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Chemical bond - Combination of atoms in a stable association 4. Bond length - measure of the distance between two bonded nuclei o bond strength (Bond enthalpy) o Multiple bonds = stronger electrostatic attractions = closer distance = shorter bond.
Chemical bond - Combination of atoms in a stable association 4. Bond length - measure of the distance between two bonded nuclei o bond strength (Bond enthalpy) o Multiple bonds = stronger electrostatic attractions = closer distance = shorter bond.
Chemical bond - Combination of atoms in a stable association 4. Bond length - measure of the distance between two bonded nuclei o bond strength (Bond enthalpy) o Multiple bonds = stronger electrostatic attractions = closer distance = shorter bond.
Chemical bond Combination of atoms in a stable association
4.1 Ionic bonding Ions form when electrons are transferred o All atoms are electrically neutral o Transfer of electrons causes an ion o Ion charged particle Ionic compounds form when oppositely charged ions attract o Ionic bond the electrostatic forces between two oppositely charged ions o Ionic compounds compounds by ionic bonding Must be electrically neutral Ionic character can be predicted from the electron configurations of a compounds element o Position of the element in the Periodic Table o Electronegativity >1.8, mostly ionic Ionic compounds have a lattice structure o Ionic lattice a predictable three-dimensional crystalline structure o Lattice enthalpy strength of force between ions Affected by size and charge of ions o Coordination number number of ions that surround a given ion 4.2 Covalent bonding Covalent bond forms by electron sharing o Covalent bond the electrostatic attraction between a pair of electrons and positively charged nuclei o Molecule group of atoms held together by covalent bonds o Octet Rule - Tendency to form an octet in outer shell o Non-bonding pairs (lone pairs) electron pairs that are not involved in bonding Atoms can share more than one pair of electrons o Double bonds o Triple bonds Lewis Structure to denote outer electrons o Place brackets for ions with charge outside Octet rule is not always followed o Some molecules form stability with less than eight electrons (incomplete octet) or more than eight electrons (expanded octet) In Dative Bonds, both shared electrons come from one atom o Shown by an arrow o Important for some reactions in acid-base Strong bonds are short bonds
o Bond length measure of the distance between two bonded nuclei
o Bond strength (Bond enthalpy) measure of energy required to break bond o Multiple bonds = stronger electrostatic attractions = closer distance = shorter bond length Polar bonds result from unequal sharing of electrons o Polar unsymmetrical electron distribution o Dipole two different poles o More electronegativity, more negative o More polar if difference in electronegativity is greater o Bonding continuum bond types can be considered as a continuous range Non-polar covalent Electronegativity difference little or not Polar covalent Electronegativity difference <1.8 Ionic Electronegativity difference > 1.8 m VSEPR theory: shape of a molecule determined by repulsion between electrons o Electrons repulse each other o Bond and triple bonds are oriented the same thus are a single unit (negative charge centre) o Number of charge centre determines geometrical arrangement o Shape determined by angles between bonded atoms o Non-bonding pairs of electrons have a greater charge than bonded pairs o Repulsion strength: lone-pair to lone-pair; lone-pair to bonding pair; bonding pair to bonding pair Number of centre Shape Angle 2 Linear 180 3 Planar triangular 120 3 + lone pair Bent 117 4 Tetrahedral 109.5 4 + lone pair Trigonal Pyramidal 107 4 + 2 lone pair Bent 105 Molecules with polar bonds not always polar o Polarity of molecule depends on The polar bonds it contains Orientation of polar bonds (shape) Some covalent substances form crystalline solids o Macromolecule crystal of a single molecule with a repeating pattern o Allotropes different forms of an element in the same physical state Carbon Graphite Diamond
Fullerence Silicon and Silicon Dioxide Covalently bonded in a tetrahedral arrangement Strong Insoluble in water High melting point Not a conductor