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Principles of Metallurgy
1. Write the Distinction between metals and non-metals?
Ans:
Distinction between metals and non-metals:
Metals
1). Metals are solids at room temperature
Non-metals
1). Non-metals present in solid liquid and
gaseous state
2). They are insulators
heat
3). They are hard and strong
4). They are reducing agents
5). They contain 1 to 3 valency electrons
6). The density of metals is high
7). They form basic oxides
8). They have makeable and ductile properties
9). They participate in reactions by losing of
electron
sharing of electrons.
2. Define Metallurgy?
Ans:
Metallurgy:
The branch of science which deals about extraction of metals and manufacture of alloys and
uses is called as metallurgy.
3. Define Mineral?
Ans:
Mineral:
The naturally occurring material which contains metal either in native state or in combined state
is called mineral.
4. Define Ore?
Ans:
Ore:
A mineral from which metal can be extracted profitable is called an ore
Metal
Na
K
Mg
Al
Mineral
NaCl (Rock Salt)
KCl MgCl2. 6H2) (Carnalite)
MgCO3 Magnasite
MgCO3.CaCO3 Dolamite
MgSO4.7H2O - Epsum
Al2O3.2H2O- Bauxite
Ore
NaCl (Rock Salt)
Carnalite
Magnesite
Bauxite
Principles of Metallurgy
Fe
Cu
Zn
Ag
Pb
Na3AlF6 Cryolite
Al2O3 Corundum
Fe2O3Heamatite
Fe3O4 Magnetite
Fe2S2 Iron Pryrites
FeCO3 - Siderite
Cu2O Cuprite
FeCu2S Copper pyrites
Cu2S Copper glance
ZnS Zinc blend
ZnO Zinkite
ZnCO3 - Calamine
Ag2S Argentile
AgCl Horn Silver
Pbs - Galena
PbO - litharge
Cryolite
Heamatite
Magnetite
Iron Pyrites
Copper pyrite
Zinc blend
Calamine
Argentile
Galena
5. Define Gangue?
Ans:
Gangue:
The earthly impurities associated with the ore are called gangue or matrix.
Impurities like sand, rock and clay are called gangue.
6. Define Flux?
Ans:
Flux:
The chemical substance added to the ore to remove gangue is called flux.
Fluxes are two types
They are
(a) Acidic fluxes
(b) Basic fluxes
a) Acidic flux:
It is used to remove the basic impurities like CaO, MgOetc
Eg: SiO2, P4O10etc
b) Basic flux:
It is used to remove the Acidic impurities like SiO2
Eg:CaO, MgO etc.
7) Define Slag?
Ans:
Slag:
Flux reacts with the gangue and form fusable product. This product is called slag.
Flux + gangue
Slag
SiO2+ CaO
CaSiO3
8) Write Extraction of metals from ore?
Ans:
Prepared by V Naga Surendra Reddy
Lecturer in Chemistry
Principles of Metallurgy
Principles of Metallurgy
1) Al2O3.H2O
Al2O3 + 2H2O
Principles of Metallurgy
In this process concentrated ore is heated with reducing agent or sometimes with a flux and
reducing agent.
Then, the metal is obtained in the fused state.
Example:
Iron ore heamatite is heated with coke and lime.
Then, Fe2O3 reduced to Fe
Fe2O3 + 3C2Fe + 3CO
The gangue (SiO2) present in the ore is removed as slag on reaction with lime.
CaO + SiO2
CaSiO3
Flux gangue
slag
17) Write about Purification of crude metal?
Ans:
3). Purification of crude metal:
The process of removal of impurities from the crude metal to get pure metal is called purification
or refining.
Eg: Electrolytic refining.
Electrolytic refining:
In this process crude metal blocks used as anode.
Pure metal sheets used as cathode.
Acidified metal salt is taken as electrolyte.
On passing current through the cell, pure metal from the anode deposits on the cathode.
Impurities left over at the anode only.
It is called anode mud.
Example:
Refining of copper.
In this process, impure copper is anode, pure copper is cathode and acidified CuSO4 is used as
electrolyte.
When current passed through the cell, the following reactions occur in the cell.
At cathode: Cu+2 + 2eCu (reduction)
+2
At anode: Cu
Cu + 2e- (oxidation)
Principles of Metallurgy
S.No
Name of Alloy
1.
Brass
2.
German Silver
3.
Nichrome
Composition of Alloy
Cu = 60-70%
Zn = 30-40%
Cu = 50%
Zn = 30%
Ni = 20%
Ni = 60%
Fe = 25%
Cr = 15%
Uses of Alloy
a). Decorative hardware
b). Machinery Parts
a). Decorative hardware
b). Rheostats
c). Resistors
a). heating coils
b). Resistance wire
Principles of Metallurgy