Types of Bonding 1. Ionic Bonding Involve the electrostatic attraction between negative and positive ions Formed between metal and non-metal Electrons are transferred from the metal to the non-metal Ionic bonds are generally very strong and hence ionic compounds tend to have high melting points, eg. NaF = 993 C; KCl = 770 C An ionic compound in its solid form is generally a crystal lattice - ions are packed together in an orderly fashion The greater the radii of the ions, the weaker the ionic bond strength The greater the charge on the ions, the stronger the ionic bond strength 2. Covalent Bonding Involve sharing of electrons by two non-metal atoms Is formed when two atoms having less that full shells of electrons are able to share one or more electrons with each other to attain full electron shells.
Chemistry 11
In general, OCTET RULE states that atoms
(particularly in columns 14-17) tend to form covalent bonds so to have EIGHT electrons in their valence shells Covalent bonds are also very strong; compounds with only covalent bonds have high melting points eg. BN = ~ 3000 C; C(diamond) = ~ 3550 C NOT all covalent compounds have high melting points: eg. CH4 = -182 C; O2 = -218 C The more electrons shared in a covalent bond, the stronger the bond and shorter the bond length The larger the atoms involved in a covalent bond, the weaker the bond Two forms of covalent bonding, depending on degree of sharing: a) Equal sharing - also known as NON-POLAR COVALENT Eg. H2 molecule each H atom is equally attracted to each atoms electron (both atoms have the same electronegativity). The H2 molecule is described as NON-POLAR
Chemistry 11
b)Unequal sharing also known as POLAR
COVALENT Eg. HCl the Cl atom is more electronegative than H atom, so Cl will have a greater attraction for the shared electron than H the electron is pulled closer toward the Cl nucleus. As a result, a partial negative pole (slight excess of negative charge) results for the Cl atom, whilst a partial positive pole (slight excess of positive charge) results for the H atom The HCl molecule is described as POLAR and a dipole exists in the molecule
3.
Van der Waals Forces
Individual molecules are held together by covalent
bonds between the atoms in the molecule. Such bonds are STRONG and are called INTRAMOLECULAR FORCES (intra = within) In addition to the bonds holding together in to molecular units, there are WEAK forces which hold one, complete, neutrally-charged molecule next to another such molecule. These INTERMOLECULAR FORCES (inter = between) are called van der Waals forces There are several types of van der Waals forces, depending upon the type of molecules involved: