13.Sr Chem PDF

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BOARD OF INTERMEDIATE EDUCATION

SENIOR INTER CHEMISTRY
MODEL PAPER (English Version)
n
.
a
Time: 3 Hours
Max. Marks: 60
h
b
i
SECTION - A
I.
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a
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(i) Very Short Answer Type questions.

(ii) Answer ALL questions.
up
10 2 = 20
(iii) Each question carries TWO Marks.
d
a
1.
What is "Ebullioscopic Constant"?
2.
Calculate the equilibrium constant of the reaction.
n
e
e
.
w
w
Cu (s) + 2 Ag+ (aq) Cu +2 (aq) + 2 Ag (s)

o
t
e
n
E cell = 0.46 V
3.
Give the composition of the alloys:
a) Brass and
.
a
h
b) German Silver
4.
NO is paramagnetic in gaseous state but diamagnetic in liquid and solid states.

Why?
5.
Why Conc. H2SO4, P4O10 and anhydrous CaCl2 can not be used to dry
ammonia?
6.
Why Zn+2 is diamagnetic where as Mn +2 is paramagnetic?
7.
What are artificial sweetening agents? Give 2 examples.
8.
What are tranquilizers? Give 2 examples.
9.
Write equations for carbylamine reaction of any one aliphatic amine and one
aromatic amine.
b
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a
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a
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10. What is Hell-Volhard - Zelensky reaction?
SECTION - B
II. (i) Short Answer Type questions.

(ii) Answer any SIX questions.
(iii) Each question carries FOUR Marks.
ONLINE-15 MP-2
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6 4 = 24
NEW SYLLABUS
11. Calculate the efficiency of packing in case of a metal of body -centred cubic
crystal.
12. What is relative lowering of vapour pressure? The vapour pressure of pure
benzene at a certain temperature is 0.850 bar. A non-volatile, non-electrolyte
solid weighing 0.5 g when added to 39 g of benzene; vapour pressure of the
solution is 0.845 bar. Calculate the molar mass of the solid substance.
t
e
n
.
a
h
b
i
13. a) Write possible chain isomers for C4H9Br.
b) Predict the order of reactivity of the following compounds in SN 1and SN 2

reactions:
t
a
r
C6H5CH2Br, (C6H5)2CHBr, C6H5CH(CH3)Br, (C6H5 )2 C(CH3)Br
p
u
d
14. Outline the principles of refining metals by the following methods.

a) Zone refining
b) Electrolytic refining
a
n
c) Poling
e
e
.
w
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d) Vapour phase refining.
15. Action of soap is due to emulsification and micelle formation. Comment.
t
e
n
16. Write the IUPAC names of the following compounds:

a) K2 [Zn(OH)4 ]
b) [Ni(CO)4 ]
d) [CO(NH3)4 (H2O)Cl] Cl2

17. Write a brief note on amino acids.
.
a
h
c) K3 [Cr(C2O4 ) 3]
b
i
t
18. a) What is PHBV? How is it useful to man?
b) Classify the following as addition and condensation polymers: Terylene,

Bakelite, Poly Vinyl Chloride, Polythene.
a
r
p
SECTION - C
u
d
a
III. (i) Long Answer Type questions.
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(ii) Answer any TWO questions.
(iii) Each question carries EIGHT Marks.
2 8 = 16
19. a) How are XeF2 and XeF4 prepared? Give their structures.
b) Explain the structures of BrF5 and IF7.
20. Discuss the effect of catalyst and temperature on the rate of reaction.
21. a) Explain the acidic nature of phenols and compare with that of alcohols.
b) Explain: i) Stephen reaction
ii) Etard reaction.
ANSWERS
SECTION - A
t
e
1.
What is "Ebullioscopic constant"?
A:
The elevation in the boiling point of one molal solution.
h
b
i
Tb = Kb . m
2.
n
.
a
Calculate the equilibrium constant of the reaction.
t
a
r
Cu (s) + 2 Ag+ (aq) Cu +2 (aq) + 2 Ag (s)

o
E cell = 0.46 V
A:
0.0591
o
E cell = log K c
n
p
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a
n
e
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.
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0.0591
E cell = log K c = 0.46 V

2
t
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n
0.46 2
log10 K c = = 15.6
.
a
h
0.0591
Kc = 1015.6 = 1015 100.6 = 3.92 1015

3.
a) Brass and
A:
b
i
t
Give the composition of the alloys:

b) German Silver
a
r
p
a) Brass: 60% Cu + 40% Zn
b) German Silver: 25 to 40% Cu + 25 to 35% Zn + 40 to 50% Ni.

4.
A:
5.
A:
u
d
a
NO is paramagnetic in gaseous state, but diamagnetic in liquid and solid

states. Why?
en
..
NO is odd number (electrons) molecule in .. N = O .. gaseous state, hence it is

paramagnetic. Whereas NO dimerises in liquid and solid states. N2O2 is having
even number of electrons (odd + odd = even), so it is diamagnetic.
e
.
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Why Conc. H2SO4, P4O10 and anhydrous CaCl2 can not be used to dry
ammonia?
NH3 reacts with Conc. H2SO4 to form (NH4)2SO4
NH3 reacts with P4O10 to form (NH4)3PO4
NH3 reacts with CaCl2 forming CaCl2 . 8 NH3
So NH3 is dried using quick lime (CaO)
6.
Why Zn+2 is diamagnetic where as Mn +2 is paramagnetic?
A:
Zn+2 = [Ar] 4s0 3d10
all electrons are paired.
Mn +2 = [Ar] 4s0 3d5
has 5 unpaired electrons.
t
e
n
.
a
h
b
i
As no unpaired electrons present in Zn+2, it is diamagnetic, As 5 unpaired d

electrons are present in Mn +2, it is paramagnetic.
t
a
r
7.
What are "Artificial sweetening agents"? Give 2 examples.
A:
The chemical substances not only controls the intake of calories but also gives
p
u
d
sweet taste are called "artificial sweetening agents".
a
n
e.g.: Sucralose, Aspartame.
e
e
.
w
w
8.
What are tranquilizers? Give 2 examples.
A:
The drugs which are used to reduce mental diseases and stress are called
t
e
n
tranquilizers.
.
a
h
e.g.: Seconal, Luminal.

9.
b
i
t
Write equations for carbyl amine reaction of any one aliphatic amine and one
aromatic amine.
A:
a
r
p
A dirty smelling compound isocyanide or carbyl amine is formed when

aliphatic or aromatic primary amine is heated with chloroform and ethanolic
u
d
a
KOH.
Heat
C2H5 NH2 + CHCl3 + 3 KOH C2H5NC + 3 KCl + 3 H2O
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.
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Heat
C6H5NH2 + CHCl3 + 3 KOH C6H5NC + 3 KCl + 3 H2O
10. What is "Hell-Volhard -Zelensky reaction"?

A:
The reaction in which halogenation takes place at alpha position of a carboxylic

acid (having alpha hydrogen) when treated with a halogen (Cl2 or Br2) in
presence of red phosphorus.
H
H
Red phosphorus
H3C C COOH
H3C C COOH + HCl
H + Cl Cl
t
e
Cl
SECTION - B
n
.
a
h
b
i
11. Calculate the efficiency of packing in case of a metal of body - centred cubic
crystal.
A:
t
a
r
B.C.C. crystal contain 8 atoms at 8 corners and one atom at the centre of the
body.
1
No.of the atoms in the unit cel = corners 8 + body centre(1) = 1 + 1 = 2.
8
In each diagonal, 3 atoms are present.
p
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a
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w
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C = AF = Length of body diagonal = r + 2r + r = 4r .......... (1)

In EFD
t
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FD2 = FE2 + ED2
.
a
h
b2 = a2 + a2 = 2a2
From (1) & (2)
3 a = 4r
b
i
t
4
a =
r
3
In AFD
u
d
a
AF 2 = FD2 + DA2
c2 = b2 + a2
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= 2a2 + a2
a
r
p
= 3a2
c = 3 a ........... (2)
Volume of the cube = a3 =
4 3
r
3
( )
4
Volume occupied by 2 atoms = 2 r3
3
Volume of 2 atoms
Packing efficiency = 100
Volume of unit cell
4
2 r3 100
3
t
e
=
3
4
3r
3
= 68%
n
.
a
( )
h
b
i
12. What is relative lowering of vapour pressure? The vapour pressure of

pure benzene at a certain temperature is 0.850 bar. A non-volatile,
non-electrolyte solid weighing 0.5 g when added to 39 g of benzene, vapour
pressure of the solution is 0.845 bar. Calculate the molar mass of the solid
substance.
t
a
r
A:
p
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d
Relative lowering of vapour pressure (R.L.V.P.): The ratio of lowering of

vapour pressure to vapour pressure of pure solvent (Po)
a
n
e
e
.
w
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P o - Ps
R.L.V.P. =
Po
P o - Ps
W2
M1
Po
M2
W1
t
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n
.
a
h
0.850 - 0.845
0.5
78
=
M2
39
0.850
b
i
t
0.850 0.5 78
M2 = = 170
39 0.005
a
r
p
13. a) Write possible chain isomers for C4H9Br.
u
d
a
b) Predict the order of reactivity of the following compounds in SN 1and

SN 2 reactions:
n
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C6H5CH2Br, (C6H5)2CHBr, C6H5CH(CH3)Br, (C6H5 )2C(CH3)Br
A:
a) CH3CH2CH2CH2Br
n - butyl bromide
CH3 CH2 CH CH3
CH3
2 - Bromobutane
Br
H3C C Br
2 - Bromo 2 - Methyl Propane
CH3
Br
b) C6H5
H5 C6
H
CH3 > H5 C6 C
H
Br > H5 C6
C Br > H5 C6 C Br (SN1)
C6H5
C6H5
CH3
CH3
Br < H5 C6
C6H5
Br < H5 C6
C6H5
t
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n
.
a
H
C Br < H5 C6 C Br (SN2)
bh
CH3
i
t
14. Outline the principles of refining metals by the following methods.
A:
a
r
a) Zone refining
b) Electrolytic refining
c) Poling
d) Vapour phase refining
p
u
d
a) Zone refining: Impurities are more soluble in molten state than in the solid
state of metal. Mobile circular heater is fixed on the impure metal at one end.
Impurities are moving along with the heater and removed at the end of the rod,
by cutting it.
a
n
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e.g.: Germanium.
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b) Electrolytic refining: In this method in pure metal is taken as anode. Thin

sheet of pure metal is taken as cathode. Soluble salt of the same metal is taken
as electrolyte. By passing electricity through it, pure metal gets deposited on
the cathode.
.
a
h
b
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t
e.g.: Copper.
c) Poling: Impurities present in molten metal can be removed either as gases or

as slag when it is stirred with poles of green wood.
a
r
p
e.g.: Blister copper.
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a
d) Vapour phase refining: In this method, metal is converted into easily

decomposable volatile vapour compound and it is decomposed to get pure
metal on heating.
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350 K
450 K
e.g: Ni + 4 CO Ni(CO)4 Ni + 4 CO
15. Action of soap is due to emulsification and micelle formation. Comment.

A: Soap is considered as Sodium Sterate. It has C H COO-
17 35
+
(Sterate) and Na ions. Sterate ion has non polar part
(C17H35 ) tail and polar part (COO-) head. Tail part dissolves
grease and head part attracts water to form emulsion (oil in
water type). In concentrated soap solution of soap, micelles
Oil
Sterate micelle
are formed due to association of many sterate ions. Due to formation of
emulsion and micelles, grease of a cloth is to be removed (upon rinsing in water).
16. Write the IUPAC names of the following compounds:
A:
a) K2 [Zn(OH)4 ]
b) [Ni(CO)4 ]
c) K3 [Cr(C2O4 ) 3]
d) [CO(NH3)4 (H2O)Cl] Cl2
a) K2 [Zn(OH)4 ]
t
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n
.
a
h
b
i
- Potassium tetrahydroxozincate (II)
- Tetracarbonyl nickel (0)

b) [Ni(CO)4 ]
c) K3 [Cr(C2O4 ) 3] - Potassiumtrioxalato chromate (III)
t
a
r
d) [Co(NH3)4 (H2O)Cl] Cl2 - Tetra ammine aqua chloro cobalt (III) chloride.
p
u
d
17. Write a brief note on amino acids.

A:
Compounds containing amino group (-NH2) and acid group (-COOH) are
called amino acids.
H
a
n
e
e
.
w
w
The general formula of - amino acid is R C COOH.
Amino acids are obtained by hydrolysis of proteins.
.
a
h
They are amphoteric. In aqueous solution they form Zwitter ions
H
R C COO+
NH3
t
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n
NH2
b
i
t
a
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p
There are 10 non -essential amino acids (which can be synthesised, in the body)
and 10 essential amino acids (supplied through food). They are classified into
acidic or basic or neutral amino acids.
u
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a
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18. a) What is PHBV? How is it useful to man?

b) Classify the following as addition and condensation polymers: Terylene,
Bakelite, Poly Vinyl Chloride, Polythene.
A:
a) PHBV: Poly - hydroxy butyrate - Co - - hydroxy valerate (PHBV) is

a copolymer of 3 - hydroxy butanoic acid and 3 - hydroxy pentanoic acid. It
is a condensation polymer.
It is used to make cover of the capsules, used in orthopaedic devices and in

speciality packing.
SECTION - C
19. a) How are XeF2 and XeF4 prepared? Give their structures.
b) Explain the structures of BrF5 and IF7.
A:
t
e
n
.
a
a) XeF2
The reaction between Xe and F2 at 1 bar pressure and 673 K temperature gives
XeF2 .
F
h
b
i
1 bar
Xe(g) + F2 (g) XeF2 (s)
673 K
t
a
r
: Xe
XeF4
Xe = 5s2 5px2 5py2 5pz1 5d1 (1st excited state)

F
Xe undergoes sp3d hybridization. Due to presence of 2 bond pairs and 3 lone
pairs, the shape of XeF2 is linear.
p
u
d
a
n
e
e
.
w
w
XeF4 is formed when Xe & F2 reacts together in 1 : 5 ratio at 7 bar pressure

and 873 K temperature.
F
F
7 bar
Xe + 2 F2 XeF4
Xe
873 K
F
F
Xe = 5s2 5px2 5py1 5pz1 5d1 5d1 (2nd excited state)
t
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n
..
.
a
h
..
Xe undergoes sp3d2 hybridization. Due to presence of 4 bond pairs and 2 lone

pairs, the shape of XeF4 is square planar.
b
i
t
a
r
p
b) BrF5
Br = 4s2 4px1 4py1 4pz1 4d1 4d1 (2nd excited state)

F
Br undergoes sp3d2 hybridization. It has square pyramidal
F
shape due to presence of 5 bond pairs & 1 lone pair.
Br
IF7
du
a
n
I = 5s1 5px1 5py1 5pz1 5d1 5d1 5d1 (3rd excited state)
F
Iodine undergoes sp3d3 hybridization. Due to presence of
7 bond pairs in its 3rd excited state, the shape of IF7 is F
pentagonal bipyramidal.
..
e
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.
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F
I
F
20. Discuss the effect of catalyst and temperature on the rate of reaction.
A:
Effect of Temperature: The temperature dependence of the rate of a chemical

reaction can be accurately explained by Arrhenius equation K = A . e-E a/RT.
Where A is frequency factor. If temperature is increased, kinetic energy of
molecules will be increased. The number of effective collisions (molecules
possess equal or greater energy than that of activation energy) increases, so the
rate of reaction increases. It has been found that for a chemical reaction with rise
in temperature by 10 , the rate constant is nearly doubled.
t
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n
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a
h
b
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t
a
r
p
u
d
a
n
By taking natural logarithm of both sides of Arrhenius equation
e
e
.
w
w
Ea
ln K = ln A -
RT
Ea
ln K1 = ln A
RT1
Ea
ln K2 = ln A -
RT2
Ea
+
RT1
At temperature T1
At temperature T2
Ea
ln K2 - ln K1 = -
RT2
K2
Ea 1
1
ln = -
K1
R T1
T2
K
K1
t
e
n
.
a
h
b
i
t
a
r
p
u
d
a[ ]
E
1
2.303R T1
1
T2
a
log 2 =
-
n
e
e
.
ww
Effect of catalyst: A catalyst increase the rate of forward reaction as well as rate
of backward reaction and helps in attaining equilibrium sooner. A catalyst does
not alter G and equilibrium constant. A catalyst gives alternate path by
reducing the activation energy between reactants and products. It is very clear
from Arrhenius equation that lower the value of Ea, faster will be the rate of
reaction.
t
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n
.
a
h
b
i
21. a) Explain the acidic nature of phenols and compare with that of alcohols.
t
a
r
b) Explain: i) Stephen reaction ii) Etard reaction
a) Proton (H +) donor is acid. -OH group is electron withdrawing group and is

attached to sp2 carbon of benzene ring. As electronegativity of sp2 carbon of
phenol is more, electron density decreases on oxygen. This will increase the
polarity of O - H bond and results increase in ionisation of phenols than that
of alcohols. In alkoxide ion (RO-), the negative charge is localised only on
oxygen, where as in phenol, negative charge is delocalised. Due to resonance,
stable phenoxide ion is formed by losing H + ion easily.
p
u
d
a
n
e
e
.
w
w
:
:
.
a
h
:O:
OH
b
i
t
+ H+
:O:
:O:
ra
:O:
:O:
d
a
p
u
t
e
n
R - O : + H+
R- O-H
A:
:O:
n
e
e
.
ww
Phenoxide ion is more stable than that of alkoxide ion. Acidity of phenols is
more than that of alcohols. When electron withdrawing group like -NO2 is
attached to benzene in ortho, para positions in phenol, acidic nature will
increases further. From pKa data we will understand that phenol is million
times more acidic than that of ethanol.
b) i) Stephen reaction: Alkyl cyanides on reaction with SnCl2 & HCl gives
imine, which on hydrolysis give aldehyde.
H3O+
CH3CN + SnCl2 + HCl CH3CH = NH CH3 CHO
ii) Etard reaction: Methyl group (-CH3) on reaction with Chromyl Chloride
(CrO2Cl2 ) gives a complex, which on hydrolysis gives aldehyde.
t
e
CH(OCrOHCl2)2
CH3 + CrO2Cl2
CHO
H3O +
CS2
n
.
a
Toluene
Chromium complex
h
b
i
Benzaldehyde
t
a
r
A.N.S. Sankara Rao,
Senior Lecturer in Chemistry.
p
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a
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a
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b
i
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a
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a
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BOARD OF INTERMEDIATE EDUCATION

(i) Very Short Answer Type questions.

(iii) Each question carries TWO Marks.

What is "Ebullioscopic Constant"?

Calculate the equilibrium constant of the reaction.

Cu (s) + 2 Ag+ (aq) Cu +2 (aq) + 2 Ag (s)

Give the composition of the alloys:

NO is paramagnetic in gaseous state but diamagnetic in liquid and solid states.

Why Zn+2 is diamagnetic where as Mn +2 is paramagnetic?

What are artificial sweetening agents? Give 2 examples.

What are tranquilizers? Give 2 examples.

10. What is Hell-Volhard - Zelensky reaction?

II. (i) Short Answer Type questions.

13. a) Write possible chain isomers for C4H9Br.

b) Predict the order of reactivity of the following compounds in SN 1and SN 2

C6H5CH2Br, (C6H5)2CHBr, C6H5CH(CH3)Br, (C6H5 )2 C(CH3)Br

14. Outline the principles of refining metals by the following methods.

d) Vapour phase refining.

15. Action of soap is due to emulsification and micelle formation. Comment.

16. Write the IUPAC names of the following compounds:

d) [CO(NH3)4 (H2O)Cl] Cl2

18. a) What is PHBV? How is it useful to man?

b) Classify the following as addition and condensation polymers: Terylene,

III. (i) Long Answer Type questions.

(ii) Answer any TWO questions.

(iii) Each question carries EIGHT Marks.

b) Explain the structures of BrF5 and IF7.

ii) Etard reaction.

What is "Ebullioscopic constant"?

The elevation in the boiling point of one molal solution.

Calculate the equilibrium constant of the reaction.

Cu (s) + 2 Ag+ (aq) Cu +2 (aq) + 2 Ag (s)

E cell = log K c = 0.46 V

Kc = 1015.6 = 1015 100.6 = 3.92 1015

Give the composition of the alloys:

a) Brass: 60% Cu + 40% Zn

b) German Silver: 25 to 40% Cu + 25 to 35% Zn + 40 to 50% Ni.

NO is paramagnetic in gaseous state, but diamagnetic in liquid and solid

NO is odd number (electrons) molecule in .. N = O .. gaseous state, hence it is

Why Zn+2 is diamagnetic where as Mn +2 is paramagnetic?

Zn+2 = [Ar] 4s0 3d10

all electrons are paired.

Mn +2 = [Ar] 4s0 3d5

has 5 unpaired electrons.

As no unpaired electrons present in Zn+2, it is diamagnetic, As 5 unpaired d

What are "Artificial sweetening agents"? Give 2 examples.

sweet taste are called "artificial sweetening agents".

e.g.: Sucralose, Aspartame.

What are tranquilizers? Give 2 examples.

e.g.: Seconal, Luminal.

A dirty smelling compound isocyanide or carbyl amine is formed when

C6H5NH2 + CHCl3 + 3 KOH C6H5NC + 3 KCl + 3 H2O

10. What is "Hell-Volhard -Zelensky reaction"?

The reaction in which halogenation takes place at alpha position of a carboxylic

presence of red phosphorus.

H3C C COOH + HCl

C = AF = Length of body diagonal = r + 2r + r = 4r .......... (1)

FD2 = FE2 + ED2

Volume of the cube = a3 =

12. What is relative lowering of vapour pressure? The vapour pressure of

Relative lowering of vapour pressure (R.L.V.P.): The ratio of lowering of

13. a) Write possible chain isomers for C4H9Br.