Beruflich Dokumente
Kultur Dokumente
Geomorphology
journal homepage: www.elsevier.com/locate/geomorph
a r t i c l e
i n f o
Article history:
Received 17 January 2014
Received in revised form 15 October 2014
Accepted 23 October 2014
Available online 18 December 2014
Keywords:
Weathering geochronology
40
Ar/39Ar
(UTh)/He
Landscape evolution
Paran
a b s t r a c t
Regional correlation of dated weathered land surfaces provides the necessary constraints to test long-term continental landscape evolution models, but major challenges remain in properly dating these surfaces. The geomorphological province of Second Paran Plateau, Paran State, Brazil, is a high elevation (ca. 800 m) land surface
characterized by widely distributed deep saprolites and scattered lateritic proles (e.g., Vila Velha and Serra das
Almas). Prolonged exposure to weathering and erosion has promoted the pseudo-karstic and ruiniform features
that are characteristic of this landscape. In this study, 40Ar/39Ar laser incremental heating geochronology on 22
grains of supergene Mn oxyhydroxides from lateritic proles at Vila Velha yielded results ranging from
17.2 0.7 to 9.1 0.7 Ma. (UTh)/He geochronology on 28 goethite grains from the same prole yielded
results ranging from 36.4 3.6 to 1.0 0.1 Ma, with an age cluster lying within the 17.2 0.7 to 7.9 0.8 Ma
interval. (UTh)/He geochronology on 17 goethite grains from the Serra das Almas lateritic prole, located
20 km from Vila Velha, yield results ranging from 35.1 3.5 to 14.1 1.4 Ma. The combined results for the two
sites reveal a common weathering history that started ca. 35 Ma, suggesting that the Second Paran Plateau results
from regional uvial incision and denudation before ~35 Ma, followed by a decline in denudation rates and proportionally more intense weathering. Consistent with the laterite prole central ages, weathering was particularly
intense during the Miocene (178 Ma). Denudation intensied after the Pliocene.
2014 Elsevier B.V. All rights reserved.
1. Introduction
Long-term landscape evolution in stable cratonic regions often produces regionally extensive erosion surfaces. These surfaces become
deeply weathered during tectonically quiescent periods when conducive climates prevail. Dating and correlating these land surfaces at
local and regional scales allow major periods of incision and denudation
to be identied and cratonic landscape chronologies to be pieced
together (Vasconcelos and Conroy, 2003; Beauvais and Chardon, 2013).
These periods of continental erosion can be independently compared
to the rate of supply of sediments into adjacent basins.
A topographic prole across the state of Paran, Brazil, reveals a
regional morphology typical of rifted continental margins, where a
http://dx.doi.org/10.1016/j.geomorph.2014.10.041
0169-555X/ 2014 Elsevier B.V. All rights reserved.
narrow, low-elevation coastal plain is separated from the elevated continental interior by a steep, high-relief scarp. Five physiographic provinces have been locally recognized: the coastal plain, the Serra do Mar
mountain range, and the First, Second and Third Paran plateaus
(Fig. 1a) (Maack, 1947). The relatively at interior land surfaces in the
hinterland show strong lithological control: Upper Cretaceous sediments and basalts underlie the Third Paran Plateau; Paleozoic sediments provide the substrate for the Second Paran Plateau; and the
First Paran Plateau displays outcrops of unconsolidated and poorly
consolidated sediments from the Miocene Curitiba Sedimentary Basin,
and Proterozoic igneous and metamorphic rocks (Fig. 1a).
Apatite ssion-track (AFT) (Gallagher et al., 1994, 1995) and apatite
(UTh)/He (AHe) thermochronology (Cogn et al., 2011) of the southeastern Brazilian Atlantic Margin reveal an overall trend of older AFT
and AHe ages in the interior and progressively younger ages towards
the coast. Thermochronological modelling has revealed a history of continuous denudation after a signicant pulse of post-rift uplift (Gallagher
et al., 1995; Cogn et al., 2011) and alkaline and peralkaline magmatism
(Thompson et al., 1998; Riccomini et al., 2005; Gomes et al., 2011;
Velzquez et al., 2011) between ~ 90 and 60 Ma. The regional cooling
53
(a)
r
ve
Santos
basin
Ri
Tibagi River
n
ra
Pa
Iva River
MS
Pi
PARA
GUAY
qu
iri
SP
Third Paran
Plateau (3PP)
Ri
ve
r
Second Paran
Plateau (2PP)
er
Riv
eira
Mountain Range
and Coastal Plain
2000
Rib
Vila Velha
Serra das Almas
1600
r
ve
Igua
u R
iver
First Paran
Plateau (1PP)
Santos
Basin
ARGENTINA
1200
Ri
a
gu
800
400
SC
Elevation (m)
0
200 (Km)
2PP
Elevation (m)
Vila Velha
Serra das Almas
1200
1000
v v v
v
v v v v
Mesozoic basalts
Mesozoic
sediments
x x- v v
- - -- - v
------- -- ------- - -- - -- - - -- -- -------- v
- - - - - - - - -- - v v
v v v - - -- - - - -- - -- - -- - - - - - - -- - - - ---------- v
600
200
1PP
r
Ma e
do Rang
rra
Se untain
o
M
v v
Paleozoic sediments
Proterozoic basement
+
+
+
+
+
++
++ +
++ +
+ ++
++
++
++ +
+ +
+ ++
++
++
+ ++
+ +
+ +
+
++
++
+ ++
+ ++
+
Miocene
sediments
Proterozoic
granites
(b)
Fig. 1. Location maps. (a) Digital elevation model and an EW topographic cross-section (SRTM 3 data: USGS, 2004) illustrate the three major geomorphological units recognized across
Paran state (First, Second and Third Paran plateaus), and their major lithological associations. (b) Simplied geological map (after Melo and Giannini, 2007) showing the distribution of
the basal units of the Paran sedimentary basin (Itarar Group and Furnas Formation) and the sites sampled (Vila Velha and Serra das Almas) for this study.
et al., 1994, 1995) and AHe thermochronology (Cogn et al., 2011) have
also suggested a possible Neogene cooling/denudation event along the
southern Brazilian margin. Thermochronological studies are useful in
54
(a)
a3
Vila Velha
(a1)
(a3)
cpl
goe
1 cm
10 cm
(b)
b1
250 cm
b3
(b1)
(b2)
(b3)
Colluvium
Ferricrete
b2
goe
Mottled zone
30 cm
5 cm
Sansdstone
Saprolite
Fig. 2. Sampling localities. Lateritic weathering proles were sampled at Vila Velha (a) and at Serra das Almas (b) sites. Vila Velha Park consists of unique landforms resulting from the
erosion of intensely ferruginized sandstone (a1). Samples of manganese and iron oxyhydroxides were sampled along fractures (a2) in sandstones at the base of the Boot landform
(a3) and on the top of the Vila Velha plateau. At Serra das Almas (elevation: ~1080 m, b), a lateritic prole developed on Furnas Formation rocks are exposed (b1) and iron oxyhydroxides
from the mottled zone and ferruginous duricrust were sampled for (UTh)/He analysis (b2). The laterite prole grades laterally to a colluvium horizon enriched in iron concretions (b3).
These were not sampled and dated in this study.
55
Table 1
Context of mineral samples collected from two weathering proles in Paran State, Brazil.
Run ID#
Sample
Latitude
Longitude
Elevation
(S, WGS84)
(W, WGS84)
(m)
Vila Velha
6586-01
6586-02
6595-01
6595-02
6597-01
6597-02
6598-01
6598-02
6599-01
6599-02
6600-01
6600-02
6601-01
6601-02
6602-01
PR 0933 bota
PR 0933 bota
PR 0933C-1
PR 0933C-1
PR 0933C-2
PR 0933C-2
PR 0933C-3
PR 0933C-3
PR 0933C-4
PR 0933C-4
PR 0933G fract1
PR 0933G fract1
PR 0933G fract3
PR 0933G fract3
PR 0933E-1
251507.86
251507.86
251508
251508
251508
251508
251508
251508
251508
251508
251509
251509
251509
251509
251508
495956.03
495956.03
495952
495952
495952
495952
495952
495952
495952
495952
495952
495952
495952
495952
495952
908
908
918
918
918
918
918
918
918
918
911
911
911
911
918
6602-02
PR 0933E-1
251508
495952
918
6603-01
6603-02
6610-01
6610-02
6622-01
6622-02
09MNK
09MNL
09MOP
09MOQ
09MPB
09MPC
09MPD
09MPE
09MPF
09MPG
09MRC
09MRD
09MSH
09MSJ
09MSK
09MSL
09MSM
09MSN
09MSO
09MSP
09MSQ
09MSR
09MSS
09MST
09MSU
09MSV
09MSW
09MSX
PR 0933E-3
PR 0933E-3
PR 0933G fract2
PR 0933G fract2
PR 0716C
PR 0716C
PR 0933I
PR 0933I
PR 0933D
PR 0933D
PR 0933G2
PR 0933G2
PR 0933G_fract_base
PR 0933G_fract_base
PR 0933G_fract_top
PR 0933G_fract_top
PR 0933G_B
PR 0933G_B
PR 0933G fract
PR 0933E-3
PR 0933E-3
PR 0933A
PR 0933A
PR 0933 bota
PR 0933 bota
PR 0933A
PR 0933B1
PR 0933B1
PR 0933B1A
PR 0933B1A
PR 0933 bota
PR 0933 bota
PR 0933H
PR 0933H
251508
251508
251509
251509
251510
251510
251509.21
251509.21
251454.68
251454.68
251509.13
251509.13
251509.13
251509.13
251509.13
251509.13
251509.13
251509.13
251509.13
251508.28
251508.28
251508.12
251508.12
251507.86
251507.86
251508.12
251507.20
251507.20
251507.20
251507.20
251507.86
251507.86
251507.95
251507.95
495952
495952
495952
495952
500009
500009
500002.92
500002.92
495924.90
495924.90
495952.13
495952.13
495952.13
495952.13
495952.13
495952.13
495952.13
495952.13
495952.13
495951.77
495951.77
495955.57
495955.57
495956.03
495956.03
495955.57
500002.44
500002.44
500002.44
500002.44
495956.03
495956.03
495954.96
495954.96
918
918
911
911
920
920
921
921
927
927
911
911
911
911
911
911
911
911
911
918
918
910
910
908
908
910
900
900
900
900
908
908
918
918
251622
251622
251622
251622
251622
251622
251622
251622
251622
251622
251622
251622
251622
251622
25.2727778
495038
495038
495038
495038
495038
495038
495038
495038
495038
495038
495038
495038
495038
495038
49.8439722
1082
1082
1082
1082
1082
1082
1082
1082
1082
1082
1082
1082
1082
1082
1082
Mineral dated
Depth
Weathering stage
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
cryptomelane
low-K cryptomelane with high porosity
and mixed phases with goethite
low-K cryptomelane with high porosity
and mixed phases with goethite
low-K cryptomelane
low-K cryptomelane
hollandite
hollandite
cryptomelane
cryptomelane
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
surface
fracture in saprolite
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
surface
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
saprock
saprock
top of the saprock
top of the saprock
top of the saprock
top of the saprock
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
fracture in saprolite
saprock
saprock
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
goethite
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
~1 m
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
ferricrete
56
Field investigations carried out for this study reveal that lateritic
weathering proles are only preserved on the high-elevation areas situated at the southern and eastern boundaries of the Second Paran
Plateau (Fig. 1b), at elevations exceeding 9001000 m. The more deeply
dissected areas at the northern and western boundaries of the Second
Paran Plateau host only soils, shallow saprolite, or detrital clay deposits
resting directly on relatively unweathered bedrock, suggesting that any
deeply weathered mantle that may have existed in this area has been
eroded. Therefore, we focused our geochronological efforts on sites
containing residual lateritic proles and most likely to contain the
oldest supergene mineral assemblages.
At Serra das Almas (~1080 m a.s.l., Fig. 2b), a lateritic prole formed
on Paran Group strata (Furnas Formation) is exposed in a road-metal
quarry. The prole consists of an in situ ferricrete at the surface, underlain by a 2 to 5 m-thick mottled zone that overlies a saprolite level of
unknown thickness (Fig. 2b1, b2). Laterally, this ferricrete grades into
a loosely cemented ferruginous colluvium, apparently the result of
local dismantling of the duricrust (Fig. 2b3). Within the ferricrete
and the mottled zone, iron oxyhydroxides containing crystalline
and visually pure goethite cements were sampled. Five different hand
specimens were collected and fteen distinct goethite/hematite grains
were dated from this site (Table 1).
Table 2
Summary of 40Ar/39Ar results from the Vila Velha weathering prole.
Run ID#
Sample
88#, 105#
Vila Velha
6586-01
6586-02
6595-01
6595-02
6597-01
6597-02
6598-01
6598-02
6599-01
6599-02
6602-01
6602-02
6603-01
6603-02
6600-01
6600-02
6610-01
6610-02
6601-01
6601-02
6622-01
6622-02
PR0933bota
PR0933bota
PR0933C-1
PR0933C-1
PR0933C-2
PR0933C-2
PR0933C-3
PR0933C-3
PR0933C-4
PR0933C-4
PR0933E-1
PR0933E-1
PR0933E-3
PR0933E-3
PR0933G fract1
PR0933G fract1
PR0933G fract2
PR0933G fract2
PR0933G fract3
PR0933G fract3
PR0716C
PR0716C
Plateau
Error
Integrated
Error
Isochron
Error
Intercept
Error
Age
Age
Age
40
(Ma)
(Ma)
(Ma)
(Ma)
(Ma)
(Ma)
(Ma)
17.2
16.6
16.0
16.1
16.0
16.3
16.5
16.1
16.2
16.1
20.9*
16.1*
16.3
15.9
15.9
9.1
9.5
0.2
0.2
0.2
0.2
0.9
0.3
0.3
0.2
0.1
0.2
0.6
0.7
0.2
0.2
0.2
0.7
0.9
23.0
17.9
16.1
16.0
17.0
16.2
17.8
16.2
16.6
15.6
143.0
94.6
70.0
30.3
16.8
17.4
78.0
270.0
15.5
15.4
17.0
21.0
2.0
1.4
0.8
0.9
3.0
0.8
1.0
0.7
0.6
0.7
8.0
2.6
4.0
1.1
1.3
1.4
10.0
60.0
1.2
0.9
4.0
4.0
17.2
0.1
301.2
1.2
16.1
0.1
298.3
1.5
16.1
0.1
300.5
1.2
16.2
0.1
302.4
1.5
16.2
0.1
296.1
1.5
91.0
9.0
15000.0
800.0
21.1
0.2
303.0
2.0
16.4
0.1
302.0
1.8
10.4
0.5
300.9
1.9
16.1
0.1
294.7
1.3
8.0
0.4
306.3
1.8
* = forced plateau ages, as described in the text. See Appendix A2 for complete results.
Accept
yes
yes
yes
yes
yes
yes
yes
yes
yes
yes
no
no
no
yes
yes
yes
no
no
yes
yes
yes
yes
Ar/36Ar
(Ma)
57
Fig. 3. Petrographic and SEM details of dated and undated samples. A photomicrograph illustrates representative pure and crystalline colloform manganese oxyhydroxide samples dated
from the Vila Velha site (a). In rare cases, (b) manganese oxyhydroxides contain small mineral inclusions, particularly kaolinite and mica. This results in unreliable 40Ar/39Ar age results.
Pure goethite grains, as illustrated in the SEM image were the primary phases dated by (UTh)/He geochronology (c). In some cases, more than one generation of goethite could be identied in some Vila Velha samples, one pre-dating and one post-dating manganese oxyhydroxides and the different generations were sampled and dated separately (d). cpl =
cryptomelane; kln = kaolinite; phyl = phyllosilicate/ goe = goethite; qtz = quartz; 1st = rst generation; 2nd = second generation.
(a) 14
12
10
Ba (wt.%)
8
6
4
2
0
K (wt.%)
(b)
5
4
K/Ba
3
2
1
0
48
50
52
54
56
58
60
Mn (wt.%)
Fig. 4. Electron microprobe analyses (n = 80) show the range in K and Ba contents for manganese oxyhydroxides from the Vila Velha site. The consistent presence of Ba in the
oxyhydroxides indicates that the oxyhydroxides should be argon-retentive (Vasconcelos,
1999a).
58
Goethite grains from Vila Velha (n = 28) and Serra das Almas
(n = 17) were inserted into 1 mm Pt-capsules and analyzed at Caltech
(USA) following the analytical procedures described in Vasconcelos
et al. (2013). Samples analyzed in duplicate allow the reliability of the
results to be assessed. To account and correct for possible radiogenic
4
He loss (Shuster et al., 2005; Heim et al., 2006), we used the approach
proposed by Heim et al. (2006), in which between 0 and 20% 4He loss
is assumed. The measured ages are corrected by adding 10% to the raw
ages and adopting a 10% uncertainty in the nal result. The nal uncertainty is much greater than the analytical uncertainty, but it takes into
account the maximum He loss expected from goethite grains as determined from previous 4He/3He experiments (Shuster et al., 2005; Heim
et al., 2006).
3.3. (UTh)/He results for iron oxyhydroxides from Vila Velha and Serra das
Almas
At Vila Velha, Mn and Fe oxyhydroxide veins are particularly abundant along fracture planes (Fig. 2a2). Manganese oxyhydroxides recovered from these veins are composed of mostly hollandite-group
minerals displaying typical colloform textures (Fig. 3). Growth bands
show alternating layers of K- and Ba-rich hollandite, suggesting periodic
changes in the composition of the weathering solutions. Electron microprobe results show an average composition of 2.6 wt.% K, 5.3 wt.%
Ba, and 55.4 wt.% Mn (n = 80) for cryptomelane, and 0.1 wt.% K,
11.7 wt.% Ba, and 52.7 wt.% Mn (n = 15) for hollandite (Appendix
A1). As expected (Vasconcelos and Conroy, 2003), Ba contents in
cryptomelane are inversely proportional to K and Mn contents
(Fig. 4). The joint presence of Ba (up to 6 wt.%) and K (14 wt.%)
(Fig. 4) in cryptomelane suggests that samples dated in this study are
highly retentive of Ar (Vasconcelos, 1999a), which is conrmed by the
shape of the incremental heating spectra. Unfortunately, some
hollandite grains contained 1012 wt.% Ba and only 0.010.14 wt.% K
and proved unsuitable for 40Ar/39Ar geochronology because the small
59
0.01
17.2 0.2 Ma
MSWD = 1, P = 0.41, n = 14
0.0030
40
30
16.6 0.2 Ma
E F
36
0.0020
20
K
0.0010
10
Integrated Age = 23 2 Ma
(b) 6586-02
(a) 6586-01
(c) 6586
100
30
0.01
16.0 0.2 Ma
16.1 0.2 Ma
36
0.0020
20
DE F
10
(d) 6595-01
J K
0.0010
(f) 6595
(e) 6595-02
0
0.0040
Age = 16.1 0.1 Ma
36
Ar/ Ar Int. = 300.5 1.2
40
0.01
16.0 0.9 Ma
16.3 0.3 Ma
36
0.0020
20
E
D
FG
K
J
H I
G
Integrated Age = 16.2 0.8 Ma
EF
10
Integrated Age = 17 3 Ma
(g) 6597-01
0.0010
(i) 6597
(h) 6597-02
100
30
0.01
16.5 0.3 Ma
20
10
0.0030
16.1 0.2 Ma
0.0020
36
E
F
D G
40
0.0040
Ar/ Ar
K/Ca
%40Ar*
100
0.0030
40
30
Ar/ Ar
100
K/Ca
K L
F G
E
C
D
J K
0.0010
(j) 6598-01
(l) 6598
(k) 6598-02
0
0.0040
100
Age = 16.2 0.1 Ma
40
36
Ar/ Ar Int. = 296.1 1.5
100
30
0.01
EFGH
D
10
E H
FG
0.0010
(m) 6599-01
20
40
60
80
(o) 6599
(n) 6599-02
100 0
Cumulative %
L M
0
0
0.0020
16.1 0.2 Ma
39
0.0030
36
16.2 0.1 Ma
20
K/Ca
40
% 40 Ar*
100
% 40 Ar*
0.0030
40
100
Ar/ Ar
0
0.0040
40
K/Ca
% 40 Ar*
36
Ar/ Ar
100
K/Ca
0.0040
Ar/ Ar
% 40 Ar*
100
20
Ar Released
40
60
80
100
0.30
0.10
39
0.50
0
0.60
40
Ar/ Ar
Fig. 5. 40Ar/39Ar incremental-heating spectra for manganese oxyhydroxides grains analyzed in duplicate (ab, de, etc.) and 39Ar/40Ar vs. 36Ar/40Ar isotope correlation diagrams (inverse
isochrons) for each pair of grains (right column). Results reveal that all but one grain yield reliable geochronological results.
60
0.0040
Age = 16.4 0.1 Ma
Ar/ 36Ar Int. = 302.0 1.8
MSWD = 1.3, P = 0.17, n = 21
100
30
0.0030
0.01
40
16.3 0.2 Ma
10
F G
0.0010
(p) 6600-01
(q) 6600-02
(r) 6600
100
30
0.01
0.0030
15.9 0.2 Ma
40
15.9 0.2 Ma
K/Ca
36
0.0020
20
GH
10
EF
DE
(s) 6601-01
0.0010
(u) 6601
(t) 6601-02
0.0040
200
0.0030
0.01
0.0020
150
100
0.0010
Integrated Age = 70 4 Ma
50
40
100
Ar/ Ar
K/Ca
40Ar/ 36Ar
(v) 6603-01
H I
(y) 6603
(w) 6603-02
100
0
0.0040
100
200
K/Ca
% 40 Ar*
36
% 40Ar*
100
0.0030
0.01
9.1 0.7 Ma
150
0.0020
9.5 0.9 Ma
36
0
0.0040
40
% 40Ar*
100
Ar/ Ar
36
0.0020
20
Ar/ Ar
K/Ca
40
Ar/ Ar
% 40Ar*
100
100
Integrated Age = 17 4 Ma
50
0.0010
Integrated Age = 21 4 Ma
(z) 6622-01
F
(aa) 6622-02
20
40
60
80
100 0
(ab) 6622
0
20
40
60
80
100
0.10
39
39
Cumulative % Ar Released
0.30
40
0.50
0
0.60
Ar/ Ar
Fig. 5. (continued).
Fifteen grains extracted from seven distinct hand samples from the
ferricretes and mottled zones at Serra das Almas yield ages ranging
from 35.1 3.5 to 14.1 1.4 Ma (Table 3). Goethites include several
grains with ages in the ~ 3527 Ma range (Fig. 6c), but also include
grains yielding younger results that are compatible with the Vila Velha
site (Fig. 6c).
Most samples from Vila Velha are rich in U (N4.8 ppm) and reveal
Th/U below 0.3, consistent with goethite precipitation in open cavities
directly from weathering solutions (Vasconcelos et al., 2013). Only
one grain (09MPF, 36.4 3.6 Ma) yields a higher Th/U value (2.2),
suggesting partial replacement of detrital phases. Th/U values for the
Serra das Almas goethite grains (all N0.9) suggest that goethite
precipitated by partial dissolution and replacement of primary minerals in the hosting sediments (quartz, clays, etc.) (Vasconcelos et al.,
2013; Monteiro et al., 2014).
3.4. Consistency between 40Ar/39Ar and (UTh)/He geochronology
Overall, the geochronological results obtained by the two independent methods are compatible. Direct comparison between 40Ar/39Ar
and (UTh)/He geochronology is difcult because cryptomelane and
goethite may not be cogenetic. The precision of the two methods is
also intrinsically different. Incremental heating 40Ar/39Ar analysis
permits extracting several apparent ages from a single grain, and if the
1.6
Vila Velha (FeOx, n=28)
Vila Velha (MnOx, n=17)
Serra das Almas (FeOx, n=15)
0.2
1.2
0.8
0.1
0.4
(b) 12
Frequency (MnOx)
4. Discussion
(a)0.3
10
8
6
4
2
0
(c)
Frequency (FeOx)
apparent ages converge into a plateau age, the pooling of several independent results into a single plateau age will greatly improve the precision of the nal result. (UTh)/He dating, on the other hand, yields
a single age from a grain obtained from two independent analytical
methods (He measured by isotope dilution mass spectrometry, and U
and Th measured by ICP-MS), with two analytical errors propagated
into a single age.
61
6
5
3
2
1
0
0
12
16
20
24
28
32
36
40
Fig. 6. Probability density plot for all results. (a) This plot illustrates a good correspondence
between the 40Ar/39Ar manganese oxyhydroxides and (UTh)/He goethites ages for the
Miocene. The diagram also illustrates good correspondence between the oldest results
at both sites (Vila Velha and Serra das Almas). The overall tendency for old results at
Serra das Almas (a, c) and younger results at Vila Velha (a, b, c) may reect our sampling
strategy, as discussed in the text.
62
Table 3
Summary of (UTh)/He results from the Vila Velha and Serra das Almas weathering proles.
Run ID#
Raw Age
Corr Age
(Ma)
(Ma)
1.90
1.53
1.28
0.94
8.89
9.11
14.75
15.58
33.06
12.44
12.37
8.01
14.56
10.80
15.88
10.70
8.43
9.54
9.40
9.43
11.06
9.67
10.35
17.36
11.18
13.32
7.21
7.58
2.09
1.68
1.41
1.04
9.78
10.02
16.22
17.14
36.37
13.68
13.61
8.81
16.01
11.88
17.47
11.77
9.27
10.50
10.34
10.38
12.16
10.63
11.38
19.09
12.30
14.65
7.93
8.33
28.60
29.34
14.12
16.47
18.42
27.33
28.27
26.63
30.73
31.45
35.15
34.93
18.77
15.56
18.66
Vila Velha
09MNK
09MNL
09MOP
09MOQ
09MPB
09MPC
09MPD
09MPE
09MPF
09MPG
09MRC
09MRD
09MSH
09MSJ
09MSK
09MSL
09MSM
09MSN
09MSO
09MSP
09MSQ
09MSR
09MSS
09MST
09MSU
09MSV
09MSW
09MSX
Error 10%
Th
He
mass
Sm
(ppm)
(ppm)
(ppm)
(ppm)
(nmol/g)
(g)
(ppm)
0.21
0.17
0.14
0.10
0.98
1.00
1.62
1.71
3.64
1.37
1.36
0.88
1.60
1.19
1.75
1.18
0.93
1.05
1.03
1.04
1.22
1.06
1.14
1.91
1.23
1.46
0.79
0.83
54.28
58.55
5.43
6.95
13.82
13.60
14.34
7.95
4.84
31.79
82.71
25.53
13.45
11.73
13.89
16.84
13.98
17.59
15.88
23.89
15.64
22.53
16.96
9.49
16.38
13.68
32.69
29.25
0.19
0.21
0.09
0.07
0.05
0.07
0.11
0.08
0.09
0.13
0.55
0.09
0.07
0.05
0.07
0.07
0.15
0.06
0.07
0.15
0.09
0.08
0.06
0.07
0.08
0.11
0.11
0.10
0.52
0.60
1.20
0.93
0.62
0.44
0.41
0.67
10.64
0.80
4.40
0.15
0.19
0.72
0.95
0.06
0.26
0.39
0.15
0.25
0.04
0.09
0.55
2.43
0.35
0.36
0.38
0.56
0.04
0.05
0.05
0.03
0.03
0.03
0.04
0.03
0.18
0.05
0.22
0.02
0.02
0.03
0.04
0.02
0.05
0.03
0.02
0.05
0.03
0.02
0.03
0.05
0.03
0.04
0.02
0.02
0.5618
0.4872
0.0398
0.0368
0.6753
0.6786
1.1584
0.6876
1.3255
2.1638
5.6380
1.1135
1.0691
0.6989
1.2203
0.9808
0.6436
0.9175
0.8134
1.2287
0.9414
1.1857
0.9616
0.9506
1.0013
0.9977
1.2852
1.2105
50.12
43.95
54.16
84.50
93.36
76.01
53.80
78.21
41.56
38.15
10.60
123.85
77.75
98.37
73.83
71.18
38.10
81.62
72.77
38.25
64.37
99.70
79.61
86.13
65.57
53.04
101.75
126.24
15.56
20.51
6.46
6.20
0.91
1.39
4.01
2.28
10.50
9.08
38.81
2.49
2.19
1.28
3.46
2.36
1.84
2.07
2.96
5.29
3.03
4.79
3.21
1.77
2.34
2.32
5.34
2.71
0.01
0.01
0.22
0.13
0.05
0.03
0.03
0.08
2.20
0.03
0.05
0.01
0.01
0.06
0.07
0.00
0.02
0.02
0.01
0.01
0.00
0.00
0.03
0.26
0.02
0.03
0.01
0.02
2.86
2.93
1.41
1.65
1.84
2.73
2.83
2.66
3.07
3.15
3.51
3.49
1.88
1.56
1.87
25.26
24.83
21.11
20.21
18.51
23.57
18.58
26.30
17.47
14.32
11.12
10.46
37.95
43.96
32.68
0.09
0.09
0.07
0.07
0.07
0.08
0.07
0.09
0.06
0.06
0.05
0.08
0.13
0.15
0.11
41.41
42.19
19.85
21.24
28.92
63.81
28.52
45.38
25.81
25.54
24.61
13.00
52.60
78.11
34.97
0.38
0.41
0.21
0.21
0.23
0.41
0.28
0.34
0.27
0.27
0.25
0.18
0.47
0.52
0.35
4.9550
5.0486
1.7997
2.0528
2.3058
5.2183
3.5382
4.8721
3.5819
3.1648
2.9439
2.3386
4.6715
4.7948
3.7767
86.01
69.27
113.30
122.67
175.78
132.97
93.64
130.30
88.49
84.01
103.24
73.63
69.32
97.43
77.08
4.23
4.18
3.43
3.36
2.63
4.03
3.28
4.57
2.99
2.79
2.84
2.94
2.14
2.47
2.72
1.64
1.70
0.94
1.05
1.56
2.71
1.54
1.73
1.48
1.78
2.21
1.24
1.39
1.78
1.07
5. Conclusions
40
Th/U
Acknowledgments
The authors are grateful for the nancial support from CAPES (PhD
scholarship 4862-06-6), and logistic and nancial support from
PETROBRAS/CENPES for the 40Ar/39Ar analyses. We are also thankful
for the environmental license granted for research at Vila Velha Park
(IAP no. 183/09). We are also grateful to the geologist Mathieu Moriss
(Paradigm Softwares Technologies Inc.) for the support on DEM volume
calculation with the GOCAD software. The construction of the UQ-AGES
facility was partially funded by ARC Large Grant A39531815.
Appendix A. Supplementary data
Supplementary data associated with this article can be found in the
online version, at http://dx.doi.org/10.1016/j.geomorph.2014.10.041.
These data include Google maps of the most important areas described
in this article.
(b)
-24
(a)
63
NW
Ti
ba
gi
Ri
ve
r
Iva
-25
ive
r
Elevation
(m)
Elevation (m)
NW
SE
1200
1330
1140
SE
V3 = 13,985 km3
800
945
r
ive
755
uR
Igu
-26
565
400
375
-51
-50
0
-51.5
-51.3
-51.1
-50.9
-50.7
-50.5
-50.3
-50.1
-49.9
-49.7
Fig. 7. Digital elevation model of the Second Paran Plateau. (a) Illustration of the greater preservation of the initial Second Paran Plateau surface in its eastern part, and its deeper
denudation and river incision towards the west and north. (b) A NWSE topographic cross-section through the region illustrates the greater depths of river incision in the NW, and
the preservation of high-elevation plateaus, blanketed by weathering proles, towards the SE.
References
Ab'Saber, A.N., Bigarella, J.J., 1961. Consideraes sobre a geomorfognese da Serra do Mar
no Paran. Bol. Paranaen. Geogr. 4 (5), 94110 (in Portuguese).
Almeida, F.F.M., 1976. The system of continental rifts bordering the Santos basin, Brazil.
An. Acad. Bras. Cienc. 48, 1526.
Beauvais, A., Chardon, D., 2013. Modes, tempo and spatial variability of Cenozoic cratonic
denudation: the West African example. Geochem. Geophys. Geosyst. 14, 15901608.
Cogn, N., Gallagher, K., Cobbold, P.R., 2011. Post-rift reactivation of the onshore margin of
southeast Brazil: evidence from apatite (UTh)/He and ssion-track data. Earth Planet. Sci. Lett. 309, 11130.
Fleck, R.J., Sutter, J.F., Elliot, D.H., 1977. Interpretation of discordant 40Ar/39Ar age-spectra
of Mesozoic tholeiites from Antarctica. Geochim. Cosmochim. Acta 41, 132.
Gallagher, K., Hawkesworth, C.J., Mantovani, M.S.M., 1994. The denudation history of the
onshore continental-margin of SE Brazil inferred from apatite ssion-track data.
J. Geophys. Res. Solid Earth 99, 181118145.
Gallagher, K., Hawkesworth, C.J., Mantovani, M.S.M., 1995. Denudation, ssion track
analysis and the long-term evolution of passive margin topography; application to
the Southeast Brazilian margin. J. S. Am. Earth Sci. 8, 677.
Gomes, C.B., Ruberti, E., Comin-Chiaramonti, P., Azzone, R.G., 2011. Alkaline magmatism
in the Ponta Grossa Arch, SE Brazil: a review. J. S. Am. Earth Sci. 32, 15168.
Heim, J.A., Vasconcelos, P.M., Shuster, D.L., Farley, K.A., Broadbent, G., 2006. Dating
paleochannel iron ore by (UTh)/He analysis of supergene goethite, Hamersley province, Australia. Geology 34, 17176.
King, L.C., 1956. A geomorfologia do Brasil Oriental. Rev. Bras. Geogr. 18, 147265 (in
Portuguese).
Kuiper, K.F., Deino, A., Hilgen, F.J., Krijgsman, W., Renne, P.R., Wijbrans, J.R., 2008. Synchronizing rock clocks of Earth history. Science 320, 50504.
Lee, J.Y., Marti, K., Severinghaus, J.P., Kawamura, K., Yoo, H.S., Lee, J.B., Kim, J.S., 2006. A
redetermination of the isotopic abundances of atmospheric Ar. Geochim. Cosmochim.
Acta 70, 4504512.
Maack, R., 1947. Breves notcias sobre a geologia dos estados do Paran e Santa Catarina.
Arq. Inst. Biol. Pes. Technol. 2, 6154 (in Portuguese, with English abstract).
Melo, M.S., Coimbra, A.M., 1996. Ruiniform relief in sandstones: the example of Vila Velha,
Carboniferous of the Paran Basin, southern Brazil. Acta Geol. Hisp. 31, 240.
Melo, M.S., Giannini, P.C.F., 2007. Sandstone dissolution landforms in the Furnas Formation, Southern Brazil. Earth Surf. Process. Landf. 32, 2142164.
Melo, M.S., Coimbra, A.M., Sayeg, I.J., Giannini, P.C.F., Atncio, D., 1999. Fringed
cryptomelane/hollandite in the Vila Velha Sandstone telogenesis. Acta Microsc. 8
(A), 336.
Monteiro, H.S., Vasconcelos, P.M., Farley, K.A., Spier, C.A., Mello, C.L., 2014. (UTh)/He geochronology of goethite and the origin and evolution of cangas. Geochim. Cosmochim.
Acta 131, 26289.
Moreira, J.L.P., Madeira, C.V., Gil, J.A., Machado, M.A.P., 2007. Bacia de Santos. Bol. Geosci.
Petrobras 15, 53549 (in Portuguese).
Riccomini, C., Velazquez, V.F., Gomes, C.B., 2005. Tectonic controls of the Mesozoic and
Cenozoic alkaline magmatism in central-southeastern Brazilian platform. In:
Comin-Chiaramonti, P., Gomes, C.B. (Eds.), Mesozoic to Cenozoic alkaline magmatism
in the Brazilian platform. EDUSP-FAPESP, So Paulo, pp. 355.
Shuster, D.L., Vasconcelos, P.M., Heim, J.A., Farley, K.A., 2005. Weathering geochronology
by (UTh)/He dating of goethite. Geochim. Cosmochim. Acta 69, 65673.
Soares, P.C., Landim, M.B., 1976. Comparison between the tectonic evolution of the
intracratonic and marginal basins in South Brazil. An. Acad. Bras. Cienc. 48, 313324
(Suppl.).
Soares, P.C., Bonacim, E.A., Nogueira Filho, J., Soares, A.P., 2002. Um olhar geolgico para a
paisagem: Curitiba a Vila Velha (PR, Brasil). Simpsio de Roteiros Geolgicos do
Paran. SBG, Ponta Grossa, Sociedade Brasileira de Geologia, pp. 896.
Steiger, R.H., Jger, E., 1977. Subcommission on geochronology: convention on the use of
decay constants in geo- and cosmochronology. Earth Planet. Sci. Lett. 36, 359362.
Stumm, W., Sulzberger, B., 1992. The cycling of iron in natural environments: considerations based on laboratory studies of heterogeneous redox processes. Geochim.
Cosmochim. Acta 56, 32333257.
Thompson, R.N., Gibson, S.A., Mitchell, J.G., Dickin, A.P., Leonardos, O.H., Brod, J.A.,
Greenwood, J.C., 1998. Migrating CretaceousEocene magmatism in the Serra do
Mar alkaline province, SE Brazil: melts from the deected Trindade mantle plume?
J. Petrol. 39, 14931526.
USGS, February 2004. Shuttle Radar Topography Mission, 3 Arc Second scene SRTM_u03_
s22-27w48-55, Unlled Unnished 2.0. Global Land Cover Facility, University of
Maryland, College Park, Maryland.
Vasconcelos, P.M., 1999a. K-Ar and 40Ar/39Ar geochronology of weathering processes.
Annu. Rev. Earth Planet. Sci. 27, 183229.
Vasconcelos, P.M., 1999b. 40Ar/ 39Ar geochronology of supergene processes in ore
deposits. Rev. Econ. Geol. 12, 73113.
Vasconcelos, P.M., Conroy, M., 2003. Geochronology of weathering and landscape evolution, Dugald River valley, NW Queensland, Australia. Geochim. Cosmochim. Acta 67,
29132930.
Vasconcelos, P.M., Onoe, A.T., Kawashita, K., Soares, A.J., Teixeira, W., 2002. 40Ar/39Ar geochronology at the Instituto de Geocincias, USP: instrumentation, analytical procedures, and calibration. An. Acad. Bras. Cienc. 74, 297342.
Vasconcelos, P.M., Heim, J.A., Farley, K.A., Monteiro, H., Waltenberg, K., 2013. 40Ar/39Ar
and (UTh)/He 4He/3He geochronology of landscape evolution and channel iron
deposit genesis at Lynn Peak, Western Australia. Geochim. Cosmochim. Acta 117,
283312.
Velzquez, V.F., Riccomini, C., Gomes, C.d.B., Kirk, J., 2011. The Cretaceous alkaline dyke
swarm in the central segment of the Asuncin Rift, eastern Paraguay: its regional distribution, mechanism of emplacement, and tectonic signicance. J. Geol. Res. 118.