Full Test

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FULL TEST
INSTRUCTIONS
Time : 3 hrs.
Chemistry (120 marks)
Question No. 1 to 30 are of 4 marks each.
Physics (120 marks)
Mathematics (120 marks) :
Negative Marking
One fourth () marks will be deducted for indicating incorrect response of each question.
. . . Best of Luck
CHEMISTRY
1.
2.
3.
4.
Max. Marks : 360
Which one of the following is an example of co-ordination

isomerism ?
(a) [Co (NH3)5 Br] SO4 and [Co (NH3)5 SO4] Br
(b) [Co (NH3)5 NO2] Cl2 and [Co (NH3)5 ONO]Cl2
(c) [Cr (H2O)6] Cl3 and [Cr (H2O)5 Cl] Cl2 H2O
(d) [Co (NH3)6] [Cr (CN)6] and (Cr (NH3)6] [Co (CN)6]
The z - component of angular momentum of an electron in
an atomic orbital is governed by the
(a) azimuthal quantum number
(b) principal quantum number
(c) magnetic quantum number
(d) spin quantum number
Two containers P and Q of equal volume (1 litre each) contain
6 g of O2 and SO2 respectively at 300 K and 1 atmosphere.
then
(a) Number of molecules in P is less than that
in Q
(b) Number of molecules in P and Q is same
(c) Number of molecules in Q is less than that in P
(d) Either (a) or (b)
A wedding ring presented to a bride contains 788 mg of
gold and rest diamond. If the ring weighs 1 g the bride
receives (At wt : Au = 197, C = 12)
(a) more number of gold atoms
(b) more number of carbon atoms

(c) equal number of gold and carbon atoms
(d) gold and carbon atoms in ratio of 4:1 approximately
5.
6.
7.
The solution containing 4.0 % PVC in one litre of dioxane

was found to have osmotic pressure of 6.0 104 atm at 300
K. The molecular mass of polymer is
(a) 6.4 102
(b) 3.0 102
(c) 1.6 105
(d) 5.6104
Urea and hydrazine react to form ammonia gas along with

compound X which reacts with aldehydes and ketones to
form specific crystalline derivatives. X is
(a) phenylhydrazine
(b) semicarbazide
(c) biuret
(d) acetylurea
The I.U.P.A.C. name of CH 2 - CH - C H 2 is

|
CN
CN
(a) 1, 2, 3-propanetrinitrile
(b) 1, 2, 3 tricyanopropane
(c) 3-cyano-1, 5-dinitrilepentane
(d) 3-cyano 1, 5-pentanedinitrile
CN
2
8.
Diborane has
(b) CH3CHMgCH2Cl,
(a) 2 two - centre - two - electron bonds and 4 three centre - three - electron bonds.
(b) 4 two - centre - two - electron bonds and 2 three centre - three - electron bonds
(c) CH3CH2CH2MgCl, H3C C OH

H3C
(d) CH3CH2CH2MgCl, CH3CH2OCH2CH3
(d) all six identical bonds.
10.
11.
12.
13.
16.
The repeating units of acrilan are
(a)
H
|
H 2 C = C - COOCH 3
(c)
H
|
H 2 C = C - CN
H
|
(b) H 2 C = C - COOC 2 H 5
(d)
CH3
|
H 2C = C - COOCH3
17.
(a) 8
(b) 12
(c) 3
(d) 6
Alcohols can be obtained from all methods except

(a) hydroboration-oxidation
(a) Mg(NO3)2
(b) Mg3 N2
(c) reduction of aldehyde/ketones with ZnHg/HCl
(c) NH3
(d) MgO
(d) fermentation of starch
During bromination of benzene in the presence of FeBr 3 the

species that attacks the ring to initiate the process is
(a) FeBr4
(b) Br+
(c) Br
(d) Br2 molecule
(b) oxymercuration-demercuration
18.
(a) [Zn(NH3)4]+2
(b) Ni(CO)4
(c) [Cd(CN)4]-2
(d) [Cu(NH3)4]+2
[H+] >
[H+] <
(d) PCl5
In which of the following cases, the stability of two oxidation
states is correctly represented
(d) Cu+ > Cu2+
A and B in the reaction,
Kw
K w and [ OH - ] > K w
(d) For a neutral solution [H+] = [OH] = 107 M at all

temperatures
(c) Cold dilute KMnO4 solution
(c) Fe2+ > Fe3+
K w and [OH - ] <
(c) For an alkaline solution
19.
(b) Mn2+ > Mn3+
Kw
(b) For an acidic solution
Di-n-propyl ether and diallyl ether can be distinguished by
(a) Ti3+ > Ti4+
Which of the following expressions is not true ?

(a) For a netural solution [H+] = [OH] =
Which of the following has a shape different from others?
(b) Sodium Metal
15.
A gaseous mixture of three gases A, B and C has a pressure

of 10 atm. The total number of moles of all the gases is 10. If
the partial pressures of A and B are 3.0 and 1.0 atm
respectively and if C has mol. wt of 2.0 what is the weight
of C in g present in the mixture.
A metal X on heating in nitrogen gas gives Y.Y on

treatment with H2O gives a colourless gas which when
passed through CuSO4 solution gives a blue colour. Y is
(a) Acetic acid
14.
CHOH
H3C
H3C
(c) 3 two - centre - two - electron bonds and 3 three centre - three - electron bonds.
9.
CH3CH2
20.
For a chemical reaction X Y, the rate of reaction increases

by a factor of 1.837 when the concentration of X is increased
by 1.5 times. The order of the reaction with respect to X is
(a) 1
(b) 1.5
(c) 2
(d) 2.5
The final product of the following sequence of reactions
NaOH , H O
LiCu (CH ) 2
2
C
B 3
H D
H 2O
Mg
1.HCHO
CH 3 CH 2 CH 2 Cl A B
ether
2.H 3O +
(a) CH3CH2CH2MgCl, CH3CH2CH2CH2OH
LiAlH
4

D
H 2O
(a) 3-ethyl-2-methyl-1-hexanol
3
(b) 2, 3-dimethyl-1-pentanol
(c) 2-ethyl-3-methyl-1-hexanol
(b) CH3CH2CHBr
OH
(c) CH3CHBrCH2
Br
(d) CH3CH2CHBr
Br
(d) 3, 3-dimethyl-1-pentanol
21.
22.
A solution containing As3+, Cd2+, Ni2+ and Zn2+ is made

alkaline with dilute NH4OH and treated with H2 S. The
precipitate obtained will consist of
(a) As2S3 and CdS
(b) CdS, NiS and ZnS
(c) NiS and ZnS
(d) Sulphide of all ions
M2SO4 (M+ is a monovalent metal ion) has a Ksp of 3.2 105

at 298 K. The maximum concentration of SO42 ion that
could be attained in a saturated solution of this solid at 298

K is
23.
24.
25.
(a) 3 103 M
(b) 7 102 M
(c) 2.89 104 M
(d) 2102M
The intermediate formad during the addition of HCl to

propene in the presence of peroxide is
(a)
CH 3 CHCH 2 Cl
(b)
CH 3 CHCH 3
(c)
CH 3 CH 2 CH 2
(d)
CH3CH 2 CH 2
28.
29.
CH2=CHCH=CH2+
(b) Californium
(c) Uranium
(d) Terbium
OH
OH
2 NBS
alc.KOH
30.
In the following compounds,

OH
A
B
Pd ,( -H )
2 D
C
Which of the following is not an actinide?

(a) Curium
The standard reduction potential for Cu2+/Cu is + 0.34.

Calculate the reduction potential at pH = 14 for the above
couple. (Ksp Cu(OH)2 = 1 1019)
(a) 0.22 V
(b) + 0.22 V
(c) 0.44 V
(d) + 0.44 V
Final product (D) formed in the following reaction sequence is
OH
(a) Naphthalene
(b) Tetralin
(c) Benzene
(d) Anthracene
A current of 2.0A when passed for 5 hours through a molten
metal salt deposits 22.2g of metal of atomic weight 177.The
oxidation state of the metal in the metal salt is
(a) +1
(b) +2
(c) +3
(d) +4
PHYSI CS
CH3
(I)
31.
NO2
NO2
(II)
(III)
(IV)
the order of acidity is
26.
(a) III > IV > I > II
(b) I > IV > III > II
(c) II > I > III > IV
(d) IV > III > I < II
The electrolyte most effective for bringing about coagulation

of Fe (OH)3 sol is
(a) K4[Fe(CN)6]
(b) BaCl2
(c) NaCl
27.
32.
(d) None
The reaction of CH3 CH = CH
OH with HBr
gives
(a) CH3CH = CH
Br..
33.
Drops of water fall from the roof of a building 9m high at

regular intervals of time. The first drop reaching the ground
at the same instant fourth drop starts its fall. What are the
distances of second and third drops from roof ?
(a) 6m & 3m
(b) 4m & 2m
(c) 6m & 2 m
(d) 4m & 1m
A 55 gm tennis ball strikes the ground and rebounds back. If

its velocities are 5 m/s and 4 m/s before and after the collision
respectively then the impulse imparted will be
(a) 0.495 Ns
(b) 0.495 Ns
(c) 495 Ns
(d) 495 Ns
The time taken by a body in sliding down a rough inclined

plane of angle of inclination 45 is n times the time taken by
the same body in slipping down a similar frictionless plane.
The coefficient of dynamic friction between the body and
4
the plane will be
34.
(a) 1/(1n2)
(b) 1 (1/n2)
(c) {1 (1/n2)}
(d) {1/(1n2)}
39.
A small ball of mass m is allowed to slip down from the top of

a hemispherical dome of radius R. At what height h from the
lower end the ball will leave contact with the dome ?
m
R
35.
40.
(a) 2R / 3
(b) R / 2
(c) R / 4
(d) R / 6
Three particles of equal mass m are situated at the vertices

of an equilateral triangle of side L. What should be the
velocity of each particle so that they move on a circular path
without changing L?
(a) (GM/2L)
36.
37.
41.
(b) (GM/L)
(c) (2GM/L)
(d) (GM/3L)
Two masses M & m situated at infinite distance apart are at
rest. Due to mutual interaction they start approaching each
other, the relative velocity of the system when the distance
between them is r, will be
(a)
2Gr
M+m
(b)
(c)
2G ( M + m )
r
(d)
42.
2Gr
M+m
2G (M + m)
r
43.
A wheel is rolling straight on ground without slipping. If the

axis of the wheel has speed v, the instantenous velocity of a
point P on the rim, defined by angle q, relative to the ground
will be
P
not a correct explanation for Statement-1.

(c) Statement-1 is true, Statement-2 is false.
(d) Statement-1 is false, Statement-2 is true.
Suppose the gravitational force varies inversely as the nth
power of the distance. Then the time period of a planet in
circular orbit of radius R around the sun will be proportional
to
(a) Rn
(b) R-n
(n+1)/2
(c) R
(d) R (n-1)/2
At a specific temperature, the energy densities for a black
body for three different wavelengths are 10, 19 and 7 units.
For these wavelengths if the absorption coefficient of a body
is respectively 0.8, 0.3 and 0.9 then the emissive powers of
this body for these wavelengths are in the ratio
(a) 10:19:7
(b) 8:3:9
(c) 8:5.7:6.3
(d) 8:9.5:4.3
A mixture of two gases X and Y is enclosed, at constant
temperature. The relative molecular mass of X, which is
diatomic, is 8 times that of Y which is monoatomic. What is
the ratio of the r.m.s speed of molecules of Y to that of
molecules of X?
(a) 2
(b) 22
(c) 4
(d) 8
A Carnots engine works as a refrigerator between 250 K
and 300 K. If it receives 750 calories of heat from the reservoir
at the lower temperature, the amount of heat rejected at the
higher temperature is
(a) 900 cal.
(b) 625 cal.
(c) 750 cal.
(d) 1000 cal.
The figure shows a process on a gas in which pressure and
volume both change. The molar heat capacity for this process
is C. Then
38.
(a)
1
v cos q
2
(b)
1
2 v cos q
2
(c)
v(1 + sin q)
(d)
v(1 + cos q)
Statement 1 : The tyres of aircrafts are slightly conducting.

Statement 2 : If a conductor is connected to ground, the
extra charge induced on conductor will flow to ground.
(a) Statement-1 is true, Statement-2 is true; Statement-2 is
a correct explanation for Statement-1.
(b) Statement-1 is true, Statement-2 is true; Statement-2 is
44.
(a) C = 0
(b) C = Cv
(c) C > Cv
(d) C < Cv
A charge Q is distributed over two concentric hollow spheres
of radii r and R (>r) such that the surface densities are equal
and placed on the same axial points. Then the potential at
the common centre is
(a)
Q(R 2 + r 2 )
4pe 0 (R + r )
(c) Zero
(b)
(d)
Q
R+r
Q(R + r)
4pe 0 (R 2 + r 2 )
5
45.
46.
Statement-1 : A paramagnetic sample display greater

magnetisation (for the same magnetic field) when cooled.
Statement-2 : The magnetisation does not depend on
temperature.
If a battery is connected across series combination of a
capacitor and a resistor, at t = 0. If at an instant t potential
difference across the capacitor be V and energy stored in it
be U. Then which of the following graph is correct.
U
(b)
O
47.
48.
49.
(c)
50.
54.
(d)
O
A cell of e.m.f. E is connected across a reistance R. The

potential difference between the terminals of the cell is found
to be V. The internal resistance of the cell must be
(a) [2(EV)V]/R
(b) [2(EV)/V]R
(c) [(EV)/V]R
(d) (EV)R
A charge +q is taken around a long charged cylinder carrying
a charge of l per unit length. The total work done is
(a) zero
(b) 4pl/e0 (c) l/e0
(d) l/4pe0
Two straight lon g conductors AOB an d COD ar e
perpendicular to each other and carry currents I1 and I2
respectively. The magnitude of the magnetic induction at a
point P at a distance a from the point O in a direction
perpendicular to the plane ABCD is
(a)
52.
m0
(I1 + I 2 )
2 pa
(b)
m 0 2 2 1/ 2
I1 + I 2
2pa
(d)
m0
(I1 I 2 )
2 pa
m 0 I1I 2
2 pa I1 + I 2
The mutual inductance of a pair of coils, each of N turns, is

M henry. If a current of I ampere in one of the coils is
brought to zero in t second, the emf induced per turn in the
other coil, in volt, will be
55.
NMI
t
(c)
MN
It
(d)
MI
Nt
In a series resonant circuit, having L, C and R as its elements,

the resonant current is i. The power dissipated in the circuit
at resonance is
i 2R
(c)
(b)
(a)
1
wL
53.
O
51.
(a)
MI
t
(a)
(b) zero
wC
(c) i2wL
(d) i2R
Two different coils have self inductances L1 = 8 mH and
L2 = 2 mH. The current in one coil is increased at a constant
rate. The current in the second coils is also increased at the
same constant rate. At a certain instant, the power given to
the two coil is the same. At that instant of time, if W1 and W2
are the energies stored in the first and the second coil,
respectively, the W1 : W2 is
(a) 1 : 2
(b) 2 : 1
(c) 4 : 1
(d) 1 : 4
56 tuning forks are so arranged in series that each fork gives
4 beats per sec with the previous one. The frequency of the
last fork is 3 times that of the first. The frequency of the first
fork is
(a) 110
(b) 56
(c) 60
(d) 52
Two slits separated by a distance of 1 mm are illuminated
with red light of wavelength 6.5 107 m. The interference
fringes are observed on a screen placed 1 m from the slits.
The distance between third dark fringe & the fifth bright
fringe is equal to
(a) 0.65 mm
(b) 1.63 mm
(c) 3.25 mm
(d) 4.88 mm
Statement 1 : A person is standing near a railway track. A
train is moving on the track. As train is approaching the
person, apparent frequency keeps on increasing and when
train has passed the person then apparent frequency keeps
on decreasing.
Statement 2 : When train is approaching the person then
c
f = f0
and when train is moving away from the
c - u
c
person f = f 0
, c is velocity of sound, u is velocity
c + u
of train and f0 is original frequency of whistle.
6
56.
A lens is placed between a source of light and a wall. It

forms images of area A1 and A2 on the wall, for its two
different positions. The area of the source of light is
(A1A 2 )
(a)
(c)
57.
58.
59.
60.
(b) (A1+A2)/2
A1 + A 2
)2
(d)
1
1
+
A1 A 2
62.
63.
64.
66.
For sky wave propagation of a 10 MHz signal, what should

be the minimum electron density in ionosphere
(a)
~ 1.2 1012 m -3
(b)
~ 106 m -3
(c)
~ 1014 m-3
(d)
~ 10 22 m -3
The counting rate observed from a radioactive source at

t = 0 second was 1600 counts per second and at t = 8 seconds
it was 100 counts per second. The counting rate observed,
as counts per second at t = 6 seconds will be
(a) 400
(b) 300
(c) 200
(d) 150
10
In a npn transistor 10 electrons enter the emitter in 106 s.
4% of the electrons are lost in the base. The current transfer
ratio will be
(a) 0.98
(b) 0.97
(c) 0.96
(d) 0.94
The vernier constant of two vernier callipers A and B are
0.01 cm and 0.01 mm respectively. Which one can measure
the length of an object more accurately?
(a) Vernier A
(b) Vernier B
(c) Accuracy in measurement does not depend on vernier
constant
(d) Both A and B are equally accurate.
MATHEMATICS
61.
65.
(c) c = bm2
67.
68.
(d) c =
m2
18
(a) 6,
5
18
(b) 6,
5
18
(c) 6,
5
18
(d) 6,
5
The locus of the mid points of the chords of the ellipse

x2/a2 + y2/b2 = k, k > 0, making equal intercepts on the
coordinate axes, is
(c)
69.
If tangents be drawn to the cricle x 2 + y2 = 12 at its points of

intersection with the circle x2 + y2 5x + 3y 2 = 0, then the
tangents intersect at the point
(a) x = y
x/a2
(b) x + y = 0
y /b2
(d) x/a2 + y/b2 = 0
I= n/m means that n is a factor of m, then the relation I, is

(a) Reflexive and symmetric
(b) Transitive and symmetric
(c) Reflexive, transitive and symmetric
(d) Reflexive, transitive and not symmetric
70.
n+4C nC 3.nC
n
n
r
r
r1 3. Cr2 Cr3 is equal to
(a) n+1Cr1
(b) n+2 Cr1
n+3
(c)
Cr1
(d) n+4Cr1
The sum of the first three consecutive terms of an A.P. is 9

and the sum of their squares is 35 . The sum to n terms of the
series is
(a) 3n2
(b) 2n2
2
(c) 6n 2n
(d) 6n n2
Let a/(a1) and b/(b1) be the roots of x2 + ax + b = 0. Then
1/a and 1/b are the roots of
(a) bx2 + ax + 1 = 0
(b) bx2 ax + 1 = 0
(c) bx2 + (a + 2b)x + a + b + 1 = 0
(d) bx2 (a + 2b) x + a + b + 1 = 0
For any real q, the maximum value of
cos2(cos q) + sin2(sin q) is
(a) 1
(b) 1+sin21
(c) 1+cos21
(d) 1/2
If tan(A/2), tan(B/2), tan(C/2) are in A.P. then sec A, sec B, sec
C are in
(a) A.P.
(b) G..P.
(c) H.P.
(d) None
The straight line y = mx + c is a tangent to the parabola
x2 = 4by if
(a) c = b/m
(b) c = bm
r 1
r
, r N value
Matrix M r is defined as M r =
r
1
r
of det( M1 ) + det( M 2 ) + det( M 3 ) + .... + det(M2007) is

(a) 2007
(c)
71.
(b) 2008
20082
(d) 20072
2 2
1 -1 1
4
1 - 3 . and (10) B = - 5 0 a .
1 1
1 -2 3
1
Let A = 2
If B is the inverse of matrix A, then a is

(a) 5
(b) 1
(c) 2
(d) 2
1
72.
The value of
(a) 1
lim (4 - 3 sin x - 2 cos 2 x ) 2 sin x -1 is
x p / 6
(b) e
(c) e
(d) e1/2
7
73.
Let f(x) = ( x - 1) 2 ( x - 2) 3 e x . Then

(c)
(a) f(x) has local maximum at x = 1

(b) f(x) has point of inflexion at x = 1
80.
(c) f(x) has local minimum at x = 2

(d) all of these
74.
The derivative of tan1[(3x2 1)/(3x x3)] with respect to

sin 1[(x2 1)/( x2 + 1)] is
(a) 2/3
75.
(b) 2/3
(c) 3/2
(d) 3/23
(a) (0, 1)
76.
77.
(b) (1, 3)
(c) (2, 3)
(d) (1, 2)
81.
A curve y = f(x) passes through the point P(1, 1). The normal
to the curve at P is a (y 1) + (x 1) = 0. If the slope of the
tangent at any point on the curve is proportional to the
ordinate of the point, then the equation of the curve is
(a) y = ea (x 1)
(b) y = ea(1 x)
(c) y = ea/2 (x 1)
(d) ea/2
Value of
(a)
(c)
0 sin
x cos 2m+1 x dx
82.
(2m + 1)!
n!
p
(b)
cos2m +1x dx
(2m + 1)!
3 1
, ,1
2 2
(b) 2 ,1, 2
(c)
1 3
, ,1
2 2
(d) None
(a)
(c)
log(3 + 8e x ) + C
1
log( 3 + 8e x ) + C
2
The primitive of
(a)
(b)
(b)
n1
l2
m2
n2 = 0
l3
m3
n3
(d) None of these

A plane makes intercepts OA, OB, OC whose measures are
a, b, c on the axes x, y, z respectively. The area of the triangle
ABC is
1 2
a + b2 + c2
2
(b)
1
b 2c 2 + c 2 a 2 + a 2 b 2
2
1
1 2
ab + bc + ac
a b + b 2 c + c 2a
(d)
2
2
If x + 2 = 6, then x = 4. So, which statement is its converse?
(c) If x = 4, then x + 2 = 6
84.
(d) none of these
1
cos x - 1
1
2 cos x - 1
+C
log
log
8
cos x + 1 2 2
2 cos x + 1
m1
(b) If x = 4, then x + 2 6
1
log(3 + 8e x ) + C
4
1
sin x - 1
1
2 sin x - 1
+C
log
log
4
sin x + 1
2
2 sin x + 1
l1
(a) If x 4, then x + 2 6
f ( x)
3 + 4f (x ) dx =
sin x
is
sin 4 x
(c)
(d) none of these
If f ( x ) = f ( x) and f (0) = 2, then
The three lines through the origin with direction cosines

l1, m1, n1; l2, m2, n2; and l3, m3, n3 are coplanar, if
(a) l1 (l2 l3) + m1 (m2 m3) + n1 (n2 n 3) = 0
(b) l1(m2n3 m3n2) + m1(n2l3 n 3l2) + n1 (l2m3 l3m2) = 0
(a)
83.
79.
(a)
(c)
(x + 1)
( where m, n N) is
78.
(d) none of these

Let coordinates of a point p with respect to the system of
r r
r
non-coplanar vectors a , b and c is (3, 2, 1). Then
coordinates of p with respect to the system of vectors
r r r r r
r r
r
r
a + b + c , a b + c and a + b c is
If 2a + 3b + 6c = 0 then at least one root of the equation

ax 2 + bx + c = 0 lies in the interval
1
sin x - 1
1
2 sin x - 1
+C
log
log
8
sin x + 1 4 2
2 sin x + 1
85.
(d) If, x 4 then x + 2 = 6

If y = f(x) be a monotonically increasing or decreasing
function of x and M is the median of variable x, then the
median of y is
(a) f (M)
(b) M/2
(c) f 1 (M)
(d) None
A fair die is tossed eight times. The probability that a third
six is observed on the eighth throw is
(a)
(c)
C2
C6
55
68
56
68
(b)
C3
53
68
(d) None
8
86.
87.
r
r
Statement-1 : If a = i + j and b = j - k then
r r r r
( a + b, a - b ) = 90
r r
r r
Statement-2 : Projection of a + b on a - b is zero.
Let A and B are two events such that P(A) = 3/5 and
P(B)= 2/3, then
Statement1 :
Let for real numbers x and y we define the relation R such

that xRy x 2 + y2 = 1
Statement-1 : The relation R is an equivalence relation.
Statement-2 : A relation R is an equivalence relation if it
is reflexive, transitive and symmetric.
4
3
P ( A B) .
15
5
Statement 1
1 4 - 1
2 3 0
: The rank of
is 3
0 1 2
Statement 2
1 4 - 1
2 3 0
: The determinant of the matrix
0 1 2
Statement2 : 5 P B 10
88.
89.
90.
Let X1 and X2 are means of two distributions such that
is not equal to zero.
X1 < X 2 and X is the mean of the combined distribution.

Statement-1
Statement-2 :
X1 < X < X 2
X1 + X 2
X=
2


HINTS AND EXPLANATIONS

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
1.
2.
3.
4.
5.
(d)
(c)
(c)
(b)
(c)
(b)
(d)
(b)
(c)
(b)
(b)
(d)
(c)
(b)
(a)
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
(b)
(c)
(d)
(b)
(c)
(d)
(d)
(b)
(d)
(d)
(a)
(b)
(a)
(a)
(c)
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
ANSWER KEY
(d)
46
(a)
47
(b)
48
(a)
49
(b)
50
(d)
51
(b)
52
(b)
53
(c)
54
(c)
55
(b)
56
(a)
57
(c)
58
(d)
59
(c)
60
(d) This type of isomerism occurs when both cation and

anion are complex. The isomerism is caused by the
interchange of ligands between the two complex ions
of the same complex. Examples are
(i) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6][Co(CN)6]
(ii) [Co(NH3)6] [Cr(C2O4)3] and [Cr(NH3)6][Co(C2O4)3]
(c)
(d)
(d)
(b)
(c)
(c)
(d)
(c)
(d)
(d)
(a)
(d)
(a)
(c)
(a)
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
Ht
7.
(d)
H 2C - CH - CH 2
|
|
|
CN CN CN
3-Cyano-1, 5-pentadinitrile
(b) Structure of B2H6 is as follows:
Ht
Ht
B
Ht
Hb
Ht
6
(c) Mol. of O2 =
& mol. of SO2 = 6 . The number of
32
64
molecules of SO2 will be less than that of O2.
(b) Atomic mass of carbon is less and hence no. of moles
will be more.
(c) W2 = 4g, V = 1000 mL = 1 L, p = 6.0 104 atm
T = 300K, R = 0.0821 Latm. K1 mol1
p = W2RT/(M2V)
\ M2 = 4 0.0821 300/ (6 1014 1) = 16.42 104
= 1.6 105
(b) NH2CONH2 + NH2 NH2

NH2NHCONH2 + NH3
(Semicarbazide)
(a)
(d)
(b)
(c)
(a)
(c)
(b)
(c)
(a)
(a)
(b)
(b)
(d)
(a)
(b)
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
Hb
h
(c) The expression is Lz = m
2p
6.
8.
(a)
(c)
(a)
(c)
(a)
(d)
(d)
(a)
(b)
(d)
(a)
(a)
(c)
(c)
(b)
Ht
Hb
B
or
1.19
Ht
97
1.33
Hb
121.5
Ht
1.77
Thus the diborane molecule has four two-centre-twoelectron bonds (2c2e bonds) also called usual bonds
and two three-centre-two-electron bonds (3c2e) also
called banana bonds. Hydrogen attached to usual and
banana bonds are called Ht (terminal H) and Hb
(bridged H) respectively.
9.
(c) Polyacrylonitrile (PAN), acrilan or orlon

CN
|
CN
|
n CH 2 = CH
(CH 2 - CH)-n
Acrylonitrile
orlon
It is hard used in preparing cloths, carpets.
10
10.
D
(b) 3Mg+ N 2
Mg3 N 2 ;
X
CH 3
O
LiAlH
H
H 2O
Mg 3 N 2 + 6H 2 O
3Mg (OH ) 2 + 2 NH 3
( colourless )
C2 H5
[Cu ( NH 3 ) 4 ] SO 4
CuSO 4 + 4 NH 3
Blue complex
11.
12.
13.
14.
15.
(b) The metallic halide (Lewi acid) polarises the halogen

molecule to yield the electrophite X+ (halonium ion)
FeBr4 + Br +
FeBr3 + Br2
(d) [Zn(NH3 )4 ]2+, Ni(CO)4 & [Cd(CN) 4 ]2 all form
tetrahedral structures where the central atom uses sp3
hybridisation.
Whereas [Cu(NH3)4]2+ uses dsp2 hybridisation and
forms square planar structure. Although Cu should use
both tetrahedral (sp 3 ) & square planar (dsp 2 )
hybridisations but the later one is confirmed through
X-ray analysis.
(c) Diallyl ether has double bond which shows addition
reaction with KMnO4 (change its colour) while di-npropyl ether does not react with KMnO4.
(b) Mn2+ (3d 5) is more stable then Mn 3+ (3d 4). due to half
filled orbitals.
(a)
Mg
ether
CH3
5
6
21.
22.
CH3CH 2CH 2 Cl CH3CH 2 CH 2 MgCl

Grignard reagent
(1) HCHO
+ CH3 - CH 2 - CH 2 - CH 2 - OH
(2) H3O
16.
17.
18.
19.
Primary alcohol
(b) Total pressure of mixture of gases A,B & C = 10atm.

Partial pressure of A = (No. of moles of A 10)/ 10
or (No. of moles of A 10)/ 10 = 3
Hence, no. of moles of A = 3
\ Partial pressure of B = (No. of moles of B 10)/ 10
(since partial pressure of B = 1atm)
\ No.of moles of B = 1
Now the no. of moles of C = 10 ( 3+1) = 6;
1 mole of C weighs = 2 gm.
\ 6 mole of C will weigh = 2 6 = 12
(c) Reduction of aldehydes and ketones with Zn(Hg)/HCl
yields alkanes (Clemmensen reduction)
(d) The statement (d) is applicable only at 25 C and is not
independent of temperature.
(b) (1.5)n = 1.837, n =
23.
OH
H
(d) As3+ and Cd2+ are the radicals of group II, whereas
Ni2+ & Zn2+ are the radicals of group IV. The solubility
product of group IV radicals is higher as compared to
group II. NH4OH increases the ionisation of H2S by
removing H+ of H2S as unionisable water.
H 2 O
H2S
2H+ + S2; H + + OH -
Thus, excess of sulphide ions are present which leads
to the precipitation of all the four ions.
Note : HCl decreases ionisation of H2S whereas NH4OH
increases the ionisation of H2S.
(d) The maximum concentration of SO42 will be same as
the solubility of M2SO4 ;
If solubility is x mol L1 M2SO4

2M+ + SO42
1/3
3
Ksp =4x , therefore x = (Ksp /4)
[SO42] = x = (Ksp /4) 1/3 = [(3.2 105)/4 ] 1 / 3
= 2 102 M
(b) The reaction proceed through Markownikoffs rule by
ionic mechanism. The initial carbonium ion
24.
25.
26.
27.
(d) Elements after lanthanum i.e. from Ce (58) to Lu (71) are

all lanthanides. Atomic number of Terbium is 65 and
hence it is a lanthanide not an actinide.
(d) NO2 group is electron withdrawing, and hence III and
IV are strong acids whereas CH3 is electron releasing
group, hence I is less acidic than the others.
(a) Fe(OH)3 is positive sol. K3[Fe(CN)6] will provide
[Fe(CN)6]4 for coagulation.
(b) Of the two possible carbocations, benzylic type (II) is
more stable than the I.
+
......(I)
CH3CHCH2
OH
+
CH3 CH2CH
O
||
C
C2 H 5
OH
28.
(a) When pH = 14 [H + ] = 10 -4 and [OH - ] = 1 M

2+
- 2
Ksp = [Cu ] [OH ] = 10 -19
LiCu (CH )
3
2
H
H 2O
......(II)
hence bromination occurs on 3rd C atom
C2 H 5
(CH3 C HCH3 ) carbonium ion.
log 1.837
=1 . 5
log1.5
OH
NaOH, H O
(c)
(CH 3CH 2 C H 2 ) rearrange into more stable
O
20.
\ [Cu 2+ ] =
10 -19
- 2
[OH ]
= 10 -19
11
The half cell reaction
Cu 2+ + 2e -
Cu
E = E
0 .059
1
log
2
[ Cu 2+ ]
= 0.34
29.
(a)
34.
For our case we get n = [g sin q /(g sin q mg cos q)]

n2 = g sin q /(g sin q - mg cos q) = 1/(1 m cot q)
But q = 45
cot q = 1 \ n2 = 1 /(1 m) or m = 1 (1/n 2)
(a) If the contact is lost at P, the velocity v would be
2g ( R - H ) (PE lost = KE gained)
v=
0.059
1
log -19 = 0.22 V
2
10
CH2
CH +
(A)
CH
CH2
2NBS
v2
= g cos q
R
Br
alc. KOH
2HBr
Tetralin (C)
(Centripetal force =
mv 2
)
R
v 2 = 2g(R - h ) = Rg cos q
Br
Thus,
(B)
2H2 Pd
2g ( R - h )
h Q cos q = h
= g
R
R
R
2g(R - h ) = gh or 2gR = 3gh h =

35.
Naphthalene
30.
(b) The resultant gravitational force on each particle

provides the necessary centripetal force.
C
(c) Emetal = (Wt of metal 96500)/No of coulombs

=
fAC
(22.2 96500)
59.5
(2 5 60 60)
For second drop, h =
1
10 0.88 0.88 = 4.05 m.
2
1
10 0.4 0.4 = 1.05 m.
2
(a) Impulse = Change in momentum
= Final momentum Initial momentum
= [ 0.055 ( 4)] [ 0.055 5]
= 0.055 9 = 0.495 N/sec
(b) Acceleration when there is no friction is a = gsinq and
acceleration when friction is there is
a = (g sin q mg cos q)
1
We know that s = ut + at2, under condition of u = 0,
2
gives, t = (2s/a).
Therefore, t'/ t = (a / a' ).
A m
33.
36.
W=
37.
m
B
\ mv2/r = (F2 + F2 + 2F2cos 60) = 3 F

But r = (3 L/2) (2/3) = 1 / 3
\ mv23 / L = 3GM2 / L2 v =(GM/L)
(d) Accordin g to law of con servation of energy,
For third drop : h =
32.
O
F
177
= +3
59.5
(d) Let t be the time interval between the drops.
3t = 1.34 t = 0.44 sec.
Oxidation no. of metal =
31.
2
R
3
(b)
GMm 1 mM 2
=
v or v =
r
2 m+M
v R = v2 + v2 + 2v 2 cos q
v
qv
q
= 2v2 (1 + cos q) = 2v cos
q
2
2G(M + m )
r
12
38.
39.
(b) During take off and landing, the friction between tyres
and the run way may cause electrification of tyres. Due
to conducting nature of tyre, the charge so collected to
a ground and electrical sparking is avoided.
(c)
2pR
2GM
T=
..... (1); V =
v
R n -1
E=
2pR
2GM
R
40.
1/ 2
.....(2)
2p
2GM
42.
V2
M
47.
y
x
V = M
y
x
V=
3RT
M
My
Vx
=
Vy
8M y
Vy
Vx
V = E Ir or r =
1 q1 q 2
( + )
4pe 0 r
R
(a) The workdone in moving a charge along an

equipotential surface is zero.
49.
(c)
q1
4pr 2
R2
or
q
=
q
2
1 2
4p R 2
r
q2
1
q
1 q1
R
1 (r + R )
( + q1 ) =
V=
2
4pe o r 2
4pe o r
r
B due to AOB and COD are ^ to each other. Hence,
net B
50.
(a)
= B12 + B 22
B=
m 0 2 2 1/ 2
( I1 + I 2 )
2pa
E=
d
dI
NMI
( NMI ) E = NM
E=
dt
dt
T
( ^ to plane ABCD)
Emf induced per unit turn =
As surface densities are equal, hence

s=
E - V E - V
=
R
V
I
48.
Q2
1 Q - 750
= 1
Q1
6
Q1
(c) According to graph, pressure is increasing, also volume

is increasing hence T also increases. It means that
energy is used both in increasing internal energy and
work done nCdt = nCvdt +PDV
\ C > Cv
(d) Let the charges on spheres of radii r and R be q1 and q2
respectively. Then, Q = q1+q2. The potential at the
centre will be :
(c) Let r be the internal resistance of the cell.

Terminal potential difference (V) < EMF of a cell (E).
=2 2
T2 300 - 250 50 1
=
=
=
(a) We know that h = 1 T1
300
300 6
V=
R+r
2
R + r2
Q
4 pe0
Q1 = 6Q1 4500 5Q1 = -4500 Q1 = 900 Cal
44.
;V=
3
8
9
:
19 : 7
10
10 10
10
or h = 1 -
43.
R + r2
1
CV2
2
From this, we get U V2
8 : 5.7 : 6.3
(b)
Q
2
(a) U =
a1 1 : a2 2 : a33
41.
46.
Therefore, T R (n +1) / 2
(c) Emissive power = a
=Q
(c) A paramagnetic sample display greater magnetisation

when cooled, this is because at lower temperature, the
tendency to disrupt the alignment of dipoles (due to
magnetising field) decreases on account of reduced
random thermal motion.
R (n +1) / 2 .
n -1
q1
r2
45.
1
GMm
mv 2 =
2
R n -1
From (1) & (2), T =
R2
Now, q1 + q2 = Q or q1 + q1
51.
(d) At resonance Lw =
E MI
=
N
t
1
, w=
Cw
Current through circuit i =
1
LC
E
R
Power dissipated at Resonance = i2R
13
52.
(d)
E = -L
dI
1
; W = LI 2
dt
2
We know that E = Hence,
Collector current, I C =
\ Current transfer ratio,
LdI
As dI is same,
dt
dt
E1 L1
=
=4
E 2 L2
a=
53.
54.
55.
56.
(a)
(b)
(b) Lower the vernier constant, more accurate measurement

is possible by it.
61.
(c)
n +4
C r - n +1C r +n +1 C r -1 + n +1 C r -1 + n +1 C r - 2
nlast = n first + ( n - 1) d 3n = n + ( 56 - 1) 4
or 2n = 55 4 n = 110Hz
= n + 4 C r - n + 2 C r + n + 2 C r -1
l D 6.5 10 7
b=
=
1 = 0.65 103 = 0.65 mm
2d
10-3
= n + 4 C r - n +3 Cr = n +3 C r -1
62.
(d)
The distance between fifth bright fringe from third dark

fringe = 2.5 b = 2.5 .65 = 1.63 mm.
(d) Statement-2 is correct and statement-1 is false.
(a) By displacement method, the size of object is given by
18 + 2d 2 + 9 = 35 d 2 = 4 d = 2
n
( 2a - 2d + nd - d )
2
Taking d = 2, we get
(Q d = 2 will not give any option)
S=
I1 I 2 ;
(a) The critical frequency of a sky wave for reflection from
10 106 = 9(N max )1/ 2
63.
6 2
10 10
12 -3
N max =
; 1.2 10 m
(c) After 8 sec., the counting rate falls to

4
100
1 1
=
= th Part ;
1600 16 2
Time period =
8
sec. = 2 sec.
4
Therefore, after 6 seconds, the counting rate should be

3
1
1
1600 = 200 .
th part of 1600, i.e.
8
2
(c) No. of electrons reaching the collector,

nC =
a -d +a +a +d = 9 a = 3
(a - d) 2 + a 2 + (a + d) 2 = 35
a layer of atmosphere is given by f c = 9(N max )1/ 2
59.
C r - (n C r +3.n C r -1 +3.n C r - 2 + n C r -3 )
+ (n C r -1 + n C r - 2 ) + ( n C r - 2 +n C r -3 )
\ A = A1 A 2
58.
n +4
= n + 4 C r - (n C r +n C r -1 ) + (n C r -1 + n C r -2 )
W1
L I
1 1
= 1 1 = 4 =
W2 L 2 I 2 2
16 4
O=
57.
IC n C
0.96 1010
=
=
= 0.96
IE nE
1010
60.
Power is constant so E 1I1 = E 2 I 2 ;

E1 I 2
1
=
= 4 We know that W = LI 2 ;
E2
I1
2
nC e
t
96
1010 = 0.96 1010
100
Emitter current, I E =
nE e
t
64.
n
S = [6 - 2n + 6] = 6n n2
2
(d) Let a' = a/(a 1), b' = b/(b 1)
a = a'/(a' 1), b = b'/(b' 1)
1/a = (a' 1)/a', 1/b = (b' 1)/b'
Then equation whose roots are 1/a, 1/b, is
x2 (1/a + 1/b)x + 1/ab = 0
x2 [(a' 1)/a' + (b' 1)/b'] x + [(a' 1) (b' 1)] / a'b' = 0
a'b'x2 [2a'b' (a' + b')]x + a'b' (a' + b') + 1 = 0
bx2 (a + 2b)x + a + b + 1 = 0
(b)
f (q) = cos 2 (cos q) + sin 2 (sin q)
Now, put q = p /2 & 0

f (0) = cos 2 1 + 0 = cos 2 1
f (p / 2) = 1 + sin 2 1
Since, sin 2 1 > cos 2 1

[Q sin q > cos q "
p
p
p
< q< &1> ]
4
2
4
Now, seeing the options 1 + sin21 is greater than all

other options.
14
65.
(c) tanA/2, tanB/2, tanC/2 are in A.P.

tanA/2 tanB/2 = tanB/2 tanC/2
4 -5 1
Cofactor Matrix C = 2 0 -2
2 5 3
sin A / 2 sin B / 2 sin B / 2 sin C / 2

=
cos A / 2 cos B / 2 cos B / 2 cos C / 2
cos(C/2)sin(A/2 B/2) = cosA/2 sin (B/2 C/2)
2 2
4
\ Adj A = C = - 5 0 5
1 - 2 3
cos B - cos A = cosC - cosB
66.
2cos B = cos A + cos C

secA, secB, secC are in H.P.
(c) Solving y = mx + c with x2 = 4by, we get,
x 2 = 4b ( mx + c ) x 2 - 4bmx - 4bc = 0
\A
-1
Hence, discriminant = 0
67.
68.
69.
70.
16b 2 m 2 + 16bc = 0 c = - bm 2
(d) Let the point of contact be (h,k); equation of chord of
contact is T = 0
..(1)
xh yk 12 = 0
Equation of common chord C1 C2 = 0
. (2)
5x 3y 10 = 0
(1) and (2) represent the same line
h/k = k/(3)= 12/(10)
h = 6.k = 18/5
(c) The equation of chord having (x1,y1) as its mid-point
is
(xx1/a2)+ (yy1/b2 ) k = (x12/a2) + (y12/b2) k
(xx1/a2) + (yy1/b2 ) = (x12/a2) + (y12/b2)...(1)
It makes equal intercepts on the axes when
(a2/x1) = (b2/y1) (x1/a2) (y1/b2 ) =0
Hence the locus of (x1, y1) is (x/a2) = (y/b2 )
(d) I is reflexive since every natural number is a factor of
itself, that is n/n for n N. I is transitive since if n is a
factor of m and m is a factor of p, then n is surely a
factor of p. thus n/m and m/p n/p. However I is
not symmetric since, for example, 2 is factor of 4 but 4 is
not a factor of 2.
(d) det (Mr) =
= 2
(a)
72.
| A |= 1 4 + (-1) -5 + 11 = 10
1/(2 sin x -1)
sin x -1
= e -1/ 2
74.
(c)
3x 2 - 1
y = tan -1
3x - x 3
3x - x 3 p
p
= + 3 tan -1 x
- tan -1
3x 2 - 1 2
2
dy
3
=
dx 1 + x 2
x 2 -1 p
2
= - cos -1 x - 1 = - p + 2 tan -1 x
u = sin -1
x2 +1 2
x 2 +1
2
du
2
=
dx 1 + x 2
dy dy du 3
=
=
dx du dx 2
2007 2008
- 2007 = (2007)2
2
4, - 5, 1; 2, 0, - 2; 2, 5, 3
(4 - 3sin x - 2 cos2 x )
(a) f(x) = (x 1)2 (x 2)3 ex

f '(x) = (x 1) (x 2)2(x2 + 2x 5)ex
f(x) has local maximum at x = 1, since f '(x) changes
from positive to negative.
f(x) has a point of inflexion at x = 2.
r =1
Cofactors of various entries are
lim
x p / 6
73.
r - 2007
1 - 1 1
A = 2 1 - 3
1 1
1
(d)
lim {1 + (2sin x - 1)(sin x - 1)}

x p / 6 1
(2sin x - 1)(sin x - 1)
2007
det (M r ) = 2
r =1
71.
Comparing , we get a = 5
r
r -1
= 2r - 1
r -1 r
2007
2 2
4
AdjA 1
=
=
- 5 0 5
| A | 10
1 - 2 3
75.
(a) Let f(x) = ax 2 + bx + c

g ( x) = f ( x ) =
\ g(1) =
ax 3 bx 2
+
+ cx
3
2
a b
+ + c = 2a + 3b + c = 0
3 2
g(0) = 0 = g(1)
15
\ g(x) is continuous apply Rolles theorem
Put sin x = t cos x dx = dt
g( x) = 0 for some value
76.
x (0,1) g' (x ) = f ( x) = ax 2 + bx + c = 0
has a root in (0, 1)
(a) Slope of the normal at (1, 1) is 1/a
Slope of the tangent at (1, 1) is a
dy
i.e., dx
=a
(1, 1)
dt
1
\I =
=
4
4(1 - t 2 )(1 - 2t 2 )
1
t1 1
t -1
1
2
= log
log
1
4 2
t +1
2
t+
...... (1)
We are given that
dy
dy
y;
= ky,,
dx
dx
80.
dy
where k is some constant y = k dx
log | y | = kx + c, where c is a constant

| y | = ekx + c
y = ec ekx = Aekx, where A is a constant.
Since the curve passes through (1, 1),
therefore, 1 = Aek A = ek
Therefore, y = ek . ekx = ek (x 1)
dy
= kek (x 1)
dx
dy
dx
=k a=k
(1, 1)
(d)
x + y + z = 3, x - y + z = 2, x + y - z = 1
On solving, we get
[Using (1)]
x=
I = sin n x cos2m +1 x dx
0
p
= sin (p - x).cos
n
2m+1
= - sin x cos
n
2m+1
(p - x) dx
81.
x dx = -I I = 0
Similarly, one can show that

p
0 cos
78.
2m+1
x dx = 0
(b) Since, f ' (x) = f (x), therefore, f (x) = aex.

Since, f (0) = 2, therefore, f (x) = 2ex.
dx
3 + 8e x
Put ex = t, \ dt = ex dx
\ I = 2
79.
(c)
1
dt
I = log(3 + 8e x ) + C
3 + 8t
4
sin x
I=
sin 4x dx
I=
2 sin 2x cos 2x dx = 4 cos x cos 2x
sin x
cos x
2
4(1 - sin x )(1 - 2 sin 2 x )
dx
82.
3
1
, y = ,z =1
2
2
3 1
Hence the new co-ordinates of point P are , ,1
2 2
(c) If the given lines are coplanar, then a line which is normal
to the plane in which they lie, will be perpendicular to
all the three given lines. Let the direction cosines of the
normal be l, m, u.
\ ll1 + mm1 + un1 = 0, ll2 + mm2 + un2 = 0,
ll3 + mm3 + un3 = 0. Eliminating l, m, u from these
equations,
ex
\ I = 2
+C
(a) Any vector (x, y, z) can be represented as a linear

combination of three non coplanar vectors.
r r
r
OP = xa + yb + zc
r r
r
r
But P is (3, 2,1) OP = 3a + 2b + c
Now if coordinate axis changes then the vector is
represented by
r r r
r r r
r r r
x(a + b + c ) + y (a - b + c ) + 2(a + b - c )
r r r
= 3a + 2b + c
r r r
Comparing coeff of a, b & c , we get
Thus, the required curve is y = ea (x 1).

77.
1
1
2
dt
2 1
t
1
t
l1
m1
n1
we get, l 2
l3
m2
n2 = 0 .
m3
n3
(b) Let OP be the normal from

O to the plane of DABC,
let l, m, n be the direction
cosines of OP
Let s be the area of DABC.
Therefore,
OAC = Projection of DABC on zx plane = s.m.
But OAC is a right angled triangle, so that area of
DOAC =
dx
1
a.c.
2
ac
1
ac = s.m. m = . Similarly, in DOBC,
2s
2
16
86.
bc
ab
and in D OAB, n =
2s
2s
Since, l2 + m2 + n2 = 1
(b) Statement 1 :
l=
+ k)
r r r r
(i + 2j - k).(i
1+ 0 -1
cos (a + b, a - b) =
=
= 0;
6 2
12
ac bc ab
+ + =1
2s 2s 2s
1
b 2 c 2 + c 2a 2 + a 2 b 2
2
(c) x + 2 = 6 x = 4, Its converse is x = 4 x + 2 = 6 i.e. if
x = 4 then 4 + 2 = 6
s=
83.
84.
(a)
r r r r
(a + b, a - b) = 90
Statement 2 :
87.
r r r r
(a + b).( a - b)
0
=
=0
r r
|a-b|
2
(b) Q P ( A B) = P ( A) + P ( B) - P ( A B) P(A) + P(B) 1
\ P(A B)
4
3 2
+ - 1 P(A B)
.. . (i)
5 3
15
Q P(A B) P(A) P(A B)

4
3
P ( A B)
15
5
Since, x1 < x 2 f (x1) < f (x 2 ) if x1 ,x 2 ,---,x n are in

ascending order
85.
C2 (55 )
68
From (iii), 15P B

( )
88.
. . .(iii)
P ( A B)
3
P ( B)
5P ( B)
2
A 9
P
B 10
5
(d) If n1 and n 2 are the numbers of items in the two

distributions then X =
89.
n1 X1 + n 2 X 2
n1 + n 2
(a) Clearly the relation is not reflexive, neither transitive. It

is only symmetric.
1 5 1
( 7 C2 p2 q5 )(p) = (7 C2 )
6 6 6
. . . (ii)
From (i) and (ii),
f(x1 ),f(x 2 ),---f(x n ) are also in ascending order..

If M is the median along x, then f (M) is the median
along y
(a) The required event occurs if two sixes are observed in
the first seven throws and a six is observed on the
eighth throw. If p is the probability that a six shows on
the die, the number of throws n is 7, and X is the number
of times a six is observed, then X ~ B(7,p). Therefore
the required probability equals P(X = 2) times the
probability of getting a six on the eighth throw, i.e., it
equals
3
5
90.
(b)
1 4 -1
2 3 0 = 1[6] 4 [4] 1 [2] 0
0 1 2
\ Rank = 3

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ABOUT DISHA PUBLICATION

Question No. 1 to 30 are of 4 marks each.

Physics (120 marks)

Question No. 31 to 60 are of 4 marks each.

Mathematics (120 marks) :

Question No. 61 to 90 are of 4 marks each.

Max. Marks : 360

Which one of the following is an example of co-ordination

(b) more number of carbon atoms

The solution containing 4.0 % PVC in one litre of dioxane

(b) 3.0 102

(c) 1.6 105

Urea and hydrazine react to form ammonia gas along with

The I.U.P.A.C. name of CH 2 - CH - C H 2 is

(c) CH3CH2CH2MgCl, H3C C OH

(d) CH3CH2CH2MgCl, CH3CH2OCH2CH3

(d) all six identical bonds.

The repeating units of acrilan are

Alcohols can be obtained from all methods except

(c) reduction of aldehyde/ketones with ZnHg/HCl

(d) fermentation of starch

During bromination of benzene in the presence of FeBr 3 the

(d) Br2 molecule

A and B in the reaction,

(d) For a neutral solution [H+] = [OH] = 107 M at all

(c) Cold dilute KMnO4 solution

(c) Fe2+ > Fe3+

K w and [OH - ] <

(c) For an alkaline solution

(b) Mn2+ > Mn3+

(b) For an acidic solution

Di-n-propyl ether and diallyl ether can be distinguished by

(a) Ti3+ > Ti4+

Which of the following expressions is not true ?

Which of the following has a shape different from others?

(b) Sodium Metal

A gaseous mixture of three gases A, B and C has a pressure

A metal X on heating in nitrogen gas gives Y.Y on

(a) Acetic acid

For a chemical reaction X Y, the rate of reaction increases

The final product of the following sequence of reactions

(a) CH3CH2CH2MgCl, CH3CH2CH2CH2OH

A solution containing As3+, Cd2+, Ni2+ and Zn2+ is made

(b) CdS, NiS and ZnS

(c) NiS and ZnS

(d) Sulphide of all ions

M2SO4 (M+ is a monovalent metal ion) has a Ksp of 3.2 105

could be attained in a saturated solution of this solid at 298

(c) 2.89 104 M

The intermediate formad during the addition of HCl to

In the following compounds,

Which of the following is not an actinide?

The standard reduction potential for Cu2+/Cu is + 0.34.

the order of acidity is

(a) III > IV > I > II

(b) I > IV > III > II

(c) II > I > III > IV

(d) IV > III > I < II

The electrolyte most effective for bringing about coagulation

The reaction of CH3 CH = CH

Drops of water fall from the roof of a building 9m high at

A 55 gm tennis ball strikes the ground and rebounds back. If

The time taken by a body in sliding down a rough inclined

A small ball of mass m is allowed to slip down from the top of