Part 4:

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Temperature is a state function but heat is not. Why?

Define system and surrounding with one example each.
Define enthalpy of formation ( Hof) and enthalpy of atomization ( Hoat)
Define first law of thermodynamics. How it is represented?
Differentiate between internal energy and enthalpy.
Explain that burning of a candle is spontaneous process.
What is the physical significance of equation, H = qp?
Draw labeled diagram of bomb calorimeter.
Define Hesss law of constant heat summation with one example.
Spontaneous reaction always proceeds in the forward direction. Give reason.

Chapter 1:
1.

Glucose C6 H12 O6 is the most important nutrient in the cell for generating chemical potential energy. Calculate
the mass% of each element in glucose and determine the number of C,H and O atoms in 10.5g go the sample.
2.
A mixture of two liquids, hydrazine N2H4 and N2 O4 are used as a fuel in rockets. They produce N2 and water
vapors. How many grams of N2 gas will be formed by reacting 100g of N2 O4 and 200g g of N2 O4.
3.
Calculate the number of grams of A12 S3 which can be prepared by the reaction of 20 g of A1 and 30 g of sulphur.
How much the non-limiting reaction is in excess?
4. Mg metal react with HC solution (27% by weight) required to produce 12. 1g of H2. The density of HC solution
1.14g/cm3.
Mg(s) + 2HC (aq) Mg C2 (aq) +H2(g)
Chapter 4:
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Define and explain London dispersion forces. What are the factors which affect London forces? Discuss briefly.
What are covalent solids? Discuss the structure of Diamond.
Define Vapour pressure. Describe manometric method for the measurement of vapour pressure.
Define metallic bond. Justify the electrical conductivity, thermal conductivity and shining surfaces of metals.

Chapter 3:
1. State Grahams law. Explain Grahams law of diffusion according to kinetic equation.
2. Describe postulates of kinetic molecular theory of gases.
3. Describe Daltons law of partial pressure. Write its all applications.
4. State and explain Grahams law of diffusion of gases.
Chapter 5:
1. Explain Millikans oil drop experiment to determine charge of the electron.
2. Derive radius of revolving electron in nth orbit of an atom.
3. (i) Write three points of Plancks quantum theory.
(ii)
Define frequency and wavelength.
4. Write down the defects in Bohrs atomic mode.
5. Derive the formula of calculating the energy of an electron in nth orbit of H atom using Bohrs model.
Chapter 6
1. What is dipole moment? Give its units. Explain the structure of CO2 FB3 and H2O on the basis of dipole moment.
2. Define hybridization. Explain the Sp2,Sp3,Sp with their examples
3. How will you describe the paramagnetic character of oxygen on the basis of MOT?
4. Write the postulate of VSEPR theory and discuss the structure of NH3 with reference to this theory.
Chapter 7
State first law of thermodynamics. How does it explain that qp = H
Discuss first law of thermodynamic and prove that E = qv
How does Born Haber cycle help to calculate lattice energy of NaCl?
Define the following giving one example in each:
a. (i)
enthalpy of solution
(ii)
Enthalpy of atomization
b. (iii)
System
(iv)
Surroundings
5. Write a note on construction and working of bomb calorimeter.
6. Define the following:
(i)
Standard Enthalpy of neutralization with example.
(ii)
Standard enthalpy of combustion with example.
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