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Various materials have been employed in the past for the protection against the ballistics with only
limited satisfaction without realizing the underlying mechanism of ballistic impact. With the advent of
high performance materials and computing techniques in the recent years, the mechanism of ballistic
penetration has clearly been established, paving a path for the selection of newer materials for better
protection and satisfying the requirements of both the wearer and the technologist. This review attempts
to coalesce the ideas of exuberant research that has gone into the field of ballistic protection right from
material selection to modelling with emphasis on evaluation methods and mechanism.
Keywords: Armour, Ballistics, Ceramics, Kevlar, Penetration mechanism, Projectile velocity, Soft
composites, Spider silk, Ultra-high modulus polyethylene fibre
1 Introduction
Ballistic protection is a class of protective
clothing which aims at protecting the individuals
from the bullets and steel fragments from handheld weapons and exploding munitions. The use of
armour to protect the personnel has a long history
and dates back to time immemorial. As the man
developed newer weapons with time, he also
looked for better clothing for protection. The list of
armour materials has included every conceivable
material '5 including the traditional materials like
aluminium, steel and less traditional ones like
leather and silk. The best known method of
protecting the human body in old days from all
kinds of missiles, was to use a hard rigid material
which resisted the penetration and dissipated the
load of impact6 " With the advent of synthetic
textiles, better ballistic protective systems have
been developed. Although the basic idea of
spreading the load over a large area is still applied,
it is better to dissipate the energy of impact by
deformation and breaking the protective material.
Nylon, which has high work of rupture
(toughness), was thought to be ideal for ballistic
protection. However, it became very clear that
simple toughness is not the only criterion for
ballistic protection. Then came the use of aramids
due to the fact that ballistic protection process is a
complex phenomenon involving the transverse
2 Ballistic Requirements
The basic objective of the body armour research
is to manage the conflicting goals of producing loweost, light-weight yet comfortable ballistic
protection systems with superior performance.
No armour design is suitable for all the situations8
and the armour system produced for a specific
application should be able to fit in both user's and
275
..
v;
3 Material Selection
No armour design is suitable for all the situations
and the performance of the protective system
depends on the interaction of its various
components. Hence, it is important to understand the
mechanism of the ballistic protection by which
10
15
Strain (01.)
20
276
22
0,
VI
:l.
.
!:!
~
'\
10
-.
co 0
..
..
i ~ __ _
Kevlar
18
c .c
o ,.,
~
20
'\ -P OLYAMIOE66
0-
",0
Entry holt
'- - -- --t~
16
Distancfl
- , ~ARAMID
,
"2
,
4
14
a.
01
III
III
c:.I
12
.... 10
~
If)
8
6
4
3.1.2 Aramids
Strain ( 0'0)
Fig. 3-Stress-strain behaviour of various high perfonnance
fibres and steel wire 20
277
Density
gcm-J
Strength
gpd (G Pa)
Elongation
%
Modulus"
gpd (G Pa)
Maximum use
temp.
C
Wave ve locitl
ms-I
Aramids
Kev lar 29
Kevl ar 49
Kev lar 11 9
Kevl ar 129
Kevlar 149
Nomex
Technora
Ekonol
Vectran
IA3
I A5
1.44
IA5
IA7
138
1.39
IA
1.47
23 (2.9)
23 (2.9)
24 (3. 1)
26.5 (3.4)
18 (2.3)
5 (0.6)
27 (3.3)
31 (3.8)
25 (3 .2)
3.6
2.8
550 (70)
950( 135)
430 (55)
780 (99)
1100 ( 143)
140 ( 17)
570 (70)
1100 ( 136)
700 (9 1)
250
250
250
250
250
250
250
150
150
6996
9649
6 180
8263
9863
3509
7096
9856
7868
UHMPE
Spectra 900
Spectra 1000
0.97
0.97
30 (2 .6)
35 (3 .0)
1400 ( 120)
2000 ( 171 )
100
100
11123
13277
1940 (308)
500
13081
4A
3.3
1.5
22
4.3
2.6
3.5
2.7
Carbon fibres
Thomel
P55 (Med M)
Thomel
'PIOO (HM)
Celion
3000 (HS)
1.8
10.8 (1.7)
1.96
10.8 ( 1.86)
0.38
3300 (5 17)
600
16241
1. 8
25 (4.0)
1.8
1440 (230)
500
11 304
Ceramics
Boron
SiC
Alumina
Nextcl
E-glass
S-glass
2.5
2.8
3.25
2.5
2.55
11 .6 (2.55)
16(4.0)
6.3 ( 1.8)
7.8 (1.72)
11 .6 (2.6)
21.9 (4.8)
1.0
0.6
1. 2
2
3
5.3
1800 (400)
1700 (420)
730 (2 10)
690(152)
320 (72)
390 (85)
2000
1300
1200
1200
350
300
12649
12247
8038
7797
5313
5854
2A8
modulus
density
20r-------------------------~
16
~
1/1
~Kevlar
.
0
C\I
.D
0
....
...
WE
12
100 year
1 year
.!Io
01
0
-J
o <----I---'__..&..---'----'__-'----'----'__..&....::::.
o
0.2
0.4
0.6
0.8
1.0
Fraction of normal breaking load
278
Alp)
Alp)
B,C
Glass
BeO
MgO
Density
g/cm)
HEL
GPa
39[
3.92
2.50
2.48
2.84
3.57
I 1.2
9.2
15 .0
7.3
85
8.9
Q.
U\
---
VI
~orpt, on
."
~
U\ -
3.1.5 Ceramics
"
'" 20
:::
z
Cor bon
II : : r----1---/-/-"_-,~-~-~ -:-u-.~-,--"'O: I
~- ~~
040
c{
0.20
U/, -'---
0___ -_-----/
~ Kev lor
----_---
p-Arom id
U\
U\
~ 10
<f1
0.3
0 .2
0 1
p-Aromid
0 10
Carbon
0.20
O L----------------~
279
inherent brittleness and lack of flexural strength of ballistic response of fabric s appears to be closely
ceramics renders them incapable of being used related to the ballistic response of the single yams.
alone as single material for the fabrication of the
In woven fabric s, since there is an extensive
armour.
interaction among the yams due to interlacements, it
was found that transverse deflection causes loading
of the crossover yams and up to 50% of the total
3.2 Influence of Yarn Structure on Ballistic Protection
energy
absorption may occur in the secondary yams.
Friction plays an important role in the ballistic
Therefore,
fabric construction particulars have a
protection, which, in tum, depends on the method of
yam production. Many of the fibres commonly used major role in the final ballistic protection 16.26. For
for ballistic protection are highly drawn, hence the instance, if the weave is too tight or the fabric is too
fibre surface is smooth which means that in the stiff, deflection will be restricted, causing shear
event of an impact by any object there is a tendency failure due to the concentration of stress at the
for the yams to slip apart simply because of their impact point. Whereas too loose a weave or a soft
low coefficient of friction, e.g. UHMPE is highly fabric having low yam-to-yam friction would allow
drawn up to draw ratios of 20-30 with very low the projectile to penetrate easily by pushing the
coefficient of friction. Therefore, efforts have been yams aside or giving too much deflection which can
put to roughen the fibre surface by chemical or cause serious injuries or trauma to the wearer.
Therefore, it is the balanced force distribution
mechanical means to overcome this problem.
with
maximum interlacements in a given unit area
Coating the surface of fibre is another slow and
which
makes plain weave construction most suitable
painstaking method. However, current practice is to
3
use corona treatmenf /plasma etching for surface for the ballistic protection. Various other weaves
like basket, satin, crowfeet, etc., though inferior to
treatment.
plain
weave, are employed depending on specific
Such high friction fibres comprise a minimum in
the total structure and should only be 10-20% by application.
weight. H6genboom 24 proposed that filaments with
high coefficient of friction should be combined with
fibres having high tensile strength and modulus and
low coefficient of friction. The two types of fibres
may even be twisted or core spun together as a yam.
It is also suggested that very thick high performance
components may be combined with very thin high
friction elements, leading to improvement in the
performance.
For polyethylene ballistic-resistant fabric, Harpell
et al. 15 suggested that the yam with a denier of not
more than 500 and a tensile modulus of atleast 200
gpd can be used.
It was also observed that the fabrics made from
fine aramid yams9 of 220-440 dtex perform better
than those made from the coarser yams. But due to
high costs of the finer yams, usually 1,100 dtex is
used.
Weinberg and Schwartz25 reported that a twist
level above 1 turn/cm for Kevlar yams lowers the
modulus and strength. A twist factor of 1.1 is found
to be suitable for Kevlar yams 20 .
3.3 Fabric Design for Ballistic Protection
280
Yam size
Denier
Decitex
1000
1500
1500
1420
1500
1500
3000
3000
3000
840
840
1110
1670
1670
1580
1670
1670
3330
3330
3330
935
935
Weave
Ends/cmx Picks/em
Wt of fabric
g/m2
Plain
Plain
Plain
Plain
2x2 basket
8x8 basket
Plain
4x4 basket
4x4 basket
Plain
Plain
12.2x I2.2
9.4x9.4
6.7x6.7
6.7x6.7
13 .8x 13.4
18.9x 18.9
6.7x6.7
7.9x7.9
9.4x9.4
12.2x 12.2
12.2x I2 .2
282
326
231
231
475
669
475
550
672
231
231
Needle-punched nonwovens are useful in the finishes to the ballistic protective garment which
ballistic applications. For ideal ballistic protection, would increase the cohesion between the warp and
the nonwoven felt has to have a high level of the weft yams.
Lamination of the fabric has been found to
entanglements of long staple fibres with only a
minimum degree of needling, as excessive needling increase the anchoring strength of the yam by a
can produce too much of fibre alignment which factor of about 10-15. As a consequence, the yams
would aid projectile penetration. Considerable care, hit by bullet do not pull from the fabric. Another
therefore, should be taken to optimize the feit positive aspect of the coating is that the yams
movement IS impeded in their sideward
structure.
displacement by piercing projectiles. Kevlar coated
Felts of lower weights are probably the most
with neoprene chlorosulphonated polymer elastomer
effective materials known for ballistic protection .
The effectiveness decreases as the weight increases is resistant to acids, fire , toxic gases and steam and
impermeable seaj28.
and the nonwovens are overtaken by woven tex- is able to form an
29
Temmerman
used
electroless
metallized
tiles and ultimately by ceramics and metals at
materials to coat a layer on the fabrics which
higher projectile velocities.
improved lightning strike protection.
Ward 30 found that for UHMPE, oxygen plasma
3.4 Finishes for Ballistic Protection
It is interesting to note that the performance of treatment reduced the delamination during impact
garments for ballistic protection is influenced with a corresponding reduction In energy
significantly with the moisture content, weaving absorption.
oils, sizes and other lubricants present in addition to
Aramid fabrics coated with heat-resistant fluoro
the fabric weave and other weaving parameters. polymers showed improved sp'uttering resistance for
This is due to the fact that the interfacial behaviour steel mill workers. The film is fonned at an angle of
of the yams is altered, so is the yam mobility in the 0-200. The composite fabric of m-aramid, p-aramid
fabric, due to the presence of moisture or weaving and fire-resistant rayon was impregnated with a
fluoroolefin-vinyl ether copolymer, squeezed and
oils.
Ballistic protective gannents are therefore made treated at 110-160 c for 8 min to give good
hydrophobic 9 . About 40% reduction in the ballistic sputtering resistance 3 '.
protection has been observed when the bulletproof
Nonwoven felts manufactured from linear
garment is made wet without any change in the polyethylene,2 modified by corona/plasma treatment
properties of the component yams 8.9 . This suggests or with a filler by folding the web of the carded
that water acts as a lubricant between the projectile fibres in zigzag direction, calendering, stretching in
and the fabric.
transverse direction, stitching or hydroentangling,
Scouring of the fabrics is therefore necessary to gave high impact resistance than conventional
remove the size, oils, etc. in addition to the anti-slip textiles,
281
282
283
5 Performance Evaluation
For quantitative assessment of the performance of
the ballistic protective clothing, two .fundamental
quantities, viz. ballistic protection and weight
efficiency, are always considered50 .
284
(Vst_V;~I/ ~
285
Wt of
projectile
Type of projectile
Velocity
ms"
2.6
320 12
10.2
381 15
11 A
18
11
IlIA
15.55
8
III
IV
(0)
332 15
425 15
358 15
838
425
223 Remington
(556 mmV'MJ)
0.3 carbine FMJ
12 gauge rifle slug
10.8
868
C=(E/p) v.
where C = Speed of the sound or longitudinal wave
velocity, E = Initial modulus, and p = Density.
The wave reaches the end of the fibre and is
reflected back as a tensile wave. This reflection of
the tensile wave is necessary so as to satisfY the
(c)
286
1/ 2
287
speed.
Elastic waves may be reflected or transmitted
according to the following :
It)
2 -- x Po
PI = ( 11+ 10
Pr=[II - Io] x p o
II + 10
where
PI = Stress amplitude of transmitted wave,
Po = Stress amplitude of incident wave,
P, = Stress amplitude of reflected wave,
II = Impedence of transmitted material, and
1'1 = Impedence of incident material.
It should be noted carefully that the waves
created by the ballistic impact are nearly elastic and
transmission of these waves to resin matrix
increases the energy absorption capability of the
laminate. Cracks are formed in the matrix and
propagate parallel to the fabric layers, through
delamination process 53 . Impact energy is dissipated
in the formation and advancement of these cracks
and in the deflection caused by the separation of
individual fabric layers.
Zee et al. 51 used helium air gun, microvelocity
sensor and PE and graphite composites with
individual fabrics woven in plain, bound together
with epoxy resin of 10 layers each, to demonstrate
the failure mechanis.m. Fig. 10 shows the behaviour
of PE composites of 10,20 and 30 layers. Velocity
measurements were made at 12 different positions
with the help of microvelocity sensor in such a way
that initial ballistic contact occurs at the 3rd position
with three measurements of incident velocity prior
to impact.
The energy loss for all the samples (Fig. 10)
started from position 3 only signifies that PE
composites do not flex but behave as a rigid system,
leading to fracture of fibres and matrix. It is
interesting to note that the slope of the energy
profile is proportional to the energy dissipation
density and the rate of energy loss in a 10-layer
composite is lesser than that in thicker composites
because of the reinforcing effect.
However, the graphite composite shows a typical
brittle failure with the energy loss observed exactly
at the point of impact and energy loss peak in less
than 2.5 mm distance (Fig. 11).
In a numerical model developed by Leech and
::; 5
oL-_ _
_ _ _L -_ _
_ _ _~_~
o
Poaftion tNn)
O~--~---~---7---7.--~
Poaition(",,,, )
288
St age II
Stage 1
Stage
Stage I'l
S tage V.
P=L.{P;
fp;
where
289
290
13
14
15
16
17
18
19
291