Beruflich Dokumente
Kultur Dokumente
Department of Chemistry
University of Hong Kong
Sept 2003
catalyst( s)
O2 ( g ) 4e
2H 2 O(l ) 4OH
The geometry of the three-phase boundary is a line and has a limited capacity for
reaction. In reality, gas molecules can dissolve at the gas-liquid interface and
diffusion to the liquid-solid interface for reaction. To reduce the diffusion path and
maximize the gas-liquid interface area, a thinly wetted layer is desirable. In
addition to the supply of gas, a connected conducting solid phase is required to carry
the electrons to or away from the reaction site.
The electrode may be composed of multiple layers. A reactive carbon layer with
catalyst supported in active carbon, was pasted in a current collector, nickel foam. The
hydrophobic film (Teflon layer) is on the outside surface which becomes the air side as shown
in figure below.
Teflon Layer
Air Side
Reaction layer:
(3 phase boundary)
Catalyst on carbon support inside
a nickel foam
III. Catalyst
The air cathode catalysts for oxygen reduction are highly active, non precious electro-catalysts,
such as metals, metal oxides and pyrolyzed metal chelates, supported on high surface area
carbons. To obtain the maximum performance, different catalysts are employed in different
chemical systems, e.g. different pH. Common catalysts include Manganese(KMnO4),
Silver(AgNO3), Cobalt Spinel, CoTMPP , Pt, La0.6Ca0.4CoO3.
Below are polarization curves of air cathodes with different catalysts.
If used in an aluminum-air cell with 12% NaCl electrolyte, using aluminum foil as negative
electrode, a cell generates 1.07 volts at a current density of 30mA/cm2
IV Experiment
An air cathode designed for use in alkaline or saline electrolytes for metal-air/fuel cells will be
prepared and tested in an aluminium-air cell.
Characteristics of the gas diffusion electrode:
Typical Thickness:
Average Weight:
Safety:
1.5mm
900 grams per square meter (typical)
Does not contain mercury, cadmium, lead, lithium, or other dangerous
materials.
Physical Description:
A 2-layer laminate consisting of (a) A current collector of nickel foam
with reactive carbon paste (b) A micro-porous PTFE film on the air
side.
The air cathode is mechanically robust and chemically resistant to a wide range of substances.
Instruments/Chemicals
1.
2.
3.
4.
5.
6.
7.
Procedure
(1) -----Paste Preparation (20% KMnO4)
Weigh 0.95g of active carbon (XC-72), 0.2g of KMnO4 add together with 10 mL of DI H2O, 5mL 95%
ethanol, 10 drops of 5% PVA solution, 5 drops of 1/:3 PTFE suspension, to a plastic Petri dish and
stir with a glass rod for several minutes until the slurry become paste like.
Use a brush or stick to apply the well-mixed paste into the pre-cut nickel foam (4X4cm2 with a lead
tab) until both sides are covered with the black paste. Dry in the 100~2000C oven for about 5-8
minutes. Use the sprayer to spray PTFE emulsion(30% in H2O) to ONE SIDE of the electrode until it is
wet, dry in the 100~2000C oven for 10 minutes.
(3) ----- Assembly of aluminum-air fuel cell and test air cathodes performance
Use scissors to cut 4X4cm2 aluminum foil (with a protruding lead tab) and place on a shallow Petri
dish, then cover with a pre-cut PP separator (6X6 cm2)or a filter paper, finally place your air
cathode on top of the separator, Teflon side up, (to make a sandwich like fuel cell), pour about
5mL 25% NaCL solution onto it (the electrolyte should flood half of the air cathode but NOT to
flood the Teflon side. Finally connect each terminal to the motor fan(or a LED ) with a voltmeter,
the fan will start turning , record the voltage change against time.
***Note:
In order to avoid electrical short-circuit between cathode and anode, the area of air cathode
must be less than the area of separator.
Air cathode
separator
Al foil
Assembly of an
Aluminum-Air
Fuel Cell
Voltmeter
DC motor
with fan
Voltage
-
Al + 4 OH > Al(OH)4 + 3e
-2.35
-
0.40
1.3
1.2
1.1
A graph showing
the effect of
catalyst loading to
the performance of
air cathode.
Cell Voltage(V)
1.0
0.9
0.8
0.7
20%
10%
5%
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0
10
15
20
25
30
35
40
Time(min) of discharge
Time
Time elapsed
Cell voltage
remark
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