NAME: Abigail Gaulke

STUDENT ID:

1342216

Chem 142 Experiment #2: Stoichiometry I

I. Reaction of Hydrogen Peroxide and Bleach
II. Reaction of Fe2+ with 1,10-Phenanthroline

Grading: 55 pts total (45 pts for this template, 10 pts for notebook pages)
Notebook pages: Purpose/Method section complete? Are they organized and legible? Have you plotted your d

Note:
ALL sections of this report MUST be typed. With this and all future Excel-based rep
the report prints correctly (graphs, tables, and text boxes are not split across page
turn it in. If you print it and it doesn't look okay, use the tools in Excel to adjust the
then re-print the report before submitting it.

By signing below, you certify that you have not falsified data, that you have not plagiarized any part o
that all calculations and responses other than the reporting of raw data are your own independent w
declaration will result in 5 points being deducted from your report score.
Signature:

DATA, CALCULATIONS AND GRAPHS

Part I: Reaction of hydrogen peroxide and bleach
Concentration of stock solutions

Measurement

1
2
3
4

Bleach, NaOCl(aq)

6.00

Hydrogen Peroxide, H2O2(aq)

3.00

Mass of 0.500 mL Bleach, g

0.543
0.546
0.545
0.545
Average Density, g/mL

Density of Bleach, g/ml

1.086
1.09
1.09
1.09
1.09

Type your calculation of the density of bleach using the mass data from measurement #1.
.543g/.500ml=1.086g/ml

Type your calculation of the average density of bleach using the mass data from all four measurements.
.543g/.500=1.086g/ml
1.086+1.092+1.090+1.090=4.358
.546/.500=1.092g/ml
4.38/4=1.0895g/ml

Type your calculation of the density of bleach using the mass data from measurement #1.
.543g/.500ml=1.086g/ml

Type your calculation of the average density of bleach using the mass data from all four measurements.
.543g/.500=1.086g/ml
1.086+1.092+1.090+1.090=4.358
.546/.500=1.092g/ml
4.38/4=1.0895g/ml
.545/.500=1.09g/ml
.545/.500=1.09g/ml

Run Number
Run 1
Run 2
Run 3
Run 4
Run 5
Run 6
Run 7
Run 8
Run 9
Run 10
Run 11

mL of Bleach
4.0ml
4.0ml
4.0ml
4.0ml
4.0ml
4.0ml
4.0ml
4.0ml
4.0ml
4.0ml
4.0ml

Grams of Hydrogen Peroxide

1.019
1.540
2.105
2.640
3.044
3.542
4.119
4.529
2.30
1.82
1.33

Put your Plot of Volume (mL) of O2 vs Mass (g) of H2O2 here. Make your graph big enough to cover this instr
appropriate size for someone else to read it.

Hydrogen Peroxide VS. Volume of Oxyge

Use the online resources if you need help figuring out how to plot a graph in Excel. (See the links on
70.0
report.)

Title the graph and label the 60.0

X and Y axis, including the correct units. Be sure to double check your u
print the report.
50.0

Using the line tool on the drawing toolbar, draw the three straight lines: 1) best fit for the data where H
40.0 and 3) a vertical line from the intersection of lines 1 and 2 down to t
the data where H2O2 is in excess,
identify
the
point.
volume
ofequivalence/stoichometric
oxygen (ml)
30.0

Indicate on your graph where20.0

the H2O2 is the limiting reagent and where it is in excess.
10.0
0.0
0.500

1.000

1.500

2.000

2.500

3.000

3.500

Mass of Hydrogen Peroxide (g)

Grams of H2O2 solution at the Eqv Point

2.65

Moles H2O2 at the Eqv Point

7.79E-02

Moles NaOCl at the Eqv Point

5.85E-02

Stoichiometry: moles H2O2/moles NaOCl

Type your calculation for the moles of H2O2 at the equivalence point.
2.65g/34.016g=.0779

Type your calculation for the moles NaOCl at the equivalence point.
4.0ml X 1.0895 X 1/74.44gNaOCl= .0585

4 to 3

4.000

Type your calculation for the moles NaOCl at the equivalence point.
4.0ml X 1.0895 X 1/74.44gNaOCl= .0585

Part II: Iron(II) -Phenanthroline Reaction

Concentration of stock 1,10 phenanthroline solution
Concentration of stock Fe2+ solution
Volume of stock 1,10 phenanthroline solution you obtained

Total Volume of Fe2+ added, L

0
100
200
300
400
500
600
700
800

Absorbance
0
0.051
0.104
0.159
0.214
0.22
0.22
0.22
0.22

Put your Absorbance vs mL Fe2+ here. Make your graph big enough to cover this instruction box so that it is
someone else to read it.

Volume of Fe^2+ VS. Absorbance

Use 0.25
the online resources if you need help figuring out how to plot a graph in Excel. (See the links
this report.)

Title the
graph and label the X and Y axis, including the correct units (Absorbance data is unitless
0.2
your units and formatting once you print the report.

Using the line tool on the drawing toolbar, draw the three straight lines: 1) best fit for the data whe
fit for
the data where Fe 2+ is in excess, and 3) a vertical line from the intersection of lines 1 and 2
0.15
to clearly identify the equivalence/stoichometric point.
Absorbance

Indicate on your graph where the iron is the limiting reagent and where it is in excess.
0.1

0.05

0
0

100

200

300

400

500

600

700

Fe ^2+ nl

L of Fe(II) at the Equivalence Point

Moles phen at the Eqv Point

Moles Fe2+ at the Eqv Point
Stoichiometry: moles phen/moles Fe2+

415

1.80 X 10^-4
1.04X 10^-6
152 to 3

Type your calculation of the moles of 1,10 phenanthroline that you transferred to the 50 mL volumetric flask.
.050L X 3.6 X 10^-3 mol/L= 1.80 X 10^-4

Type your calculation of the moles of 1,10 phenanthroline that you transferred to the 50 mL volumetric flask.
.050L X 3.6 X 10^-3 mol/L= 1.80 X 10^-4

Type your calculation for the moles Fe2+ at the equivalence point.
.0025mol/l X .415 X 1L/100ml = 3.625 X 10^-6

Type your calculation for the ratio of moles of phen to moles of Fe2+.
(1.80 X 10^-4)/ (3.625 X 10^-6)= 50.66
50.66 X 3=

Results and Discussion

Part I
1. The expected stoichiometry is 1:1. How does your result compare (calculate the % error between your mole ratio a
within 5% of this value? (2 pts)
(1-1.3)/1.0 = -.3
.3 X 100= 30%
No, we are not within a 5% of this value as we got a a percent error of 30%.

2. What is your biggest source of error in this part of the experiment? (2 pts)

The biggest source of error in this eperiment is probably human error, for example the rubber tubing could not hav
perhaps we did not wait for the reaction to be completed. This could have cause us to incorrectly measure the amoun
.

3. On the basis of the stoichiometry above, predict the other two products (O2 was one of the products) and write a ba
between H2O2 and NaOCl. (2 pts)
1H2O2 +1 NaOCl
1O2 + 1NaCl + 1H2O

Part II

1. The expected stoichiometry is 3 phen:1 Fe2+. How does your result compare (calculate the % error between your m
you within 5% of this value? (2 pts)
(50.66-3)/3 = 15.89
15.89 X 100 = 1589%
No i am not within 5% of the value.

2. What is your biggest source of error in this part of the experiment? (2 pts)
The biggest source of error may have been not waiting all 5 minutes between each addition.

Laboratory Waste Evaluation (1 pt)

Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, throw
container for disposal by the UW Environmental Health & Safety department, or released into the environment. Based o
actions during the lab, list the identity and approximate amount (mass or volume) of waste that you generated while perfo
30g of hydrogen peroxide
44 ml of bleach
10 wipes

Laboratory Waste Evaluation (1 pt)

Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, throw
container for disposal by the UW Environmental Health & Safety department, or released into the environment. Based o
actions during the lab, list the identity and approximate amount (mass or volume) of waste that you generated while perfo
30g of hydrogen peroxide
44 ml of bleach
10 wipes
removable tip
1ml phen
plastic pipets
800 microliters of Fe2+

QUIZ SECTION:
LAB PARTNER:

AQ
Briana Jarrot

try I

ch
e

d and legible? Have you plotted your data as instructed?

d all future Excel-based reports, make sure that

es are not split across page breaks) before you
e tools in Excel to adjust the page breaks and

you have not plagiarized any part of this lab report, and
data are your own independent work. Failure to sign this
score.

2 pts
%m/m NaOCl
% m/m H2O2

rement #1.

from all four measurements.

2 pts

rement #1.

from all four measurements.

1 pt

mL of Oxygen
Generated
22.0
30.0
47.0
59.0
60.0
58.0
59.0
61.0
54.00
43.00
29.00

r graph big enough to cover this instruction box so that it is an

S. Volume of Oxygen

a graph in Excel. (See the links on the postlab page for this

s. Be sure to double check your units and formatting once you

nes: 1) best fit for the data where H 2O2 is limiting, 2) best fit for
rsection of lines 1 and 2 down to the x-axis in order to clearly

4 pts

Column C

here it is in excess.

2.500

3.000

3.500

4.000

4.500

5.000

drogen Peroxide (g)

1 pt

moles
moles

1 pts

3 pts

4 pt

3.6X10^-3

1 pt

2.50E-03

1 pt

1.00

mL

cover this instruction box so that it is an appropriate size for

VS. Absorbance

ot a graph in Excel. (See the links on the postlab page for

units (Absorbance data is unitless). Be sure to double check

ht lines: 1) best fit for the data where Fe 2+ is limiting, 2) best

m the intersection of lines 1 and 2 down to the x-axis in order
Column D

d where it is in excess.

500

600

5 pts

700

800

900

l
L

1 pt

moles
moles

ed to the 50 mL volumetric flask.

1 pt

3 pts

ed to the 50 mL volumetric flask.

3 pts

1 pt

e the % error between your mole ratio and the expected value)? Are you

xample the rubber tubing could not have been hooked up right, or
e us to incorrectly measure the amount of Oxygen relaeased.

was one of the products) and write a balanced equation for the reaction

e (calculate the % error between your mole ratio and the expected)? Are

en each addition.

disposed of down the sewer drain, thrown in the garbage, collected in a

released into the environment. Based on the written lab procedure and your
) of waste that you generated while performing this experiment.

disposed of down the sewer drain, thrown in the garbage, collected in a

released into the environment. Based on the written lab procedure and your
) of waste that you generated while performing this experiment.