Beruflich Dokumente
Kultur Dokumente
net
Max. Marks: 60
SECTION - A
Note: 1) Very Short Answer type questions.
2) Answer ALL questions.
1.
2.
3.
4.
5.
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What are "Anti septics"? Give two examples.
What is PHBV? How is it useful to man?
How many unit cells share each of the following lattice points in a cubic lattice.
a) a lattice point at the corner of the cell
b) at the face centre
6.
7.
8.
9.
10.
10 2 = 20
b) CH3CHO
alc. KOH
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SECTION - B
Note: 1) Short Answer type questions.
2) Answer any SIX questions.
6 4 = 24
11. State Raoult's law. The vapour pressure of a solution containing 108.24 g. of a
13.
14.
State and explain Faraday's first law of electrolysis. A current of 0.25 amp is
passed through a CuSO4 solution for 45 minutes. Calculate the mass of Copper
deposited on the Cathode. (At. wt. of Cu = 63.6 g)
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Write any four differences between physical adsorption and chemical adsorption.
b) Extensive property
15.
16.
a) PCl3
17.
18.
b) Calcination
b) PCl5
c) P4O6
d) P4O10
Give one source and one deficiency disease caused by the vitamins, A, E, D, K.
SECTION - C
19.
2 8
16
b) Give the reactions of bleaching powder with the following and give equations.
i) H2O
ii) CO2
iii) Ethanol
iv) Excess of dil. acid
20.
Discuss the collision theory of reaction rates. Support your explanation with a
relevant diagram.
21.
Write any two methods of preparation of Aniline. What happens when Aniline
is treated with the following? Give equations.
i) HCl
ii) CH3COCl
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ANSWERS
1.
A:
The alkaloid having addictive property that cause depression of central nervous
system and relieves strong pains like cardiac pain, post operative pain.
e.g.: Morphine, Codeine.
2.
A:
3.
A:
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4.
A:
Schottky defect: A stoichiometric, point defect that occurs when the size of the
ions are same and same number of cations and anions are missing from the lattice points are called "Schottky defect".
Frenkel defect: A stoichiometric, point defect that occurs when small size
cation occupies interstitial site instead of lattice site is called "Frenkel defect".
5.
How many unit cells share each of the following lattice points in a cubic lattice
(a) lattice point at the corner of the cell
(b) at the face centre
A:
1
a) ___
8
1
b) ___
2
c) 1
1
d) ___
4
6.
A:
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7.
A:
8.
A:
9.
A:
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What is Reimer - Tieman reaction? Give equation.
10.
CHO
OH
65 C
O + CHCl3 + 3 NaOH O
+ 3 NaCl + 3 H2O
Complete the following reactions.
LiAlH4
a) CH3COOH
NH2NH2
b) CH3CHO
alc. KOH
A:
Li AlH4
a) CH3 C O O H + CH3CH2OH + H2O
+H2 H2
Ethyl alcohol
b) CH3CH O + H2 N NH2
H3C
alc. KOH
C = N - N H2 N2 + C2H6
-H2O H
Ethane
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SECTION - B
11.
Hg. The vapour pressure of H2O at 20 C is 17.540 mm Hg. Find the molecular weight of the substance.
A:
P - Ps
W2 ________
M1
_________
________
=
P
M2
W1
17.540 - 17.354
108.24
18
___________________________ = __________ __________
17.540
M2
1000
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108.24 18 17.540
... M = ___________________________ = 183.73
1000 0.186
12.
A:
State and explain Faraday's first law of electrolysis. A current of 0.25 amp
is passed through a CuSO4 solution for 45 minutes. Calculate the mass of
copper deposited on the cathode. (Gram atomic weight of Cu = 63.6 grams)
The mass of substance deposited or liberated or dissolved at an electrode during the electrolysis of an electrolyte is directly proportional to the quantity of
electricity passing through the electrolyte.
cEt
m = c e t = __________
96500
0.25 31.8 45 60
96500
13.
A:
Physical
Chemical
adsorption
adsorption
Weak
Strong
3. Energy of Activation
Very low
Very high
4. Nature of adsorbate
Multi layered
Unilayered
1. Nature of adsorption
2. Enthalpy of adsorption
layers formed
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14.
A:
b) Extensive property
d) Heat of combustion.
a) Enthalpy: The total heat content of a substance or a system at constant pressure and at certain temperature.
b) Extensive property: The property of a system which depends on the total
amount of the substance present in the system.
c) First law of thermodynamics: Energy neither can be created nor be
destroyed but can be converted from one form to another form.
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15.
A:
b) Calcination.
a) Roasting: The process of heating an ore strongly below its melting point in
presence of air.
650 C
ZnSO4
16.
A:
b) PCl5
c) P4O6
d) P4O10
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17.
A:
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Every complex compound has a central atom or ion.
is non - directional.
is directional.
18.
A:
Give one source and one deficiency disease caused by the vitamins A, E, D,
K.
S.No.
1.
2.
Vitamin
Source
Deficiency disease
Fish oil,
Night blindness,
rice polishing
Redness of eyes
Sterility, neurosis
egg yolk
of heart muscles.
3.
Butter, milk
Rickets, osteomalacia
4.
Green leafy
Continuos bleeding,
vegetables,
Cabbage
SECTION - C
19.
A.
ii) CO2
iii) Ethanol
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1. Induction Coil
4
3
2
O2
O3 + O2
4
2. Dry Oxygen
3. Ozonized Oxygen
4. Cu Wire
5. Dilute H2SO4
6. Annular Space
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1
Brodie's Ozonizer
silent electric
3 O2
2 O3
discharge
H = 284.5 K.J.
iv) Bleaching powder reacts with excess of dilute acid to liberate Cl2 gas.
20.
A:
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Energy Barrier
Potential Energy
-ET -
Reaction Coordinate
A + A A + A
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A + A Products.
21.
A:
i) HCl
ii) CH3COCl
Preparation:
Zn
C6H5NO2 + 6 (H)
HCl
C6H5NH2 + 2 H2O
From Phenol: Aniline is formed when Phenol is heated with NH3 at 300 C under
reduced pressure.
ZnCl2
C6H5 OH + H - NH2 C6H5NH2 + H2O
300 C
Properties:
i) It forms Anilinium chloride with HCl.
C6H5NH2 + HCl C6H5N+ H3Clii) It gives acetanilide on reaction with CH3COCl.
Pyridine
C6H5NH H + Cl COCH3 C6H5NHCOCH3
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iii) Carbyl amine reaction: Aniline reacts with CHCl3 and alcoholic KOH to
form foul smelling carbyl amine.
C6H5NH2 + CHCl3 + 3 alc. KOH C6H5NC + 3 KCl + 3 H2O
iv) Diazotization: Aniline reacts with HNO3 at 0-5 C to form Benzene diazonium chloride.
O-5 C
C6H5NH2 + NaNO2 + 2 HCl C6H5N2Cl + 2 H2O + NaCl.
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