Beruflich Dokumente
Kultur Dokumente
7, JULY 2012
I. INTRODUCTION
[ISSN: 2045-7057]
II.
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46
q e [(C o
C e ) V / m]
% Adsorbed
III.
[(C o
(1)
C e ) / C o ] x 100
(2)
Activated
Carbon wt
%
OPF
EFB
OPS
NPN
PPN
[ISSN: 2045-7057]
Moisture
content wt
%
3.43
3.22
2.15
4.80
4.10
Volatile
matter wt
%
23.61
22.42
20.3
24.60
18.14
Ash
content
wt %
4.39
4.0
3.0
3.88
3.30
Fixed
carbon
72.0
73.58
76.67
71.52
78.56
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Bulk
Density,
g/cm3
0.56
0.58
0.64
0.53
0.61
pH
6.6
6.7
6.7
6.9
6.8
Iodine
number
(mg/g)
676.88
802.45
810.75
815.62
785.78
Surface
area
(m2/g)
715.63
850.11
863.42
871.22
820.37
47
% Adsorbed
80
70
NPN
PPN
60
EFB
OPF
50
OPS
40
30
20
10
0
0.5
1.5
2.5
Adsorbent dosage, g
Fig. : Effect of adsorbent dosage on the adsorption of Cu 2+ on the adsorbents
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48
F. Isotherm Studies
120
NPN
PPN
EFB
OPF
OPS
100
% Adsorbed
80
60
40
20
qe
0
0
100
200
300
400
500
600
700
800
b Ce
1 b Ce
(3)
Ce
qe
1
Ce
Qo
RL
1
1 bCO
(5)
100
80
NPN
PPN
EFB
OPF
OPS
60
(4)
120
% Adsorbed
1
Qob
40
20
0
0
20
40
60
80
100
120
140
160
180
200
Fig. 2:
contact
on the of
adsorption
Cu on the
Fig. 5: Effect
of Effect
contactoftime
on thetime
adsorption
Cu2+ on theofadsorbents
adsorbents
[ISSN: 2045-7057]
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49
K F Ce1/ n
qe
Inq e
(6)
log qe
log K F
Where
/ n log Ce
(7)
qe
RT
In ( ACe )
b
(8)
qe
RT
In A
b
RT
In Ce
b
(9)
qe
qm e
(10)
[ISSN: 2045-7057]
qm
Inq m
(11)
RT In 1
1
Ce
(12)
1
2
(13)
Isotherm model
298
Langmuir
Q (mg/g)
b (L/mg)
RL
R2
Temkin
b (J/mg)
A (L/g)
R2
Freundlich
N
Kf (L/g)
R2
Dubinin-Radushkevich
qD (mg/g)
(mol2/J2)
E (KJ/mol)
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Temperature, K
303
313
166.67
0.00598
0.6297
0.937
142.86
0.00666
0.6002
0.993
142.86
0.00611
0.6207
0.999
71.03
0.062
0.946
82.49
0.061
0.989
87.41
0.059
0.998
1.7182
4.000
0.993
1.8349
4.2462
0.993
1.8519
4.0644
0.983
79.679
0.000
0.000
0.805
76.096
0.000
0.000
0.838
75.641
0.000
0.000
0.889
50
Isotherm model
Langmuir
Q (mg/g)
b (L/mg)
RL
R2
Temkin
b (J/mg)
A (L/g)
R2
Freundlich
N
Kf (L/g)
R2
Dubinin-Radushkevich
qD (mg/g)
(mol2/J2)
E (KJ/mol)
298
Temperature, K
303
200
0.0039
0.7502
0.874
166.67
0.0040
0.7143
0.901
166.67
0.0035
0.7402
0.875
71.07
0.0436
0.931
77.27
0.0427
0.937
81.68
0.0413
0.934
1.6051
2.6669
0.985
1.6750
2.9242
0.980
1.6313
2.4889
0.978
52.720
6x10-8
0.00003
0.503
52.039
2x10-7
0.0002
0.514
50.249
3x10-7
0.0001
0.500
Langmuir
Q (mg/g)
b (L/mg)
RL
R2
Temkin
b (J/mg)
A (L/g)
R2
Freundlich
N
Kf (L/g)
R2
Dubinin-Radushkevich
qD (mg/g)
(mol2/J2)
E (KJ/mol)
298
Temperature, K
303
Isotherm model
313
Isotherm model
313
333.33
0.0008
0.9259
0.915
333.33
0.0006
0.9434
0.940
333.33
0.0006
0.9434
0.977
73.32
0.020
0.931
75.97
0.019
0.937
80.64
0.019
0.934
1.1049
0.3698
0.997
1.2005
0.4943
0.999
1.2034
0.4656
0.999
59.561
0.001
22.361
0.955
58.265
0.001
22.361
0.955
55.701
0.001
22.361
0.951
Langmuir
Q (mg/g)
b (L/mg)
RL
R2
Temkin
b (J/mg)
A (L/g)
R2
Freundlich
N
Kf (L/g)
R2
Dubinin-Radushkevich
qD (mg/g)
(mol2/J2)
E (KJ/mol)
298
Temperature, K
303
313
333.33
0.0006
0.9434
0.911
333.33
0.0006
0.9434
0.940
333.33
0.0006
0.9434
0.977
80.13
0.019
0.975
81.16
0.018
0.976
85.63
0.018
0.979
1.1876
0.4150
0.998
1.1574
0.3589
0.999
1.0795
0.0755
0.999
53.091
0.001
22.361
0.946
51.728
0.001
22.361
0.939
51.111
0.001
22.361
0.945
Temperature, K
Isotherm model
Langmuir
Q (mg/g)
b (L/mg)
RL
R2
Temkin
b (J/mg)
A (L/g)
R2
Freundlich
N
Kf (L/g)
R2
Dubinin-Radushkevich
qD (mg/g)
(mol2/J2)
E (KJ/mol)
IV.
298
303
313
250
0.0008
0.9259
0.980
250
0.0008
0.9259
0.992
250
0.0006
0.9434
0.998
76.00
0.016
0.983
78.31
0.015
0.987
82.66
0.015
0.987
1.2136
0.4375
0.999
1.1933
0.3873
1.000
1.1507
0.3214
0.999
60.886
0.002
15..811
0.967
59.561
0.002
15.811
0.972
71.916
0.002
15.811
0.974
CONCLUSION
The potential of NPN, PPN, EFB, OPF and OPS as lowcost adsorbents for the removal of Cu2+ from aqueous
solutions was studied. The study shows that NPN and PPN
are very efficient adsorbents for removing Cu2+ from aqueous
solutions while EFB, OPF and OPS are very adsorbents for
the removal of Cu2+ from aqueous solutions. The ranking of
adsorbents for Cu2+ adsorption showed this order:
NPN>PPN>EFB>OPF>OPS. Copper (II) adsorption was
found to vary with adsorbent dosage, pH, initial ion
concentration, particle size, and contact time. Isotherms for
the adsorption of lead on the adsorbents were developed and
[ISSN: 2045-7057]
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[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
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