Paper 1 Answera

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Answer Keys
1
40
85.68
10
11
12
13
119.5
14
15
29.81
16
17
67.2
18
18.18
19
20
21
22
23
11.40
24
25
26
27
28
29
30
31
0.975
32
33
34
31
35
36
90.713
37
16.54
38
39
40
13.49
41
42
43
44
45
46
47
88581
48
49
50
51
52
9.44
53
54
55
56
57
58
59
60
61
62
63
64
65
Explanations:-
1.
We have,
x x
x
y y
y
1.5
x 10 0.6
y 20
2
x 0.45 y 1
2.
We know that f (z) u iv is analytic then

u v
u
v
and
x y
y
x
verify the options, only (A) satisfies
3.
2 2 2
x 2 y 2 z 2
12xy 2 z 4 4x 3 z 4 24x 3 y 2 z 2
2
4.
1, 1,1
12 4 24 40
2 sin
Let f log
2 sin
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2 sin
f log
2 sin
2 sin
log
2 sin
f f
It is an odd function
2
2 sin
log
d 0
2 sin
2
Q f x dx 0 If f x is an odd function
a
5.
U2 U1 PE2 PE1 kE2 kE1

Here pE2 0;kE1 0 kE2
U2 U1 pE1
mCp T2 T1 mCp T2 T1 mc g H
water
copper
mCP T2 m Cp T2 T1
H
6.
c
mC g
107 4.17 7 0.85 (33 20) 1000

7 9.8
85.68 km.
H Q Wactual
10
m w Cpw Tw 2 Tw1
0.72
6.5
10
4.2 20 10
60
0.72
4.55 13.88 9.338 kW
Now H m Cp T2 T1
9.338 m 1 45 32
m 0.718 kg
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7.
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Fraction of available energy lost due to irreversibility

Q
Q
303
603 943 0.2666.
303
Q 1
943
.
Mass flow rate, m A 2 u 22 0.4166
8.
A 2 7.38 104
700 A 2
1.24
2
d
4
d 3.07cm
For the block, F f Ma M
9.
dv
dt
M
V Vy
f
dA A
V
dy
b
dv
A
F
V M
dt
b
1
10.
Oil
x
1
F A b
dt n
F
M
0
1
Mdv
F A / b
A
1
e 5 0.1813 Pas
Fb
4Q
0.0099 m / s
d 2
ud
Re
399.72 400
gC
5

1
0.3
w w 1 0 4 0.5 0.3 1 1 0.3 m / sec
k
2
2 w
2 0.5
11.
12.
Dia of pipe, d=200mm=0.20m
Velocity, v=3m/s; length L=5m

Kinematic viscosity, 0.01stoke = 0.01 1004 m 2 / s
Vd
3 0.20
Reynold Number Re x
6 105
4
0.01 10
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Value of f = 0.02166+
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0.9
0.09
0.9
0.02
0.02
0.3
0.3
Re
54.13
6 105
0.02 0.00166 0.2166

Head lost due to friction, h g
13.
4fLv 2
0.993m of water
2gd
The discharge through the Venturimeter is given by

Q
ka1a 2 2gh
a12 a 2 2
,Q
8.1
0.135m 3 / s, K 0.96
60
2
0.25 0.049m 2 , h 7.6m
4
0.96 0.049 a 2 2 9.81 7.6
By substitution, we have 0.135
2
0.049 a 2 2
a1
or, a 2 0.0112m 2 d 2
14.
cos
0.0112 4
0.1195m 119.5mm
rd
rR
r 5.3
r 19
r 169.14 mm
cos 22
Dia. 2 169.14 338.288 mm
15.
Operating speed
75% of NC 0.75 39.75 29.81.
16.
n
N u R e,max
;
n0
u max d
sn d
R e,max
u max
s n tube pitch, d tubediameter

s n u max R e,max N u h
17.
K
2
3.02 106
Cp 1020 650
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0.10
s
0.05; a1 2.467
2
2
2
at 3 min or 180s F0
t T 3.02 106 180
0.217
2
s2
0.05
a1F0 0.536
Ts Tb
0.45
Ts Ta
18.
r1
42 Tb
0.45 Tb 67.2C
42 98
12mm
6mm
6
T1 70o C, T2 25o C, K 0.140 W / m o C

h 0 7.2 W / m o C
K
rC
For Cylinder rC Critical radius
h0
0.140
m 0.0144 m 19.44 mm
7.2
2 T1 T2
2 70 25
Q max
L
r
19.44
ln
ln C
1
6
r1 1
3
0.140
10 7.2 19.44
K
h r
rC
r1
0 C
Q max
18.18 W / m
L
19.
Rate of diffusion, N A
D AB 4 105
A
DAB A PA1 PA2
RT
Z
m2
, Z x 2 x1 30 m
s
4 103 1.256 105 , R 8314
T 300 k, PA1 1.0132 105 N m 2 , PA2 0

NA
4 105 1.256 105 1.0132 105 0

8314 300 30
N A 6.80 1013 kg mole h

Mass flow rate of NH 3 N A M NH3
6.80 1013 17 1.156 1011 kg h.
20.
For irreversible gas phase reaction
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y
16
N t n 2 n
3.
0.8
y1
21.
f=
23.
Diffusion coefficient
10
cm
1000
= 10-2 x 105 =
sec
105 cm 2 / sec
60
Potassium hydroxide is the commonly chemical for determination of acid value and
saponification value of oil or fat.
=
22.
d 2 Element or Sin gleof element
ln
ln
CAo CO CA
CA C o CAo
12 12.2 CA
= (CA0 + CRO)kt
CA 12.2 CAO
CO = CAO + CRO = CA + CR
= 12 + 0.2
= (12.2) 12 x 0.01= 12.2 mol/m3
12 12.2 CA
12 12.2 CA
ln
= 1.464 ln
= 1.464
CA 12.2 12
CA 0.2
12 12.2 CA
CA 0.2
= 4.3232 12(12.2- CA) = 0.8646 CA
146.4 12A = 0.846 CA CA =11.40 mol/m3

24.
26.
Copper is used as material of construction in food industry particularly in brewing.

Lipase is the enzyme used to bring about hydrolysis of oils and fats [on hydrolysis glycerol
and fatty acids are obtained].
Skew- symmetric of even order, is a perfect square (non-zero)
Hence, option (d) i.e., 9 is a perfect square.
(or)
Using expansion, we get 9.
27.
x 2
dy
3
3y 12 x 2
where x 2
dx
dy
3
2
. y 12 x 2
dx x 2
3
2
P
Q 12 x 2
x2
3
3
dx
I.F e x 2
e3 log x 2 x 2
Solution is
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y x 2
12 x 2
x 2
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dx c
12 x 2 dx c
5
y x 2 12
3
x 2
1
y 3 2 2 1 12 c c 0
6
y x 2 12
3
28.
x 2
y 2 x 2
1
s
1
1
L1 2
L1 2
2
2
4
s
2s
2
s
2s
2
s 2s 2 s 2s 2
1 1
1
1
L
L
2
2
4 s 1 1
s
1 1
1 t 1 1
e t L1 2
e L 2
4 4
s 1
s 1
1
e t sin t e t sin t
4
1
1
sin t e t e t sin t sin ht
4
2
29.
X
------
P(X)
1
n
1
n
1
n
1
n
------
1
n
1
1
1
1 n 1
Mean 1. 2. 3. .... n.
n
n
n
n
2
30.
Let
1
1
2
x f x 2 27 0, f 1 x 3
x
x
27
The Newton-Raphson formula is
x n 1 x n
31.
f xn
f 1 xn
x n 1
P
For the process T2 T1 1
P2
3x n 27x 3n
2
x 1
y
Here given PV1.3 = constant; So y = 1.3

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1.31
0.8 1.3
T2 74 273
225.28 k
5.2
P
Here, V2 V1 1
P2
V3 V2
5.2
0.15
0.8
1
1.3
0.633 m3
T3
T2
V3 0.633
32.
347
0.975 m3
225.28
T1 298K
For minimum requirement, by the relation
Q1
Q1 T1 298
2
Q2 T2 263
W
T
So, Q1 1 Q2 2.2661kW
T2
R
Q2
T2 263K
Minimum power requirement,
W = Q1 Q2 = 2.2661 2 = 0.2661 kW
33.
The mean velocity of flow V is given by
2R 2 Vmax
2Vmax
r
Q R V 2r Vmax 1 d
V
n 1 n 2
n 1 n 2
R
0
n
n 1 n 2
r
1
1 , dA
V
2
A A V
R
n
and
R
n 1 n 2
1 n 1 n 2
r
1 2r dr
2
R 0
2
4 3n 1 3n 2
R
3
3n
34.
Operating speed of the ball mill is 0.5 * 62= 31

Because operating speed is 50 percent of the critical speed.
35.
We know that a gas mixture obeying he viral emanation of state, the fugacity coefficient of
the mixture can be represented by
ln x1 ln
For various component it can be expressed as
ln x1 ln 1 x 2 ln 2 x 3 ln 3
We are given that

x1 0.3, x 2 0.25, x3 0.45
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1 fugacity of coefficient of component 1 = 0.7

Substituting in equation (1) we get

ln 0.3l 0.3 ln 0.7 + 0.25 ln 0.85 + 0.45 ln 0.75
ln 0.276
0.7588
f p 0.7588 60 0.7588 45.53 bar
36.
Re
2 0.25
ux
28,802
17.36 106
Nu 0.3317 NRc
0.3317 28,802
0.5
0.5
Pr 3
1
0.7 3 = 49.98
h
k
0.0275
2
Nnu 49.98
5.4978w / m K
x
x
0.25
And
h 2h x 2 5.4978 10.9956w / m2 K
The heat flow rate is q hA T2 T1

10.9956 0.25 1 333 300 90.7137W
37.
x2
30 0.05 0.96 0.01532

94
y 3x 2 3 0.01532 0.04596
*
2
At the bottom of the column
y2 y*2 0.05 0.04596 0.00404
Liquid L
At the top of the column

y1 y1* y1 0 y1 0.05 0.04 0.002
NTU
y 2
y y 2 y1 0.05 0.002
y 2
y 2
y 2
y*2 y1 y1*
2.9014 103
y2 y
n
y1 y1*
0.05 0.002
NTU
16.54.
2.9014 103
*
2
2
Gas mixture
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38.
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3004.05
T 33.81
At dew point 294 K
n psat 14.20
n psat 14.20
3004.05
294 33.81
psat 14.216
At dew point p A pSat
A
partial pressure vapour pressure
PA
Pt PA
Pt 760 mm Hg
101.325 kpa
14.216
0.1632
101.325 14.216
% saturation 0.67
ys
y
y5
0.1632
0.2435
0.67
saturated humidity ys
0.2435
PAsat
PT PAsat
PAsat
PT PAsat
PAsat 19.848 kpa.
39.
Cavg 1 2
M avg 2 M1 M 2
10
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consider 100kg of solution,

10 92
0.02127
10 90
92 18
3 92
X A 2 mole fraction of A at location 2
0.006
3 92 97 18
100
kg
M1 Mol.wt. at location 1
19.574
10
90
kg mol.

92
18
100
kg
M 2 mol.wt. at location 2
18.445
kg mol.
3 97

92 18
1 1030
1020
kg mol
so, Cavg
53.96
m3
M avg 2 19.574 18.445
X A1 mole fraction of A at location 1
X BM
NA
40.
1 X A1 1 X A 2
X A1 X A 2
0.9863
1 XA2
ln
1 X A1
1 X A1
ln
1 XA2
9 1010 53.96 0.02127 0.006
0.9863 1.6 10
da
= 10-3/hr
df
XA =
4.7 107
k mol
m 2 .s
da 103 dt 1 a = 10-3 t a = 1 10-3

0
0.16 1 103 t
1 0.16 1 10 t
3
; at t = 24 hr=
0.156
= 0.1348
1 0.156
XA = 13.49%
41.
The liquid volume vl = t x Ve = 2x(2 x 60) = 240lt

(Vg) Gas volume = V Vl = 500 240 = 260 lt
260
Fraction of gas =
= 52%
500
42.
Heat removed to cool the fish= sensible heat + latent heat + sensible heat
= 680 x 3.182 (5 (-2) + 234.5 x 680 + 680 x 1.717 x (-2+12)
= 15146.32 + 159460 + 11675.6= 18682 K= 186.282 MJ
Percentage of latent heat
43.
159460
x 100 = 85.6%
186282
1 mole N2 2 moles NH3
11
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2moles 4moles NH3

4 17 68
44.
L f t f s
1
1 eas e2as ........ s 1 1eas
s
sin ce 1 e 1 e
as
45.
as
e 2as .......
For PD controller, Gc s Kc 1 0s
AR G c j K c 1 02 2
AR
Kc
1 02 2
So, Nyquist plot when ,
AR
AR
1
and when 0,
Kc
Kc
Therefore, (C) is the correct option.

47.
Net present value for the carbon steel pump

30000
48.
25000
1.12
25000
1.12
25,000
1.12
25,000
1.12
88581.
Roots (poles) of the 2nd order system are - n jd .

4
TS settling time
so for i TS is constant.;
n
d is cons tan t TP
n
so for ii TP is constant.
d
is constant cos Mp e
12
so for iii M P is constant.
49.
Formulate Rouths Table

s3 1 2 0
s2 3 6 0
s 0 0 0 one zeroed row
s0 6 0 0
There is one zero row. So marginally stable.
50.
From Arrhenius equation, k = k0 e- (E/RT) ------ (1)

Let activation energies for the reaction with out and with catalyst be E and E, and k and k
be the respective rate constants of the reaction.
Therefore, from equation (1), we have
12
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(k/k) = e- (E/RT) / e- (E/RT) = e (E-E)/RT = e (E-E)/RT = e (70-50)*1000/ (8.314 * 303)

Since, Room temperature is 300 C=30 + 273 =303 K,
E is given in KJ, hence convert to joule by multiplication with 1000 and
R = 8.314 J/mol K
(k/k) = e(7.939)= 2658.257
i.e., the rate of reaction is decreases 2658 times that in without catalyst (k)
51.
r Ko T
RT
T 12
r2
1 1
ln E R ln 21
T 2
r1
T1 T2
1
r 6000 1
1
600
ln 2
ln
2 400 600
400
r1
r2
14.92
r1
52.
y1
y1
0.16
0.1904
1 y1 1 0.16
y 2 1 0.95 ; y1 0.00952
For pure water as solvent: x2 = 0
At equilibrium y* 16x (unit in kg)
16 x
44
1
29
18
y 0.659 6.5454x
1
44
y 9.932x
For minimum valid rate x1
y1
0.1904
0.01916
9.932 9.932
x2 0
Mass balance gives G y1 y2 Lmin X1 X2

Lmin Y1 Y2 0.1904 0.00952
9.44
G
X1
0.01916
53.
1
1
1
Kx Kx Ky 4
1
1
1 760

K x 2 1.15 0.12 106
K x 19.622
13
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Ky
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H
1
Kx Ky
1
0.12 106
1
Ky
760 20 1.15
K y 0.1141
54.
A cascade control is compared of a secondary loop inside the primary loop.

In the figure, transfer function for secondary loop G sec s
G c2 G p2
1 G c2 G p2
G c2 G p2
a
G a, then G(s)
So, transfer function of the entire system, let G c1
1 G G p1
1 a
c2 p2
G c2 G p2
G 0
So, characteristics equation 1 G c1
1 G c2 G p2 p1
55.
For two non-interacting tanks in series

Q2 s
Q s
Q s
s 1
1
1
Q2 s
2
s
s s 1
Taking inverse
t
Q2 t 1 e e
56.
8 145 140 135 130 125 120 115
28.77%
10 150 150 150 150 150 150 150
57.
Exaggerate blowing out of proportion, overstate
58.
H
i.
, False
ii.
, True
14
CHTest ID: 158254
iii.
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, True
iv.
, False,
Hence (C) only (II) and (III)

59.
Exulted- to express great pleasure or happiness, especially at someone else's defeat or failure
60.
Reluctant unwilling
61.
x 1, only if 1 x
1 1
1 1
1 80
4 108 0, 4 108 0............................................, 4 108 0
1 81
1 188
4 108 1,.............................................................., 4 108 1
1 189
1 190
1 216
4 108 2, 4 108 2,......................................., 4 108 2
For1, 2,..................................., 80, x 0

For 81,82,83,..........................,188, x 1
108 x1 108
For189,190,..........................., 216, x 2
28 x 2 56
Hence the required sum 108 56 164
62.
Let N 120120120120120120120120...............................................278times
We know that a number is divisible by 72 8 x 9 , if it is divisible by 8 and 9

Clearly the last three digits of the given number is120, so it is divisible by 8
Sum of digits 1 2 0 278 834, so if we divide the number by 9, then theremainder is 6
N 8K 9M 6 8K 9M 6
The values that fits in for 8K = 9M +6 = 24 or 96
96
The required remainder rem 24
72
Alternate Solution:
15
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120
48
72
120120
24
72
120120120
0
72
120120120120
48
72
Forms a cycle,
1 - 48
2 - 24
30
278th - 24
63.
Let the total work be 120 units

A
B C
D
E
F
Number of days
10 12 15 20 24 30
Units/day
12 10 8
-6
-5
-4
Any three alternate days, whatever way they be paired up, net work done would be the same
i.e.,30 15 = 15 units every 3 days.
Hence, (D)
64.
1 P(x) 50%
7 1 0 2 7 7 1 1 2 6 7 1 2 2 5
1 C0 C1 C2 0.4293 50%
3 3
3 3
3 3
0
8
1
7
2
6
1 2
1 2
1 2
1 8 C0 8 C1 8 C2 0.5317 53.17%
3 3
3 3
3 3
65.
(B) and (C) qualify, but (C) best sums up the passage as it is clearly stated in the passage.
16

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CHTest ID: 158254

We know that f (z) u iv is analytic then

verify the options, only (A) satisfies

CHTest ID: 158254

U2 U1 PE2 PE1 kE2 kE1

107 4.17 7 0.85 (33 20) 1000

CHTest ID: 158254

Fraction of available energy lost due to irreversibility

603 943 0.2666.

Mass flow rate, m A 2 u 22 0.4166

For the block, F f Ma M

Dia of pipe, d=200mm=0.20m

Velocity, v=3m/s; length L=5m

CHTest ID: 158254

0.02 0.00166 0.2166

The discharge through the Venturimeter is given by

Dia. 2 169.14 338.288 mm

75% of NC 0.75 39.75 29.81.

s n tube pitch, d tubediameter

CHTest ID: 158254

t T 3.02 106 180

T1 70o C, T2 25o C, K 0.140 W / m o C

DAB A PA1 PA2

4 103 1.256 105 , R 8314

T 300 k, PA1 1.0132 105 N m 2 , PA2 0

4 105 1.256 105 1.0132 105 0

N A 6.80 1013 kg mole h

For irreversible gas phase reaction

CHTest ID: 158254

d 2 Element or Sin gleof element

= (12.2) 12 x 0.01= 12.2 mol/m3

= 4.3232 12(12.2- CA) = 0.8646 CA

146.4 12A = 0.846 CA CA =11.40 mol/m3

Copper is used as material of construction in food industry particularly in brewing.

CHTest ID: 158254

The Newton-Raphson formula is

Here given PV1.3 = constant; So y = 1.3

CHTest ID: 158254

For minimum requirement, by the relation

Minimum power requirement,

The mean velocity of flow V is given by

Operating speed of the ball mill is 0.5 * 62= 31

For various component it can be expressed as

We are given that

CHTest ID: 158254

1 fugacity of coefficient of component 1 = 0.7

Substituting in equation (1) we get

f p 0.7588 60 0.7588 45.53 bar

The heat flow rate is q hA T2 T1

30 0.05 0.96 0.01532

At the bottom of the column

y2 y*2 0.05 0.04596 0.00404

At the top of the column

CHTest ID: 158254

PAsat 19.848 kpa.

CHTest ID: 158254

consider 100kg of solution,

da 103 dt 1 a = 10-3 t a = 1 10-3

The liquid volume vl = t x Ve = 2x(2 x 60) = 240lt

1 mole N2 2 moles NH3

CHTest ID: 158254

2moles 4moles NH3

So, Nyquist plot when ,

(k/k) = e- (E/RT) / e- (E/RT) = e (E-E)/RT = e (E-E)/RT = e (70-50)1000/ (8.314 303)