Class XI

Chemistry
Time :-3 Hrs.
M.M.70
General Instructions:
(i) All questions are compulsory.
(ii) Q. No. 1 to 8 carry 01 mark
each. (iii) Q No. 9 to 18 carry 02
marks each. (iv) Q No. 19 to 27
carry 03 marks each.
(v) Q. No. 28 to 30 carry o5 marks each.
(vi) Use log table if necessary, calculator is not permitted.
Q1.

How many inner transition series are present in the f-block?

[1]

Q2.

Give the general electronic configuration of the members of

the carbon
family.

[1]

Q3.

Write Charless law.

[1]

Q4.

When is bond energy equal to bond dissociation energy?

[1]

Q5.

What are conjugate acid and conjugate base of H2O?

[1]

Q6.

Write formula of Kc for following equilibrium.

[2]

N2 + O2 2NO
Q7.
Balance the following reaction in acidic
medium.

[2]

NO3- NO2
Q8.

Give one use of dihydrogen (H2).

[2]

Q9.

Give reasons:

[2]

(i) Water can extinguish most fires but

petrol fire. (ii) Temporary hard water
on boiling.
Q10. becomes
Calculate soft
the molar
mass of water if water sample contains 50%
heavy water
(D2O).
Q11. State as to why:

[2]

[3]

(i) The hydroxide of alkali metals are

strong bases. (ii) Sodium is stored in
kerosene oil.
Q12. Define disproportionate with suitable example.

www.parthaedu.com

[3]

Q13. Write short notes on any

[3]

two. (i) Adiabatic process

(ii) Extensive properties
(iii) Entropy
(iv) Isolated system
Q14. Same mass of diamond and graphite (both being carbon) are

[3]

burnt in oxygen. Will the heat produced be same or diferent?

Q15. Why?
Calculate the no. of atoms in 64 g of SO2

[3]

at N. T. P. (S = 32, O = 16)
Q16. Sodium Chloride (NaCl) gives white ppt with AgNO3 solution but

[5]

chloroform doesnt. Explain.

Q17. Explain the following:

[5]

(i) Fluorine is most electronegative

element. (ii) Cesium is used in
cell. configuration of the
Q18. photoelectric
Give the electronic
following ions: (i) CO3+ (At No. of CO = 27)
(ii) Fe2+ (at. No. of Fe = 26)
Q19. Chorine is prepared by action of HCl on MnO2.
4HCl + MnO MnCl + 2N O + Cl
2

How many grams of HCl react with 3.84 g. (At mass of Mn = 55)
Q20. The mass of an electron is 9.1 x 10-31 kg. If its K.E. is 3 x 10-25 J.
Calculate its wavelength.
Q21. (a) What is the basic diferences between the terms electron
gain enthalpy and electro negativity.
(b) In terms of period and group, where would you locate the
element with atomic number 10.
Q22. Calculate No. of sigma and pi bond in
following: (i) CH2 = CH CH3
(ii) CH3C CCH2OH

(iii) CH3CH2CH3
Q23.

Predict the type of hybridization and shape of the following

molecules on the basis of VSEPR theory.
(i) BF3
(ii) SF4
(iii) CH4

Q24.

Calculate the total pressure in a mixture of 8 g of oxygen and 4

g of hydrogen confined in a vessel of 1 dm3 at 270 C.
(R = o.o83 bar dm3 K-1 mol-1)

Q25.

Balance the following equation by used oxidation number

method in basic medium.
P4 + OH- PH3 + H2PO-2

Q26.
270 C. ItWhat
its do you mean by solubility product. Calculate Ksp of AgCl at
solubility in a saturated solution is 1.435 x 10-3gL-1 at same
temperature. (Ag = 108, Cl = 35.5)
Q27. What are hydrides. Write diferent types of hydrides with
examples.
Q28. What transition in the hydrogen spectrum would have same
wavelength as
Balmer transition n = 4 to n = 2 of He+ spectrum.
OR
The work function for calcium atom is 1.9 e.v.
Calculate: (a) The threshold wavelength
(b) the threshold frequency
If the metal is irradiated with a wavelength 500 nm. Calculate
Kinetic energy and the velocity of the ejected photoelectrons.
Q29.

(a) State the law governing entropy and temperate.

(b) Define enthalpy of formation under standard conditions.
Calculate the enthalpy of formation of methane at 298 K. If
enthalpies of combustion of methane, graphite and hydrogen
at 298 K are 890.2 KJ, 393.4 KL and 285 mol-1 respectively.

OR
(a) State and explain first law of thermodynamics with its
mathematical form.
(b) H for the reaction

Is 150 KJ. Calculate the bond energy of C N bond.

-1

-1

Bond energy of C H = n414 KL mol , H H = 435 KJ mol ,

-1

C N = 293 KJ mol , N H = 396 KJ mol

Q30.

-1

(a) For a general reaction, derive a relation between Kc and Kp

with absolute temperature and gas constant Rx is aA + bB cC
+ dD.
(b) What is the importance of HCl during the precipitation of
sulphide of 2nd
group.
OR
(a) What do you mean by Le-Chateliers principle. By using it
identify the suitable conditions for good yield of ammonia.
N2 + 3H2 2NH3.
(b) For reaction:
2A B + C
the equilibrium constant Kc is 2.0 x 10-3. In which direction the
reaction will proceed if the composition of the reaction mixture
at any time is:
[A] = [B] = [C] = 3.0 x 12 mol L-1.