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Revision Notes
1)
a)
The Bronsted-Lowry theory says that acids are proton donors (H+ donors).
Bases are proton acceptors.
Strong acids and bases are fully dissociated (or ionised)
Weak acids and bases are partially dissociated
Acid-base pairs
Conjugate acid-base pairs are two species differing by H+
There is one member of the pair on each side of the equation
For any weak acid, HA:
HA(aq) + H2O(l) H3O+(aq) + A-(aq)
Acid
base
conjugate acid
conjugate base
2)
a)
Example
Calculate the pH of 0.100 mol dm-3 HCl
[H+]
pH
= 0.100
= -log[0.100]
= 1.00
b) pH of water
Water is very slightly dissociated:
[H+][OH-]
[H2O]
pH
=
=
=
=
=
Kw
4.02 x 10-14
2.01 x 10-7 mol dm-3
-log[H+]
6.70
c)
pH of a strong base
The Kw expression is used to calculate the pH of a strong base
=
=
=
=
=
=
0.100
Kw/[OH-]
10-14/0.100
10-13
-log[10-13]
13.00
d)
pH of a weak acid
The weak acid HA dissociates as follows.
HA H+ + AThe equilibrium constant for the weak acid is:
Ka =
[H+][A-]
[HA]
pH
Source
=
=
=
=
=
=
(Ka x [HA])
(1.38 x 10-3 x 0.100)
(1.38 x 10-4)
0.0117
-log[H+]
1.93
http://www.chemsheets.co.uk/
e) pKa
Calculate the pH of the solution formed when 100 cm3 of water is added to 25
cm3 of 0.50 mol dm-3 KOH
[OH-]new
New vol
[OH-]new
=
[H+]
=
=
pH
=
Source
http://www.chemsheets.co.uk/
3)
Acid-base titrations
a) pH curves
b) Titration calculations
4)
=
=
=
=
=
=
=
=
=
=
=
0.10 x 20/1000
0.0020 mol
0.04 x 30/1000
0.0012 mol
= 0.0020 0.0012
0.0008 mol
50 cm3
moles/volume
0.0008/(50/1000)
0.016 mol dm-3
-log(0.016)
1.80
http://www.chemsheets.co.uk/
Buffer solutions
a) Acidic buffers
An acidic buffer consists of a weak acid and the salt of a weak acid (e.g.
ethanoic acid & sodium ethanoate)
For ethanoic acid/sodium ethanoate, the following equilibrium exists:
CH3COOH(aq) CH3COO-(aq) + H+(aq)
b) Basic buffers
A basic buffers consists of a weak base and the salt of a weak base (e.g.
ammonia solution & ammonium chloride)
For ammonia/ammonium chloride, the following equilibrium exists:
NH4+(aq) NH3(aq) + H+(aq)
If a small amount of acid is added, the H+ will react with ammonia to form
ammonium ions i.e. the equilibrium will shift to the left to remove the
added H+
If a small amount of base is added, the OH- will react with H+ to form water.
Some ammonium ions will dissociate to replace the H+ that has been
removed
The pH of an acidic buffer can be calculated using the K a expression for the
weak acid e.g. for ethanoic acid/sodium ethanoate:
Ka = [CH3COO-][H+]
[CH3COOH]
Rearranging gives:
[H+] = Ka x
[CH3COOH]
[CH3COO-]
moles CH3COOH/volume
Moles CH3COO-/volume
moles CH3COOH
Moles CH3COO-
The mole form of the equation is often more useful than the concentration
version.
Example
Ethanoic acid is a weak acid with a Ka value of 1.74 x 10-5 mol dm-3 at 25C. In
a buffer solution, the concentration of ethanoic acid is 0.150 mol dm-3 and the
concentration of sodium ethanoate is 0.100 mol dm-3. Calculate the pH of this
buffer solution
[H+]
pH
Source:
=
=
=
=
Ka x [CH3COOH]/[CH3COO-]
1.74 x 10-5 x 0.150/0.100
2.61 x 10-5 mol dm-3
4.58
Example
A buffer solution is formed when 2.00g of sodium hydroxide are added to 1.00
dm3 of a 0.220 mol dm-3 solution of ethanoic acid. Calculate the pH of this
buffer solution at 298K
Moles NaOH used
=
=
Moles CH3COOH
at start
Moles CH3COONa formed
=
Moles CH3COOH left
=
=
2.00/40.0
0.050 mol
= 0.220 mol
0.050 mol
0.220 - 0.050
0.170 mol
=
=
=
=
pH
Source:
Ka x [CH3COOH]/[CH3COO-]
1.74 x 10-5 x 0.170/0.050
5.916 x 10-5 mol dm-3
4.23
(i)
[H+]
pH
(ii)
=
=
=
=
Ka x [CH3COOH]/[CH3COO-]
1.74 x 10-5 x 0.150/0.100
2.61 x 10-5
4.58
= 0.150 mol
= 0.100 mol
Moles H+ added
= 1.00 x 10.0/1000
= 0.010 mol
On addition of H+:
CH3COO- + H+ CH3COOH
In this case, moles CH3COO decreases by 0.010 and moles
CH3COOH increases by 0.010
New moles CH3COOH = 0.160 mol
New moles CH3COO- = 0.090 mol
New [H+]
= Ka x mol CH3COOH/mol CH3COO= 1.74 x 10-5 x 0.160/0.090
= 3.90 x 10-5
New pH = 4.51
(iii)
= 1.00 x 10.0/1000
= 0.010 mol
On addition of OH-:
CH3COOH + OH- CH3COO- + H2O
In this case, moles CH3COOH decreases by 0.010 and moles
CH3COO- increases by 0.010
New moles CH3COOH = 0.140 mol
New moles CH3COO- = 0.110 mol
New [H+]
= Ka x mol CH3COOH/mol CH3COO= 1.74 x 10-5 x 0.140/0.110
= 2.21 x 10-5
New pH = 4.65