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Based on all industrial sector, mostly reactor is the main equipment that are used where it changes
from the raw materials into the desire product that are needed. The criteria for the good reactor is it
produced a high production and also economical. There are many types of reactor depending on the
nature of the feed materials and products. The rate of reaction is the most important thing that we are
considered in the reactor because it showed the effectiveness of the processing of the reactor. A most
common ideal reactor type in chemical engineering is the continuous stirred tank reactor or known as
CSTR.
In a continuous stirred tank reactor (CSTR), reactants and products are continuously added
and withdrawn from the reactor. The CSTR is the idealized opposite of the weel-stirred batch and
tubular plug flow reactors. Analysis of selected combination of these reactors types can be useful in
quantitatively evaluating more complex gas-, liquid-, and solid-flow behaviours.
need to know in the various chemical reaction was the rate of the reaction.
By studying the saponification reaction of ethyl acetate and sodium hydroxide to form sodium
acetate in a batch and in a continuous stirred tank reactor, we can evaluate the rate data needed to
design a production scale reactor.
A stirred tank reactor (STR) may be operated either as a batch reactor or as a steady state flow
reactor (CSTR). The key or main feature of this reactor is that mixing is complete so that properties
such as temperature and concentration of the reaction mixture are uniform in all parts of the vessel.
Material balance of a general chemical reaction described below.The conservation principle requires
that the mass of species A in an element of reactor volume dV obeys the following statement:
(Rate of A into volume element) - (rate of A out of volume element) + (rate of A produced within
volume element) = (rate of A accumulated within vol. element)
Objectives :
THEORY
1
The conservation principle required that the mass of species A in an element of reactor volume V
obeys the following statement:
Rate of
Rate of
Rate of A
Rate of A
Accumulate
into
out of
produced
within
within
volume
volume
volume
volume
element
element
element
Element
Rate of A
accumulate
produced
within
within
volume
volume
element
element
1/-rA
Area = t
CA
the rate of reaction. Collisions between molecules will be more violent at higher
temperatures. The higher temperatures mean higher velocities. This means there will be less
time between collisions. The frequency of collisions will increase. The increased number of
collisions and the greater violence of collisions result in more effective collisions. The rate
for the reaction increases. Reaction rates are roughly doubled when the temperature increases
by 10 degrees Kelvin.
In any single homogenous reaction, temperature, composition and reaction rate are
uniquely related. They can be represented graphically in one of three ways as shown below:
r3
r2
r1
CSTR runs at steady state with continuous flow of reactants and products; the feed assumes a uniform
composition throughout the reactor, exit stream has the same composition as in the tank.
Assumptions
Steady state, therefore dNA/dt = 0
PROCEDURES
4.
5.
6.
7.
8.
iiiiiiivv-
0% conversion
25% cinversion
50% conversion
75% conversion
100% conversion
: 100 mL NaOH
: 75 mL NaOH + 25 mL Et (Ac)
: 50 mL NaOH + 50 mL Et (Ac)
: 23 mL NaOH + 75 mL Et (Ac)
: 100 mL Et (Ac)
1.
2.
3.
4.
5.
RESULTS
Reactor volume : 40 L
Concentration of NaOH in feed tank : 0.1 M
Concentration of Et(Ac) in fee tank : 0.1 M
No
Outlet
Amount
NaOH
of
(mL/min)
(mL/min)
Solutions
0.11
0.10
(mL/min)
0.21
(m/S/cm)
2.14
26.37
0.14
0.15
0.29
1.95
26.23
0.20
0.21
0.41
1.86
25.90
0.24
0.25
0.49
1.80
25.87
0.29
0.30
0.59
1.77
25.80
of
NaOH (mL)
Average amount of
NaOH (mL)
0.10
26.0
26.6
26.5
26.37
0.15
25.9
26.5
26.3
26.23
0.20
25.8
25.9
26.0
25.90
0.25
25.9
25.8
25.9
25.87
0.30
25.6
25.9
25.9
25.80
SAMPLE CALCULATIONS
10
F0 = 0.21 ml/min
i-
ii-
iii-
iv-
v-
vi-
vii-
Flowrate
of
(mL/min)
26.37
26.23
25.9
25.87
25.8
94.52
95.08
96.40
96.52
96.80
47.00
34.48
24.39
20.41
16.95
97
96.5
96
95.5
95
94.5
94
93.5
93
16.95
20.41
24.39
20.41
16.95
To achieve three objectives which are to carry out the saponification process between NaOH
and Et (Ac) in a CSTR reactor, to determine the effect of the residence time onto the reaction
extent of conversion and lastly to determine the constant rate of reaction. From the data
collected, graph had been plotted is residence time versus conversion.
From the graph, the conversion of NaOH is seen to be increasing as the time increase,
this is true from the theoretical analysis of the CSTR reactor.
For the saponification process, it is one kind of process to make a soap. Saponification
process is a continuous reaction. In this experiment, the reaction of saponification is
quenching with hydrochloric acid to stop the reaction. The reaction rapidly reacts in
increasing of experiment. Back titration is done to investigate if the reaction is stop.
12
CONCLUSION
Based on the objectives of this experiment, which is to determine the residence time onto the
reaction extent of conversion, the relationship conversion and residence time was directly
proportional. But the reaction rates constant were determined for all varies flow rate. From
the calculated data, the rate constant of reaction is increasing when the conversion is higher.
The experiment that was conducted can be described as successful as it obey the theoretical
analysis with little errors.
RECOMMENDATIONS
1. Make sure reactor does not have any leaks and valve closed and opened as needed,
controlled the valve carefully and slowly when adjusting the flow rate to obtain 0.10
L/min. It is to make sure flow rate will stabilize and the experiment will run smoothly.
2. Repeat titrations two or three times because a lot of error comes from titration or use
another method other than titration.
3. Divide into two teams which is the first team in charge of the CSTR 40 liters machine
while the second team would carry out the back titration procedures.
4. Take conductivity reading when the conductivity not changes in time because it can
change rapidly in short of time.
REFERENCES
13
14
APPENDICES
15