. NH 4OH + H+
pH = pK a + log
1
( 474
. + 2 ) = 3.37
2
p = h 1 cm of water column
h 1 = 0.0072 76 13.6 cm
h = 7.4 cm
S =
T
66.9 + 41.8
=
300
= 0.08367 kJ K 1 mol 1
G330
= H TS
= 6 8.314 10 3 kJ
123.77 = H1 (300 K)
6 8.314 10 3 700
or
General Name
(A)
(B)
(C)
Calomel
Glass
Hydrogen
Reference
Memberane
Gas
(D)
Quinhydrone
3+
24. 2H +2e
+3e
Redox
2+
0.0591
[Zn ]
log
2
[Cu 2 + ]
= 1.1
Al
0.0591
[Zn 2 + ]
log
2
[Cu 2 + ]
H 2
hv
NH3
NH2
ZnCl2
Aniline
(Primany amine)
Phenol
compound A is CH 3 C CH 2 C OC 2H 5 .
CH 3I +
yellow ppt
CH2CH3
OH
(III)
O
O
NaOC CH 2 C ONa
Al
w(H 2 ) E(H 2 ) 1
=
=
w(Al) E (Al) 9
H + Br2
28.
(II)
26.
(I)
O
O
NaOH/I 2
CH 3 C CH 2 C OC 2H 5
[Zn 2 + ]
>1
[Cu 2 + ]
1
1
w(H 2 ) = 4.5 = 0.5 g = mol H 2
9
4
22.4
=
= 5.6 L H 2 at STP
4
25.
>
>
CH 2OH CH 3CHOH (CH 3 )2 COH
H1 (300 K) = 88.85 kJ
21
(i) Mg /ether
(ii) 1. D O
2
Br
H +
O
O
O
CH 3 C OH HOC CH 2 C OH
C
CH 3 C CH 3 + 3I2 + 4NaOH
O
22
+
CH 3 C ONa + H CH 3 C OH
Na +
K2 Cr2 O7 + H2 SO 4
CH 3 C CH 3
soap
in hard water
36.
O
O
CH 3 C H + HC OH
Structure of compound
(a)
Name of
compound
Ascorbic acid
CH (OH) CH2OH
HO
OH
(b)
Coumarin
37.
S.No.
CH3COOH
(i)
Adenine
DNA, RNA
Guanine
DNA, RNA
(CH3COO)2Mn +
(iii)
Cytosine
DNA, RNA
(HCOO)2Mn
(iv)
Thymine
DNA
(v)
Uracil
RNA
MnO
HCOOH
Heterocycli
Abbreviatio Occurrenc
c amine
n
e
base
(ii)
33.
CH3CHO
34.
NH2
= (1.6 10 19 C) (1.41 10 10 m)
NH2
Br2 water
Br
Br
NaNO2 / HCl
0C
= 2.60 10 30 Cm
Br
N2Cl
Br
Br
Br
(i) BF
4
(ii)
= 2.26 10 29 Cm
observed value
100
theoretical value
2.60 10 30
100
2.26 10 29
Br
Br
= 11.5%
45.
2
+4
H2O2 + MnO2
+2e
B2O 3 + 2Al 2B + Al 2O 3
j Na + Cl
H O j H + OH
2
H + + e H
H + H H 2
at anode
Cl Cl + e 1
H 2O 2 : MnO 2 = 3 : 2
KCl AsNO 3
=
M1V1
M2V2
1 20
M1 =
25
= 0.8 M
i = (1 + x ) = 1 + 1 = 2
Tf = molality K f i
= 0.8 2 2 = 3.2
Cl + Cl Cl 2
Na 2SnO 2
sodium stannite
+ 2H 2O
Thus,
46.
at cathode
Sn(OH)2 + 2NaOH
Mn+7O4 + 2H2O4
3e
NaCl
23
1
1
1 (He + , Z = 2) = RH (2) 2 2 2
n 1 n 2
1
1
2 (Be 3 + ,Z = 4) = RH = (4)2 2 2
n2
n1
2 (4)2 16
=
=
=4
1 (2 )2
4
2 = 41
2 = 4 x cm 1
acid
[Ag + ] < [I ]
x
1
49. log = log k + log p
m
x
= 0.4
m
24
(B) + (C ) + z(D ) (E ) a
H = ( 635.1) + ( 65.2) + 2 ( 393.5)
( 1299.58) ( 127.9) kJ mol 1
= 59.82 kJ mol 1
Biology
1. The fruit of Ananas comosus (pineapple or
A 1 A 2
P700
25
A 3
P430
14. In
26
27
30. Polygenic
inheritance
involves
the
determination of a particular phenotypic
characteristic by many genes, called
polygenes (i.e., the group of genes
influencing a quantitative characteristic), each
having a small effect individually.
The characteristics controlled in this way
show continuous variation and are called
polygenic characters, e.g., height and stun
colour in humans.
The polygenic inheritance is called
multifactorial inheritance or quantitative
inheritance. The pink flower colour in Mirabilis
jalapais an example of incomplete dominance
white production of male honey bee is an
example of parthenogenesis.
28
Parents RRYY
yellow, round
green, wrinkled
Gamete
formation
RY
RrYy
F1 yellow, round (in both cases)
RrYy RrYy
RY
RY
Ry
1/16 RRYY
2/16 RRYy
2/16 RrYY
4/16 Rryy
1/16 RRyy
2/16 Rryy
1/16 rryy
2/16 rrYy
1/16 rryy
F2 phenotypic ratio
9/16 yellow,round
ry
Fertilisation
F1
F2 genotypic ratio
rY
ry
RRYY
RRYy
RrYY
RrYy
yellow, round
yellow, round
yellow, round
yellow, round
RRYy
RRyy
RrYy
Rryy
rY
ry
RrYY
RrYy
rrYY
rrYy
yellow, round
yellow, round
green, round
green, round
Rryy
rrYy
rryy
RrYy
yellow, round
F2 generation
XCX
XY
X
Fertilisation
XC
Gametes
29
XCX
XC Y
XX
(Normal
(Carrier
daughter) daughter)
(Colour
blind son)
(Colour blind
woman)
XY
XCXC
XC
XC
XCX
XY Progenies
(Normal
son)
Fertilisation
XCY
(Colour
(Carrier
daughter) blind son)
Gametes
XCX
XCY Progenies
(Carrier
(Colour
daughter) blind son)
40. The
41. ClassOligochaeta
includes
terrestrial
earthworms and some other species that live
in fresh water. Aquatic oligochaetes excrete
ammonia, while terrestrial oligochaetes
excrete urea but Lumbricus produces both
ammonia and urea.
in
monocots
and
H 2CO 3 H + + HCO 3
30