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baking soda. What volume of CO 2 (at r.t.p.) would be released when the reaction
between the two components proceeds to completion?
(c) Calculations Involving Volumetric Titration
Q1. The following experiment was carried out to determine the concentration of ethanol
in a brand of spirit:
10.0 cm3 of a sample of the spirit was diluted to 250 cm 3. To a 25.0 cm3 portion of
the diluted solution, 25.0 cm3 of 0.156 mol dm-3 of K2Cr2O7 (aq) and excess dilute
H2SO4 was added. Ethanol reacted with acidified Cr2O72- as follows:
3CH3CH2OH + 2Cr2O72- + 16H+ 3CH3COOH + 4Cr3+ + 11H2O
After allowing the mixture to stand for about an hour at room temperature, the
excess K2Cr2O7 in the mixture was titrated with 0.118 mol dm -3 (NH4)2Fe(SO4)2 (aq)
using an appropriate indicator. In the titration, 12.25 cm 3 of the Fe2+ solution was
used.
What is the concentration of ethanol, in mol dm-3, in this brand of spirit?
Q2.
H2 Chemistry 9647
Which of the following have the same number of particles as 32.0 g of oxygen gas?
A
B
C
D
Q2.
10 cm3 of a hydrocarbon CxHy was exploded with 100 cm3 of oxygen. After cooling to room
temperature, the resultant gaseous mixture has a volume of 80 cm 3. When the resultant
gaseous mixture was treated with a solution of potassium hydroxide, the volume of the
gaseous mixture decreased to 40 cm3. What is the molecular formula of the hydrocarbon?
[All gas volumes are measured at r.t.p.]
A
C3H6
C3H8
C4H8
C4H10
Q3.
A 1.0 g sample containing 0.0065 mol of organoboron compound, with the formula C xHyBOz,
was burnt in an excess of oxygen. The carbon dioxide and steam produced were passed into
solid NaOH and P2O5, which increased in mass by 2.29 g and 0.877 g respectively. What is the
molecular formula of the organoboron compound?
A CH2BO2
B C8H7BO2
C
C8H15BO2
D
C9H15BO
Q4.
In order to measure the rate of respiration, a person exhales into a respirometer in which the
exhaled air is bubbled at 37 oC and 1 atm through 200 cm 3 of 1.00 mol dm-3 of calcium
hydroxide to obtain a white precipitate. The equation for this reaction is
CO2(g) + Ca(OH)2(aq) CaCO3(s) + H2O(l)
The white precipitate was filtered, washed and dried before reaction with 150 cm 3 of 0.200 mol
dm-3 of hydrochloric acid. The resultant solution was transferred into a volumetric flask and
made up to 250 cm3 with de-ionised water.
A 25.0 cm3 aliquot of this diluted solution required 6.0 cm3 of a 0.200 mol dm3 solution of
sodium hydroxide for complete neutralisation. Calculate the amount of HCl that reacted with
the white precipitate.
Q5.