Beruflich Dokumente
Kultur Dokumente
with FlexEneTM
Christian Dupraz
Agenda
12%
52%
36%
From Refineries
(DCC/RFCC/FCC)
From Steam crackers
On purpose production*
2012
2013
2014
2015
AAGR %/yr
10.2%
9.2%
3.3%
14.8%
15.6%
19.9%
21.3%
3.7%
13.1%
4.7%
14.6%
15.6%
14.0%
40%
20%
0%
11.0%
9.7%
2010
27.4
Mbdoe
2020
35.4
Mbdoe
1.5
3.6%
3.2%
1.0
4.9%
0.5
2010-2020
AAGR
2.6%
2.0
0.0
G Je
as t
o
N lin
ap e
ht
ha
60%
Other*
LPG
Naphtha
Motor Gasoline
Jet Kerosene
On-road diesel
Off-road diesel
Fuel Oil
80%
2.5
10.9%
D
ie
se
100%
Mbdoe
Incremental Demand
2010-2020
50
C3= with ZSM5
LN with ZSM5
LN without ZSM5
12
Propylene, wt%
48
46
10
44
42
40
38
36
LN, wt%
14
34
76
78
80
82
Conversion, wt%
84
86
6
50
Molar profile
Feed=100
Aromatics
C5=
20
40
C3=
15
30
10
20
C6=
C4=
10
C7=
0
0
50
100
150
Increasing
Conversion
200
0
250
Other Options:
C4 Cut Direct Recycle Cracking
18
14
12
Olefin
Paraffin
50
Aromatics
40
10
Wt%
Wt%
60
Gas
Propylene
Gasoline
16
30
20
10
20
40
60
Butene Conversion, %
80
20
40
60
Butene Conversion, %
80
C4 Raffinate
Gasoline
Gasoline
Recycle
FCC Feed:
VGO/Resid
GTF ARTC 2012 - Bangkok
Distillate
Fuel Gas
Propylene
LPG
Gasoline
Distillate
Fuel Oil
TM
PolyNaphthaTM
Oligomerization
Recycle Selected
Oligomers to FCC Riser
to Maximize Propylene
Distillate
Motor
Fuels
Recover Oligomers as
or Gasoline or
or Distillate
Distillate to
to
optimize G/D
G/D ratio
ratio
10
LCN
C4 Oligomers
11
Flexibility Example:
FlexEne Applied to C4 or C3/C4 Cut
100%
90%
80%
70%
Dry gas
60%
50%
Gasoline
40%
Distillate
DCO
30%
Coke
20%
10%
0%
Max Gasoline
FCC alone
GTF ARTC 2012 - Bangkok
12
Propylene
PolyNaphtha
Gasoline Mode
Propylene for
Max Gasoline
FCC C4 cut
Distillate
GTF ARTC 2012 - Bangkok
Gasoline
Motor
Fuel
13
Flexibility Example:
FlexEne Applied to C4 or C3/C4 Cut
100%
90%
80%
70%
Dry gas
60%
50%
Gasoline
40%
Distillate
DCO
30%
Coke
20%
10%
0%
Max Gasoline
Max Gasoline
FCC alone
FCC + FlexEne
14
Propylene
Propylene for
Max Distillate
FCC C4 cut
Gasoline
GTF ARTC 2012 - Bangkok
PolyNaphtha
Distillate Mode
Distillate
Motor
Fuel
15
Flexibility Example:
FlexEne Applied to C4 or C3/C4 Cut
100%
90%
80%
70%
Dry gas
60%
50%
Gasoline
40%
Distillate
DCO
30%
Coke
20%
10%
0%
Max Gasoline
FCC alone
Max Gasoline
Max Distillate
16
Propylene
FCC C4 cut
Gasoline
&
Distillate
PolyNaphtha
Conversion Mode
Motor
Fuel
17
Flexibility Example:
FlexEne Applied to C4 or C3/C4 Cut
100%
5.0
90%
80%
4.0
70%
Dry gas
60%
G/D
3.0
50%
40%
2.0
30%
Coke
20%
1.0
G/D
10%
0%
0.0
Max Gasoline
FCC alone
Max Gasoline
Max Distillate
Max Propylene
FCC + FlexEne
18
19
FlexEne Advantages
20
68,000 bpsd
R2R technology, >10 wt% Propylene
FlexEneTM, Gasoline & Propylene mode
Feed: API=23, CCR=3, S = 1.6 wt%
21
VGO Application:
PETRON Bataan Refinery
Source:Petron
35,900 bpsd
250 000 ktpa of Propylene
FlexEneTM, Gasoline & Propylene mode
Feed: VGO + Hydrotreated Coker Gasoil
22
Conclusion
23