Propiedades a la temperatura de referencia del liquido y el gas:

tempe. de referencia
T de entrada del gas y liq
Cp del NH3
Cp del H2O
Cp del aire
calor latente de NH3 a Tr
calor latente del H20 a Tr
entalpia de solucion
Gas entrante:

Tr
Tin
CpA
CpC
CpB
A0
C0
H

flujo de gas total

G1 =
yA =
yC =
YA =
YC =
GA =
GC =
GB =

fracciones molares
relaciones molares
flujo de A en el gas
flujo de C en el gas
flujo de B
Entalpia del gas
HG1 =

20 C
20 C
36.39 J/mol.K
75.481 J/mol.K
29.1 J/mol.K
0 J/mol
4.424E+04 J/mol
-40.65 J/mol

0.29 mol
0 mol
0 mol
0.0000 mol
0 mol
0.00000000 mol
0 mol
0.29000 mol

de
de
de
de
de
de
de
de

gas/s
A/ mol
C/ mol
A/ mol
C/ mol
A/s
C/s
B/s

de
de
de
de
de
de
de

liq/s
A/ mol
C/ mol
A/ mol
C/ mol
A/s
C/s

de
de
de
de

gas total
gas total
aire (B)
airen(B)

de
de
de
de

liq total
liq total
C
A

0.000E+00 J/kmol

Liquido entrante:
flujo de Liquido total
fracciones molares
relaciones molares
flujo de A en el Liquido
flujo de C en el Liquido

L2=
xA =
xC =
XA =
XC =
LA =
LC =

Entalpia del liquido

HL2 =

0.28 mol
0.0115 mol
0.9885 mol
0.0116 mol
86.2069 mol
0.00321 mol
0.27679 mol

Porque delta de Hs es cero?

-40.65 J/kmol

Gas saliente:
G2 =
yA =
yC =
YA =
YC =
GA =
GC =
GB =

flujo de gas total

fracciones molares
relaciones molares
flujo de A en el gas
flujo de C en el gas
flujo de B

0.2946 mol
0.0153365329 mol
0.01763 mol
0.015850 mol
0.018231 mol
0.004518 mol
0.00519380 mol
0.28489 mol

de
de
de
de
de
de
de
de

gas/s
A/ mol
C/ mol
A/ mol
C/ mol
A/s
C/s
B/s

de
de
de
de
de
de
de

liq/s
A/mol de liq total
C/ mol de liq total
A/ mol de C
C/ mol de A
A/s
C/s

de
de
de
de

gas total
gas total
aire
aire

Entalpia del gas

HG2 =

7.303E+02 J/mol

Liquido saliente:
flujo de Liquido total

L1 =
xA =
xC =
XA =
XC =
LA =
LC =

fracciones molares
relaciones molares
flujo de A en el Liquido
flujo de C en el Liquido

0.2754 mol
0.0057991734 mol
0.9942008266 mol
0.005833 mol
171.438367907 mol
0.00160 mol
0.27380 mol

Entalpia del liquido

HL1 =

-795.46 J/mol

-6.511E+01

Balance de energia:
G1*HG1+L2*HL2 =G2*HG2 + L1*HL1
TL1 =

10.2084638397

Tgas
entrada

1
2
3
4
5
6
7
8
9
10

XA
20
19.92
19.83
19.75
19.67
19.58
19.50
19.42
19.33
19.25

YA
0.0116
0.0114
0.0112
0.0110
0.0108
0.0106
0.0104
0.0103
0.0101
0.0099

0.0000
0.00053
0.00106
0.00159
0.00212
0.00265
0.00318
0.00371
0.00424
0.00477

11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31

19.17
19.08
19.00
18.92
18.83
18.75
18.67
18.58
18.50
18.42
18.33
18.25
18.17
18.08
18.00
17.92
17.83
17.75
17.67
17.58
17.50

0.0097
0.0095
0.0093
0.0091
0.0089
0.0087
0.0085
0.0083
0.0081
0.0079
0.0078
0.0076
0.0074
0.0072
0.0070
0.0068
0.0066
0.0064
0.0062
0.0060
0.0058

0.00530
0.00583
0.00636
0.00689
0.00742
0.00795
0.00848
0.00901
0.00954
0.01007
0.01060
0.01113
0.01166
0.01219
0.01272
0.01325
0.01378
0.01431
0.01484
0.01537
0.01590

0.0001922333

0.00053

mol
mol
mol
mol

1 atm
NH3=A
Aire=B
Agua=C

T
T
T
T

de
de
de
de

entrada del gas

entradadel liq
salida del gas
salida del liq

abs =

Como a la entrada del liquido no hay NH3 sera la entalpia del agua sola.

de
de
de
de

gas total
gas total
aire (B)
airen(B)

mol de liq total

mol de liq total

ta de Hs es cero?

20
20
17.5
10

mol
mol
mol
mol

de
de
de
de

gas total
gas total
aire
aire

0
suponer un valor de fraccion molar de agua

mol de liq total

mol de liq total

para el liquido se tiene

yc

Tliq (c)
0 20.6574787942
0.0006077 20.3000176882
0.0012154 19.942696675
0.0018231
19.5855295
0.0024308 19.2285161632
0.0030385 18.8716566646
0.0036462 18.5149510041
0.0042539 18.1583991819
0.0048616 17.8020011978
0.0054693 17.4457570519

XA
Tliq (c)
0.01173614
20.66
0.01153941
20.30
0.01134275
19.94
0.01114617
19.59
0.01094966
19.23
0.01075324
18.87
0.01055688
18.51
0.01036061
18.16
0.01016441
17.80
0.00996829
17.45

0.006077 17.0896667442
0.0066847 16.7337302747
0.00729241 16.3779476434
0.00790011 16.0223188502
0.00850781 15.6668438953
0.00911551 15.3115227785
0.00972321 14.9563554999
0.01033091 14.6013420596
0.01093861 14.2464824574
0.01154631 13.8917766933
0.01215401 13.5372247675
0.01276171 13.1828266799
0.01336941 12.8285824304
0.01397711 12.4744920191
0.01458481 12.1205554461
0.01519251 11.7667727112
0.01580021 11.4131438145
0.01640791 11.059668756
0.01701561 10.7063475356
0.01762331 10.3531801535
0.01823101 10.0001666095
0.00101134

0.00977224
0.00957627
0.00938037
0.00918456
0.00898881
0.00879315
0.00859756
0.00840204
0.0082066
0.00801124
0.00781595
0.00762074
0.0074256
0.00723054
0.00703555
0.00684064
0.00664581
0.00645105
0.00625637
0.00606176
0.00586722

17.09
16.73
16.38
16.02
15.67
15.31
14.96
14.60
14.25
13.89
13.54
13.18
12.83
12.47
12.12
11.77
11.41
11.06
10.71
10.35
10.00

C
C
C
C

datos d equilibrio a 1 atm para NH3-agua

tenemos:
Lo de negrita
x
TC
H=y*/x
10
0.44
15.5
0.59
0.0117361392
20
0.74
0.0113427484
21.2
0.78
0.0103606084
25
0.96
0.0099682863
26.6
1.03
0.0089888127
30
1.22
0.00840204
32.2
1.34

son datos teoricos?

y*

0.00868474
0.00884734
0.00990397
0.01026733
0.0109503
0.01125873

0.0076207371
0.0062563664
0.0058672245

35
40
41.3
Interpola y extrapola

1.50
0.011393
1.77 0.01108494
1.84 0.0108177
?

E1
xH
0
0.06

E2
0.74
0
0.0444

E3
0.78
0
0.0468

E4
0.96
0
0.0576

1.03
0
0.0618

curva de equilbrio

E5

E6
1.22
0
0.0732

E7
1.34
0
0.0804

E8
1.5
0
0.09

equilbrio

curva deEquilibrio
E1
E6
E9

E9
1.77
0
0.1062

1.84
0
0.1104