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5. . Repeat (but with more care!) the above steps 4a-d using, in turn, magnesium oxide, aluminium
oxide, silicon ( IV) oxide phosphorus (V) oxide.
6. Measure the pH of the water in the seventh test-tube by adding 2-4 drops of universal indicator
solution or by using pH paper, for comparison with the above.
7. . Bubble sulphur dioxide slowly through the water in the sixth test-tube until there is no further
change in the colour of the indicator. Note the final pH of the solution.
(You will probably be
given sulphur dioxide in liquid form in a cylinder. To obtain the gas you carefully open the valve
and the sudden decrease in pressure inside the cylinder causes the surface liquid to vaporise.
Make sure there is a Drechsel bottle between the cylinder and the water in case of suck-back.
Alternatively, your teacher may suggest other ways of generating the gas.)
8. To test the solubility of sulphur dioxide lower the delivery tube from your generator to the bottom
of the 100 cm3 measuring cylinder filled with water. Pass a slow steady stream of gas through the
water and when the air has been expelled from your apparatus look for a change in the size of
the sulphur dioxide gas bubbles as they rise up through the water.
Results Table 1
Na2O2A MgO
AI2O3
SiO2
P4O10
SO2
Appearance
On mixing with water
Initial temperature
Final temperature
Does it dissolve?
pH of solution
Other observation(s) (if any)
Question
1. Use your experimental results, your data book and your textbook(s) if necessary to complete a larger
copy of Table 2 below
Formula of oxide
NazOz*
MgO
A4C>3
SiOz
P40,o*
SOa*
ClaO*
Melting point/C
Boiling point/C
State at s.t.p.
Action of water
pH of aq. solution
Acid-base nature
Conductivity of liquid
Solubility in cyclohexane
Structure
Bonding
Table 2
2. Write equations for any reactions which took place when you added the oxides to water.
3. Comment on the change in structure and bonding in the oxides between sodium and chlorine.
4. How does the acid-base nature of the oxides of the elements in Period 3 change with increasing
atomic number?
5. Can you relate this change to the change in structure and bonding that takes place along the
period?