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Chemical Engineering Department

RESEARCH GUIDE

Chemical Engineering Department

Research Guide

Chemical Engineering Department

Chemical Engineering Department


The Petroleum Institute

Chemical Engineering Department

Prepared by: Dr. Abdallah Sofiane Berrouk


Carmen Gutierrez
Salaheddin Abuyahya
Ahmed Syed
Copyright@2012, The Petroleum Institute, Abu Dhabi

The department of chemical engineering at the Petroleum Institute (PI) hosts a variety of research programs
spanning a wide array of activities. Our faculty members and research associates lead research efforts in
fundamental as well as applied research in the traditional and emerging fields of chemical engineering. As you will
see from this booklet, our research activities fall into the following research areas:

Oil refinery and gas processing


Catalysis and reaction engineering
Process simulation, modeling and optimization
Thermodynamics and molecular modeling
Polymers and advanced materials
Flow assurance and enhanced oil recovery
Computational flow modeling
Colloid and surface science and interfacial engineering
Mass transport and separation technology
Energy and environmental engineering
Applied and environmental chemistry

Gas Processing
and Treating

Chemical Reactor
Modeling,
Simulation, and
Optimization

Catalysis and
Reaction
Engineering

New and
advanced
Materials

Polymer
Science and
Engineering

Desalination
and Corrosion

These areas represent key domains in which we like to offer expertise and research solutions specific to the needs of
our shareholders: the Abu Dhabi National Oil Company (ADNOC) and its operating companies; as well as our
strategic international partners (BP, Shell, Total and Japan Oil Development Company). These partnerships supply
funding for our research program and help us attract world-class experts to the department. Our ultimate goal is to
achieve practicable and pragmatic solutions to our partners and offer the potential of creating new knowledge and
make important gains against the challenges they face.
Research in our department is supported by state-of-the-art laboratories and equipment. Our laboratories include
the Catalysis, Reaction Engineering and Process Intensification laboratory, the Flow Assurance and Production
Chemistry laboratory, the Polymer laboratory (polymer chemistry, polymer characterization and testing as well as
polymer processing), and the Environmental Chemistry laboratory. There are also dedicated facilities and software
for computational work. In our labs, safety is of paramount importance. All researchers adhere to strict safety
measures and go through safety training before they can access the labs.

Chemical Engineering Department

Chemical Engineering Research Vision and Activities

The chemical engineering faculty members play a major role in interdisciplinary research and collaborate actively
with other researchers in other PI units such as the petroleum engineering department (collaborations in the areas
of enhanced oil recovery and carbon sequestration), mechanical engineering department (collaborations in energy
systems, computational flow modeling, and materials), and the chemistry department (collaborations in
environmental projects and corrosion). Our faculty members collaborate also widely in joint research projects
through the PI standing agreements with partner universities (e.g. University of Minnesota, University of Maryland,
Colorado School of Mines, Rice University, University of Texas - Austin, China University of Petroleum - Beijing, and
Johannes Kepler University at Linz - Austria).
All in all, the department of chemical engineering at the PI is committed to a strong research program. I hope you
will enjoy reading about our current research activities. Contact us for more information or if you wish to initiate any
collaboration or standing agreement.
Sincerely,
Chair, Department of Chemical Engineering,
The Petroleum Institute,
Bu Hasa Building, Room 2207
Sas Al Nakhl Campus,
P.O. Box 2533,
Abu Dhabi, United Arab Emirates
Tel: +971 2 607 5276
Fax: +971 2 607 5200
E-mail: chego@pi.ac.ae
URL: http://www.pi.ac.ae/PI_ACA/ce/index.php

Chemical Engineering Department

Chemical Engineering Research Vision and Activities

The Petroleum Institute (PI) is the research arm of ADNOC. The Chemical Engineering department (CE) has been
very active in terms of research and development for both upstream and downstream activities of ADNOC and its
different operating companies. CE research activities aim to either respond to immediate needs and requirements
of the local industry or develop new, cost-effective and environmentally friendly technologies.
CE has developed strong research ties with international universities with strong research reputation in different
fields which greatly boosted research within the department.
CE faculty and research staff have been very active in attracting internal and extramural funds to finance their
growing research activities. CE is among the leading PI departments in terms of attracting funds from different
sources such as Gas Research Center (GRC), Gas Subcommittee, Oil Subcommittee, and ADNOC different operating
companies.

Chemical Engineering Department

Research Partners

CE Faculty and research staff have obtained several strategic grants for developing research laboratories in different
fields of chemical engineering. These research Laboratories are populated with modern scientific equipment needed
to conduct state-of-the-art research. CE faculty and research staff are also involved in different ADNOC research
centres creating a synergy between academia and the ADNOC R&D sector.

Research Laboratories

Catalysis and Process Development laboratory


Applied and Environmental Chemistry laboratory
Polymer Characterization and Polymer Processing Laboratories
Flow Assurance and Production Chemistry laboratory

Research Centres

Takreer Research Centre [2009]


Bourouge Innovation Centre [2012]
ADNOC-PI Research Centre(ADPIRC) [2014]
Gas Research Centre (Virtual)

Chemical Engineering Department

Research Facilities

Although the PI has started primarily as an educational institution, emphasis on research has increased
substantially. This has been witnessed by the increasing number of publications over the past six years. The CE
publications are diverse and multipurpose, consisting of books, book chapters, international peer-reviewed papers,
conference papers and patents. The figure below shows our increasing trend of peer-reviewed journal articles.

Chemical Engineering Publications


71

75

59

38

17
7

2006

2007

2008

2009

2010

Peer-reviewed Journal Articles 2006-2011

2011

Chemical Engineering Department

Research Publications

The Chemical Engineering department at PI has been running a Masters degree program for the past 6 years. The
CE Masters modern curriculum has been designed and constantly revised to give students a rigorous education in
the fundamentals of engineering science and specific training in the applications of chemical engineering in the oil
and gas industry. The aim of the program is to equip students with the necessary knowledge to perform high quality
research and development. The program strives to meet the international standards of excellence in chemical
engineering education, research, and life-long learning.
Admission to the Master of Science (M.Sc) and Master of Engineering (M.Eng) Full Time Programs is open to all
qualified UAE national and International students. Outstanding graduates with excellent academic credentials, who
are highly motivated to undertake a challenging and rigorous graduate program of study are invited to apply. They
will be expected to have at least a B.S. degree from a well-recognized university.

Admission Requirements
The following general criteria apply to all applicants:
A minimum GPA of 3.0 (on a 4.0 point scale or its established equivalent) from a reputable B.Sc. Program;
applicants must submit an academic transcript attested by the UAE Ministry of Higher Education and Scientific
Research.
Recently certified TOEFL score of 550 or higher on Paper-Based, 213 on the Computer-Based, or 79 on the
Internet-Based test, or an IELTS score of 6.0.

Contacts
The Graduate School
P.O. Box 2533 | Abu Dhabi | United Arab Emirates
Phone: +971 2 6075936 | Fax: +971 2 6075200 | Email: ALLgs@pi.ac.ae
Web site: http://www.pi.ac.ae/graduatestudies

Chemical Engineering Department

Graduate Studies

Chemical Engineering Department

Chemical Engineering Faculty Members

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Purdue University,


West Lafayette, Indiana, USA.

A. Betancourt-Torcat, A. Elkamel, and L. Ricardez-Sandoval,


Integration of Nuclear Energy and Water Management into
the Oil Sands Operations, AIChE J., accepted, (2012).

EXPERTISE

Planning and Scheduling of Process Operations


Supply Chain Management
Process Modeling and Simulation
Process Optimization
Combinatorial Optimization

CURRENT INTERESTS

Energy and Environmental Engineering Systems


Air Pollution Modeling, Simulation, and Control
Refinery modeling, planning, and optimization
Sustainable Development of the Petrochemical
Industry
Computer-Aided Product Formulation and
Design
Modeling and Optimization of Complex Systems
Carbon management

I. Kantor, M. Fowler, and A. Elkamel, Optimized production


of hydrogen in an eco-park network accounting for life-cycle
emissions and profit, International Journal of Hydrogen
Energy, in press, (2012).
A. Hajimiragha, C. A. Caizares, M. Fowler, S. Moazeni, and
A. Elkamel, and S. Wong, Sustainable convergence of
electricity and transport sectors in the context of a hydrogen
economy, International Journal of Hydrogen Energy, 36 (11),
pages 6357-6375, (2011).
W. Al-Gherwi, H. Budman, and A. Elkamel, Selection of
Control Structure for Distributed Model Predictive Control in
the Presence of Model Errors, Journal of Process Control,
20, pages 270-284, (2010).

Chemical Engineering Department

Dr. Ali ElKamel


Visiting Professor
Bu Hasa Building, Room 2211
Sas Al Nakhl Campus,
Office:+971-2-607-5114
Fax: +971 2 607 5200
Email: aelkamel@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Delft University of


Technology, Delft, The Netherlands.

B. Breure, E.J.M. Straver, L.J. Florusse, M.P.W.M. Rijkers, I.G.


Economou, F.M. Vargas & C.J. Peters, Phase equilibria in
binary mixtures of propane and phenanthrene: experimental
data and modeling with the GC-EoS, Journal of Chemical and
Engineering Data, vol. 56, no. 4, pp. 1407-1413, 2011.

EXPERTISE

Classical Thermodynamics
Statistical Thermodynamics
Complex Phase Behavior
High-Pressure Phase Equilibria

CURRENT INTERESTS

Gas separation with ionic liquids


Gas separation with gas hydrates
Gas separation with high gravity forces
Reactions and separations with ionic liquids
Asphaltene phase behavior
Hydrogen Storage
CO- Capturing and Sequestration
Desalination of seawater with gas hydrates
Mobility control in reservoirs

N.I. Papadimitriou, I.N. Tsimpanogiannis, A.K. Stubos, A.


Martin, L.J.
Rovetto, L.J. Florusse & C.J. Peters,
Experimental and computational investigation of the sII
binary He-THF hydrate, Journal of Physical Chemistry
Letters, vol. 115, no. 6, pp. 1411-1415, 2011.
H. Yoshioka, M. Ota, Y. Sato, M. Watanabe, H. Inomata, R.L.
Smith Jr. & C.J. Peters, Decomposition kinetics and recycle
of binary hydrogen-tetrahydrofuran clathrate hydrate, AIChE
Journal, vol. 57, no. 1, pp. 265-272, 2011.
S. Raeissi, L.J. Florusse & C.J. Peters, Scott-van
Konynenburg phase diagram of carbon dioxide plus
alkylimidazolium-based ionic liquids, The Journal of
Supercritical Fluids, vol. 55, no. 2, pp. 825-832, 2011.

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Johns Hopkins


University, Baltimore, Maryland, USA

G.P. Lithoxoos, A. Labropoulos, L. Peristeras, N.


Kanellopoulos, J. Samios and I.G. Economou, Absorption of
N2, CH4, CO and CO2 Gas in Single Walled Carbon Nanotubes.
A Combined Experimental and Monte Carlo Molecular
Simulation Study, J. Supercrit. Fluids, 55, 510 523 (2010).

EXPERTISE
Molecular Thermodynamics and
Simulation of Complex Fluid Systems

CURRENT INTERESTS

Ionic Liquids
Carbon capture and sequestration
Gas to Liquid conversion
Aqueous systems

Molecular

Z.A. Makrodimitri, D.J.M. Unruh and I.G. Economou,


Molecular Simulation of Diffusion of Hydrogen, Carbon
Monoxide, and Water in Heavy n-Alkanes, J. Phys. Chem. B,
115(6), 1429 1439 (2011).
N.M. Garrido, M. Jorge, A.J. Queimada, M.E.A. Macedo and
I.G. Economou, Using Molecular Simulation to Predict
Solvation and Partition Coefficients in Solvents of Different
Polarity, Phys. Chem. Chem. Phys., 13(20), 9155 9164
(2011).
N. Diamantonis and I.G. Economou, Evaluation of Statistical
Associating Fluid Theory (SAFT) and Perturbed Chain-SAFT
Equations of State for the Calculation of Thermodynamic
Derivative Properties of Fluids Related to Carbon Capture
and Sequestration, Energy & Fuels, 25(7), 3334 3343
(2011).

Chemical Engineering Department

Dr. Ioannis G. Economou


Professor
Habshan Building, room 5333A
Sas Al Nakhl Campus
Office: +971 2 607 5884
Fax: +971 2 607 5200
Email ieconomou@pi.ac.ae

RESEARCH AREAS

EDUCATION
PhD in Chemical Engineering.
Waterloo, Ontario, Canada

REPRESENTATIVE PUBLICATIONS
University of

EXPERTISE
Rheology of Dispersed Systems
Physical Properties of Composites
Pipeline Flow of Dispersed Systems

CURRENT INTERESTS
Rheology of Emulsions
Mechanical/Thermal/Electrical Properties of
Composites
Drag Reduction in Pipeline Flow by
Polymeric/Surfactant Additives

Rajinder Pal. Rheology of Simple and Multiple emulsions,


Current Opinion in Colloid & Interface Science, Vol. 16,
2011, pp. 41-60.
Rajinder Pal. Influence of interfacial rheology on the
viscosity of concentrated emulsions , Journal of Colloid &
Interface Science, Vol. 356, 2011, pp. 118-122.
Rajinder Pal. Thermal conductivity of three-component
composites of core-shell particles , Materials Science and
Engineering A, Vol. 498, 2008, pp. 135-141.
Ali Mohsenipour, Rajinder Pal. Drag reduction in turbulent
pipeline flow of mixed non-ionic polymer and cationic
surfactant systems The Canadian Journal of Chemical
Engineering, 2012, in Press.

Chemical Engineering Department

Dr. Rajinder Pal


Visiting Professor
Arzanah Building, Room 8317
Sas Al Nakhl Campus,
Office: +971 2 607 5652
Fax: +971 2 607 5200
Email: rpal@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. McGill University,


Montreal, Canada

F. Banat, S. Al-Asheh, M. Al-Rawashdeh, M. Nusair,


Photodegradation of Methylene Blue Dye by the UV/H2O2
and UV/acetone oxidation processes. Desalination 181, 225232 (2005).

EXPERTISE
Application of membrane distillation process in
desalination, water treatment, food industry, and
separation of azeotropes
Coupling solar energy with membrane distillation
for desalination
Multicomponent mass transfer using StefanMaxwell approach has been applied widely in my
research

CURRENT INTERESTS

Desalination and water purification processes


Membrane separation processes
Wastewater treatment
Coupling desalination processes with renewable
energy sources

F. Banat, N. Jwaied, M. Rommel, J. Koschikowski, M.


Wieghaus, Performance evaluation of the large SMADES
autonomous desalination solar-driven membrane distillation
plant in Aqaba, Jordan. Desalination, 217 17-28 (2007).
F. Banat, N. Jwaied, M. Rommel, J. Koschikowski, M.
Wieghaus, Desalination by a "compact SMADES"
autonomous solar powered membrane distillation unit.
Desalination, 217 29-37 (2007).
S. Al-Asheh, F. Banat, F. Lattieff, Comparison between
Activated Charcoal, Bentonite and Phillipsite as Storing
Media for Methane, Oil and Gas Technology, 104, 83-89
(2011).

Chemical Engineering Department

Dr. Fawzi Banat


Visiting Professor
Bu Hasa Building, Room 2212
Sas Al Nakhl Campus
Office: +971 2 607 5099
Fax: +971 2 607 5200
Email: fbanat@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Institute National


Polytechnique de Grenoble (INPG), Grenoble,
France

Yves Gunaltun, Matina Thammachart. Importance of TLC


stabilization process for TLC rate prediction. Presented at
the Second Top of Line Corrosion Conference at Bangkok.
January 28-30, 2009.

EXPERTISE
Corrosion control and monitoring in oil and gas
production
Corrosion Engineering
Modeling CO2 &H2S corrosion
Coating and painting
Cathodic protection
R&D in CO2 and H2S corrosion

Yves Gunaltun, Suchada Punpruk, Assoc. Prof. Siriporn


DAOPISET. SSC resistance of 13% Cr and Super 13% Cr
below pH 3.5 in low H2S environment. NACE 2009.

CURRENT INTERESTS

Yves Gunaltun, Suchada Punpruk, Matina Thammachart,


Pornthep Tanaprasertsong. Worst case top of line corrosion:
cold spot corrosion. NACE 2010.

Corrosion monitoring tools


Corrosion inhibitors
H2S modeling
3 layer polymer coatings
Cathodic protection
Materials selection
Flow related corrosion

Yves Gunaltun, Tong Eak Pou, Marc Singer, Claude Duret,


Stephane Espitalier. Laboratory testing of volatile corrosion
inhibitors. NACE 2010.

Chemical Engineering Department

Dr. Yves Gunaltun


Chair Professor
Habshan Building, room 5248
Sas Al Nakhl Campus
Office: +971 2 607 75121
Fax: +971 2 607 5200
Email: ygunaltun@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemistry. University Politehnica of


Timisoara, Timisoara, Romania

M.A. Panthaki, R. V. Vladea, A. Lphi, R.R. Hudgins, P.L.


Silveston, Trickle-bed removal of flugas SO2 using nonaqueous solvents Can. J. Chem. Eng. 79,765, 2001.

P.L. Silveston, M.A. Panthaki, K. Duval, R. V. Vladea, A. Lohi,


R. R. Hudgins, Low-temperature, carbon-catalyst, solventwashed trickle-bed sulfuric acid process Stud. Surf. Sci.
Catal. 133, 195-203, 2001.

R. Vladea, N. Hinrichs, R. R. Hudgins, S. Suppiah, P.L.


Silveston, High-efficient structured-packing with activated
carbon for SO2 oxidation from flue gas Energy & Fuels, 11,
277, 1997.

R. Vladea et al. Managing hydrogen production and use


on refinery platforms, Downstream Technology
Conference, Kuwait, 19-22 February, 2012.

EXPERTISE
Catalytic process development
Petroleum processing
Oilfield chemicals

CURRENT INTERESTS
New catalytic system and rector for
hydrotreating and hydrocracking oil fractions
New catalytic system for Steam Reforming of
Methane
Photocatalytic splitting of H2S into elements
Highly efficient system for dehydration of natural
gas
Highly efficient system for separating CO2/CH4
mixtures
Nanosized zeolites grown on SiC foams

Chemical Engineering Department

Dr. Radu Vladea


Research Professor
Arzanah Building, Room 8315
Sas Al Nakhl Campus,
Office:+971-2-607-5201
Fax: +971 2 607 5200
Email: rvladea@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Indian Institute of


Technology, Madras, India

Jimmy Lim, C. Srinivasakannan, N. Balasubramanian,


Activation of palm shells by phosphoric acid impregnation
for high yielding activated carbon, Journal of Analytical and
Applied Pyrolysis, 88, 181-186, 2010.

EXPERTISE
Heat and Mass Transfer Operations

CURRENT INTERESTS

Fluidization
Biomass gasification / Pyrolysis
Porous Carbons / Adsorption
Waste water treatment

Duan Xin-hui, C. Srinivasakannan, Peng Jin-hui, Zhang Li-bo,


Zhang zheng-yong, Comparison of activated carbon prepared
from Jatropha hull by conventional heating and microwave
heating, Biomass Bioenergy , 35 (9), 3920-3926, 2011.
C. Srinivasakannan, N. Balasubramanian, Variations in the
Design of Dual Fluidized bed Gasifiers and Quality of Syngas
from biomass, Energy Sources A: Recovery, Utilization, and
Environmental Effects, 33(4), 349-359, 2011.
Duan Xin-Hu, C. Srinivasakannan, Peng Jin-Hui, Zhang Li-Bo,
Zhang Zheng-yong, Preparation of activated carbon from
jatropha hull with microwave heating: optimization using
response surface methodology, Fuel Processing Technology,
92(3), 394-400, 2011.

Chemical Engineering Department

Dr. C. S. Kannan
Associate Professor
Bu Hasa Building, Room 2008
Sas Al Nakhl Campus
Office: +971 2 607 5580
Fax: +971 2 607 5200
Email: ckannan@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. University of


Queensland, Australia

J. Chen, Leslie Loo, and K. Wang, D.D. Do, The Structural


Characterization of a CMS Membrane Using Argon Sorption
and Permeation, J. Membr. Sci., 335, 1-4, 2009.

EXPERTISE
Adsorption and Membrane Separation
Technology
Synthesis & Characterization of Carbon
Nanomaterials
Modeling Mass Transport in Porous Media
Energy Storage via Adsorption Technology
Low Cost Adsorbent for Separation and
Purification Applications

C. Li, S. Hein, and K. Wang, Separation of GMP from Milk


Whey Using Modified Chitosan Beads, Adsorption, 16, 85,
2010.

CURRENT INTERESTS

Yi Wang, Chun Xian Guo, Xin Wang, Cong Guan, Hongbin


Yang, Kean Wang, Chang Ming Li, Hydrogen Storage in Ni-B
nanoalloy-doped Three-dimensional Graphene
Material, Energy & Environmental Science, 4, 195, 2011.

Natural gas purification


Energy storage
Membrane Separation
Water treatment

D. Xu, Leslie Loo, K. Wang, Pervaporation Performance of


Novel Chitosan-POSS Hybrid Membranes: Effects of POSS
and Operating Conditions, J. of Polymer Science Part B:
Polymer Physics, 48(21), 2185-2192, 2010.

Chemical Engineering Department

Dr. Kean Wang


Associate Professor
Bu Hasa Building, Room 2215
Sas Al Nakhl Campus,
Office: +971 2 607 5116
Fax: +971 2 607 5200
Email: kwang@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. North Carolina State


University, USA

H. Kim, A. Abdala, and C. Macosko, Graphene/Polymer


Nanocomposites, Macromolecules, 43(16), 6515-6530,
2010. (Prospective article)

EXPERTISE

Nanomaterials (Graphene)
Polymer nanocomposites
Polymer rheology
Enhanced oil recovery

CURRENT INTERESTS
Graphene
Production, characterization, and
functionalization
Polymer graphene nanocomposites
Functionalized graphene for acid gas
removal
Graphene applications in water treatment
Polymers
Polymer nanocomposites
Synthesis and rheology of polymers for
enhanced oil recovery (EOR)

S. Mahammad, A. A. Abdala, G. Roberts, and S. Khan,


Manipulation of hydrophobic interactions in associative
polymers using cyclodextrin and enzyme, Soft Matter, 6
(21), 4237-4245, 2010.
T. Ramanathan, A. A. Abdala, S. Stankovich, D. A. Dikin, M.
Herrera-Alonso, R. D. Piner, D. H. Adamson, H. C. Schniepp,
X. Chen, R. S. Ruoff, S. T. Nguyen, I. A. Aksay, R. K.
Prud'Homme, and L. C. Brinson Functionalized Graphene
Sheets for Polymer Nanocomposites, Nature
Nanotechnology, 3, 327-331, 2008.
M. McAllister, J. Li, D. Adamson, H. Schniepp, A. Abdala, J.
Liu, M. Herrera-Alonso, D. Milius, R. Car, R. PrudHomme & I.
Aksay, Single Sheet Functionalized Graphene by Oxidation
and Thermal Expansion of Graphite, Chemistry of Materials,
vol. 19 (18), 4396-4404, (2007). (Cover Article)

Chemical Engineering Department

Dr. Ahmed A. Abdala


Associate Professor
Bu Hasa Building, Room 2214
Sas Al Nakhl Campus
Office: +971 2 607 5584
Fax: +971 2 607 5200
Email: aabdala@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Imperial College,


London, United Kingdom.

A. Almansoori, and N. Shah, Design and operation of a


stochastic hydrogen supply chain network under demand
uncertainty, International Journal of Hydrogen Energy, 2012
(DOI: 10.1016/j.ijhydene.2011.11.091).

EXPERTISE
Process Systems Engineering

CURRENT INTERESTS
Design, operation, and management of energy
supply chain
Optimization of energy systems
Modeling and simulation of fuel cell systems

W. Hu, A. Almansoori, P. K. Kannan, S. Azarm, and Z. Wang,


Corporate dashboards for integrated business and
engineering decisions in oil refineries: An agent-based
approach, Decision Support Systems, vol. 52, pp. 729-741,
2012.
A. Elkamel, I. Alhajri, A. Almansoori, and Y. Saif, Integration
of hydrogen management in refinery planning with rigorous
process models and product quality specifications,
International Journal of Process Systems Engineering, vol.
1(3/4), pp. 302330, 2011.
D. Georgis, S.S. Jogwar, A. S. Almansoori, and P. Daoutidis,
Design and control of energy integrated SOFC systems for
in-situ hydrogen production and power generation,
Computers & Chemical Engineering, vol. 35(9), pp. 1691
1704, 2011.

Chemical Engineering Department

Dr. Ali Al Mansoori


Assistant Professor
Bu Hasa Building, Room 2223
Sas Al Nakhl Campus,
Office: +971 2 607 5074
Fax: +971 2 607 5200
Email: aalmansoori@pi.ac.ae

Fax: +971 2 607 5200


Email: gbassioni@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemistry. Technical University of Munich,


Munich, Germany.

Ghada Bassioni, Mechanistic aspects on the influence of


inorganic anion adsorption on oilfield scale inhibition by
citrate, Journal of Petroleum Science and Engineering, vol.
70, pp. 298-30, 2010.

EXPERTISE

Organometallic magnetic materials


Homogeneous catalysis
Inorganic chemistry of binders
Interfacial science phenomena

CURRENT INTERESTS
Mitigation of Oilfield scales and asphaltenes
Optimization and Synthesis of Chemicals for Oilwell cementing
Environmental Construction and Oilfield
Chemicals

Yasser Al Wahedi, Jafar Awayes, Ghada Bassioni, Influence of


Classical & Modern Superplasticizers on the Chemical and
Rheological Behavior of Oil Well Cement- A comparative
study, Advances in cement research, Vol. 23 (4), pp. 175-184,
2011.
Ghada Bassioni, A study towards "greener" construction,
Applied Energy, in press 2012. DOI:
10.1016/j.apenergy.2010.09.012.
Ghada Bassioni, Fareed Abdulla, Zeinab Morsy, Nabil ElFaramawy, Evaluation of Naturally Occurring Radioactive
Materials (NORM) in Inorganic and Organic Oilfield Scales
from the Middle East, Archives of Environmental
Contamination and Toxicology, in press, 2012.
DOI: 10.1007/s00244-011-9706-7.

Chemical Engineering Department

Dr. Ghada Bassioni


Assistant Professor
Arzanah Building, Room 8317
Sas Al Nakhl Campus,
Phone:+971-2-607-5201

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Colorado School of


Mines, USA.

Al Shoaibi, A., Dean, A. M., Kinetic Analysis of C4 Alkane


and Alkene Pyrolysis: Implications for SOFC Operation, J.
Fuel Cell Sci. Technol., vol. 7(4), 2010, pp. 041015-8.

EXPERTISE

Detailed Chemical Kinetics


Pyrolysis/Gasification
Combustion
Fluidization

CURRENT INTERESTS
Experimental and Modeling analysis of
Hydrocarbon reactions
Sulfur Recovery in Gas Processing
Contaminants Removal in Gas Processing
Waste Plastic Gasification

Selim, H., Al Shoaibi, A., Gupta, A. K., Experimental


examination of flame chemistry in hydrogen sulfide-based
flames, Journal of Applied Energy, Vol. 88, Issue 8, August
2011, pp. 2601-2611.
Selim, H., Al Shoaibi, A., Gupta, A. K., Fate of sulfur with
H2S injection in methane/air flames, Journal of Applied
Energy, Vol. 92, Issue 8, November 2011, pp. 57-64.
Xu, C., Al Shoaibi, A., Wang, C., Carstensen, H.H., Dean,
A.M., Kinetic Modeling of Ethane Pyrolysis at High
Conversion, Journal of Physical Chemistry A, Vol 115, August
2011, pp.10470-10490.

Chemical Engineering Department

Dr. Ahmed Al Shoaibi


Assistant Professor
Bu Hasa Building, Room 2220
Sas Al Nakhl Campus,
Office: +971 2 607 5586
Fax: +971 2 607 5200
Email: aalshoaibi@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Mechanical Engineering. The University of


Manchester, Manchester, United Kingdom.

Jieqing Gan, Hui Zhao, Abdallah S. Berrouk, Chaohe Yang,


Honghong Shan. Impact of the drag law formulation on the
predicted binary-particle segregation patterns in a gas-solid
fluidized bed. Powder Technology, Vol. 218, Mar. 2012,
pp.69-75.

EXPERTISE
Computational Fluid Dynamics
Large Eddy Simulation
Stochastic Modelling for Particle-laden Turbulent
Flows
Aerosol Dispersion and Deposition Indoors
Discrete Particle Modelling of Fluidized Bed
Reactors

CURRENT INTERESTS

Sour Gas Sweetening


Heavy Oil Catalytic Cracking
Waste Plastic Gasification
Foam Bubble Dynamics

Wael A. Fouad, Abdallah S. Berrouk, Cornelis J. Peters.


Mixing MDEA, TEA shows benefit for gas-sweetening
operations. Oil and Gas Journal. Vol. 109 (45), Nov. 2011,
pp. 25-33.
Jieqing Gan, Hui Zhao, Abdallah S. Berrouk, Chaohe Yang,
Honghong Shan. Numerical simulation of hydrodynamics
and cracking reactions in the mixing zone of a multi-regime
gas-solid riser reactor. Industrial & Engineering Chemistry
Research, Vol. 50(20), Oct. 2011, pp.11511-11520.
Abdallah S. Berrouk, D. Laurence, J. J. Riley, D. E. Stock.
Stochastic modelling of inertial particle dispersion by subgrid motion for LES of high Reynolds number pipe flow.
Journal of Turbulence, Vol. 8(50), Nov. 2007, pp. 1-20.

Chemical Engineering Department

Dr. Abdallah Sofiane Berrouk


Assistant Professor
Bu Hasa Building, Room 2210
Sas Al Nakhl Campus,
Office: +971 2 607 5408
Fax: +971 2 607 5200
Email: aberrouk@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Rice University,


Houston, Texas, USA.

Sai R. Panuganti, Francisco M. Vargas, Walter G. Chapman.


Modeling of Reservoir Connectivity and Tar-mat using
Gravity-Induced Asphaltene Compositional Grading. Energy
& Fuels, DOI: 10.1021/ef201280d.

EXPERTISE
Thermodynamics
Petroleum Phase Behavior Modeling
Asphaltene Deposition

CURRENT INTERESTS
Petroleum Thermodynamics
Asphaltene Precipitation and Deposition
Flow Assurance and Production Chemistry

Sai R. Panuganti, Francisco M. Vargas, Doris L. Gonzalez,


Anju Kurup, Walter G. Chapman. PC-SAFT characterization
of crude oils and modeling of asphaltene phase behavior.
Fuel, 2012, 93, pp. 658669.
Anjushri S. Kurup, Francisco M. Vargas, Jefferson L. Creek,
Jianxin Wang, Jill Buckley, Hariprasad Subramami, Walter G.
Chapman. Development and application of an asphaltene
deposition tool (ADEPT) for well bores, Energy & Fuels,
2011, 25 (10), pp. 4506-4516.
Francisco M. Vargas and Walter G. Chapman, Application of
the One-Third rule in Hydrocarbon and Petroleum Systems,
Fluid Phase Equilibria, 2010, 290, pp 103-108.

Chemical Engineering Department

Dr. Francisco M. Vargas


Assistant Professor
Bu Hasa Building, Room 2203
Sas Al Nakhl Campus,
Office: +971 2 607 5456
Fax: +971 2 607 5200
Email: fvargas@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Swiss Federal Institute


of Technology, Zurich, Switzerland .

V. Mittal. Modification of Montmorillonites with Thermally


Stable Phosphonium Cations and Comparison with
Alkylammonium Montmorillonites. Applied Clay Science,
2012, 56, 103-109.

EXPERTISE
Polymer nanotechnology
Surface functionalization of inorganic
surfaces
Hybrid nanostructured composite materials
Optimization of interactions at interfaces
Bio-nanocomposites
Polymer colloids
Functional latex particles
Polymer monoliths
Living polymerization methods
Coating technologies
Design of Experiments (DoE) and Six Sigma
applications on various systems

CURRENT INTERESTS

Polymer blends and nanocomposites


Biodegradable nanocomposites
Oil sensors
Surface engineered self-healing nanoparticle
coatings

L.A. Fielding, O.O. Mykhaylyk, S.P. Armes, P.W. Fowler, V.


Mittal , S. Fitzpatrick. Correcting for a Density Distribution:
Particle Size Analysis of CoreShell Nanocomposite Particles
Using Disk Centrifuge Photosedimentometry. Langmuir,
2012, in print.
V. Mittal. Polypropylene nanocomposites with thermally
stable phosphonium- and pyridinium-modified layered
silicates: Thermal, mechanical and gas barrier properties.
Journal of Thermoplastic Composite Materials, 2012, in
print.
V. Mittal, A. Voelkel, H. Coelfen. Analytical
Ultracentrifugation of Model Nanoparticles: Comparison of
Different Analysis Methods. Macromolecular Bioscience,
2010, 10(7), 754-762.

Chemical Engineering Department

Dr. Vikas Mittal


Assistant Professor
Bu Hasa Building, Room 2204
Sas Al Nakhl Campus,
Office: +971 2 607 5491
Fax: +971 2 607 5200
Email: vmittal@pi.ac.ae

RESEARCH AREAS

EDUCATION

REPRESENTATIVE PUBLICATIONS

PhD in Chemical Engineering. Case Western Reserve


University, Cleveland, Ohio, USA.

Alhassan, S. M.; Schiraldi, D.; Agag, T.; Qutubuddin, S.;


Ishida, H., Various approaches for main-chain type
benzoxazine polymers In Handbook of Benzoxazine Resins,
Ishida, H.; Agag, T., Eds. Elsevier: 2011.

Schiraldi, D. A.; Gawryla, M. D.; Alhassan, S. M., Clay


Aerogel Composite Materials. Advances in Science and
Technology 2010, 63, 147-151.

Agag, T.; Geiger, S.; Alhassan, S. M.; Qutubuddin, S.; Ishida,


H., Low-Viscosity Polyether-Based Main-Chain Benzoxazine
Polymers: Precursors for Flexible Thermosetting Polymers.
Macromolecules 2010, 43 (17), 7122-7127.

Alhassan, S. M.; Qutubuddin, S.; Schiraldi, D., Influence of


Electrolyte and Polymer Loadings on Mechanical
Properties of Clay Aerogels. Langmuir 2010, 26 (14),
12198-12202.

EXPERTISE
Nanoparticle processing in aqueous media using
fundamental understanding of colloida
interactions and stability
Porous solids processing from colloidal
dispersions and the effect of processing
conditions on the properties of these solids
Processing and structure-property relationships
in polymeric nanocomposites
Nanoparticles characterization:

CURRENT INTERESTS

Polymer nano-composites
Colloids and porous solids
Surface science & catalysis
Nano particles processing & application
Enhanced oil recovery
Process design & simulation
Poly-benzoxazine synthesis, properties and
application

Chemical Engineering Department

Dr. Saeed M. Alhassan


Assistant Professor
Bu Hasa Building, Room 2219
Sas Al Nakhl Campus,
Office: +971 2 607 5944
Fax: +971 2 607 5200
Email: salhassan@pi.ac.ae

Chemical Engineering Department

Industrial Research Projects and Scientific collaboration

RESEARCH PROJECTS

New Equation of State for Asphaltene Phase Behavior Prediction


Dr. C. Peters (PI), Dr. I. Economou (PI), Dr. B. Breure (PI), Dr. M. Anisimov (UMD*)
Sponsor: Gas Research Center (GRC)

Objectives

Background
Asphaltenes are a very complex and ill-defined
petroleum fraction often referred to as the cholesterol
of petroleum
Asphaltenes can precipitate and deposit spontaneously
upon changes in P, T and x thereby blocking critical parts
of the oil production system

Elucidate the behavior of asphaltenes by studying welldefined model compounds


Develop an accurate and realistic thermodynamic model
based on correct fundamental principles to predict
asphaltene phase behavior

Due to the complexity of asphaltenes, their (phase)


behavior is still poorly understood

Approach

Research Personnel

Dynamic Light Scattering study of


aggregation behavior

Phase behavior
measurements (Cailletet)

Dr. Bianca Breure


Research Associate

Molecular simulations

Accurate thermodynamic model for


asphaltene phase behavior prediction
*UMD: University of Maryland, US

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

RESEARCH PROJECTS

Interfacial tension and its influence on Asphaltene precipitation and


deposition
Dr. C. Peters (PI), Dr. B. Breure (PI), Dr. I. Economou (PI), Dr. F. Vargas (PI)
Sponsor: Gas Research Center (GRC)

Background
Asphaltene precipitation and deposition is major
problem during oil production, transportation and
processing
Understanding the behavior of Asphaltene is crucial to
develop efficient mitigation strategies

Objectives
Development of a simulator to calculate interfacial
tensions for petroleum systems, including Asphaltene
Study the influence of interfacial tensions
Asphaltene behavior in petroleum systems

Still little is known about the role of interfacial tension in


Asphaltene precipitation and deposition

Approach
Interfacial properties of petroleum mixtures, including
Asphaltene are calculated using the so-called density
gradient theory
Calculated interfacial tensions are validated with
experimental data for petroleum systems
Interfacial properties of petroleum systems with and
without Asphaltene precipitation and/or deposition are
compared

Research Personnel
Dr. Bianca Breure
Research Associate

on

RESEARCH PROJECTS

Ionic Liquids for Gas Separation


Dr. C. Peters (PI), Dr. M. Kroon (TU-Eindhoven), Mr. F. Geuzebroek (Shell)
Sponsor: Gas Research Center (GRC)

Objectives

Background
Increasing need for capturing CO2 from gas streams
(e.g. natural gas & flue gas ) followed by a societal
responsible way to store the captured CO2
This important process is identified as
Capture-Storage (CCS)

Carbon-

Approach
Selection of an optimum ionic liquid
Introduction of high-gravity separation technology
Exergy and economic analysis of the new technology

Identify more effective and selective solvents for


capturing CO2 from gas streams, for example, higher
generation ionic liquids
Develop novel and highly efficient separation
technology to capture the CO2, for instance the
application of high-gravity forces

Research Personnel
Mara Teresa Mota
Martnez
Graduate Research
Assistant

Mamoun Althuluth
Graduate Research
Assistant

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

RESEARCH PROJECTS

Evaluation of Solid Sorbent S6 to Absorb H2S under simulated industrial


tail gas stream
Dr. C. Peters (PI), C. Gutierrez (PI)
Sponsor: GASCO/ADGAS*

Background
A re-generable Zinc Oxide based solid sorbent has been
identified for effective removal of low levels of
hydrogen sulfide from tail streams of natural gas

Objectives
Evaluate effectiveness that PI sorbent S6 has to
absorb H2S under a simulated industrial tail gas stream

This sorbent S6 has been determined to have great


industrial potential, but there are several factors
needed to be understood at lab scale before a robust
economic analysis can be done

Approach
The experiments are performed at 1.0 bar in the Cahn
Versa ThermTM thermo gravimetric analyser (TGA)

Research Personnel
Carmen Gutirrez
Research Associate

The sorbent mass is measured with the TGA

An increase in sample mass would express H2S uptake


The experimental results would be expressed as
change in mass of the sorbent sample (mass %)

*GASCO/ADGAS: Abu Dhabi gas companies

Student:
Tareq Dabash (PI)

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

RESEARCH PROJECTS

Improved Performance of Gas-Sweetening Processes


Dr. C. Peters (PI), Dr. Abdallah S. Berrouk (PI)
Sponsor: GASCO/ADGAS

Objectives

Background
High production volumes have placed stringent new
requirements on GASCO/ADGAS gas-processing
operations to consistently meet required financial
performance

Improve GASCO/ADGAS asset utilization by applying

Reliable equilibrium and transport thermo-physical


properties are needed for the optimization of the gassweetening units

Identify potentially problematic corrosion inhibitors

Approach
Simulation of the
design and real
GASCO and ADGAS
data using ProMax
simulator

new modelling and design tools for amine sweetening


plants

and antifoaming agents based on phase behavior


measurements

Research Personnel
Optimization of GASCO
and ADGAS units in
terms of energy
requirement using
ProMax Simulator

Built a thermodynamics
facility to measure the
effects of antifoaming
agents (AFA) and corrosion
inhibitors (CI) on acid gas
solubility in Amine solutions

Sabbir Samdani Islam


Research Lab
Engineer
Developing models for
acid gas solubility in
Amine solutions in
presence of AFAs and
CIs
Implementation of the
new models in ProMax
Simulator

Richard Ochieng
Graduate Research
Assistant

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

RESEARCH PROJECTS

Thermodynamic Model Development for the ADCO CO2 EOR Project


Ioannis Economou (PI), Hisham Saadawi (ADCO)
Sponsor: ADCO

Background
ADCO commissioned recently the first CO2 EOR unit in
the Middle East
Accurate knowledge of physical properties and phase
equilibria of the mixtures involved is needed for the
efficient simulation and optimization of the process

Approach
Development focuses on (a) Peng-Robinson and (b)
Soave-Redlich-Kwong EoS
Properties of interest: vapor pressure, saturated
densities, heat of vaporization, thermal expansion and
isothermal compressibility, Joule-Thomson coefficient,
speed of sound

Objectives
Development and validation of a thermodynamic
model based on cubic equations of state
Extensive testing of model accuracy against literature
and proprietary data

Research Personnel
Nikos Diamantonis
Graduate student

Chemical Engineering Department

Dr. Ioannis G. Economou


Professor
Habshan Building, room 5333A
Sas Al Nakhl Campus
Office: +971 2 607 5884
Fax: +971 2 607 5200
Email ieconomou@pi.ac.ae

RESEARCH PROJECTS

Deterioration of solvent Quality and Foaming Problems in a Gas Sweetening


Unit
Dr. Fawzi Banat (PI), Mr. S. Sayegh (GASCO), Mr. D. Prabhu (GASCO), Mr. A. Demmers (SHELL)
Sponsor: Gas Research Centre (GRC)

Background
Amine degradation and foaming is a critical problem in
gas treating plants and needs persistent research
efforts to get into the mechanism and find solutions

Objectives
Reduction of cost by cutting down or eliminating use of
antifoam in the amine column
Reduction of operating problems also leading to cost
saving

Approach

Research Personnel
To Be Hired

Chemical Engineering Department

Dr. Fawzi Banat


Visiting Professor
Bu Hasa Building, Room 2212
Sas Al Nakhl Campus,
Office: +971 2 607 5099
Fax: +971 2 607 5200
Email: fbanat@pi.ac.ae

RESEARCH PROJECTS

Advanced chemistry laboratory and materials laboratory


Corrosion monitoring tools for corrosion under heat insulation
Corrosion modeling for best and worst contaminants
Dr. Yves Gunaltun (PI), Dr. Dyana Saju Ambrose (PI)
Sponsor: Gas Research Center (GRC)

Background

Objectives

Corrosion in oil/gas pipelines are major problem leads


to
shut down of plant process and productivity.
Proper selection of corrosion inhibitors can be
effective for corrosion control
Proper corrosion control and monitoring of pipeline
reduce the risk of plant shut down and improve HSE
Modeling of H2S corrosion is important for the
development of new fields with H2S

Approach

Modeling

Testing of different corrosion monitoring tools to apply


in oil/gas pipelines for inspection and monitoring
Study of various factors involved H2S corrosion by
modeling

Research Personnel

Research in Chemicals
and materials
Development of
Corrosion control
and monitoring
systems

Development of advance chemistry and materials


laboratory for the testing of corrosion inhibitors and
materials (metallic and non metallic

Improvement of
Corrosion control
in oil and gas
pipelines

Dr. Dyana Saju Ambrose


Research/Teaching
Associate

Chemical Engineering Department

Dr. Yves Gunaltun


Chair Professor
Habshan Building, room 5248
Sas Al Nakhl Campus
Office: +971 2 607 75121
Fax: +971 2 607 5200
Email: ygunaltun@pi.ac.ae

RESEARCH PROJECTS

Highly Efficient Catalytic System for Production of Syngas or Hydrogen


Dr Radu Vladea (PI), Dr Saeed AlHasan (PI), Dr Nicoleta Doriana Banu (PI), Dr Gisha Luckachan
(PI), Dr Ionut Banu (PI), Dr Marios S. Katsiotis (PI), Jamie Whelan (PI), Anjana Tharalekshmy (PI),
Samuel Stephen (PI)
Sponsor: Takreer

Background
Ca. 85% of hydrotreating and hydrocracking operating
costs are due to hydrogen cost. Steam reformer is at
the heart of hydrogen production. Catalysts efficiency
is extremely low (6 to 10%)

Objectives
Development of new catalytic material grown on
silicon carbide/titanium carbide foams with high
geometric surface area and very high efficiency (ca.
90%)
The support has very high thermal conductivity and
very low pressure drop

Approach
Silicon carbide foams coated with TiO2 are oxidized and
loaded with micro-layers of nano-metallic catalysts.
Several catalytic systems are investigated. The size and
dispersion of nano-crystallites define most of the
catalyst performance and depends on the preparation
methods
The catalysts are characterized by FT-IR, Raman, BET,
XRD, TPD-MS, TGA/DTA/MS, TEM, and are tested in
Autoclave Engineers Microreactors system

Research Personnel
Dr. Nicoleta Doriana Banu
Dr. Gisha Luckachan
Dr. Ionut Banu
Dr. Marios S. Katsiotis
Mr. Jamie Whelan
Mr. Sam Stephen
Ms. Anjana Tharalekshmy

Chemical Engineering Department

Dr. Radu Vladea


Research Professor
Arzanah Building, Room 8315
Sas Al Nakhl Campus,
Office:+971-2-607-5201
Fax: +971 2 607 5200
Email: rvladea@pi.ac.ae

RESEARCH PROJECTS

Intensified Technology for Hydro-processing Crude Oils and/or Fractions


Dr Radu Vladea (PI), Dr Saeed Alhasan (PI), Dr Gisha Luckachan (PI), Dr Nicoleta Doriana Banu
(PI), Dr Ionut Banu (PI), Dr Marios S. Katsiotis (PI), Jamie Whelan (PI), Anjana Tharalekshmy (PI),
Samuel Stephen (PI)
Sponsor: Takreer

Background
The Project Program is aiming to generate a new
generation of catalysts with high thermal conductivity,
low pressure drop even at high LHSV or GHSV, high
thermal and chemical resistance and very good
mechanical strength

Approach
Functionalization of carbon nanotubes or nanofibers
through oxidation
Loading nanoparticles of metallic catalysts using either
reductive solvo-thermal decomposition of thioprecursors or reductive precipitation in supercritical
carbon dioxide as non-solvent on pre-oxidized CNTs or
CNFs
Optimize distribution and stability of nanoparticles

Objectives
Replacing current hydrocracking and hydrotreating
adiabatic reactors by isothermal multi-tubular reactors
with large inner diameter of the catalytic tubes
The research is focused on developing new types of
carbons nanostructures anchored on foams made on
vitrified carbon, silicon carbide, metals, or ceramics

Research Personnel
Dr. Nicoleta Doriana Banu
Dr. Gisha Luckachan
Dr. Ionut Banu
Dr. Marios S. Katsiotis
Mr. Jamie Whelan
Mr. Sam Stephen
Ms. Anjana Tharalekshmy

Chemical Engineering Department

Dr. Radu Vladea


Research Professor
Arzanah Building, Room 8315
Sas Al Nakhl Campus,
Office:+971-2-607-5201
Fax: +971 2 607 5200
Email: rvladea@pi.ac.ae

RESEARCH PROJECTS

Development of Catalyzed High Surface Area Porous Carbons Suitable for


Gas Processing
Dr. C.S. Kannan (PI), Dr Suresh Kumar Reddy (PI)
Sponsor: Petroleum Institute

Background
Removal of inorganic contaminants such as hydrogen
sulfide and mercury from the natural gas stream is one
of the biggest challenges of the oil and gas industry as
the contaminants vary significantly depending on the
nature of the gas

Objectives
Develop high adsorption capacity porous carbons for
mercury removal from natural gas

The porous carbons can be derived either from carbon


materials or from carbonaceous material (biomass)
utilizing appropriate activation process

Approach
Assess the present state of art of the adsorbents in
terms of their maximum adsorption capacity, the rate
of adsorption, cost effective ness
Surface modification and development of porous
carbon through statistical design of experiments to
optimize the process parameters
Development of appropriate adsorption isotherm
models

Research Personnel
K. Suresh Kumar Reddy
Research Associate

Chemical Engineering Department

Dr. C.S. Kannan


Associate Professor
Bu Hasa Building, Room 2208
Sas Al Nakhl Campus,
Office: +971 2 607 5580
Fax: +971 2 607 5200
Email: ckannan@pi.ac.ae

RESEARCH PROJECTS

N2 Removal from Natural Gas

Dr. Kean Wang (PI), Dr. Vikas Mittal (PI), R. Wang (SMTC)
Sponsor: Gas Research Centre (GRC)

Background
N2-contaminated natural gas (NG) has to be upgraded.
The current cryogenic processes are energy intensive
and complex
De-N2 processes to small-scale plants are very
attractive. For large scale plants, cheaper more reliable
technologies are required
Membrane technology is low-cost and environmentally
benign. It is the next generation technology for this
application

Approach
The project will develop carbon molecular sieve
membrane for this application. This material is famous
for its high selectivity and chemically-inert surface
In this project, low cost polymer/co-polymers will be
first screened for membrane precursors. Then the
polymeric membrane will be converted to carbon
molecular sieve via thermal treatment. Both slab and
hollow fiber membrane will by synthesized and tested
for N2/CH4 separation

Objectives
Setup the membrane spinning (Phase Inversion) rig
Setup the thermal treatment rig
Setup the permeation-testing rig
Fabricate slab/hollow fiber polymeric/ molecular sieve
membrane
Test the membrane performance for the separation of
N2/CH4, and CO2/CH4 gas mixtures
Optimize the membrane structure for high selectivity
and permeability

Research Personnel
To Be Hired

Chemical Engineering Department

Dr. Kean Wang


Associate Professor
Bu Hasa Building, Room 2215
Sas Al Nakhl Campus,
Office: +971 2 607 5116
Fax: +971 2 607 5200
Email: kwang@pi.ac.ae

RESEARCH PROJECTS

Semi-conductive Cross-linked Polyethylene (X-PE) for Medium and High


Voltage Cables via Graphene Composites
Dr. Ahmed Abdala (PI)
Sponsor: Petroleum Institute (PI)

Background
Semiconductive crosslinked polyethylene (X-PE) is used
as a shielding in high voltage power cables. To achieve
the required conductivity level, high loading of carbon
black (40-50-%) is usually required. This high loading of
typically used as a conductive filler
This high loading of carbon black is not only difficult to
process but also deteriorates the mechanical
properties of XPE

Approach
Prepare crosslinkable PE composite with different
loading of graphene (1, 3, 5, 10%)
Thermally crosslink the crosslinkable PE composite

Measure the electrical, thermal, and mechanical


properties of the composite

Objectives
Develop a semiconductive X-PE based on X-PEgraphene nanocomposite with low loading of graphene
and enhanced mechanical properties

Research Personnel
Mohd Farhan Ansari
visiting MS student from
IIT, Kerla, India

Muhammad Jamil
visiting MS student
from KTH, Sweden

Chemical Engineering Department

Dr. Ahmed A. Abdala


Associate Professor
Bu Hasa Building, Room 2214
Sas Al Nakhl Campus
Office: +971 2 607 5584
Fax: +971 2 607 5200
Email: aabdala@pi.ac.ae

RESEARCH PROJECTS

Graphene/Polymer Composites
Dr. Ahmed Abdala (PI), Chris Macosko (UMN*)
Sponsor: Petroleum Institute (PI)

Background
Although plastics have many outstanding properties,
their low stiffness, low strength, electrical and thermal
resistance, flammability, permeability to gases and
solvents limits their use in some special applications
Incorporation of stiff, strong, and conductive nanofiller
such as graphene can improve these weaknesses

Approach
Blend polyethylene with thermally reduced graphene
(TRG) using melt and solution blending methods

Objectives
Develop electrically conductive linear low density
polyethylene (LLDPE) with enhanced mechanical and
thermal properties and investigate the effects of the
blending method and polymer functionalization on
these properties

Research Personnel
Hyunwoo Kim
Graduate Student (UMN)

Vary TRG loading from 0.5 to 3%. Functionalize


polyethylene to improve the dispersion of TRG
Examine the morphology, electrical properties, and
mechanical properties of the composite

*UMN: University of Minnesota, US

Mohammed Abdulrahim
Graduate Student (PI)

Chemical Engineering Department

Dr. Ahmed A. Abdala


Associate Professor
Bu Hasa Building, Room 2214
Sas Al Nakhl Campus
Office: +971 2 607 5584
Fax: +971 2 607 5200
Email: aabdala@pi.ac.ae

RESEARCH PROJECTS

Conversion of CO2 into Polymers and Chemicals


Dr. Ahmed Abdala (PI), Friedrich Srienc (UMN)
Sponsor: Petroleum Institute (PI)

Background
Plants, algae and bacteria converts CO2 into cell
material by sunlight energy. Valuable metabolite
products such as polyhydroxyalkanoic acid (PHA) and
its copolymers can be produced by chemolithoautotrophic bacterium

Objectives
Synthesis and characterization of biopolymers
Improve the properties of the bio polymer through
their graphene nanocomposites

This polymer making process can be engineering to be


carbon neutral negative process

Approach
Extract and purify polymers synthesized with bacteria
Examine the physical and mechanical properties of PHA
and its copolymers

Blend the polymers with graphene to enhance the


mechanical, electrical, and thermal properties of these
polymers

Research Personnel
To Be Hired

Chemical Engineering Department

Dr. Ahmed A. Abdala


Associate Professor
Bu Hasa Building, Room 2214
Sas Al Nakhl Campus
Office: +971 2 607 5584
Fax: +971 2 607 5200
Email: aabdala@pi.ac.ae

RESEARCH PROJECTS

Graphene Functionalization and Nanocomposite Applications


Dr. Ahmed Abdala (PI), Matthew Liberatore (CSM)
Sponsor: Petroleum Institute (PI)

Background
Incorporation of graphene into polymer matrices
improves the mechanical, thermal, and electrical
properties of the polymer matrix. However, dispersion
of graphene into nonpolar polymer such as
polyethylene and polypropylene remains a challenge.
Therefore, attachment of alkyl and other functional
groups onto the surface of graphene should improve
the dispersion and enhance the composite properties

Approach
Synthesis of chemically converted graphene (CCG)
Covalent and noncovalent functionalization of CCG
with different function groups

Investigate the effect of functionalization on graphene


compatibility with different polymers

Objectives
Develop functionalized graphene sheets that are
compatible with different polymers
Establish the relation between the functionalization
type and level and the polymer-graphene composite
properties

Research Personnel
Muhammad Iqbal
Graduate Student

Chemical Engineering Department

Dr. Ahmed A. Abdala


Associate Professor
Bu Hasa Building, Room 2214
Sas Al Nakhl Campus
Office: +971 2 607 5584
Fax: +971 2 607 5200
Email: aabdala@pi.ac.ae

RESEARCH PROJECTS

Integration of Engineering and Business Decisions for Robust Optimization


of Oil Refinery Systems
Dr. A. Almansoori (PI), Dr. A.Elkamel (PI), Dr. S. Azarm (UMD), Dr. P.K. Kannan (UMD)
Sponsor: Petroleum Institute (PI)

Objectives

Background
Oil refinery is a complex processing system with a
series of highly nonlinear and strongly coupled
subsystems
Managing the inherent tradeoffs in decisions in
business and engineering processes are most essential
to an oil refinerys success and profitability

Uncertain
parameters

Demonstrate the framework , using a simple oil


refinery system, with a dashboard that involves twostage decision making and robust optimization

Research Personnel
Decision maker

Goals

Dashboard

Business decisions

Business
model
Business objective

Decision Flow

Information Flow

Approach

Develop a framework for integrating engineering and


business decisions

Engineering decisions
Business
outputs

Engineering
outputs

Engineering
model

Engineering objective

Robust Optimization

Uncertain
parameters

Students:
W. Hu (UMD)
A. Butt (PI)

Chemical Engineering Department

Dr. Ali Al Mansoori


Assistant Professor
Bu Hasa Building, Room 2223
Sas Al Nakhl Campus,
Office: +971 2 607 5074
Fax: +971 2 607 5200
Email: aalmansoori@pi.ac.ae

RESEARCH PROJECTS

Simulation, Optimization and Control of Solid Oxide Fuel Cell Systems


Dr. A. Almansoori (PI), Dr. P. Daoutidis (UMN)
Sponsor: Petroleum Institute (PI)

Background
Solid Oxide Fuel Cells (SOFC):
1) highly efficient energy production
2) high operating temperature
3) stationary and stand-alone applications
Hydrogen:
1) favorable for fuel cell applications
2) environmentally friendly zero emissions
3) high energy density suitable energy carrier

Approach
Proposed two energy integrated configurations
Developed and simulated lumped nonlinear models,
and linear/nonlinear control strategies

Objectives
Combine SOFC with steam reformer for in-situ
hydrogen production from methane
Achieve tight energy integration through coupling of
exothermic and endothermic processes
Study complex dynamics of integrated system
Develop control strategies to ensure stability and
operational feasibility

Research Personnel
Students:
S. Jogwar (UMN)
D. Georgi (UMN)

Chemical Engineering Department

Dr. Ali Al Mansoori


Assistant Professor
Bu Hasa Building, Room 2223
Sas Al Nakhl Campus,
Office: +971 2 607 5074
Fax: +971 2 607 5200
Email: aalmansoori@pi.ac.ae

RESEARCH PROJECTS

A Direct Internal-Reforming Protonic-Ceramic Fuel Cell


Dr. A. Almansoori (PI), Dr. R. OHayre (CSM*), Dr. N. Sullivan (CSM)
Sponsor: Petroleum Institute (PI)

Background

Objectives

Solid state reaction sintering produces dense


electrolyte at lower temperatures

Develop BCZRe fabrication process for thin electrolyte


under 1400 C

BCZRe materials (i.e. BaCe0.7Zr0.1Y0.1Yb0.1) exhibit good


performance for direct natural gas reforming (Re is Y or
Yb from 0.1-0.3)

Fabricate cells with BCZRe electrolyte


Characterize electrochemical and physical properties of
cells
Compare performance to standard SOFC

Approach
Optimize and characterize each material system
sintering/calcining condition
Electrolyte: BaCe0.7Zr0.1Y0.1Yb0.1 (BCZYYb)
Anode: 35 wt.% BCZYYb/65 wt.% NiO

Research Personnel
Students:
D. Clark (CSM)

Develop inexpensive fuel cell fabrication

*CSM: Colorado Schololof Mine

Chemical Engineering Department

Dr. Ali Al Mansoori


Assistant Professor
Bu Hasa Building, Room 2223
Sas Al Nakhl Campus,
Office: +971 2 607 5074
Fax: +971 2 607 5200
Email: aalmansoori@pi.ac.ae

RESEARCH PROJECTS

Conversion of Waste Plastics to Energy by Fluidized Bed


Gasification
Dr. Ahmed Al Shoaibi (PI), Dr. Abdallah S. Berrouk (PI), Dr. Chandrasekar S. Kannan (PI)
Sponsor: Bourouge (Plastic Company)

Background
Gasification is a promising route for utilizing increasing
volumes of waste plastics as a significant energy source
The conversion efficiency of the process has not been
maximized yet, owing to difficulties in optimizing the
numerous variables controlling the process

Approach

Objectives
Study both experimentally and numerically the thermal
conversion of plastic waste to synthetic gas (H2+CO)
that can be used as a source of energy

Research Personnel
Dr. Pravin Kannan
Research Associate

Chemical Engineering Department

Dr. Ahmed Al Shoaibi


Assistant Professor
Bu Hasa Building, Room 2220
Sas Al Nakhl Campus,
Office: +971 2 607 5586
Fax: +971 2 607 5200
Email: aalshoaibi@pi.ac.ae

RESEARCH PROJECTS

BTX Removal in the Sulfur Recovery Process using Adsorption


Ahmed Al Shoaibi (PI), C. S. Kannan (PI), Mohammed Abdul Sater (GASCO), Frank (SHELL)
Sponsor: Gas Research Centre (GRC)

Background

Objectives

To ensure uninterrupted Gas supply to GASCO


customers

To reduce the BTX concentration to acceptable levels,


before entry to the furnace

To avoid catastrophic shut down of SRU, eventually the


whole plant

To facilitate 2/3rd bypass of the inlet H2S stream directly


to the clause process

To Reduce operating cost of the plant and improve


catalyst life

To maintain high flame temperature in the furnace

Approach
Acquire SHELL best Technology practices
Design and fabrication of test rig and establishing
laboratory facilities
Procurement of commercial adsorbents
In house sorbent development, characterization,
equilibrium and kinetics parameter estimation
Assessment of commercial sorbents
Adsorption modeling, simulation of packed bed
adsorber with experimental verification
Design recommendation and report for commercial
adoption of technology

Research Personnel
Suleiman Mazin Suleiman Hasan
PI Student

Chemical Engineering Department

Dr. Ahmed Al Shoaibi


Assistant Professor
Bu Hasa Building, Room 2220
Sas Al Nakhl Campus,
Office: +971 2 607 5586
Fax: +971 2 607 5200
Email: aalshoaibi@pi.ac.ae

RESEARCH PROJECTS

Sulfur Recovery from Gas Stream using Flameless and Flame Combustion
Reactor
Dr. Ahmed Al Shoaibi (PI), Dr. Ashwani Gupta (UMD)
Sponsor: Petroleum Institute (PI)

Background
Removal of hydrogen sulfide from gaseous fuels is
crucial since it is hazardous, highly corrosive and
flammable gas.

Objectives
Obtain fundamental information on the thermal
process of sulfur recovery from sour gas using
numerical and experimental studies

Proper reaction pathways of hydrogen sulfide can


produce valuable sulfur without any environmental
impact.

Approach
Perform detailed simulations using the Fluent and
Chemkin computer codes.
Conduct experiments using flameless and flame
combustion over a range of dynamic conditions
determined in the numerical study .

Determine optimal operating conditions for enhanced


sulfur conversion

Research Personnel
Hatem Selim
UMD Graduate Student

Chemical Engineering Department

Dr. Ahmed Al Shoaibi


Assistant Professor
Bu Hasa Building, Room 2220
Sas Al Nakhl Campus,
Office: +971 2 607 5586
Fax: +971 2 607 5200
Email: aalshoaibi@pi.ac.ae

RESEARCH PROJECTS

Pyrolysis Reactions of Butene Isomers at Low Temperatures


Dr. Ahmed Al Shoaibi (PI), Dr. Anthony Dean (CSM), Dr. Hans-Heinrich Carstensen (CSM)
Sponsor: Petroleum Institute (PI)

Background
Hydrocarbons remains to be a major source of fuel
amidst growing sustainability and environmental
concerns
Accurate kinetic models describing butene pyrolysis
and oxidative process is vital for any process
development

Approach
Perform butene pyrolysis using a tubular reactor setup
at various conditions
Quantitative characterization pyrolysis products using a
GC/MS/FID
Comparison with predictions from CHEMKIN to identify
specific deficiencies using rate and sensitivity analysis

Objectives
Characterize the pyrolysis chemistry of the three
butene isomers using a tubular reactor setup
Update the CSM kinetic model by employing high-level
electronic structure calculations and other theories

Research Personnel
Kun Wang
CSM Graduate Student

Chemical Engineering Department

Dr. Ahmed Al Shoaibi


Assistant Professor
Bu Hasa Building, Room 2220
Sas Al Nakhl Campus,
Office: +971 2 607 5586
Fax: +971 2 607 5200
Email: aalshoaibi@pi.ac.ae

RESEARCH PROJECTS

Proposed solutions for the new challenges facing GASCO existing and new
Habshan gas plants: High H2S and CO2 concentrations and unconventional
contaminants
Dr. A. S. Berrouk (PI), Dr. C. Peters (PI).
Sponsor: Gas Research Center (GRC)

Background
Abu Dhabi has significant undeveloped gas reserves
which a large portion of them is sour. Gas fields such
as Shah, Bab Arab, and Hail are known for their high
H2S and CO2 contents (up to 30% of H2S)
Dealing with much sourer gas containing
unconventional contaminants such as N2, COS,
Mercaptan and Mercury will pose many challenging
technical problems for these gas plants

Approach
Simulation of
GASCO existing
and new units
using ProMax
simulator

Objectives

Investigate, through analytical and simulation work,


the effects the new very sour gas feeds will have on
the operations of the existing and new GASCO
Habshan amine sweetening units

Propose technical solutions for the new challenges


facing GASCO Habshan existing and new gas plants in
dealing with the highly sour natural gas

Research Personnel
Optimization of ProMax
simulator to efficiently
simulate sour gas
streams treated by
GASCO existing and new
units

Optimization of GASCO
new units in terms of
energy requirement
using ProMax Simulator

To Be Hired

Chemical Engineering Department

Dr. Abdallah Sofiane Berrouk


Assistant Professor
Bu Hasa Building, Room 2210
Sas Al Nakhl Campus,
Office: +971 2 607 5408
Fax: +971 2 607 5200
Email: aberrouk@pi.ac.ae

RESEARCH PROJECTS

Discrete Particle Modeling of Hydrodynamics and Heat Transfer in


Fluidized Catalytic Cracking Reactors
Abdallah. S. Berrouk (PI), Dr. H. Zhao (PI), Dr. A. Koudil (TRC*)
Sponsor: Takreer (Oil Refining Company)

Objectives

Background
Fluid catalytic cracking (FCC) is the most important
conversion process used in petroleum refineries
Major advancements in the area of multiphase flow
modeling can offer substantial FCC process
improvements that have the potential to significantly
improve FCC unit operations.

Approach
Development of an
efficient serial threedimensional discrete
particle model
Implementation of heat
transfer and reaction
models in the discrete
particle model

Develop an efficient mesoscopic numerical model


named Discrete Particle Model (DPM) to be used to
study the fluid dynamics and heat transfer of
multiphase flows taking place in fluidized catalytic
cracking (FCC) units
Improve FCC unit components functioning using the
developed numerical models for multiphase flows

Research Personnel
Dr. Hui Zhao
Research Associate
Simulation of commercial
FCC units.
Purpose: Optimization of
the catalytic cracking
process, hardware,
capacity increase and
debottlenecking

Development of a
parallel version of the
above serial model
*TRC: Takreer Research Centre

Chemical Engineering Department

Dr. Abdallah Sofiane Berrouk


Assistant Professor
Bu Hasa Building, Room 2210
Sas Al Nakhl Campus,
Office: +971 2 607 5408
Fax: +971 2 607 5200
Email: aberrouk@pi.ac.ae

RESEARCH PROJECTS

Prediction of Asphaltene Deposition Tendency Through Simultaneous


determination of Phase Behavior and Interfacial Tension
Francisco M. Vargas (PI), Bianca Breure (PI), Cor Peters (PI), Ioannis Economou (PI), Shawket
Ghedan (PI)
Sponsor: ADNOC Oil Subcommittee

Background
Asphaltene deposition represents one of the most
challenging and widely occurring flow assurance
problem in Abu Dhabi Oil Fields
This flow assurance problem is most likely to spread
out even more and aggravate with time, as CO2 and
hydrocarbon gases are been injected to the oil fields as
part of the enhanced oil recovery strategies

Approach
Analytical Methods: Develop improved methods using
spectroscopy and microscopy to understand the
mechanisms of asphaltene precipitation and
aggregation
Modeling: Enhance PVT and IFT predictions using EOS,
as well as molecular simulations of asphaltene
aggregation
Flow Assurance Analysis: Analyze the precipitation of
asphaltenes at high pressure and temperature using
SDS apparatus, as well as core flooding test to
understand the potential damage cause by deposition
of asphaltenes in the formation

Objectives
Develop experimental and modeling methods to
determine the onset of asphlatene precipitation in a
wide range of operating conditions
Develop a molecular simulation model for asphaltene
aggregation mechanism
Develop a model to predict the phase behavior and
interfacial properties of asphaltene phase
Study the potential formation damage caused by
deposition of asphaltene in the reservoir

Research Personnel
Lab Engineers: Sudha Prasad, Nevin Mathew
Graduate Students: Sameer Punnapala, Mohammed
Abutaqiya, Saoud Al Darmaki, Fahad Syed

Undergraduate Students: Ayesha Khalil, Mariam Al


Rashedi, Sara Al Hashmi, Sama Al Hallaq, Salama Al
Marzouqi, Hadel Al Asafen

Chemical Engineering Department

Dr. Francisco M. Vargas


Assistant Professor
Bu Hasa Building, Room 2203
Sas Al Nakhl Campus,
Office: +971 2 607 5456
Fax: +971 2 607 5200
Email: fvargas@pi.ac.ae

RESEARCH PROJECTS

Development of a Rigorous Computational Fluid Dynamics Model for


Asphaltene Deposition
Francisco M. Vargas (PI), Yap Y. Fatt (PI), John C. Chai (PI)
Sponsor: Petroleum Institute (PI)

Background
Asphaltene deposition can cause a significant reduction of
oil production with the corresponding economical losses
that this represents. Some wells in Abu Dhabi are so
severely affected by this problem that shutdowns and cleanup jobs are conducted every three months
The development of a simulation tool that predicts the
occurrence and the magnitude of Asphaltene deposition in a
wide range of operating conditions is necessary to help in
the decision making process to mitigate this problem
This simulation tool should include a very rigorous
computational fluid dynamics model to account for the
transport of particles in the well

Approach
Two approaches to be developed: (1) Assuming that
the deposited particles are in solid phase, (2) Assuming
that the precipitated Asphaltene phase is liquid-like but
that rapidly ages with time to become solid-like.
Inclusion of energy equation for non-isothermal
process, multiple particle sizes, first and second order
deposition rate.

Objectives
Provide a better understanding of the flow conditions
that affect Asphaltene deposition both in experimental
setups and wellbore
Develop a computer code that rigorously accounts for
the effects of temperature, pressure and flow field
under laminar and turbulent regimes
Perform sensitivity analyses to identify the process
variables that play the most important role in
Asphaltene deposition process

Research Personnel
Yap Y. Fatt

Qiaoyu Ge

Research Associate

Research Assistant

Chemical Engineering Department

Dr. Francisco M. Vargas


Assistant Professor
Bu Hasa Building, Room 2203
Sas Al Nakhl Campus,
Office: +971 2 607 5456
Fax: +971 2 607 5200
Email: fvargas@pi.ac.ae

RESEARCH PROJECTS

Development of Experimental and Modeling Methods to Predict Asphaltene


Deposition
Francisco Vargas (PI), John Chai (PI), Dalia Abdullah (ADCO*), Sanjay Misra (ADCO), Walter
Chapman (Rice University)
Sponsor: ADNOC Oil Subcommittee

Background
The mechanism by which Asphaltene precipitate and
deposit, their structure and molecular weight distribution
are not completely understood, and
Asphaltene deposition data both in the lab and the field are
scarce. However, it is well accepted that
Asphaltene precipitation is a necessary but not a sufficient
condition for deposition. Therefore,
A successful simulation tool to predict the occurrence and
magnitude of Asphaltene deposition in the wellbore
requires a rigorous thermodynamic model to predict the
phase stability and a CFD model to account for flow
conditions

Approach
Experimental Work: Capillary tube and dynamic
deposition experiments using reservoir fluid at high P
and T. Characterization of deposited and non-deposited
Asphaltene and effect of inhibitors
Modeling Work: Integration of EOS and CFD models
Field Work: Effect of operating conditions on
deposition rate

Objectives

Increase the understanding of the mechanism of


Asphaltene deposition
Develop an integrated simulation tool that
incorporates thermodynamic and CFD modeling to
forecast the occurrence and magnitude of Asphaltene
deposition in the wellbore
Evaluate the performance of Asphaltene inhibitors
under dynamic conditions at reservoir conditions
Understand the physical and chemical differences of
deposited and non-deposited Asphaltene

Research Personnel
Research Associate: Yap Y. Fatt
Lab Engineers: Nevin Mathew and Sudha Prasad
Graduate Students: Sai Panuganti (Rice), Ali Al Hammadi
(Rice), two PI MSc student to be appointed
Undergraduate Students: Ayesha Khalil, Mariam Al
Rashedi, Hadel Al Asafen
*ADCO: Abu Dhabi Oil Company

Chemical Engineering Department

Dr. Francisco M. Vargas


Assistant Professor
Bu Hasa Building, Room 2203
Sas Al Nakhl Campus,
Office: +971 2 607 5456
Fax: +971 2 607 5200
Email: fvargas@pi.ac.ae

RESEARCH PROJECTS

Inverse Opals for Oil Sensors


Dr. V. Mittal (PI), Dr A. Chaudhry (PI)
Sponsor: Petroleum Institute (PI)

Background
Frequent corrosion of storage and transport facilities
by interaction with gas, oil, humidity, chemicals etc.
Chromate based corrosion protectors are
environmentally unfriendly due to their leachability on
coatings surface

Objectives
To develop use of inverse opal photonic crystals for oil
sensing
To demonstrate the selectivity of opals towards local
oils of different refractive indices like octane, diesel oil,
wax oil etc.

Approach

Research Personnel
A. Chaudhry
Graduate Student

H Li, J Wang, L Yang,


and Y Song, Advanced
Functional Materials, 2008,
18, 3258.

Chemical Engineering Department

Dr. Vikas Mittal


Assistant Professor
Bu Hasa Building, Room 2204
Sas Al Nakhl Campus,
Office: +971 2 607 5491
Fax: +971 2 607 5200
Email: vmittal@pi.ac.ae

RESEARCH PROJECTS

Surface-Engineered Self-Healing Anti-Corrosion Particle Coatings for Pipes


and Storage Tanks
Dr. V. Mittal (PI)
Sponsor: Gas Research Centre (GRC)

Background
Frequent leakage of petroleum products from
reservoirs, tanks, underground or undersea pipelines
causes significant pollution and environmental hazards
It would be very beneficial if a straightforward oil

Objectives
Self healing anti-corrosion particle coatings are
beneficial alternatives
The coatings have higher lifetime owing to the
controlled release of corrosion inhibitor from the
particles

sensor is present to detect such leakages

Approach

Research Personnel
To Be Hired

D G Shchukin and H Mhwald,


Advanced Functional
Materials, 2007, 17, 1451

Chemical Engineering Department

Dr. Vikas Mittal


Assistant Professor
Bu Hasa Building, Room 2204
Sas Al Nakhl Campus,
Office: +971 2 607 5491
Fax: +971 2 607 5200
Email: vmittal@pi.ac.ae

RESEARCH PROJECTS

Fundamental Understanding and Applications of Water based Colloidal


Glass and Gel
Dr. S. M. Alhassan (PI)
Sponsor: Petroleum Institute (PI)

Background
Laponite is synthetic discotic nanoparticle that is
readily disperse in water due to extensive negative
charges on the face of the particle and positive charges
on edge of the particle

Objectives
Understand the fundamentals of laponite-water
colloidal glasses/gels
Utilize Laponite/water colloidal glasses/gels in different
applications

Laponite is important to both academia and industry.


From a fundamental point of view, laponite is one of
the few particles that can form unique colloidal phases
such empty liquid, equilibrium gel and Wigner glass

Approach
Sample preparation will be done by direct exfoliation of
laponite in water at different processing conditions
Samples will be analyzed using: x-ray diffraction (XRD),
small angle x-ray scattering (SAXS), Raman
spectroscopy, optical microscopy, rheology, light
scattering and nuclear magnetic resonance (NMR)
Solids samples prepared using the colloidal glass will be
analyzed using thermal measurements, Fouriertransform Infrared (FTIR), surface characterization,
mechanical measurements, scanning electron
microscopy (SEM), transmission electron microscopy
(TEM) and electrical measurements

Research Personnel
To Be Hired

Chemical Engineering Department

Dr. Saeed M. Alhassan


Assistant Professor
Bu Hasa Building, Room 2219
Sas Al Nakhl Campus,
Office: +971 2 607 5944
Fax: +971 2 607 5200
Email: salhassanl@pi.ac.ae

Chemical Engineering Department

Chemical Engineering Research Laboratories

Dr. Saeed M. Alhassan


Assistant Professor
Bu Hasa Building, Room 2219
Sas Al Nakhl Campus,
Office: +971 2 607 5944
Fax: +971 2 607 5200
Email: salhassanl@pi.ac.ae

RESEARCH LABORATORIES

Applied Catalysis and Process Development Laboratory


Team members
Dr. Radu V. Vladea Research Professor
Dr. Saeed M. Alhassan Assistant Professor
Dr. Nicoleta Doriana Banu Research/Teaching Associate
Dr. Gisha Luckachan - Research/Teaching Associate
Dr. Ionut Banu - Research/Teaching Associate
Dr. Marios S. Katsiotis - Research/Teaching Associate
Mr. Jamie Whelan - Laboratory Engineer
Mr. Sam Stephen - Laboratory Engineer
Ms. Anjana Tharalekshmy Laboratory Engineer

Chemical Engineering Department

Dr. Radu Vladea


Research Professor
Arzanah Building, Room 8315
Sas Al Nakhl Campus,
Office:+971-2-607-5201
Fax: +971 2 607 5200
Email: rvladea@pi.ac.ae

Dr. Saeed M. Alhassan


Assistant Professor
Bu Hasa Building, Room 2219
Sas Al Nakhl Campus,
Office: +971 2 607 5944
Fax: +971 2 607 5200
Email: salhassanl@pi.ac.ae

RESEARCH LABORATORIES

Applied Catalysis and Process Development Laboratory


Research Projects
On-going projects
Intensified Technology for Hydro-processing Crude Oils and/or Fractions Research Contract with TAKREER
The Project Program is aiming to generate a new generation of catalysts with high thermal conductivity, low pressure
drop even at high LHSV or GHSV, high thermal and chemical resistance and very good mechanical strength. Such
catalysts are using only micro-layers of metallic components, practically avoiding any intra-particle diffusional
resistance. Due to the much lower amount of metals, it becomes feasible to use precious metals enabling much
higher reaction rates. Hydrocracking and hydrotreating adiabatic reactors using inter-layers of catalysts, hydrogen
quenching for temperature control, may be replaced by isothermal multi-tubular reactors with large inner diameter
of the catalytic tubes. The use of supercritical fluids may increase the reaction rate more than 100 times. The use of
nanosized zeolites anchored on SiC foams may offer much better catalysts for hydrocracking process.

Confocal Raman

XRD

Micro-reactors

Chemical Engineering Department

Dr. Radu Vladea


Research Professor
Arzanah Building, Room 8315
Sas Al Nakhl Campus,
Office:+971-2-607-5201
Fax: +971 2 607 5200
Email: rvladea@pi.ac.ae

Dr. Saeed M. Alhassan


Assistant Professor
Bu Hasa Building, Room 2219
Sas Al Nakhl Campus,
Office: +971 2 607 5944
Fax: +971 2 607 5200
Email: salhassanl@pi.ac.ae

RESEARCH LABORATORIES

Applied Catalysis and Process Development Laboratory


Research Projects
On-going projects
Steam reforming of methane
Hydrogen contributes with 80-86% to the operating costs of hydrotreating and hydrocracking processes. Any
reduction of H2 cost will increase the profit margin of the refinery. Current catalysts for Steam Reforming of Methane
have very low efficiency due to the intra-particle diffusion limitations. Our goal is to develop a new generation of
catalysts with high efficiency and thermal conductivity which will improve the economics of the process while
reducing the H2 production cost.

NMR

FT-IR

TPD-MS

Chemical Engineering Department

Dr. Radu Vladea


Research Professor
Arzanah Building, Room 8315
Sas Al Nakhl Campus,
Office:+971-2-607-5201
Fax: +971 2 607 5200
Email: rvladea@pi.ac.ae

Dr. Saeed M. Alhassan


Assistant Professor
Bu Hasa Building, Room 2219
Sas Al Nakhl Campus,
Office: +971 2 607 5944
Fax: +971 2 607 5200
Email: salhassanl@pi.ac.ae

RESEARCH LABORATORIES

Applied Catalysis and Process Development Laboratory


Research Projects
Other research topics of interest
Recovery of both hydrogen and sulfur from hydrogen sulfide by photocatalytic splitting of H2S molecule
Synthesis of nanosized zeolites on SiC support with multiple applications, either as catalysts with low coke propensity
or as highly efficient adsorbents
Carbon dioxide separation from methane using new rotating separators
Stabilized CO2 foams for enhanced oil recovery using modified silica nanoparticles

TGA-DTA-MS

TEM

Chemical Engineering Department

Dr. Radu Vladea


Research Professor
Arzanah Building, Room 8315
Sas Al Nakhl Campus,
Office:+971-2-607-5201
Fax: +971 2 607 5200
Email: rvladea@pi.ac.ae

Fax: +971 2 607 5200


Email: gbassioni@pi.ac.ae

RESEARCH LABORATORIES

Applied and Environmental Chemistry Laboratory


Team members
Dr. Ghada Bassioni Assistant Professor
Mrs. Sabna Khadar Research Laboratory Engineer
Mrs. Nicy Kallely - Laboratory Engineer
Mr. Mohammed Ali Graduate student
Mr. Khalfan Al Marzouqi - Graduate student
Mr. Syed Taha Haider Taqvi - Graduate student

Chemical Engineering Department

Dr. Ghada Bassioni


Assistant Professor
Arzanah Building, Room 8317
Sas Al Nakhl Campus,
Phone:+971-2-607-5201

Fax: +971 2 607 5200


Email: gbassioni@pi.ac.ae

RESEARCH LABORATORIES

Applied and Environmental Chemistry Laboratory


The Lab for Applied and Environmental Chemistry is focused on mitigation of oilfield scales and asphaltenes,
optimization and synthesis of chemicals for oil-well cementing and environmental construction and oilfield chemicals.
The lab has all equipment required to conduct high level research for chemical analysis and properties testing and is
seen as an opportunity to seek external industrial funding.

Ion chromatography

Gel permeation
chromatography

Mixer

Chemical Engineering Department

Dr. Ghada Bassioni


Assistant Professor
Arzanah Building, Room 8317
Sas Al Nakhl Campus,
Phone:+971-2-607-5201

Fax: +971 2 607 5200


Email: gbassioni@pi.ac.ae

RESEARCH LABORATORIES

Applied and Environmental Chemistry Laboratory


The laboratory mission statement is:
To enhance research activities aiming to develop environmentally acceptable chemicals ready for application in
the industry.
To generate scientific reports, presentations, papers and patents.
To serve as a base for useful informational exchange.
To build a facility for PI students for further development in material science and link to engineering.
To facilitate technical and scientific cooperation with local and international research groups or individuals
belonging to chemical companies, universities, or independent research organizations.
To provide solutions to field problems in ADNOC and the OPCOs.
To expand the experimental activities by means of workshops and seminars.
To undertake other activities as necessary to announce and emphasize the role of the lab.
To support PI and its faculty in any related projects.

Compressive Strength
Tester

Roller Oven for Aging


of Drilling Fluids

Scanning Electron
Microscope

Chemical Engineering Department

Dr. Ghada Bassioni


Assistant Professor
Arzanah Building, Room 8317
Sas Al Nakhl Campus,
Phone:+971-2-607-5201

Dr. Abdallah Sofiane Berrouk


Assistant Professor
Bu Hasa Building, Room 2210
Sas Al Nakhl Campus,
Office: +971 2 607 5408
Fax: +971 2 607 5200
Email: aberrouk@pi.ac.ae

RESEARCH LABORATORIES

Thermodynamics Measurements Laboratory


Team Members
Dr Cornelis J Peters
Dr Abdallah S Berrouk
Dr Bianca Breure
Mr. Sabbir Samdani
Mr. Mamoun Althuluth
Miss Maria Teresa Martinez

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

Dr. Abdallah Sofiane Berrouk


Assistant Professor
Bu Hasa Building, Room 2210
Sas Al Nakhl Campus,
Office: +971 2 607 5408
Fax: +971 2 607 5200
Email: aberrouk@pi.ac.ae

RESEARCH LABORATORIES

Thermodynamics Measurements Laboratory


Mission
The thermodynamics Laboratory has been recently established to help gather reliable
equilibrium and transport thermo-physical properties that are needed for the design,
operation, and optimization of gas sweetening units. It is well known that uncertainties
in these thermo-physical properties can lead to non-optimum operation of the plant,
deteriorating plant economics. Dynamic simulation and control based on thermophysical properties of acid gases in the pure solvents should account for the presence of
extraneous species in the system, such as corrosion inhibitors and antifoaming agents. It
is expected that these extrinsic materials will cause a shift in the thermo-physical
properties, such as acid gas solubility in the liquid solvents. Acid gases solubility in
different amine solutions will be measured in presence of different anti-foaming agents
and corrosion inhibitors used by the gas-sweetening industry.

Titanium
Reactor

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

RESEARCH LABORATORIES

Gas Absorbents Research Laboratory


Team Member
Dr Cornelis Peters - Distinguished Professor
Mrs. Carmen Faride Gutierrez- Research Associate
Mr. Tareq Dabash - PI student
Mr. Subhan Zafar Ali PI student
Mr. Sherif Mohamed Abdel Rasoul Mohamed PI student

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

RESEARCH LABORATORIES

Gas Absorbents Research Laboratory

Mission
This laboratory has a research oriented thermo gravimetric
analyzer (TGA) that is utilized to monitor the uptake of H2S
from waste gas tail streams by solid sorbents under
predetermined pressure, temperature, and gas concentration.

Thermal Gravimetric
Analyzer

Chemical Engineering Department

Dr. Cornelis Peters


Distinguished Professor
Habshan Building, Room 5311A
Sas Al Nakhl Campus,
Office: +971 2 607 5492
Fax: +971 2 607 5200
Email: cpeters@pi.ac.ae

Dr. Vikas Mittal


Assistant Professor
Bu Hasa Building, Room 2204
Sas Al Nakhl Campus,
Office: +971 2 607 5491
Fax: +971 2 607 5200
Email: vmittal@pi.ac.ae

RESEARCH LABORATORIES

Polymer Laboratory
Team Member
Dr Ahmed Abdala - Associate Professor
Dr Vikas Mittal Assistant Professor
Mr. Mohamed Harith Sharif - PI Graduate student
Mr. Mohamed Zafar Iqbal - PI Graduate student
Mr. Ali Usman Chaudhry- PI Graduate student
Mr. Fakhruddin Patwary - PI Graduate student

Mini Extruder (Haak)


CTW5572286

Injection Molding
VC 2500/70 TECH

Chemical Engineering Department

Dr. Ahmed A. Abdala


Associate Professor
Bu Hasa Building, Room 2214
Sas Al Nakhl Campus
Office: +971 2 607 5584
Fax: +971 2 607 5200
Email: aabdala@pi.ac.ae

Dr. Vikas Mittal


Assistant Professor
Bu Hasa Building, Room 2204
Sas Al Nakhl Campus,
Office: +971 2 607 5491
Fax: +971 2 607 5200
Email: vmittal@pi.ac.ae

RESEARCH LABORATORIES

Polymer Laboratory
Ongoing Projects
Factors effecting the synthesis of thermally reduced grapheme
Crosslinkable Polyethylene-Graphene composites for HV cables
Functionalization of graphene for making polymer Nano- composites for advanced applications
Amine functionalization of graphene for adsorption applications
Biopolymer-graphene composites
Applications of graphene in oil spill cleanup and wastewater treatment
Current Activities
Compounding of different polymers and fillers. Injection molding to form test samples
Rheological and mechanical testing. TGA and DSC analysis
Synthesization of nano-composites with uniform distribution of filler

Different polymers like PE, PP, biopolymers are used. The fillers include clay, graphene,
silica etc.

Single Screw Extruder/


Film Blowing
LE20-30/C

Chemical Engineering Department

Dr. Ahmed A. Abdala


Associate Professor
Bu Hasa Building, Room 2214
Sas Al Nakhl Campus
Office: +971 2 607 5584
Fax: +971 2 607 5200
Email: aabdala@pi.ac.ae

Chemical Engineering Department

The Petroleum Institute


P.O. Box 2533 | Abu Dhabi | United Arab Emirates
Phone: +971 2 6075936
Fax: +971 2 6075200
http://www.pi.ac.ae

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