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212 F = a 100 C + b
32 F = 0 + b
F
b = 32 F, a = 1.8 C
If = :
= a + b,
b
so = = - a - 1 = - 40 C = - 40 F
If = 2:
.........
2 = a + b
b
so = 2 - a = 160 C = 320 F.
Thermal Physics
Thermodynamics: laws relating macroscopic variables (P, V,
T etc.).
Statistical Mechanics: molecular explanation.
Difference between heat and temperature
Intensive or extensive properties?
Which relates to sense of hotness?
Define temperature:
Thermal equilibrium:
Thermal properties do not change with time
Definition of Temperature (T):
T is equal in any 2 bodies at thermal equilibrium.
Zero th Law of Thermodynamics:
if TA = TB and TB = TC, then TA = TC.
What is temperature? How to measure it?
Thermometers: Hg in glass, thermocouple, thermistor, liquid
crystal layer, constant volume gas thermometer
Scales. Obvious definition of temperature : choose a property X
and make X proportional to or linear with . This can only
be done once for any temp scale .
Reference temperature
Melting or freezing? Depends on the pressure.
Thermal Expansion
T
T + T
L
L
Usually, L T for small T
Define
L
L = T
e.g.
Al
Volume Increase
define
V
V = T
V = (L + L) - L
3
L 3 3
= L 1 +
-L
L
L
L + L
3
3 L
= L 1 +
+ . . . . . . . . . - 1
L
V 3T
3
Note:
V
M
V = - V
2
V
V
= - V = - = .... = - 0.33%
t
R
L + Lst = 2R . 360
subtract
= 3.4 C
~
e.g. oven switch:
Example: thermometer, Volcylinder << Volsphere
x
What is its calibration slope T ?
a
x
V
V T
a x Vfl - Vsphere
= f1 VT - g1 VT
x
V
=
T
a ( f1 - g l)
s
same limit
tr
lim P
T = Ttr.
tr0 Ptr V
where Ttr = 273.16 K
Why 273.16? This defines the Kelvin so that
T = 1 K
T = 1 C
(Working defn. is more complicated)
at PA
Farenheit Scale
Heat
Definition: that which is transferred between a system and its
surroundings as result of T only.
Joule showed:
mechanical energy heat
t showed
(Cheata ratn ohigh
T heat at low T + work)
Q
Heat Capacity: (for a body) C =
T
Specific Heat: (of a substance) c =
-1
5
extensive quantity
Q
intensive quantity
M
-1
-1
-1
dW = F.ds = PA ds = PdV
Internal Energy
Heat dQ added to a system increases its internal energy U.
Work dW done by the system lowers its internal energy.
1st Law
dU = dQ - dW
where U is a state function
Digression
V
Vo
T
P
P
V = V o 1 + ( T - T o )
B
Volumetric coefficient
1 V
of thermal expansion V T P
1
1 V
B V P T
Bulk modulus
Tut prob 3:
Lo
L therm
Th
Tc
m
Tc
L stress
L
stress
force/area
strain L modulus
Y
o
Phase diagram in one dimension:
L therm L stress
L = Lo 1 +
Lo +
Lo
mg
= Lo 1 + (T - T o ) + AY
Heat conduction
A
TH
TC
T T
H kA H l C
defines the thermal conductivity k
H in W, so
Copper
Stainless Steel
Glass
Water
Pine (wood)
Dry air
k in W.m-1.K-1.
401
W.m-1.K-1
14
1
0.5
0.11
0.026
so
T
H = AR
Th
A
P
l
R k = 0.09 K.m2W-1
T T
T
H kA H l C
or = A
R
lH
T H TC = kA
0.010 m * 300 W
=
0.11 W.m -1 .K -1 * 8 m 2
= 3 K.
Other benefits: wind, rain, radiation
What if he has a friend?
2 students at 300 W 600 W 7 K.
Example. To reduce thermal noise, a low temperature circuit is
immersed in liquid nitrogen (77 K, L = 199 kJ.kg-1). It is
connected to the outside circuitry by 3 well-insulated copper wires,
length l = 100 mm, diameter 0.3 mm. What is the rate of N2
evaporation due to the heat conducted down the wires?
insulator
nitrogen
T T
H kA H l C
dm
kA T H T C
=
dt
L
l
= .....
= 90 gs-1 = 340 mg.hr-1
dT
kA T T C
=
dt
mc
L
T
T0
T
mcL
Characteristic time: = kA Solve DE
T = TC + (To TC) et/
81 C = 20 C + (70 C)e(1 h)/
= 7.3 h
no. of molecules
gas constant
Boltzmann's Constant
R
R = 8.31 JK-1
k=
= 1.38 10-23 JK -1
NA
NB not the same k and R as in heat conduction!
vi)
(~ 10-3 of time)
Each collision
momentum = 2mvx
t = 2L/vx.
momentum
2mv
mvx2
= 2L/vx =
L
x
time
F on all N molecules is
___
Nm v x2
Fall molecules =
= PA
L
v 2 = vx 2 + v y 2 + v z 2 ;
___ ___
___
___
___
1 2
2
2
2
2
random motion vx = v y = v z
vx = 3 v , so:
___
___
___
N
Nm 2
2
2
=
P = 3V v
PAL = PV = Nm v x
3mv
Molecular speeds:
vrms root mean square velocity
___
vr.m.s. v2
F =
3P
=
3 x 10 5
= 480 ms-1
1.3
Meaning of temperature:
We had
___
N
PV = 3 m v2
both sides are familiar
___ _
1
m v2 = average K.E. per molecule
2
But T defined by (1 and 5): PV = NkT
___
_
3 PV
3
1
= 2 m v2 = 2 N = 2 kT (7)
For ideal gas all energy E is kinetic so:
_
3
E = N = 2 NkT
(8)
kT 4 10-21 J )
___
1
= 3 v2
10
vrms =
for O2 :
mol wt
m =
3kT
3kT N A
So what?
vs =
Kad
=
vrms
vs =
so
P
=
kT
m
~ 1.5
3kT
m
pollen 2 mm s-1
He
air
kT
m
= 1.1
v
vHe =
air
Hemair
airmHe
mair
He
fair =
c c
340 ms -1
= 4L 4 x 0.17 m = 500 Hz
fHe 1350 Hz
30
2.7
3
r3(air gas) 3r2 = 4 m
3m
r
4 air(1 gas/ air)
hot
T
273 K
= Tcold = 373 K
hot
cold
r 3.6 m
r 5.3 m
check approxn
11