Beruflich Dokumente
Kultur Dokumente
Institute
of
1464
FtG .2. (a) Thin section of a Darwin glass showing layering, stress,
and flow features. (b) The thin section shows large elongated vesicles
(flow structure) and layering (both pictures: crossed nicols, picture
size: 1.66 X 1.11 mm).
146.5
wt%, MgO from 0.61 to 2.51 wt%, and CaO from 0.03 to
0.23 wt%).
To study the variations of major elements within individual
samples and between differently colored layers, electron microprobe analyses were performed for each glass chip The
results for EPMA (average of several data points 1, DCP, and
INAA are in good agreement with each other. Because of the
good agreement of the average microprobe analyses with the
other techniques, only the results of the bulk sample analyses
are given in Table 1 (except for SiOz 1. For a more detailed
study of the chemical variations between individual layers,
a microprobe profile of 0.6 mm length was measured on one
Darwin glass section (distance between indi~du~ points
varied between 20 and 250 rm). The variations of SiOz,
KzO, and MgO in the profile are shown in Fig. 3a,b. The
high-silica regions most probably represent lechatelierites,
corresponding to depletions of all other major elements.
Correlation plots of A1z03 vs. Fe0 or K20 vs. Fe0 (not
given here) show two different sections in the resulting curve:
a positively correlated part with a steep slope grading into a
negatively correlated curve with a less pronounced slope. The
Siq vs. Alz03 and MgO vs. Fe0 plots exhibit only one trend:
a negative correfation for the first pair and a positive one for
the latter. A thr~~imensional
plot of SiO2 vs. Fe0 and MgO
is given in Fig. 4 and demons~ates clearly these two components. This observation can be explained by mixing at least
two components with dissimilar elemental abundance ratios,
with one component being rich in K20 and SiO, . The mixing
of the silica-rich component (quartzite?) may not have been
complete, leading to lechatelierite inclusions.
The color differences between individual layers are probably due to changes in the oxidation state of Fe, because no
major variation of the Fe content was found in the microprobe
profiles. The Fe content of the frothy white parts does not
differ significantly from the colored parts of the glass. Thus
the optical appearance might be due to a variable number of
vesicles and differences in the oxidation state of Fe.
The trace element abundances (Table I ) also show large
variations between individual samples. The concentrations
of Li, Be, SC, Rb, REE, Ta, and Th vary by a factor of less
than 2; Be, Zr, Cd, Ba, Hf, and U show variations by a factor
of about 2; and Cr, Mn, Co, Ni, Cu, Zn, and Sb vary by
factors that are larger than 2. Some of these differences have
been observed before by TAYLORand SOLOMON( 1964) and
led them to divide the Darwin glasses into two distinct groups:
one with average element abundances and another enriched
in Cr, Ni, and Co.
4.2. Group ~lassl~cation
Since we have a more extensive data set available, we tried
to verify and expand the group classification of TAYLORand
SOLOMON( 1964). Statistical methods were used for discriminating the data (cluster and discriminant analysis with the
elements Fe, Mg, Na, Ti, Cr, Co, and Ni, following techniques
described by HOWARTH and SINDINGLARSEN, 1983, and
MILLIGAN, 1980). The results of these calculations show that
our glass samples form three distinct chemical groups. The
groups are termed A, B, and C and can be characterized as
foIlows: group A (56% of our samples) as average Darwin
1466
SKI,%
DGOI
C
DGO2
B
DG03
A
DG04
A
DG05
A
DG06
A
DG07
B
DG08
A
DG09
A
DGlO
C
DGII
A
DG12
A
DGl3
C
DG14
B
DG15
B
DG16
C
DG17
DGl8
84.7
85.1
87.8
87.8
87.0
66.6
84.1
87.1
89.3
84.6
85.8
863
86.9
84.0
84.5
847
87.5
86.1
AVG
66.1
Al,O,%
7.66
8.04
6.75
7.19
6.77
659
7.63
7.44
7.00
7.50
6.83
7.21
7.25
8.20
8.47
5.79
7.17
6.90
725
FeO'%
2.62
3.49
1.08
1.16
2.14
2.11
3.37
1.79
1.06
2.70
2.44
2.67
1.89
3.33
3.78
2.37
1.&j
2.25
2.51
085
0.09
t&O%
1.13
0.61
0.67
0.67
0.70
0.68
0.66
0.66
0.62
0.78
0.66
0.63
1.46
0.63
0.73
2.51
0.75
061
GO%
0.06
0.03
0.04
0.11
0.04
0.03
0.03
0.09
0.11
0.06
0.08
0.07
0.16
0.07
0.12
0.23
0.10
0.08
361
217
211
215
232
220
217
231
tO%
2.16
2.93
1.76
2.42
1.60
2.12
2.36
240
248
283
1.99 2.76
TiO,%
0.61
0.59
0.55
0.58
0.53
053
056
0.55
0.58
25
0.2
7.2
55
42
6.3
70
3
7
27
0.3
8.2
52
50
5.2
51
u
Be
E
E
CN:
Zn
Ga
As
Fib
Zr
32
0.2
7.6
103
201
22.0
207
38
0.2
8.1
51
54
4.6
30
20
27
0.5
0.2
6.9
7.3
54
522
53
32
4.9
5.5
52
59
3
1:
1:
7
1:
______-_._-5
24
0.2
7.4
56
38
6.7
67
1:
1:
0.56
20
227
243
1.69 2.02
0.52
22
25
0.3
0.3
0.2
7.2
6.3
6.9
48
65
95
43
48
202
6.1
7.9 16.8
84
112
147
12
IO
19
15
19
13
18
0.2
6.9
50
51
5.7
55
0.7
0.4
04.
I::
0.55
22
462
230
1.66 2.08
0.53
20
059
14
277
708
299
245
1.73 1.51 1.62 1.70
0.62
29
0.52
15
0.2
0.2
03
0.3
0.2
6.5
6.0
7.4
6.6
7.6
60
151
99
83
324
46
98
251
207
282
4.6 18.2 14.6 16.0 39.0
82
315
68
80
536
10
10
1;
12
::
1:
10
4
9
6
5
0.54
0.54
26
27
0.3
7.2
77
54
6.4
74
9
9
3
0.2
6.9
68
54
4.9
62
1;
4
106
117
86
86
84
86
102
80
77
100
72
102
98
122
137
71
93
94
461
410
547
460
403
470
363
454
360
410
412
278
476
295
293
254
281
516
0.6
0.1
0.03 0.2
0.1
0 1
0.1
0.2
0.2
0.2
0.1
0.2
0.1
0.1
0.1
0.1
0.1
0.1
_
_
0.6
0.5
0.3
0.2
0.5
0.3
0.3
3.0
2.9
3.9
3.2
3.0
3.9
2.9
2.5
3.2
4.3
4.3
2.5
3.2
3.3
4.5
3.2
2.9
3.6
182
306
288
218
253
265
240
232
258
346
266
349
302
436
450
257
257
339
43.6 43.6 46.5 42.4 44.0 43.2 43.9 42.4 37.3 35.0 38.0 36.2 35.5 37.5 42.3 35.2 40.7 37.0
96.0 96.6 97.8 97.6 96.6 94.0 93.7 93.6 87.8 81.8 85.3 70.0 74.0 72.3 86.6 80.6 SO.2 83.1
38
42
37
34
38
34
32
35
36
33
30
33
33
29
34
31
40
36
7.6
7.5
7.4
7.5
7.2
7.5
7.0
7.4
8.3
7.9
6.9
9.0
8.1
6.7
8.0
6.6
6.1
8.5
1.4
1.2
1.4
1.4
1.5
1.3
1.3
1.4
1.3
1.2
1.2
1.3
1.4
1.3
1.3
1.3
1.3
0.9
1.4
1.4
1.2
1.3
1.4
1.2
1.3
1.4
1.4
1.4
1.4
1.3
1.2
1.3
1.1
1.0
1.3
1.3
7.7
7.8
6.7
66
7.1
6.0
7.7
8.1
7.9
7.5
7.8
6.8
6.5
6.5
6.8
5.5
65
6.1
3.0
4.0
4.0
4.0
4.4
3.2
4.0
36
2.7
34
3.9
3.5
4.2
4.0
4.0
3.8
3.5
4.5
0.7
0.7
0.5
0 7
0.8
0.6
06
0.7
0.7
0.7
0.7
0.6
0.6
0.5
0.5
0.6
0.7
0.8
20
20
16
16
14
15
15
13
14
12
13
11
13
15
14
13
15
13
1.4
1.7
1.1
14
1.6
1.3
1.2
1.1
1.2
1.2
1.1
1.1
1.3
1.4
1.5
1.3
1.3
1.6
19
19
18
17
17
17
15
15
16
14
12
15
16
16
16
15
18
18
3.1
2.4
2.1
5.4
3.0
2.8
1.9
2.3
1.5
3.7
34
2.6
2.6
2.8
2.0
2.6
3.3
3.2
7.6
7.4
8.3
7.4
7.9
6.5
6 7
8.7
72
69
6.0
8.6
7.8
8.2
8.3
6.8
'bN)7.8
7.2
265
2.04
0.56
24
0.2
7.1
86
99
11.0
120
9
13
5
0.5
95
397
0.2
0.4
3.3
291
40.3
87.7
34.7
7.7
1.3
1.3
7.1
3.8
0.6
15
1.3
163
2.8
7.5
1467
90
L.
80
0
0,5
1,5
23
3.5
4,5
5.5
3.5
4,5
5.5
mm
2,5
0
0
0,5
1,5
2.6
mm
ination might be considered. MgO, Cr, Co, and Ni are positively correlated with each other (see Fig. 5b); thus, a single
component may have been the source for these anomalies.
1468
Mgo
wty
F@O
0
wt%
FIG. 5. (a) Three-dimensional plot of Ni vs. Fe0 and MgO. This is one of the plots that can be used to distinguish
the three glassgroups (A, B, C) . Note the large variation of Ni and MgO in group C glasses.(b) This three-dimensional
ulot of Ma0 vs. Ni and Cr shows the strone wsitive correlation of these three elements in glasses of group C; T
= glassesf;otn TAYLORand SOLOMON (1964).-
~~e~t~rnposkon
Etl-DG
A-DG
Gw#uits
SiO, %
92.7
S2-DG
8%DG
Cl-DG
shaln
70.4
77.3
14.3
14.7
11.4
4.18
FeO* %
0.11
4.14
4.91
C2.OG
87.4
89.4
87.4
7.10
5.78
6.87
1.44
0.36
0.40
0.57
0.90
MgO%
0.42
3.42
3.13
1.85
0.56
0.58
CaO%
0.06
0.71
0.05
0.06
0.04
0.05
Na
458
647
396
C3-DG
Sandstones
68.6
A$Os
oftafgetfwks
352
1020
239
0.08
245
uzo %
1.15
3.84
3.65
3.96
2.30
2.14
1.91
TiO, %
0.44
0.80
0.79
0.71
0.45
0.43
0.41
H20-%
0.08
0.15
0.01
0.16
0.04
0.01
0.01
L.O.I.%
0.67
4.07
2.31
3.17
1.55
1.08
1.77
SC
3.1
11.6
11.8
9.9
7.1
5.2
8.4
Cf
66
100
94
65
41
61
72
Mn
36
11
21
13
co
1.1
6.3
0.4
Ni
61
42
15
23
11
11
cu
33
17
<2
s2
15
2.6
1.2
5.0
0.5
30
123
82
24
18
Ga
15
18
15
23
Ii
1t
Rb
67
323
326
204
130
103
118
Zr
634
118
104
195
96
272
256
Sb
<t
<t
Cl
7.2
7.1
Zll
cs
Ba
1.4
133
9.1
195
587
461
4.0
353
33
27s
1
3.5
315
La
17.0
34.4
41.6
36.8
29.4
21.3
Ce
25.7
72.8
90.4
64.5
63.1
46.4
36.1
59.4
29
34
28
27
19
21
Nd
9.8
Sm
2.0
5.5
8.2
6.4
4.6
2.9
4.7
EU
0.4
1.0
1.4
1.1
1.0
0.5
0.9
Tb
0.5
0.7
1.5
1.0
0.7
0.6
0.8
DY
Yb
2.7
4.6
7.0
5.4
4.2
3.7
3.9
2.2
2.5
3.4
2.f
2.6
2.3
2.7
LU
0.4
0.5
0.6
0.5
0.5
0.4
0.4
Hf
18
11
Ta
1.0
1.2
1.3
1.5
1.0
1.0
1.1
Th
6.2
17.3
18.4
16.4
13.1
4.7
7.7
2.5
3.2
4.9
3.6
3.1
2.2
1.4
exceptwere
~rk~in~%
~lconcentmti~in
l:Totat Fe
ppm
expressed as&C
1469
vary si~ificantly. Figure 7a gives the range of REE abundances by plotting the samples with the highest and lowest
REE contents in comparison with PAAS ( post-Archean Australian sediment). All patterns have pronounced negative EUanomalies and are typical of post-Archean sedimentary rocks.
The samples of group C show the lowest REE concentrations.
Figure 7b and c gives the REE patterns of the target rocks,
again in comparison with PAAS. The quartzite ( A-DG) has
the lowest abundances, while one of the shales (B2-DG) has
higher REE contents than the glasses. Mixing calculations
reproduce the shape of the patterns very well. The REE pattern of PAAS is simiku to Darwin glasses regarding the absolute abun~nc~
of LREEs, but Darwin glass shows sii~~y
higher HREE contents, which can be explained by a higher
zircon contribution from the target rocks.
6. MIXING CALCULATIONS FOR ANOMALOUS
ELEMENT ENRICHMENTS
None of the country rocks analyzed by TAYLORand SOLOMON( 1964) or the target rocks analyzed in the course of
this work can be considered as source of enrichments of Cr,
Ni, and Co that are found in Darwin glass. This implies another, non-~dimenta~
source, for which two ~ssibilities
can be proposed: i ) a terrestrial ultrabasic source rock; or 2)
contribution from an extraterrestrial body. Ultrabasic source
rocks as cause of the enrichments have been suggested by
MEISELand KOEBERL( 1988). However, such rocks are not
known from the crater area, and are rather unlikely to occur
in the Silurian and Devonian sedimentary series of the Darwin
crater, but their existence cannot be ruled out completely.
If the enrichment is of extraterrestrial origin (from the
impactor), platinum group element abundances are important to identify the composition of the impacting body (e.g.,
MORGANet al., 1975; PALMEet al., 198 1). For Darwin glass,
P&group data am very sparse. BAEDECKERand EHMANN
(1965) reported 0.2 ppb Ir in one sample, and KOEBERL
(unpubl. data) found 0.02 ppb in another sample. Our INAA
analyses did not show any evidence of an Ir enrichment and
only an upper limit of detection of 0.2-0.6 ppb was calculated.
We performed mixing calculations aimed at reproducing
the anomalous enrichments of Cr, Ni, Co, and other elements
in group C glasses. A variable amount (i.e., a few percent)
of terrestrial ultrabasic or meteoritic material was added to
a normal glass (DG 8703) from group A (representing a
homogeneous mixture of the target rocks present at the impact site, including loss of voiatiles and other physico-chemical impact processes). The materials used for these calculations were a dun&e, IIB and IIIB iron meteorites, an achondrite ( ureilite ), and a C 1 chondrite. The results are given in
Table 4.
By comparison with data from a typical group C glass, DG
87 16, it is evident that the mixing calculations do not provide
a straightfomard explanation for the origin of the enrichments. Addition of ultrabasic material yields excess MgO
(and FeO), but otherwise gives a good agreement for most
of the minor elements. Only iron meteorites with low Ir
abundances have been chosen for the mixing calculations,
since there is a clear Ir deficiency in Darwin glass. The a8ree-
1470
Table 3. Average data for the Darwin glass groups and comparison with the mixing models
A
SiO, %
AVG
Ml
M2
M3
87.1 (1.0)
84.4 (0.5)
85.3 (1.0)
86.1 (1.5)
78.6
82.8
il 1
AI,O, %
7.0 (0.3)
8.1 (0.4)
7.1 (0.9)
7.3 (0.6)
10.6
8.6
9.5
FeO' %
2.0 (0.7)
3.7 (0.3)
2.5 (0.85)
2.5 (0.87)
2.9
1.9
1.3
MgO%
0.69 (0.06)
0.66 (0.05)
1.47 (0.75)
0.85 (0.46)
2.1
16
1.6
0.08 (0.03)
0.06 (0.04)
0.13 (0.08)
0.09 (0.05)
0.19
0.19
0.13
490
480
433
cao
Na
237
(25)
235
(28)
453
(185)
285
(123)
K,O%
1.95 (0.29)
2.28 (0.51)
2.02 (0 56)
2.04 (0.40)
2.79
2.39
3.11
TiO, %
0.55 (0.02)
0.60 (0.01)
0.55 (0.04)
0.56 (0.03)
0.66
0.59
0.64
SC
6.9 (0.3)
7.9 (0.4)
7.1 (0.6)
8.5
7.0
8.0
168 (106)
86
(65)
92
89
75
(8)
159 (124)
177 (53)
99
(85)
15
14
19
6 (1)
72 (18)
lo (6)
57 (21)
58
(9)
MIl
44
CO
Ni
71
6.8 (0.7)
(24)
24
(10)
301 (171)
11 (9)
120 (124)
1.4
31
24
17
CU
7 (3)
(3)
11
(5)
(4)
14
11
Zn
12 (4)
18
(4)
12
(1)
13
(4)
67
55
36
8 (3)
0.4
(1)
(2)
13
12
13
Ga
4 (1)
AS
0.4
Rb
Zr
86 (8)
418(W)
119
(14)
340
(57)
0.7
94 (16)
401 (102)
0.5 (0.2)
95
(18)
171
141
166
397
(ee)
283
352
319
Cd
0.1 (0.05)
0.1 (0.02)
0.2 (0.2)
0.2 (0.1)
Sb
0.3
0.6
0.4
0.4 (0.2)
1.6
CS
3.0 (0.3)
4.2 (0.2)
3 2 (0.6)
3.3 (0.6)
5.5
5.6
Ba
271
(51)
342
265
La
40.8 (3.6)
41.8 (3.0)
37.3 (4.2)
40.3 (3.8)
35
30
37
Ce
89.6 (8.6)
87.3 (10.9)
83.1 (9.3)
87.7 (9.1)
77
64
80
Nd
35.2 (3.3)
34.8 (2.7)
33.5 (4.9)
34.7 (3.4)
28
23
26
Sm
8.0 (0.7)
7.7 (0.3)
7.2 (0.8)
7.7 (0.7)
5.2
4.1
4.9
Eu
1.3 (0.1)
1.4 (0.1)
1.2 (0.2)
1.3 (0.1)
0.9
0.7
0.9
lb
1.3 (0.1)
1.3 (0.1)
1.2 (0.2)
1.3 (0.1)
1.0
0.8
0.9
DY
7.3 (0.6)
7.2 (0.7)
6.5 (1.0)
7.1 (0.8)
6.4
5.8
Yb
3.8 (0.3)
4.1 (0.5)
3.3 (0.7)
3.8 (0.5)
2.9
2.7
LU
0.6 (0.1)
0 7 (0.1)
0.6 (0.1)
0.6 (0.1)
0.5
0.5
Hf
Ta
15 (3)
1.3 (0.2)
'3
(1)
1.5 (0.2)
14 (1)
1.2 (0.2)
15 (2)
1.3 (0.2)
11.3
Th
16.6 (1.6)
16.7 (1.5)
15.4 (2.6)
16.3 (1.8)
12.4
2.8 (1.0)
3.3 (0.4)
2.5 (0.9)
2.8 (0.9)
3.6
371
(91)
262
(29)
291
(71)
1.2
12
1.1
10
3.1
336
0.5
13
1.5
19
3.4
M 7: Mixing model 30% A-DG + 20% Bl-DG + 40% EZ-DG + 10% CP-DG
M2: Mixing model 40% A-DG + 20% Bl-DG + 20% BPDG + 20% CZ-DG
M3: Mixing mode/ 30% A-DG + lo% El-DG + &J% 193.DG
cerned. we are left with a dilemma. Stony meteorites (chondrites and achondrites) provide too much Ir, although some
other elements can be fitted very well. Furthermore, PALME
et al. ( 198 1) state that most small impact craters are produced
by iron or stony-iron projectiles because ofatmospheric bmakup of the more fragile stony meteorites. But iron meteorite
mixtures give no good agreement at all (a similar problem
has been noted by OKEEFE, 1987, for two other craters). A
dunite mixture would provide a better fit, except for a slight
Fe excess (which is nevertheless smaller than for all other
mixtures), but ultrabasic rocks am not known horn the crater
area. It seems that either some ultrabasic rock or an achondrite (with slightly different absolute abundances than the
ones used for our calculations) would provide a good agreement. However, a cometary impact cannot be ruled out either,
as already suggested for other impacts (e.g., !WHMI~~, 1989 1.
For example, Halley dust has lower Fe and Ni abundances
1471
M
i
M
i
i
t
1
t
M
0
d
e
CaO
d
e
O,f
091
1 I I I 111I
1 1
10
100
(A)
REE
PW
1000 E
M
i
ripm
100
10
m
0
Ti02
d
e
d
e
IJ
001-J-u
0.01
0.1
10
100
@3
10
100
1000
ppm
REE
DC. 6. Correlation plots of data from the mixing models (using target rock data, see TabIe 3) vs. Darwin glass: (a)
major and (b) trace elements of model M2 vs. the average of glass group A (average Darwin glass group); (c) major
and (d) trace elements of model M3 vs. the average of the glass group A. A very good fit is evident for most elements,
with the exception of some volatile elements which are lost during the impact.
CONCLUSIONS
From the data and discussions given in this paper the following conclusions can be drawn:
I. The chemical composition of 18 Darwin glass samples
has been studied for major and trace elements, and is in
1472
.___-_
c
~l)!x3713
-+oUGa:04
--.-
L__ ..i2
La Ce Pr Nd
---pAAS
__l- .I ..__
---
_-.-_...
.~~._~L_..~.~.~_~__~
Sm Eu Gd Tb
L ._.. _Li_
Dy
Ho
Er
Tm
Yb
.._.A..
La
Lu
i..._
Ca
Pr
.._
,..._?
AL
Sm
Nd
Eu
__I_
_i._i
Gd
Tb
_i
_A._.._.i._
Dy
Ho
Er
Tin
_~_..~....
Yb
LU
REE
REE
..:d-._Lu_1
. ..I_
La Ce Pr
Nd
Sm
Eu
Gd
,...
x.
_.l_-i._.
Tb
Dy
_a._-_
Ho
Er
__L
L.....L
Tm
Yb
Lu
REE
shale B3-DC, and 10% shale B 1-DC provides the best fit
for the parent material of group A and B glasses. Most
elemental abundances (major and trace) are in good
agreement between the mixing model and the average glass
Table 4.
element
composition,
This may be due to the limited variety of target rock samples available for this study, and other ~sjrnilar) rocks in
the impact area may exist.
enrichments
DG8703
Af#s
Fe0
(%)
(%)
7.66
0.39
2.43
1.82
7.51
7.28
7.30
7.40
7.20
5.79
2.62
124
113
117
20.8
34
12.61
5.t
8.14
3.53
4.2
3.42
2.37
&IO
(%)
1.13
36.6
23.4
37.9
1.11
1.07
2.90
2.24
4.07
2.51
cao
(%)
0.06
1.2
1.94
1 01
0.06
0.06
0.12
0.15
0.14
0.23
Na
(ppm)
361
207
7790
1485
354
343
353
732
451
706
$0
(%)
2.16
0.002
0.11
2.12
2.05
2.05
2.06
1.99
1.51
fro,
(%)
0.61
0.2
0.11
0.09
0.60
0.58
0.59
0.59
0.57
0.54
(ppm)
54
13
33
5280
3500
3500
53
52
315
226
330
324
Mn
(ppm)
53
170
3000
2700
5650
55
51
200
166
501
207
Co
(ppm)
5.5
4600
5600
5210
175
765
119
98
285
14
43
15
39
52
5.9%
10.2%
8.44%
1030
1.51%
3000
1231
5149
141
804
288
536
co.2
27
24
416
580
975
0.74
1.4
29
49
0.1
<0.2
Cr
Nf
(PP~)
fr (W)
ffefprencec
flS84f
F, and B during the impact event, which is expected because of the high formation temperature. This can be explained by selective volatilization of these elements from
the impact melt, similar to observations made for tektites.
5. The elements Na, K, Rb, and Cs show lower abundances
in the glass than in the target rocks. This is also evidence
for a selective volatilization of the elements, but it is interesting to note that Cs shows the least depletion.
6. While the compositions of group A and B glasses can in
general be reproduced by mixing of local country rocks,
the absolute abundance of Ni and Co and also the Nil
Co, Cr/Ni ratios in glasses of group C are anomalous and
cannot be explained by contributions from the normal
(sedimentary) target rocks. Other sources, such as contamination by ultrabasic rocks, or from the impacting
body, have to be considered.
We have performed mixing calculations by adding a few
percent of ultrabasic or meteoritic material to Darwin glass
of average composition to reproduce the Cr, Ni, Mn, and
Co enrichments. Iron meteorites provide the least acceptable fit, while chondritic contamination would result
in a much higher Ir concentration than actually observed.
Better agreements are found for an ultrabasic ~ont~bution,
but no such rocks are known from the crater area, or for
an achondritic projectile; but here again an Ir excess is
present. Further investigations are clearly necessary to obtain conclusive chemical data to identify the projectile.
Acknowledgments-We
thank D. Futrell for donating some Darwin
glass samples for this study. We are grateful to K. Fredriksson, B. P.
Glass, and R. A. Schmitt for comments on the manuscript, and to
J. W. Delano, S. M. McLennan, and an anonymous reviewer for
very helpful reviews. The Lunar and Planetary institute is operated
by the Universities Space Research Association under contract no.
NASW-4066 with the National Aeronautics and Space Administration. This is Lunar and Planetary Institute ~ont~bu~on No. 739.
Editorial handling: R. A. Schmitt
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