PHYSICALSTATEPROBLEMS!

1. If325.0mlofoxygenarecollectedat298Kand98.5kPa,
whatwillbethevolumeofdryoxygenatSTP?
2. Whatisthemassof3.00litersofhydrogenatSTP?
3. Whatisthevolumeof190.0gramsofnitrogenat23.5Cand99.0kPa?
4. ThedensityofagascompoundatSTPis3.90g/l.Calculateitsmolarmass!
5. Whatisthedensityofelementaloxygeningramsperliterat250Cand.850atm?
6. Calculatethedensitying/LofSF6gasat27.0Cand2.0atmpressure.
7. Calculatethedensityofheliumingramsperliterat210Cand752mmHg.Sincethedensityof
airundertheseconditionsis1.188g/L,thatiswhyheliumfloats.
8. Halothaneisaninhalationanesthetic.Thedensityofhalothanevaporat710Cand768mmHg
is7.05g/L.Whatisthemolarmassofhalothane?
9. Asampleofgaseoussubstanceat250Cand650mmHghasadensityof2.26g/L.Whatisthe
molarmassofthesubstance?
10. Chloroform,CHCl3,isavolatile(easilyvaporized)liquidsolvent.Calculatethedensityof
chloroformvaporat98oCand781mmHg.Obtainthedensityingramsperliter.
11. Calculatethedensityofhydrogensulfidegasat560Cand967mmHg.Obtainthedensityin
gramsperliter.
12. Youvaporizealiquidsubstanceat1000Cand755mmHg.Thevolumeof.548gramsofvapor
is237mL.Whatisthemolarmassofthesubstance?
13. A2.30gramsampleofwhitesolidwasvaporizedina345mLvessel.Ifthevaporhasa
pressureof103Kpaat1480C,whatisthemolarmassofthesubstance?
14. A1.00Lsampleofdryairat250Cand786mmHgcontains.925gofnitrogen,plusother
gasesincludingoxygen,argon,andcarbondioxide.Whatisthepartialpressure,inmmHg,of
thenitrogenintheair?Whatisthemolefractionormolepercentofnitrogeninthemixture?
15. A10.0literflaskcontains1.013gramsofoxygenand.572gramsofcarbondioxideat180C.
Whatarethepartialpressuresofoxygenandcarbondioxide?Whatisthetotalpressure?What
isthemolefractionofoxygeninthemixture?
16. TheU.S.Navydevelopedanunderseahabitat.Inoneexperiment,themolepercent
compositionoftheatmosphereinthehabitatwas79.0%helium,17.0%nitrogen,and4.0%
oxygen.Whatwillbethepartialpressureofeachgaswhenthehabitatis58.8metersbelowsea
level,wherethepressureis6.91atm?
17. Calculatethetotalpressureinatmofamixtureof.0300molesofhelium,and.0200molesof
oxygen,ina4.00literflaskat200C.Assumeidealgasbehavior!
18. FormicAcid,HCHO2,isaconvenientsourceofsmallquantitiesofcarbonmonoxide.When
warmedwithanacidcatalyst,itdecomposestogiveoffwaterandcarbonmonoxide.If3.85
litersofCOwascollectedoverwaterat250Cand689mmHg,howmanygramsofformic
acidwereused?
19. Hydrogengasisisolatedfromzincandhydrochloricacid.Ifthegasiscollectedoverwater,
and156mLofhydrogenarecollectedat190Cand769mmHgtotalpressure,whatisthemass
ofhydrogencollected?
20. Oxygencanbepreparedfromheatingpotassiumchlorate.Howmanymolesofoxygenwould
beobtainedfrom1.300gramsofpotassiumchlorate?Iftheoxygeniscollectedoverwaterat
230Candatotalpressureof745mmHg,whatvolumewouldtheoxygenoccupy?

21. Calculatethermsspeedofoxygenmoleculesinatankat210Cand15.7atm.Usethe
appropriateRvalue!
22. Whatisthermsspeedofcarbontetrachloridemoleculesat220C?
23. Calculatethermsspeedofbrominemoleculesat230Cand1.00atm.Whatisthermsspeedof
bromineat230Cand1.50atm?
24. Atwhattemperaturewouldthermsspeedofoxygenmoleculesbe400m/s?
25. Calculatetheratioofeffusionratesofmoleculesofcarbondioxideandsulfurdioxidefromthe
samecontainerandthesameTandP.
26. Ifittakes3.52secondsfor10.0mLofheliumtoeffusethroughaholeinacontainerata
particulartemperatureandpressure,howlongwouldittakefor10.0mLofoxygentoeffuse
fromthesamecontaineratthesameTandP?
27. Ifittakes4.67timesaslongforaparticulargastoeffuseasittakeshydrogenunderthesame
conditions,whatisthemolecularweightofthegas?
28. Agivenvolumeofnitrogengasrequired68.3stoeffusefromaholeinachamber.Underthe
sameconditions,anothergasrequired85.6sforthesamevolumetoeffuse.Whatisthe
molecularweightofthisgas?
29. If65gramsofsodiumsulfitepowderisreactedwithexcessphosphoricacid,thenhowmany
mLofgasoverwaterarecollectedat55oCand842mmHgtotalpressure?
30. Ifthetotalpressureinsideofthespaceshuttleis142kPa,thenwhatisthepartialpressureof
theoxygeninsidetheshuttle,iftheshuttleisfilledwithair,ornitrogen,oxygen,andcarbon
dioxide?Assumethespaceshuttlecontains3300gramsofoxygen.Theshuttleiskeptata
constant25oC,andthetotalvolumeoftheshuttleis10.0m3.Howmanytotalmolesofgasare
inthespaceshuttle?
31. Thenavyhassmall400literpatrolvesselsthattravelunderthewaterinsearchformines.If
theatmosphereinsideapatrolvesselcontains1672mmHgtotalpressure,andtheatmosphere
ismadeofoxygenandnitrogen,thenwhatisthepartialpressureofthenitrogeninthevessel,if
thetemperatureis350C?Thepartialpressureoftheoxygenis335mmHg.Whatisthetotal
numberofmolesinthevessel?
32. Ifittakes52secondsfor.10molesofiodinevaportoeffusefromanopeninginavessel,then
howlongwouldittake.10molesofhydrogentoeffuseunderthesameconditions?
33. Ifittakes10.6hoursfor1.00litersofnitrogengastoeffusethroughporesinaballoon,then
howlongwouldittakeanequalvolumeofheliumtoeffuseunderthesameconditions?
34. Howlongwouldittakeethanolvaportoeffusethroughasmallporousholeinawinebottle,if
ittook2.30hoursforchlorinegastoeffusethroughthesamehole?
35. Howmanylitersofgasarerequiredtoreactwithexcessaluminumhydroxidepowderat350C
and25psi,ifthegasisreactedoverwater?Assumethat85.5gramsofaluminumsulfiteand
waterareproductsofthereaction!
36. Calculatetherootmeansquarespeedofavaporousethanolmoleculeat1.5atmospheresof
pressureand1200C?
37. Howmanylitersofgascanbecollectedoverwaterat550Cand1.6atm,whenexcess
phosphoricacidisreactedwith25gramsofcupricsulfite?
38. Whatisthetotalpressureinsideofagascollectiontubeifthetemperatureis340C,and115
gramsofsodiumsulfidereactedwithexcessbromicacid?Assume15litersofgasisthen
collectedoverwaterinthetube.