NOVA SPECIALTY CHEMICALS

MATERIAL SAFETY DATA SHEET

Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, New Zealand, Japanese, and European Union Standards

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

TRADE NAME:
CHEMICAL NAME:
Hazchem Code (Australia):
Poisons Schedule Num (Australia):
MANUFACTURER:

This MSDS covers all Xylene based Novasolve products

Solvent Dye
3YE
Category 5
NOVA SPECIALTY CHEMICALS
404 E. Main Street, Rockaway NJ 07866
1-800-424-9300
973-586-1900 or 973-586-2147
07012013

EMERGENCY NUMBER:
BUSINESS PHONE:
MSDS LAST REVISED

2. COMPOSITION, INFORMATION ON INGREDIENTS

TSCA Status: The components of this product are not included in the public TSCA Inventory. All components of this product
are in compliance with the Toxic Substance Control Act.
CHEMICAL NAME
Organic Dye

CAS #
Proprietary

EINECS
Listed

AICS
Listed

TSCA
Listed

%w/w
40-60

Xylene

1330-20-7

Listed

Listed

Listed

40-60

Ethylbenzene

100-41-4

Listed

Listed

Listed

5-10

EU Classification
Hazard Classification: None
Hazard Classification: Xn, F
R/S Phrases : R10, S16
Hazard Classification: Xn, F
R/S Phrases : R10, S16/23

NOTE: ALL Canadian WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004
format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR. All European Union, Australian (NOHSC: 2011, 8.308.48) information, and Japanese
Industrial Standard (JIS Z 7250: 2000) required information is included. See Section 16 for full text of Ingredient Risk
Phrases

3. HAZARDS IDENTIFICATION
EU Classification: Xn (Harmful), F (Flammable)
EU Risk Phrases: R10
EMERGENCY OVERVIEW:
Product Description:
Health Hazards:
Flammability Hazards:
Reactivity Hazards:
Environmental Hazards:
Emergency Considerations:

This product is xylene based liquid.

Inhalation of fumes can cause headaches, nausea, fatigue and loss of consciousness.
Avoid contact with skin as some components may be absorbed through skin. Irritant to
skin, eyes and mucous membranes.
This product is flammable. Keep away from sources of heat, flame or sparks.
This product is not reactive.
Large quantities released to the environment may have an adverse effect. Release to
bodies of water may choke off aquatic organisms.
Responders should wear respiratory protection to guard against fumes.

SYMPTOMS OF OVEREXPOSURE BY ROUTE OF

EXPOSURE: The health hazard information provided below is
pertinent to employees using this product in an occupational
setting. The toxicological properties of this product have not
been thoroughly investigated. The following paragraphs
describe the symptoms of exposure by route of exposure.
INHALATION: Breathing high concentrations may be harmful.
Mist or vapor can irritate the throat and lungs. Breathing this
material may cause central nervous system depression with
symptoms including nausea, headache, dizziness, fatigue,
drowsiness, or unconsciousness. Breathing high
concentrations of this material, for example, in an enclosed
space or by intentional abuse, can cause irregular heartbeats
which can cause death.

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM

HEALTH

FLAMMABILITY

REACTIVITY

PERSONAL PROTECTION
EYES

HANDS

RESP

BODY

See
Section 8

See
Section 8

For Routine Handling and Industrial Applications

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CONTACT WITH SKIN or EYES: This material can cause eye irritation with tearing, redness, or a stinging or burning
feeling. Further, it can cause swelling of the eyes with blurred vision. Effects may become more serious with repeated or
prolonged contact. May cause mild skin irritation with redness and/or an itching or burning feeling. Effects may become
more serious with repeated or prolonged contact. It is likely that some components of this material are able to pass into the
body through the skin and may cause similar effects as from breathing or swallowing it.
INGESTION: Swallowing this material may be harmful. Swallowing this material may cause stomach or intestinal upset with
pain, nausea, and/or diarrhea. This material can get into the lungs during swallowing or vomiting. Small amounts in the
lungs can cause lung damage, possibly leading to chronic lung dysfunction or death. Swallowing this material may cause
effects similar to those described in the inhalation section (see "inhalation" above).
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
Overexposure to this product may cause the following:
ACUTE: The dye may stain hair, skin, and other contaminated tissue. Inhalation of vapors can cause dizziness, headaches
and loss of consciousness. Ingestion can cause nausea and vomiting.
CHRONIC: Prolonged or repeated skin overexposures may cause dermatitis (dry red skin). Reports have associated
repeated and prolonged occupational overexposure to solvents with irreversible brain and nervous system damage
(sometimes referred to as "Solvent or Painter's Syndrome").
TARGET ORGANS: ACUTE: Eyes, lungs. CHRONIC: Blood, liver, kidneys, lungs.

4. FIRST-AID MEASURES
EYES:
SKIN:
INGESTION:

INHALATION:

Flush eyes with water for at least 15 minutes. Hold eyelids apart to ensure complete irrigation. Contact
a physician.
Rinse exposed area with water. The dye can be removed with hand cream or hand cleaner. Contact a
physician if irritation develops.
Do not induce vomiting. If spontaneous vomiting is about to occur, place victims head below knees. If
victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to
a person who is not fully conscious. Do not leave victim unattended. Seek medical attention
immediately.
Remove the individual to fresh air. If not breathing, give artificial respiration. If breathing difficult, give
oxygen. Call a physician.

5. FIRE FIGHTING MEASURES

FLAMMABILITY PROPERTIES
FLASHPOINT (oC)
AUTO IGNITION TEMP (oC)
o
o
28-26 C (84-81 F)
432C (810F)
FLAMMABLE LIMITS (AIR VOL %)
UEL
LEL
7%
1%
Special fire fighting Procedures:

FIRE EXTINGUISING MATERIALS

WATER OK
FOAM OK
CO2 BEST
HALON NO
DRY CHEMICAL BEST

Protective clothing and self-contained

NFPA RATING
breathing apparatus should be worn
FLAMMABILITY
when
fighting
fires
involving
chemicals. Contain water runoff when
fighting
fire
as
it
may
be
contaminated with product. In case of
REACTIVITY
fire water can only be used to cool HEALTH
containers to prevent them from
rupturing. Use sand, CO2, or foam to
extinguish flames.
Flammable liquid! This material
releases vapors at or below ambient
temperatures. When mixed with air in
certain proportions and exposed to an
ignition source, its vapor can cause a
flash fire. Use only with adequate
ventilation. Vapors are heavier than air and may travel long distances along the
ground to an ignition source and flash back. A vapor and air mixture can create an
explosion hazard in confined spaces such as sewers. If container is not properly
cooled, it can rupture in the heat of a fire.

Fire and Explosion Hazards:

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6. ACCIDENTAL RELEASE MEASURES

Stop, contain and clean up the spill immediately. Contain liquids using absorbents. Sweep up powders carefully, minimizing
dusting. Dye residue on concrete and metal surfaces may be wiped and cleaned with light mineral oil. Shovel all spill
materials into disposal drums and follow all Federal, State and Local disposal regulations.

7. HANDLING AND STORAGE

STORAGE AND HANDLING PRACTICES: Employees must be trained to properly use this product. Keep away from heat,
sparks, and other sources of ignition. Store outdoors. If stored in enclosed space adequate ventilation must be provided to
minimize vapor buildup. Use non-sparking tools. Open containers slowly on a stable surface. When pouring or dispensing to
or from drums or other containers, insure that all containers are properly grounded/bonded to prevent static charge build up.
Store containers in a cool, dry location, away from sources of intense heat. Store away from incompatible materials (see
Section 10, Stability and Reactivity). Storage areas should be made of fire resistant materials. Post warning and NO
SMOKING signs in storage and use areas, as appropriate. Have appropriate extinguishing equipment in the storage area
(i.e., sprinkler system, portable fire extinguishers). Keep container tightly closed when not in use. Inspect all incoming
containers before storage to ensure containers are properly labeled and not damaged. Empty containers may contain
residual dye that is combustible; therefore, empty packages should be handled with care.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained
below the limits provided below. Exhaust directly to the outside, taking necessary precautions for environmental protection.
If necessary, refer to Australian National Code of Practice for the Control of Workplace Hazardous Substances [NOHSC:
2007 (1994)] for further information.
EXPOSURE LIMITS IN AIR
ACGIH-TLV
OSHA-PEL
NIOSH-RELs
NIOSH
OTHER
Chemical Name
Dye

CAS #
Proprietary

Xylene

1330-20-7

Ethylbenzene

100-41-4

TWA
mg/m3

STEL
mg/m3

TWA
mg/m3

100
(8hr)
100
(8hr)

150
(15min)
150
(15min)

100
(8hr)
100
(8hr)

STEL
mg/m3

TWA
mg/m3

STEL
mg/m3

IDLH
mg/m3

mg/m3

The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with
OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132), equivalent standards of Canada (including CSA
Standard Z94.4-02 and CSA Standard Z94.3-02), standards of EU member states (including EN 529:2005 for respiratory
PPE, CEN/TR 15419:2006 for hand protection, and CR 13464:1999 for face/eye protection), or standards of Australia
(including AS/NZS 1715:1994 for respiratory PPE, AS/NZS 4501.2:2006 for protective clothing, AS/NZS 2161.1:2000 for
glove selection, and AS/NZS 1336:1997 for eye protection). Please reference applicable regulations and standards for
relevant details.
RESPIRATORY PROTECTION: If necessary, use only respiratory protection authorized in the U.S. Federal OSHA
Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-02,
the European Standard EN 529:2005, and EU member state standards, the Australian Standard 1716-Respiratory
Protective Devices and Australian Standard 1715-Selection, Use, and Maintenance of Respiratory Protective Devices, New
Zealand standards, or Japanese standards. Oxygen levels below 19.5% are considered IDLH by OSHA. In such
atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary selfcontained air supply is required under OSHAs Respiratory Protection Standard (1910.134-1998).
EYE PROTECTION: Wear safety glasses with side shields (or goggles) and a face shield. If necessary, refer to U.S. OSHA
29 CFR 1910.133, Canadian CSA Standard Z94.3-02, or the European Standard CR 13464:1999, the Australian Standard
1337-Eye Protection for Industrial Applications and Australian Standard 1336-Recommended Practices for Eye Protection in
the Industrial Environment, New Zealand standards, or Japanese standards.
HAND PROTECTION: Wear nitrile, Viton, or Tychem SL gloves. Check gloves for leaks. Wash hands before putting on
gloves and after removing gloves. If necessary, refer to U.S. OSHA 29 CFR 1910.138, appropriate Standards of Canada,
and the Australian Standard 2161-Industrial Safety Gloves and Mittens and the European Standard CEN/TR 15419:2006,
New Zealand standards, or Japanese standards.
BODY/SKIN PROTECTION: Use body protection appropriate for task (e.g., coveralls or apron). If necessary, refer to
appropriate Standards of Canada, the European Standard CEN/TR 15419:2006, Australian Standard 3765-Clothing for
Protection against Hazardous Chemicals, New Zealand standards, or Japanese standards. If a hazard of injury to the feet
exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employees feet may be
exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136 and the Canadian CSA
Standard Z195-02, Protective Footwear.

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9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point:
Freezing Point:
Vapor Density:
Appearance and Odor:

280oF (138oC)
< -13 oF (-25oC)
>3.7 (Air =1)
Dark Liquid with aromatic odor.

Specific Gravity:
Percent Volatile:
Vapor Pressure:
Solubility in Water:

0.88
30-50%
7.0mmHg @ 20oC
Insoluble

10. STABILITY AND REACTIVITY

STABILITY: This product is stable when properly stored at normal temperature and pressures (see Section 7, Handling and
Storage).
DECOMPOSITION PRODUCTS: If exposed to extremely high temperatures, thermal decomposition may generate irritating
fumes and toxic gases (e.g., carbon oxides, nitrogen oxides).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is incompatible with strong oxidizers and
reducers such as liquid chlorine, hydrogen peroxide and oxygen. Keep away from all sources of heat, flame and ignition.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid exposure to or contact with extreme temperatures, sparks, flames, and incompatible
chemicals.

11. TOXICOLOGY
TOXICITY DATA: The toxicological properties of this product have not been thoroughly investigated. The specific toxicology
data available for the components of this product are as follows:
Xylene:
ORAL (LD50), Acute: 4,300 mg/kg [Rat].
INHALATION (LC50), Acute: 4,550 ppm for four hours [Rat].
DERMAL (LD50), Acute: 14,100 uL/kg [Rabbit].
Ethylbenzene:
ORAL (LD50), Acute: 3,500 mg/kg [Rat].
DERMAL (LD50), Acute: 17,800 uL/kg [Rabbit].
INTRAPERITONEAL (LD50), Acute: 2,624 mg/kg [Rat].
IRRITANCY OF PRODUCT: Overexposures to this product may slightly to moderately irritate eyes, skin, and other
contaminated tissues.
SENSITIZATION OF PRODUCT: This product is not known to be a human skin or respiratory sensitizer.
SUSPECTED CANCER AGENT: IARC has classified ethyl benzene as possibly carcinogenic to humans (Group 2B).
Based on this criteria this product is not considered a carcinogen by the US, EU, Australia or Japan but is listed by Canada
as a possible carcinogen.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects this product and its
components on human and animal reproductive systems.
MUTAGENICITY: Xylene: YES (animal studies), Ethylbenzene: YES (animal studies)
EMBRYOTOXICITY: Xylene: YES (animal studies), Ethylbenzene: YES (animal studies)
TERATOGENICITY: The components of this product are not reported to cause teratogenic effects in humans.
REPRODUCTIVE TOXICITY: The components of this product are not reported to cause human reproductive effects.
ACGIH BIOLOGICAL EXPOSURE INDICES (BEIS): Currently, there are no ACGIH Biological Exposure Indices (BEIs)
determined for the components of this product.

12. ECOLOGICAL INFORMATION

If applied to leaves, this product may kill grasses and small plants by interfering with transpiration and respiration. This
product Is not toxic to fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. Product
may be moderately toxic to amphibians by preventing dermal respiration. This product may cause gastrointestinal distress
to birds and mammals through ingestion during peliage grooming. This product is not expected to bioaccumulate through
food chains in the environment.

13. DISPOSAL CONSIDERATIONS

PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations or with regulations of Canada and its Provinces, Australia, New Zealand, Japan, the EU, or EU member
States. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local
hazardous waste regulatory authority. EPA Hazardous Codes: Ignitibility (D001) and toxic (D018).

14. TRANSPORT INFORMATION

US DOT Status:
PROPER SHIPPING NAME:
HAZARD CLASS NUMBER and DESCRIPTION:
UN IDENTIFICATION NUMBER:
PACKING GROUP:

Revision 3.6

A U.S. Department of Transportation regulated material.

RQ, Xylene, 3, UN 1307, PG II or III
3
1307
II / III

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DOT LABEL(S) REQUIRED:

REPORTABLE QUANTITY:

Flammable 3.
RQ 166 lbs (Based upon maximum Xylene concentration of 60% and an
RQ of 100 lbs.)
EMERGENCY RESPONSE GUIDEBOOK NUMBER (2004): 130
MARINE POLLUTANT:
This product is not classified by the U.S. DOT as a Marine Pollutant (as
defined by 49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: Hazardous Material
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): Dangerous Goods.
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
Proper Shipping Name:
Xylene
Class:
3.2
UN Number:
UN 1307
Symbol:
Flammable Liquid N.O.S.
Pollution Category:
C
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR):
ADR/RID class:
3 Flammable liquids.
Danger code (Kemler):
30
AUSTRALIAN FEDERAL OFFICE OF ROAD SAFETY CODE FOR THE TRANSPORTATION OF DANGEROUS GOODS

15. REGULATORY INFORMATION

BY ROAD OR RAIL: This product is classified as dangerous goods, per regulations of the Federal Office of Road Safety.
SARA TITLE III Hazard Classifications:
Acute: Yes
Reactivity: No
Chronic: Yes
Pressure:
No
Fire: Yes
This information may be subject to the provisions of the Community-Right to Know reporting requirements (40 CFR 370)
if threshold quantities are met.
SARA Section 313 Toxic Chemicals Xylene, Ethylbenzene
SARA Section 304 Reportable Quantity No regulated ingredients.
SARA Section 302 Extremely Hazardous Material No regulated ingredients
SARA Section 313 Supplier Notification No regulated ingredients
CERCLA Xylene, Ethylbenzene
Ozone Depleting Chemicals No regulated ingredients
California Prop 65: Ethylbenzene
Chemical Inventory Listing:
Listed on the following Countrys Chemical Inventories:
USA
Toxic Substance Control Act
Listed
Australia
Australian Inventory
Listed
Republic of Korea
Korean Inventory
Listed
Japan
Japanese MITI Inventory
Listed
Philippines
Philippines Inventory
Listed
Canada
Domestic Substances List
Listed
China
Existing Chemical Substance List
Listed
New Zealand
NZIoC
Listed
CANADIAN REGULATIONS:
This product is a 'controlled product' under the Canadian Workplace Hazardous Materials Information System (WHMIS).
Canadian WHMIS Hazard Classification: According to the Controlled Products Regulations (Sections 33 to 66), this product
is classified as a flammable liquid (Class B, Division 3). This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
EUROPEAN UNION INFORMATION:
EU LABELING/CLASSIFICATION: Xn, F
EU RISK PHRASES: R10,20/22
EU SAFETY PHRASES: S16, 37/39
EUROPEAN UNION ANNEX II HAZARD SYMBOL: Not applicable.
AUSTRALIAN INFORMATION:
HAZARDOUS SUBSTANCES INFORMATION SYSTEM (HSIS): Listed
CLASSIFICATION: Xn, F
RISK PHRASES: : R10,20/22,
SAFETY PHRASES: S16/, S37/29
POISONS SCHEDULE NUMBER: Category 5.
NEW ZEALAND HAZARDOUS SUBSTANCES AND NEW ORGANISMS ACT (1996): The components of this product are
registered as hazardous substances with the Environmental Risk Management Authority.
JAPAN POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW: Xylene is listed as a deleterious substance.

OTHER DATA
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA WHICH IS BELIEVED
TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND, EXPRESSED OR IMPLIED, IS MADE
WITH RESPECT TO THE INFORMATION CONTAINED HEREIN.

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