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[R ]2
[R ]1
[R ]
=
T2 T1
T
[ ]# ' [ ]!(
)
[R ]
velocidad =
T
+
,)
45
FISICA
40
V = ESPACIO/TIEMPO
ESPACIO(M)
VELOCIDAD
V = 45/7
35
30
25
V = 25/4
20
15
10
V = 10/2
5
TIEMPO(S)
2
[
P ]2 [P ]1
velocidad =
T2 T1
[P ]
T
)/
#
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=
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1 d [ A]
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1 d [D ]
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si
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Principio de Le Chtelier
Si un sistema que ha alcanzado el equilibrio
qumico es perturbado (cambio de concentracin,
T, P, V), reacciona oponindose a la perturbacin,
de modo de volver a la condicin de equilibrio.
N2(g) + 3H2(g)
2NH3(g)
Principio de Le Chtelier
N2(g) + 3H2(g)
2NH3(g)
2NH3(g)
=
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K P = K c (RT )
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l
atm l
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0,082
1000 K
2
mol
mol K
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J
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1.0 X10
X 10
X
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HC 2 H 3O2 H + C2 H 3O2
[H ][C H O ] = 1.8 X 10
+
[HC 2 H 3O2 ]
&"
8;
0;1
[H ] = 1.8 X 10
+
09>8
0;1
M
5
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6
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[H ][A ] = Ka
+
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6
[
A ]
log [H ]+ log
= log Ka
[HA]
[
A ]
log [H ] log
= log Ka
[HA]
[
A ]
pH log
= pKa
[HA]
pH = pKa + log
[A ]
[HA]
C sal
pH = pKi + log
C acido
6
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Concentr. equilibrio
(mol/l)
K L
[SO2]
[O2]
[SO3]
Kc
B
#
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0?
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0?
0,030
0,115
0,170
279,2
B
#
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0,014
0,332
0,135
280,7
B
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0,053
0,026
0,143
280,0
B
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0,066
0,568
280,5
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0,037
0,343
0,363
280,6
K
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Kc =
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Kc =
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K c = [CO2 ] [H2O ]
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0,0922 M 2
Kc =
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1,0623 M 3 0,354 M
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4;68.9
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x
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0,25
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<
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0,0014
0,013
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