Beruflich Dokumente
Kultur Dokumente
CRISTAL STRUCTURS
Basis
NET
BASE
ATOMIC
RADIOS
UNIT CELD
PACKING FACTOR
Definition of the
lattice
parameters and
their use in
cubic,
orthorhombic,
and hexagonal
crystal systems.
CC o FCC
Aluminium
Cooper
Gold
Nickel
Iron
4
1/8
1/2
By Pitagora
h2= c2 + c2
But h = 4r
Then
a0
4r
c = ao
(4r)2 = 2ao2
ao2 = (4r)2 / 2
APF =
Chrom
Molibden
Tantalium
Wolframium
Iron
No atomos = (1/8)x8 + 1
2 atoms in BCC
Coordination number = 8
a0
4r
Atoms by cell
To the hexagon
2*1/2= 1 face
3 center
6*1/3*1/2*2= 2 corner
Total 6 atoms by cell
Number coordination = 12
c
a2
a1
a3
Allotropic or Polymorphic
Transformations
Allotropy - The characteristic of an element being able
to exist in more than one crystal structure, depending
on temperature and pressure.
Polymorphism - Compounds exhibiting more than one
type of crystal structure.
Fusion point
Deltha iron FCC
Change of the cristal
structure
Change of the
volume
Room temperature
SOLUTION
Atoms/cell = 2, a0 = 0.2866 nm = 2.866 10-8 cm
Atomic mass = 55.847 g/mol
3
a
Volume of unit cell = 0= (2.866 10-8 cm)3 = 23.54 10-24 cm3/cell
7
.
882
g
/
cm
(23.54 10 24 )(6.02 10 23 )
Density