Beruflich Dokumente
Kultur Dokumente
4 QUESTIONS PART 2 MS
1.
(a)
(b)
(c)
Homogeneous
(i)
(ii)
(iii)
Equation 1
2Fe
3+
+ 2I I2 + 2Fe
Equation 2
2Fe
2+
(i)
(ii)
2+
(1)
3+
(1)
Identity of metal 1
W (1)
Identity of metal 2
Ag (1)
Ease of adsorption (not too weak) and desorption (not too strong)
balance out (1)
5
(d)
Catalyst
Pt or Rh or Pt/Rh (1)
Identity of reductant
CO (1)
Equation
3
[14]
2.
(a)
(b)
(i)
(ii)
Mn or Mn
Self-catalysing not allowed
(i)
(c)
2+
3+
Reducing agent CO
(ii)
(d)
Pt, Pd or Rh
(i)
(ii)
[10]
3.
(i) Increase the rate of the forward and backwards reactions (1)
by an equal amount (1)
(ii)
Equation
Catalyst
N2 + 3H2
Iron (1)
4.
(a)
(i)
or Fe + 2H Fe
(ii)
2+
+ H2
= 4.53 10 (mol)
(answer must have at least 3 sig. figs. Ignore units)
(iii)
1
1
(iv)
2+
3+
(i)
Fe Fe + e (ignore state symbols)
2
+
3+
Cr2O7 + 14H + 6e 2Cr + 7H2O
2
2+
2Cr
3+
+ 7H2O + 6Fe
1
1
3+
2+
= 4.53 10 /6 = 7.55 10
Volume of dichromate = moles/concentration
(mark is for this method)
4
(= (7.55 10 1000)/0.0200)
3
V = 37.75 (cm )
(allow 37.7 to 37.8, allow no units but penalise wrong units)
(allow conseq on moles of dichromate)
1
1
(KMnO4) will also oxidise (or react with) Cl (or chloride or HCl)
1
[14]
5.
(a)
(or KOH) 1
(ii)
(iii)
(i) NaOH
+6
(or 6 or +VI or VI)
H2O2
(orNa2O2 or BaO2)
3
1
+
(c)
[Cr(H2O)6]
2+
Reducing agent
(mark independently)
(i)
(ii)
1
[8]
6.
(a)
(b)
(i)
Orange
(ii)
Red-violet/ruby/violet/ green
(ii)
Purple
(i)
MnO 4 /Mn
(ii)
2+
1
1
1
1
[7]
7.
(a)
Metal 1
Explanation
Metal 2
Ag, or Au (1)
Explanation
(i)
E s te r if ic a tio n
(ii)
H 2 S O 4 /a c id
I+ S 2O
Fe
2+
/F e
8
3+
SO
+ O
N O
d e c o m p o s itio n (1 )
C l
(1 )
4
[10]
8.
(a)
(b)
V2O5 (1)
1
SO2 + 2 O2 SO3 (1)
(c)
(d)
(i)
(ii)
(iii)
H2O2 (1)
NaOH (1)
K M n O 4 [ 1 ] d il H 2 S O
K 2C r2O 7
O 2 , a ir
[1 ]
C l2
[2 ]
K 2S 2O or
H 2O 2
[2 ]
6
[12]
9.
(a)
(i)
(ii)
(iii)
C 2 O 24 /MnO 4
OR
Fe /Fe
3+
Mn
2+
or
Co /Co
3+
(1)
(i)
(ii)
Penalise absorption
Reaction/equivalent (on surface) (1)
Allow correct statement e.g. bonds weakened, conc. increased
(Products) desorbed (from surface) (1)
Steps must be in the correct order
(c)
Not Fe
2+
or Fe
3+
(i)
Iron
(ii)
(1)
3
[12]
10.
(a)
1 C r
(ii)
(i)
3+
+ 8 O H
1 C rO
2
4
+ 4 H 2O + 3 e
(b)
+ 2H Cr2O7
(i)
2CrO4
(ii)
yellow (1)
orange (1)
1
2
11.
2+
2Cr
3+
+ 7H2O + 6Fe
3+
(2)
2+
+ 7H2O + 4Zn
2+
(2)
9
[9]
12.
(a)
(b)
(c)
(i)
(ii)
3
[6]
13.
(a)
(i)
(ii)
(iii)
+1 (1)
4 (1)
(iv)
(b)
+ H
(i)
or C6H10 + H2 C6H12
(ii)
(iii)
Reagent(s)
Observation(s)
no change (1)
4
[11]
14.
(a)
(b)
(c)
(i)
(d)
Meausre 1
Meausre 2
6
2
[12]
15.
(a)
(b)
Fe
2+
MnO4 + 8
5 Fe
(c)
3+
+e (1)
H+
5e Mn
Fe
2+
2+
+ 4H2O (1)
+ MnO 4 + 8H 5 Fe
3+
+ Mn
2+
= 5 5 10
2+
+ 4H2O (1)
= 5 10
3
4
(1)
3
= 25 10 (1)
Mr compound
3
= 392
(1)
= 098g
(1)
4
[9]
16.
(a)
2+
3+
(i)
[Cu(H2O)6 ] (1)
(ii)
[Cr(H2O)6 ] (1)
(b)
MO4 (1)
(i)
(c)
(ii)
Cr2O7 (1)
(i)
max 5
(ii)
2+
2
6
(i)
(ii)
2
[14]
17.
(a)
(b)
(c)
3+
2 Fe
2+
2+
if Fe
(d)
(i)
2
4
2+
(aq) (1)
(aq) + 2 Fe
3+
3+
(aq) (1)
(ii)
2NH3 (g)
5
[12]
18.
(a)
2+
+ S2O8 2Fe
2Fe
3+
+ 2I 2Fe
2+
3+
+ 2SO4 (1)
+ I2 (1)
6
[6]
19.
(a)
(i)
2+
2+
is catalyst (1)
3+
+ 2I
2Fe
2+
+ I2 (1)
}
}
}
}
2+
10
27.5 0.02
4
1000
moles MnO4 =
= 5.5 10
(1)
5
4
moles Mo = 3 5.5 10
(1)
wrong ratio = max 2 (marks 1 & 3)
5
4
g Mo = 96 3 5.5 10
(1)
96 5 5.5 10 4
10 2
3
0
.
33
% Mo =
(1)
= 26.7 (1)
26.6 if Mo = 95.9 used
5
[15]
20.
(a)
effect on reaction rate: catalyst provides an alternative reaction route.; 1
with a lower Ea;
1
more molecules able to react or rate increased; 1
equilibrium:
(b)
active site:
1
1
reasons:
1
1
lead adsorbed;
lead not desorbed or site blocked;
(lead adsorbed irreversibly scores both of these marks)
(c)
catalyst poison:
1
1
2Fe
2+
+ S2O8 2Fe
2Fe
3+
+2I
2Fe
3+
2+
+ 2SO4
+ I2
Species;
Balanced;
1
1
Species ;
Balanced;
1
1
[17]
21.
(a)
(b)
(i)
Heterogeneous:Catalyst:-
(ii)
Feature:- QoL
Equations
2+
2+
+ 2e (given)
VO2 + 4H + 3e V
Zn Zn
+
2+
+ 2V
2+
2
4
5V
2+
+ 5VO2 (2)
6
[15]
10
22.
Iron
Heterogeneous; catalyst in a different phase from that of the reactants
1
1
1
1
1
[5]
23.
(a)
Then Mn
2+
3+
2+
3+
MnO4 + 4Mn
(b)
+ 8H 5Mn
3+
2+
+ 8H2O + 4CO2
+ 4H2O
2+
1
1
Active sites are where reactants are adsorbed onto a catalyst surface
(or bind or react on a catalyst surface)
(do not allow absorbed)
[10]
11
24.
(a)
reactants brought together / increased concentration on surface
or increased collision frequency (1)
reactants must be correctly orientated (1)
reaction on the surface (1)
products desorbed (1)
example of a catalysed reaction (not a named process) (1)
a suitable catalyst for this reaction (1)
penalise incorrect second reactions and catalysts
max 8
Equations:
2
2+
Cr2O7 +14 H + 6 Fe 6 Fe
Zn + 2 Fe
3+
Zn
2+
+2 Fe
2+
3+
+ 2 Cr
3+
+ 7 H2O (1)
(1)
Method
Titrate measured volume solution against K2Cr2O7 (1)
Reduce same volume solution with zinc (1)
Filter off excess zinc (1)
Titrate total Fe
Percentage Fe
n+
3+
7
[15]
25.
2+
3+
3+
2+
24.0 0.1
3
= 1000 (1) = 2.4 10
2
O7
moles Cr2
2.4 10 3
3
6
=
(1) = 0.4 10
3
0.101 0.122
= 252 : 53.5 (1)
or 4 10
12
26.
(a)
Plan 5 marks
known mass or weight (1)
H2O (1)
dil H2SO4 (1) (scores 2 if no H2O previously)
titrate or Cr2O72 in burette (1)
indicator needed (1)
n
Calc 3 marks
2+
2
+
3+
3+
6 Fe + Cr2O7 + 14H 6Fe + 2Cr + 7H2O (1)
2
2+
= 6 moles (1)
2
Cr2O7
2+
2+
(i)
(ii)
1
2
or in words
O2 V2O5 (1)
2+
Mn
catalyst (1)
none or little present initially slow or 2 negative ions reacting (1)
more as reaction proceeds faster (1)
autocatalysis (1)
or explanation of
Max 7
[15]
13
27.
(a)
Ag or Au or Sc adsorb too weakly (1)
A consequence of weak adsorption
reactants not brought together on the surface
no increase in reactant concentration on surface
bonds not weakened
correct orientation on surface not achieved (1)
W, Zr, Nb, Mo, Hf or Ta adsorb too strongly (1)
A consequence of strong adsorption
products not desorbed
active sites blocked
reactants unable to move on catalyst surface (1)
(b)
(c)
(d)
Max 4
3
[15]
14
28.
(a)
(i)
2+
or Cr
2+
3+
(1)
(b)
(i)
(1)
10
same phase (1) speeds rate (1) new route (1) of lower AE (1)
unchanged at end (1)
n
example: Fe /Fe
3+
in S2O
2
8
/I rn (1) or
Mn 2+ in MnO 4 /C2O 4
mechanism: 2Fe
Fe
2+
3+
+ I Fe
or Mn
Mn
3+
+Mn
(ii)
2+
Mn
3+ or
MnO 4 oxidises
+ I2 or in words (1)
3+
+ C2O 4 CO2
2+
2+
(1)
(i)
(ii)
2+
catalyses (1)
12
2+
25 02
4
= 1000 = 5 10 (1)
= 5 5 10
(1) (25 10 )
= 83 25 10 (1)
(1)
% VO2
83 2 5 10 3
03
=
100 (1)
= 692 (1)
8
[30]
15