IIT-JEE-MAIN-TEST-1-CHEMISTRY-FULL SYLLABUS

JEE-MAIN TEST-1
SUBJECT: CHEMISTRY

(SINGLE CHOICE OBJECTIVE)

MARKS : 90
TOPIC: FULL SYLLABUS
TIME: 60 MIN

1.

2.

The number of moles of a gas in 1 m3 volume at STP is

(a) 44.6
(b) 4.46
(c) 1.46

The oxidation states of sulphur in caros acid and Marshalls acid are
(a) +4,+6
(b) +6,+6
(c) +4,+4
(d) +6,+5

AlO-2
3.

Among KO2,

NO+2
,BaO2 and

unpaired electron (s) is/are present in

KO 2 and AlO 2

+
2

NO and BaO2
(a)

(b)

BaO 2 Only

KO 2 Only
(d)

(c)
4.

(d) 14.6

Prosthetic group is glycoprotein is

(a) Protein
(c) Fat

(b) Carbohydrate
(d) Nucleic acid

5.

The hybrid state of B-atom in BF3 is sp2 but in diborane (B2H6), it has sp3 hybird state
because
(a) B2H6 is less stable
(b) B2H6 is an electron deficient molecule
(c) Overlapping between s and p-orbitals of B and H forms a -bond
(d) One of the empty orbitals of boron takes part in hybridisation

6.

The correct sequence of molecules in increasing order of number of lone pairs of

electron
on central atom is
(a) H2O < NH3 < XeF2
(b) NH3 < H2O < XeF2
(c) XeF2 < H2O < NH3
(d) NH3 < XeF2 < H2O

ClO - , ClO -2 ,ClO3- and ClO -4

7.

The correct order of ClO bond lengths in

ClO ClO < ClO ClO

4

, is

(a)

ClO3- ClO-2 < ClO- ClO 4

(b)

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ClO-4 ClO3 = ClO 2 ClO

(c)

ClO- ClO-2 = ClO3 ClO4

(d)
8.

The first , second and third ionisation potentials (E 1, E2 and E3) for an element are 7
eV, 12.5 eV and 42.3 respectively. The most stable oxidation state of the element will
be
(a) +1
(b) +2
(c) +3
(d) All are equally stable

9.

A radioactive nucleide can decay simultaneously by two different processes through

which
the half lives are found to be t1 and t2 respectively . The mean half life of the
nucleide t is given by

t +t
t = 1 2
t1 t 2

t = t1 t 2
(a)

t=

(b)

t1 t 2
t1 + t 2

(c)

t=

1
2
t1 + t 2
2

(d)

10.

The ratio of volumes of atoms to the total volume available in a simple cubic lattice is
(a) 74%
(b) 66%
(c) 52%
(d) 22%

11.

The pre-exponential factor in the Arrhenius equation of a second order reaction has
the
units
(a) mol L-1 s-1 (b) L mol-1 s-1 (c) s-1
(d) dimensionless

12.

8 moles of a gas AB3 are introduced into a 1.0 dm3 vessel. On dissociation 2 moles of
A2 are
found to be present. The equilibrium constant of the reaction is
(a) 27 mol2 L-2 (b) 3 mol2 L-2 (c) 36 mol2 L-2
(d) 2 mol2 L-2

13.

If pKb for fluoride ion at 25C is 1

this
temperature is

10 83

6 8 10-2
(a)
14.

6 8 10-3
(b)

, the ionisation constant of hydrofluoric acid at

6 8 10-4
(c)

6 8 10-5
(d)

Silver nitrate solution is gradually added to an aqueous solution containing

equimolars
each
chloride, bromide or iodide ions. The correct order or precipitation of three ions will
be

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IIT-JEE-MAIN-TEST-1-CHEMISTRY-FULL SYLLABUS

Cl , Br , I

Br , I , Cl
(b)

(a)
15.

I , Br , Cl
(c)

I , Cl , Br
(d)

A binary solution contains x1 and x2 mole fraction of two components having vapour

p1
pressure

(a)

p2
and

p x1 p

in their pure states. The total pressure of the above solution is

(b)

p x1 p

p1 x1 p2

p2 x1 p2

(d)

(c)

SO 2-4
16.

The ionic conductance of Al3+ and

ions at infinite dilution are x and y ohm -1cm2
respectively. If Kohlraush law is valid, the molar conductance of aluminum sulphate at
infinite dilution will be
(a) 2x + 2y
(b) 3x + 3y
(c) 3x+2y
(d) 3y + 2x

Cl
17.

The equivalent ionic conductance of Na and

and

ions in 0.1 M NaCl and 45 ohm-1 cm2

Cl
-1

665 ohm cm respectively, at 298K. The transport number of

solution is

0 409

0 152

18.

0 848

0 591

(b)

(a)

ions in this

(c)

(d)

G andH for a reaction at 300 k are -66 kJ mol-1 and -42 kJ mol-1 respectively. G
for the same reaction at 330 K will be

68 4 kJ mol1

68 4 kJ mol1

(a)

(b)

69 4 kJ mol

69 4 kJ mol 1

(c)

(d)

19.

KMnO4/H+
CH3 CH COOH
OH
X and Y are respectively
(a) Oxalic acid , acetic acid

FeSO4 +
alkaline H2O2

(Fenton's regent)

X
Y

(b) Acetic acid, oxalic acid

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IIT-JEE-MAIN-TEST-1-CHEMISTRY-FULL SYLLABUS
(c) Pyruvic acid, acetic acid

(d) Acetic acid, pyruvic acid

20.

Which one of the following has the most acidic hydrogen ?

(a) Hexan -3-one
(b) Hexane-2,4-dione
(c) Hexan-2, 3-dione
(d) Hexane-1,3-dione

21.

Volume strength of 10N H2O2 is

11 2

22.

(a) 112
(b)
(c) 56
The compound(s) which have OO bond (s) is/are
(a) Na2O2
(b) BaO2
(c) CrO5

5 6
(d)
(d) All of these

23.

GaAs (Gallium arsenide) is used

(a) in making of heart valve
(b) in laser diodes
(c) in making memory chips of computers
(d) both (3) and (4)

24.

The regent used in the gravimetric analysis of Co2+ ion is

(a) -nitro--naphthol
(b) -nitro--naphthol
(c) DMG
(d) K4[Fe(CN)6]

25.

Blister copper is refined by stirring molten impure metal with logs of green wood. This
process is called . And then metal contains the impurities of
(a) cupellation , CuO2
(b) poling , Cu2O
(c) cupellation, CuO
(d) cupellation, CuO

26.

The most stable conformation of ethylene glycol is

(a) Gauche
(b) Anti
(c) Partially eclipsed
(d) Full eclips

27.

In the reaction

the product formed will be

(a)

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(b)

(c)

(d)
28.

An organic compound A of molecular formula C 4H9Br reacts with Na in the presence

of dry ether and gives a hydrocarbon B which on monochlorination gives only one
isomer. a is
(a) sec-butyl bromide
(b) n-butyl bromide
(c) isobutly bromide
(d) tert. butyl bromide

29.

Order of melting points of o, m and pcresol is

(a) o > m > p
(b) p > o > m
(c) p > m > o
(d) o > p > m

30.

In a Grignard reaction , the Girgnard regent (RMgX) is a

(a) strong nucleophile
(b) weak nucleophile
(c) strong electrophile
(d) weak electrophile
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