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TOPIC 1
FUNDAMENTAL CONCEPT OF THERMODYNAMICS
At the end of the topic you will be able to:
Describe the concepts of dimension, SI and imperial units
Describe the dimensional homogeneity
Solve unit conversion
Define the principles of a system, boundary, surrounding, differentiate between
open and closed system.
Define energy conversion.
Compare the properties of systems, state and equilibrium.
Define process and cycle.
State and explain Zeroth's law of thermodynamics.
1.0
INTRODUCTION
he study of thermodynamics is concerned with the ways energy is stored within a body
and how energy transformations, which involve heat and work, may take place. One of
the most fundamental laws of nature is the conservation of energy principle. It simply
states that during an energy interaction, energy can change from one form to another but the
total amount of energy remains constant. That is, energy cannot be created or destroyed.
Did you realize that the work of an engineer is limited unless he has a source of power
to drive his machines or tools? However, before such a study can begin, it is necessary to be
sure of the number of definitions and units, which are essential for a proper understanding of
the subject. We are familiar with most of these items in our everyday lives, but science
demands that we have to be exact in our understanding if real progress is to be made.
When engineering calculations are performed, it is necessary to be concerned with the
units of the physical quantities involved. A unit is any specified amount of a quantity by
comparison with which any other quantity of the same kind is measured. For example, meters,
centimeters and millimeters are all units of length. Seconds, minutes and hours are alternative
time units.
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1.1
Any physical situation can be described by certain familiar properties e.g. length,
velocity, area, volume, acceleration etc. These are all known as dimensions. Of course
dimensions are of no use without a magnitude being attached. We must know more than that
something has a length. It must also have a standardized unit - such as a meter, a foot, a yard
etc. Dimensions are properties which can be measured. Units are the standard elements we use
to quantify these dimensions. In dimensional analysis we are only concerned with the nature of
the dimension i.e. its quality not its quantity. The following common abbreviation are used:
length = L, mass = M, time = T, force = F.
In this module we are only concerned with L, M, T and F. We can represent all the
physical properties we are interested in with L, T and one of M or F (F can be represented by a
combination of LTM). These notes will always use the LTM combination.
The following table lists dimensions of some common physical quantities:
Quantity
velocity
acceleration
force
energy (or work)
power
pressure ( or stress)
density
specific weight
SI Unit
m/s
m/s2
N
kg m/s2
Joule J
N m,
kg m2/s2
Watt W
N m/s
kg m2/s3
Pascal P,
N/m2,
kg/m/s2
kg/m3
N/m3
kg/m2/s2
.
ms
ms-2
Dimension
LT-1
LT-2
kg ms-2
M LT-2
kg m2s-2
ML2T-2
Nms-1
kg m2s-3
ML2T-3
Nm-2
kg m-1s-2
kg m-3
ML-1T-2
ML-3
kg m-2s-2
ML-2T-2
-1
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Unit
Symbol
Mass
Time
Length
Thermodynamic temperature
Electric current
Luminous intensity
kilogram
second
meter
degree Kelvin
ampere
candela
kg
s
m
K
A
cd
All other physical quantities, which can be expressed in terms of one or more of these,
are known as derived quantities. The unit of length, mass, time, electric current,
thermodynamic temperature and luminous intensity are known as fundamental units. Physical
quantities like area, volume, density, velocity, acceleration, force, energy, power, torque etc. are
called derived quantities since they depend on one or more of these fundamental quantities. The
units of the derived quantities are called derived units as shown in Table 1.1-2.
Table 1.1-2 Derived units
Quantity
Unit
Symbol
Area
Volume
Velocity
Acceleration
Density
meter square
meter cube
meter per second
Meter per second
squared
kilogram / meter cube
kg/m3
Force
Pressure
Newton
Newton/meter square
N
N/m2
m2
m3
m/s
m/s2
Notes
1 m3 = 1 x 103 litre
1 N = 1 kgm/s2
1 N/m2 = 1 Pascal
1 bar = 105 N/m2 = 102 kN/m2
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Often times, the engineer must work in other systems of units. Comparison of the
United States Customary Units (USCS), or English, and the slug systems of units with the SI
system is shown below.
mass
time
length
force
1.1.2
SI
kilogram (kg)
second (s)
meter (m)
Newton (N)
USCS
pound-mass (lbm)
second (s)
foot (ft)
pound-force (lbf)
Slug
slug-mass (slug)
second (s)
foot (ft)
pound-force (lbf)
Dimensional Homogeneity
1.1.3
Unit conversion
We all know from experience that conversion of units can give terrible headaches if
they are not used carefully in solving a problem. But with some attention and skill, conversion
of units can be used to our advantage.
Measurements that describe physical quantities may be expressed in a variety of
different units. As a result, one often has to convert a quantity from one unit to another. For
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example, we would like to convert, say, 49 days into weeks. One approach is to multiply the
value by ratios of the equivalent units. The ratios are formed such that the old units are
cancelled, leaving the new units.
The example of unit conversions are:
1 kg = 1000 g
1 m = 100 cm = 1000 mm
12
10
109
106
103
102
101
10-1
10-2
10-3
10-6
10-9
10-12
Prefix
Symbol
tera
giga
mega
kilo
hector
deca
desi
centi
milli
micro
nano
pico
T
G
M
k
h
da
d
c
m
n
p
Example 1.1
Convert 1 km/h to m/s.
1 km 1 km 1000 m
1h
x
x
h
h
1 km
3600 s
1000 m
3600 s
0.278 m/s
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Example 1.2
Convert 25 g/mm3 to kg/m3.
Solution to Example 1.2
1 kg = 1000 g
1 m = 1000 mm
1 m3 = 1000 x 1000 x 1000 mm3
= 109 m3
25 g
25 g
1 kg
10 9 mm 3
x
x
1000 g
mm 3
mm 3
1 m3
25 x 1 x 10 9 kg
1000 m 3
25 x 10 6 kg/m 3
Example 1.3
Convert 15 MN/m2 to N/m2
15 MN 15 MN 10 6 N
x
1 MN
m2
m2
Example 1.4
15 x 10 6 N/m 2
15 mg
15 mg
1 kg
1000 litre
x
x
litre
litre
1 000 000 mg
1 m3
15 x 10 -3 kg/m 3
1.2.1
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System
Figure 1.1
A system can either to be close or open, depending on whether a fixed mass or a fixed
volume in space is chosen for study. A close system (also known as a control mass) consists of
a fixed amount of mass, and no mass can cross its boundary. That is, no mass can enter or leave
a close system, as shown in Fig. 1.2. But energy, in the form of heat or work can cross the
boundary, and the volume of a close system does not have to be fixed. Examples of closed
systems are sealed tanks and piston cylinder devices (note the volume does not have to be
fixed).
SURROUNDINGS
SYSTEM
S
I
S
T
E
M
BOUNDARY
Fig. 1.2 A closed system with a moving boundary
An open system, or a control volume, as it is often called, is a properly selected region
in space. It usually encloses a device, which involves mass flow such as a boiler, compressor,
turbine or nozzle. Flow through these devices is best studied by selecting the region within the
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device as the control volume. Both mass and energy can cross the boundary of a control
volume, as shown in Fig. 1.3. Examples of open systems are pumps, compressors, turbines,
valves, and heat exchangers.
Fluid Inlet
SURROUNDINGS
QOUT
SYSTEM
WOUT
BOUNDARY
Fluid Outlet
Fig 1.3 Open system in turbine
1.2.2
Energy Conversion
Thermodynamics is the science of the relationship between heat, work, and systems that
analyze energy processes. The energy processes that convert heat energy from available sources
such as chemical fuels into mechanical work are the major concern of this science.
Thermodynamics consists of a number of analytical and theoretical methods which may be
applied to machines for energy conversion.
Energy is used in almost all facets of living and in all countries, and makes possible the
existence of ecosystems, human civilizations and life itself. Different regions and societies
adapt to their environments and determine their own energy resources and energy uses. The
standards of life achieved in countries are often a function of energy-related factors.
Energy can exist in many forms, and can be converted from one form to another with
energy conversion technologies. We use energy carriers (often simply referred to as energy),
produced from energy sources, in all aspects of living. It is important to distinguish between
energy forms, sources and carriers.
Energy forms. Energy comes in a variety of forms, including fossil fuels, fossil fuelbased products (e.g., gasoline, diesel fuel), uranium, electricity, work (such as the mechanical
energy in a rotating engine shaft), heat, heated substances (e.g., steam, hot air), light and other
electromagnetic radiation.
Energy sources. Energy resources (sometimes called primary energy forms) are found
in the natural environment. Some are available in finite quantities (e.g., fossil fuels, fossil
fuelcontaining substances such as oil sands, peat and uranium). Some energy resources are
renewable (or relatively renewable), including sunlight (or solar energy), falling water, wind,
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tides, geothermal heat and biomass fuels (when the growth rate exceeds or meets the rate of
use). Energy resources are often processed from their raw forms prior to use.
Energy carriers. Energy carriers (sometimes called energy currencies) are the energy
forms that we transport and use, and include some energy resources (e.g., fossil fuels) and
processed energy forms (e.g., gasoline, electricity, work and heat). Processed energy forms are
not found in the environment.
1.2.3
JJ207-THERMODYNAMICS 1
(a) Before
(b) After
Fig. 1.4 Thermal equilibriums
1.2.4
When there is a change in any of the properties of a system, the state changes and the
system are said to have undergone a process. A process is a transformation from one state to
another. However, if a system exhibits the same values of its properties at two different times,
the state remains the same at these times. A system is said to be at a steady state if none of its
properties changes with time. A process occurs when a systems state (as measured by its
properties) changes for any reason.
Processes may be reversible or actual (irreversible). In this context the word reversible
has a special meaning. A reversible process is one that is wholly theoretical, but can be
imagined as one which occurs without incurring friction, turbulence, leakage or anything which
causes unrecoverable energy losses. All of the processes considered below are reversible and
the actual processes will be dealt with later. Processes may be constrained to occur at constant
temperature (isothermal), constant pressure, constant volume, polytropic and adiabatic (with no
heat transfer to the surroundings).
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Fig. 1.5 Process path from initial (1) to final (2) state
A process (or a series of connected processes) with identical end states is called a cycle.
Below is a cycle composed of two processes, A and B. Along process A, the pressure and
volume change from state 1 to state 2. Then to complete the cycle, the pressure and volume
change from state 2 back to the initial state 1 along process B. Keep in mind that all other
thermodynamic properties must also change so that the pressure is functions of volume as
described by these two processes. The cycles studied in thermodynamics are combinations of
various thermodynamic processes, primarily isothermal, adiabatic, polytropic, isobaric(constant
pressure) and isochoric (constant volume) processes.
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1.2.5
If T (A) = T(B)
And T (B) = T(C)
Then T (A) = T(C).
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