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Solubility of Metals
Solubility is the ability of a substance to go into
solution(dissolve).
Substances that are soluble readily dissolve in
solution and do not precipitate.
Substances that are insoluble do not easily
dissolve in solution and stay in their solid form.
Ref:
Solubility of Metals
MCO3(s) M2+(aq) + CO32-(aq)
Ksp = [M2+].[ CO32-]
+ mx
where m=1
pCO32-
[CO32-]
Mg2+ logKsp = 5
Ca2+ logKsp = 8.5
Ex :
pCO32- = 3
[CO32-] = 10-3
Ca solubility?
Ksp = 10-8.5
Ex :
pCO32- = 3
No!!!
[Ca2+] . [CO32-] =10-4. 10-3 = 10-7 > Ksp = 10-8.5
So precipitation occurs.
Ex :
pCO32- = 1
occur?
Yes!!!
[Ca2+] . [CO32-] =10-7. 10-1 = 10-8 > Ksp
Slightly greater than Ksp. So precipitation occurs.
Ex :
CO32- = 10-3 M,
[Ca2+] ? in mg/L
zOH-
Ksp = [Mz+].[OH-]z
log[M z+] is a function of pH
log Ksp = log[Mz+] + log[OH-]z
log[Mz+] = log Ksp z.log[OH-]
Kw = 10-14 = [H+].[OH-]
p Kw = pH + pOH
pOH = p Kw pH
log[Mz+] = log Ksp z( pH pKw )
log[Mz+] = log Ksp + zpKw zpH
m.X
M(OH)z(s) Mz+ +
When pH , [OH]
Ksp = [Mz+] . [OH-]
zOH, [M+]
Ca2+ + CO32-
CaCO3
H2CO3
H+ + HCO3-
Ka1 = [H+].[HCO3-]
[H2CO3 ]
HCO3-
H+ + CO32-
Ka2 = [H+].[CO32-]
[HCO3- ]
H2 O
H+ + OH-
Kw= [H+].[OH-]
[CO32-] is a function of pH
TOTCO3 =
CB
[CO3 ]
2
TOTCO3
1
[H ]2
[H ]
1
TOTCO3
[CO ]
[H ]2
[H ]
1
[Ca ]
K sp
[CO3 ]
[Ca2 ] K sp
[H ]2
[H ]
1