Visijet FTX Green

Safety Data Sheet
according to Regulation (EC) No 1907/2006 (REACH),

GHS Rev 04 (2011): US, OSHA, CMA, ANSI,
WHS Regulations Australia; JIS Z 7253 (2012): Japan
VisiJet FTX Green

Revision Date: September 15, 2014
1. IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY/UNDERTAKING

1.1 Identification of the mixture:
VisiJet FTX Green
1.2 Use of the preparation: For use with ProJet 1200 system
1.3 Company/undertaking identification:
3D Systems, Inc.
333 Three D Systems Circle
Rock Hill, South Carolina
U.S.A.
Phone: 803.326.3900 or
Toll-free Phone:
800.793.3669
e-mail:
moreinfo@3dsystems.com
Chemical Emergency:
800.424.9300 Chemtrec
3D Systems Europe Ltd.

Mark House, Mark Road
Hemel Hempstead
Herts HP2 7
United Kingdom
Phone: +44 144-2282600
e-mail:
Chemical Emergency:
+1 703.527.3887 Chemtrec
3D Systems / Australia
5 Lynch Street
Hawthorn, VIC 3122
+1 03 9819-4422
e-mail:
Chemical Emergency:
+(61) 29037.2994 Aus
Chemtrec
3D Systems Japan K.K.

Ebisu Garden Place Tower 27F
4-20-3, Ebisu, Shibuya-ku, Tokyo
50-6027 Japan
Telephone No. +81-3-5798-2500
e-mail:
Chemical Emergency
+(81)-345209637 Chemtrec
2. HAZARDS IDENTIFICATION
2.1 Classification:
GHS : Regulation (EC) No. 1272/2008, HazCom 2012, Australian Dangerous Goods Code:
Eye irritation
Category 2
H319
Skin irritation
Category 2
H315
Skin Sensitization
Category 1
H317
Regulation (EC) 67/548/EEC and 1999/45/EC:

Xi, R 36/38, R 43
2.2 Label Elements
Regulation (EC) No, 1272/2008:
Hazard pictograms and signal word:
GHS07
Signal word: Warning
Hazard determining components of labelling: Triethylene glycol diacrylate
Hazard statements:
H319:
Causes serious eye irritation
H315:
Causes skin irritation
H317:
May cause an allergic skin reaction
Precautionary statements:
P280:
Wear protective gloves, protective clothing, eye protection
P302+350:
If on skin, wash with soap and water
P305+351+338:
If in eyes, rinse cautiously with water for several minutes. Remove contact lenses if
present and easy to do. Continue rinsing
P410+403:
Protect from sunlight. Store in a well-ventilated place
P501:
Dispose of contents/container in accordance with local/regional regulations
SDS VisiJet FTX Green 341600-S12-01-A ENGLISH GHS
Safety Data Sheet

VisiJet FTX Green

1
2
Hazardous Materials Identification System

(HMIS):
(Degree of hazard: 0 = low,
4 = extreme);
Health
2
Flammability
1
Physical Hazards
1
NFPA Ratings
0 = Minimal
1 = Slight
2 = Moderate
3 = Serious
4 = Severe
Personal Protection:
Skin, eye protection
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Chemical characterization:
Description: Organic mixture
3.2 Dangerous components:
Classification
Chemical name
CAS-No
EC-No
Triethylene glycol diacrylate
1680-21-3
216-853-9
40-55
Tricyclodecane dimethanol
diacrylate
42594-17-2
255-901-3
Phenylbis (2,4,6-trimethyl
benzoyl)- phosphine oxide
162881-26-7
423-340-5
Regulation (EC)
1272/2008
Eye Irrit.2, H319,
Skin Irrit. 2, H315
Skin Sens. 1, H317
Regulation 67/548/EEC,
1999/45/EC
15-25
Skin Irrit.2, H 315
Xi, R38
1.5-2.5
Skin Sens. 1, H317

Aqu. Chron. 4, H413
Xi, R43,53
Xi, R36/38, 43
4. FIRST AID MEASURES

4.1 General Information: Ensure that eyewash stations and safety showers are close to the workstation location.
4.2 In case of inhalation: May cause respiratory irritation. Move affected person to fresh air. If respiratory
irritation occurs, if breathing becomes difficult seek medical attention immediately.
4.3 In case of skin contact: May cause irritation or sensitization by skin contact , including redness and/or
swelling. Immediately flush skin with plenty of soap and water. Remove contaminated clothing and shoes. Get
medical attention if symptoms occur. Wash clothing before reuse.
4.4 In case of eye contact: Irritating to eyes. Causes redness, swelling and pain. Immediately flush eyes with plenty
of water for at least 15 minutes. Get medical attention if symptoms persist.
4.5 In case of ingestion: Irritating to mouth, throat and stomach. If ingested, drink plenty of water and seek
immediate medical attention. Do not induce vomiting.
4.6 Self-protection of the first aider: Put on appropriate protective equipment (see section 8). Move exposed
person to fresh air. Remove contaminated clothing and shoes.
5. FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media: Water mist, dry chemical, carbon dioxide, or appropriate foam.
5.2 Extinguishing media which must not be used for safety reasons: High volume water jet.
Safety Data Sheet

VisiJet FTX Green

5.3 Special exposure hazards arising from the substance or preparation itself, combustion products,
resulting gases: Thermal decomposition products can include CO2, CO, NOx and smoke.
5.4 Special protective equipment for fire-fighters: Wear full protective clothing, including helmet, selfcontained positive-pressure or pressure demand breathing apparatus, protective clothing and facemask.
5.5 Additional information: Move container from area if it can be done without risk. Cool containers with water
spray. Avoid inhalation of material or combustion by-products.
6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions: Keep unnecessary personnel away. Wear appropriate protective equipment and
clothing. Consult expert immediately.
6.2 Environmental precautions: Stop the flow of material, if this is without risk. Ventilate contaminated area.
Eliminate sources of ignition. In case of contamination of aquatic environment inform local authorities.
6.3 Methods for cleaning up: Wear appropriate protective equipment and clothing. Absorb spillage with suitable
absorbent materials. Place all waste in an appropriate container for disposal. The material and its container must
be disposed of as hazardous waste. Keep away from sources of ignition.
7. HANDLING AND STORAGE

7.1 Handling Provide adequate ventilation. Use suitable protective equipment. Avoid contact with skin and eyes.
Do not breathe vapors or mist. Avoid ignition sources. Do not allow to enter drains or watercourses.
7.2 Storage: Store sealed in the original container at room temperature. Keep this material indoors in a cool, dry,
well ventilated place. Store out of direct sunlight or UV light sources. Storage Temperature: below 35 C / 95 F.
Storage class 10, environmentally hazardous liquids.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Exposure limit values:
General Product Information: No occupational exposure limits (PEL/TWA) have been established for this product.
Component Analysis:
Component Manufacturer IEL
Component
(Internal Exposure Limit)
Phenylbis (2,4,6-trimethyl benzoyl)- phosphine oxide
Inhalation: 7,8 mg/m3

Dermal: 3,3 mg/kg
8.2 Exposure controls

Technical measures to prevent exposure: Use explosion-proof local exhaust ventilation.
Instructual measures to prevent exposure: When using, do not eat, drink or smoke. Wash hands after handling
and before eating, smoking and using the lavatory and at the end of the day.
Personal protection equipment:
Respiratory protection: If ventilation cannot effectively keep vapor concentrations below established limits,
appropriate certified respiratory protection must be provided.
Hand protection: Use impervious nitrile gloves.
Eye protection: Wear safety glasses or chemical goggles.
Body protection: Use apron and closed shoes.
Safety Data Sheet

VisiJet FTX Green

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Appearance:
Physical state: Liquid
Colour: Green
Odour: Mild
9.2 Important health, safety and environmental information
pH (20 C):
Melting point/range (C):
Boiling point/range (C):
Flash point (C):
Ignition temperature (C):
Vapour pressure (C):
Density (g/cm3):
Bulk density (kg/m3):
Water solubility (20C in g/l):
Partition coefficient:
n-Octanol/Water (log Po/w):
Viscosity, dynamic (mPa s):
Dust explosion hazard:
Explosion limits:
NA
NA
NA
176C
NA
NA
1.1
NA
insoluble
NA
NA
NA
NA
NA
10. STABILITY AND REACTIVITY

10.1 Conditions to avoid: Avoid exposure to heat and light. Take necessary actions to avoid static electricity
discharge.
10.2 Materials to avoid: Oxidizing materials, strong acids and strong bases
10.3 Hazardous decomposition products: Carbon dioxide, carbon monoxide and other toxic fumes can be
released at high temperatures or upon burning.
11. TOXICOLOGICAL INFORMATION

11.1 Toxicokinetics, metabolism and distribution: NA
11.2 Acute effects (toxicity tests)
Component
Triethylene glycol diacrylate
LD50 Oral
NA
> 2000 mg/kg
LD50 Dermal
NA
>2000 mg/kg
Irritation to respiratory tract: irritating

Skin irritation: irritating
Eye irritation: irritating
Sensitisation: Causes sensitisation
11.3 Experiences made in practice
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
11.4 General remarks:
Carcinogenicity: None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP.
Safety Data Sheet

VisiJet FTX Green

12. Ecological information

12.1 Ecotoxicity: The aquatic toxicity of the product is unknown; however based on components, it is predicted
that this material may be harmful to aquatic organisms or cause long-term adverse effects in the aquatic
environment. Prevent contamination of soil, drains and surface waters.
Component
Data
EC50 > 1.175 mg/L (48 h, Daphnia magna)

LC50 > 0.09 mg/L (96 h, Zebra fish)
12.2 Mobility: No information available for product.

12.3 Persistence and degradability: No information available for product.
12.4 Results of PBT assessment: No information available for product
12.5 Other adverse effects: No information available for product
13. DISPOSAL CONSIDERATIONS
13.1 Appropriate disposal / Product: Do not contaminate drains, soil or surface waters with this material or its
container. Reduce waste by attempting to utilize product completely. Dispose of this container and its contents in
accordance with all local, state, and federal regulations. Do not reuse or refill.
13.2 Waste codes / waste designations according to EWC / AVV: 070208
13.3 Appropriate packaging: NA
13.4 Additional information: Prior to disposal 3D Systems recommends consulting an approved waste disposal
firm to ensure regulatory compliance.
14. TRANSPORT INFORMATION
14.1 Land transport (ADR/RID/GGVSE): Not Regulated
Official transport designation:
Class:
Classification Code:
UN-No.:
Packing group:
Hazard label:
Tunnel restriction code:
Special provisions:
14.2 Sea transport (IMDG-Code/GGVSee): Not Regulated
Proper Shipping Name:
Class:
UN-No.:
Packing group:
EmS:
Marine Pollutant:
Special provisions:
14.3 Air transport (ICAO-IATA/DGR): Not Regulated
Proper Shipping Name:
Class:
UN-No.:
Packing group:
Special provisions:
Safety Data Sheet

VisiJet FTX Green

15. REGULATORY INFORMATION

15.1 EU regulations
EINEC/ELINCS/NLP: All materials are listed
REACH Annex XVII: None listed
15.2 National EU regulations
Wassergefhrdungsklasse (water hazard class, Germany): WGK 2: Hazard to waters
15.3 US FEDERAL
TSCA: All materials are listed on the TSCA Inventory or are not subject to TSCA requirements
SARA 302 EHS List (40 CFR 355 Appendix A): None listed
SARA 313 (40 CFR 372.65): None listed
CERCLA (40 CFR 302.4): None listed
15.4 Australian regulations
SUSDP, Industrial Chemicals Act 1989:
Australian Inventory of Chemical Substances, AICS: Listed
15.5 Japanese regulations
Chemical Risk Information platform (CHRIP):
Industrial Health and Safety Law
Hazardous material
Organic solvent poison prevention rule
Ordinance on prevention of hazard due to
specified chemical substances
Lead Poisoning Prevention Rule
Poison and Deleterious Substance Control law
PRTR and Promotion of Chemical
Management law (PRTR Law)
Fire Services Act
Explosives Law
High pressure gas safety law
Export Trade Control Order
Waste Disposal and Public Cleaning Law
Listed
not applicable
not applicable
not applicable
not applicable
not applicable
not applicable
no listed components
Category 4, Class 3, oil
not applicable
not applicable
not applicable
applicable, industrial waste
16. OTHER INFORMATION

16.1 Relevant Hazard Statements (number and full text) referred to in sections 2 and 3 (according to (EC)
No. 1272/2008):
Skin irrit. 2, H 315- Skin irritation, category 2, H315: Causes skin irritation
Skin sens. 1, H 317- Skin sensitization, category 1, H317: May cause an allergic skin reaction
Eye Irrit. 2, H319- Eye irritation, category 2, H319: Causes serious eye irritation
Aqu. Chron. 4, H413 - Aquatic environment long-term hazard, category 4, H413: May cause long lasting harmful
effects to aquatic life
Relevant R-Phrases (number and full text) referred to in sections 2 and 3:
R36/38- Irritating to eyes and skin
R43: May cause sensitization by skin contact
R53: May cause long-term adverse effects in the aquatic environment
16.2 Further information:
SDS Creation Date: ....... February 17, 2014
SDS Revision #: .......... 01-A
SDS Revision Date: ....... September 15, 2014
Reason for Revision: ..... Update Section 15
Safety Data Sheet

VisiJet FTX Green

www.3dsystems.com
800.793.3669 (Toll-free in the US GMT-07:00; N. America, Mon Fri, 6:00 a.m. to 6 p.m.)
803.326.3900 (Outside the U.S. GMT-07:00; N. America, Mon Fri, 6:00 a.m. to 6 p.m.)
+44 144-2282600 (Europe GMT+01:00; Mon Fri, 08:00 a.m. - 17:00 p.m. MEZ
DISCLAIMER OF LIABILITY: The following supersedes any related provision in your companys forms, letters, and agreements
from, by or with 3D Systems Corporation. 3D Systems, Inc. makes no warranty whether expressed or implied, including
warranties of merchantability or of fitness for a particular purpose for this product. No statements or recommendations contained
in the product literature are to be construed as inducements to infringe any relevant patent now or hereafter in existence. Under
no circumstances shall 3D Systems, Inc. be liable for incidental, consequential, or other damages from alleged negligence,
breach of warranty, strict liability or any other theory, arising out of the use or handling of this product. The sole liability of 3D
Systems, Inc. for any claims arising out of the manufacture, use or sale of its products shall be for the buyers purchase price.
The contents of this safety data sheet are subject to change without notice. 3D Systems, Inc. recommends that you periodically
check www.3dsystems.com to make sure you are using the most current safety data sheet.
Copyright 2014 by 3D Systems, Inc. All rights reserved. The 3D logo, ProJet and VisiJet are registered trademarks of
3D Systems, Inc.

Visijet FTX Green

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Safety Data Sheet

according to Regulation (EC) No 1907/2006 (REACH),