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Introduction
Catalyst Portfolio
10
12
O4-66 Catalyst
14
O4-88 Catalyst
16
O4-29 Catalyst
18
O4-29 HiFlex
18
INTRODUCTION
BASF The Chemical Company
The worlds leading chemical company offers intelligent
solutions and high-quality products for almost all industries, uses new technologies to open up additional
marketopportunities and combines economic success
with environmentalprotection and social responsibility.
BASF at a Glance
Founded in 1865 by Friedrich Engelhorn under the name
Badische Anilin- und Sodafabrik, today, BASF is the
Worlds Leading Chemical Company The Chemical
Company. Around 109,000 employees of the BASF
Group work to make customers from nearly all sectors
and almost every country in the world become more
successful.
Plasticizers
52%
Other Applications
14%
Alkyde Resins
16%
Unsaturated Polyesters
18 %
Offgas
Steam
60 bar
Pure P A
tank
Post
reactor
SC
Predecomposer
2 column
distillation
Ludwigshafen
Iselin, New Jersey
Headquarters
Hong Kong
Regional Marketing
Technical Service
Typical concentrations in
reactor outlet gas (ROG) at
100 g/Nm3
Research
Institutes
Universities
Chemicals
Research &
Engineering
Specialty
Chemicals
Research
BASF
Research
Verbund
Polymer
Research
Plant
Biotechnology
Research
High-Tech
Joint Ventures
Industry
Partners
+ Air
Catalyst Research
BASF
Test Facilities
Universities
Online Monitoring of
Test Results
Phthalic
Anhydride Plant
O
O
+ Byproducts
Catalyst Marketing
Customers
Zeolites
Amination Catalysts
49 Professionals
135 Technicians
Hydrogenation Catalysts
Oxidation Catalysts
Acid/Base Catalysis
Catalyst Supports
O468
O466
O488
Load [g/Nm3]
max. 80
80 100
80 100
4.0
4.0
4.0
2.2* 3.4
3.0 3.7
3.0 3.7
345 350
345 350
345 350
PA-Yield
(Reactor Gas) [wt.-%]
114 115
114 115
115.5 116.5
Phthalide
(Reactor Gas) [wt.-%]
0.02 0.07
0.02 0.1
0.02 0.1
20 40
20 40
20 40
Start-Up Time
To 80 g/Nm3 To
100 g/Nm3 [Days]
18
18
45
24
52
Restart Time
To 80 g/Nm3 To
100 g/Nm3 [Days]
1
12
1
12
Aromatics
(In Off Gas) [mg/m3]
10
O429
O429 HiFlex
Feed (Ratio)
Naphthalene:
o-Xylene:
Load [g/Nm3]
Naphthalene: 80
Mixed Feed:
80
Naphthalene:
Mixed Feed:
Naphthalene:
104 105
o-X/Naphthalene (50:50): 109 110
Naphthalene:
105 106
o-X/Naphthalene (50:50): 110 111
Layers
0.05 1.0
0 0.1
3
2.9 3.4
100 35%
0 65%
80
85
0.05 1.0
0 0.1
4
2.9 3.4 m
11
Description:
Phthalic Anhydride
o-Xylene Load:
max. 80 g/Nm3
Maleic Anhydride
Citraconic Anhydride
Benzoic Acid
Composition:
Phthalide
Shape:
Rings, 7 x 7 x 4 mm
o-Toluic Aldehyde
Filling Density:
o-Xylene
Filling Height:
2.2* 3.4 m
(at 80 g/Nm3 OX Loading and 4.0 Nm3 Air per Tube and Hour)
345 350C
Phthalic
Anhydride Yield:
114 115%
Purity:
PD Content:
0.02 % in CPA
Solidification Point:
> 131.0C
SO2:
no need
Colour (Hazen):
5 10 APHA
Heat Stability:
12
Reference List
Company
Country
Company
Country
OCI
Korea
Kamtex
Russia
Japan
Lanxess
Germany
Mysor Petrochemicals
India
BASF Corporation
USA
Nimir
Pakistan
Koppers
USA
Lijin Petrochemicals
China
Kemiplas
Slovenia
Vartego
Argentina
Mexichem
Mexico
Orgachim
Bulgaria
BASF SE
Germany
CEPSA
Spain
Isegen
South Africa
13
Description:
Phthalic Anhydride
o-Xylene Load:
Maleic Anhydride
Citraconic Anhydride
Benzoic Acid
Composition:
Phthalide
Shape:
Rings, 7 x 7 x 4 mm
o-Toluic Aldehyde
Filling Density:
o-Xylene
Filling Height:
3.0 3.4 m
(at 100 g/Nm3 OX Loading and 4.0 Nm3 Air per Tube and Hour)
345 350C
Phthalic
Anhydride Yield:
114 115%
Purity:
PD Content:
0.02% in CPA
Solidification Point:
> 131.0C
SO2:
no need
Colour (Hazen):
5 10 APHA
Heat Stability:
14
Reference List
Company
Country
Company
Country
Company
Country
Henan Qingan
China
UPC Zhuhai
China
Lanxess
Germany
Shandong Hongxin
China
UPC Zhongshan
China
Perstop
Sweden
Jiangyin Zhongrun
China
UPC Taizhou
China
ZAK
Poland
Qilu Plasticizer
China
Movalledan
Iran
Lida
Belarus
Zhenhai Taida
China
IG Petrochemical
India
CarboQuimica
Colombia
UPC
Taiwan
Zhejiang Qingan
China
BASF-Petronas
Malaysia
Thirumalai
India
China
Continental
Petrochemical
Thailand
Asian Paints
India
Shijiazhuang Bailong
China
Petkim
Turkey
Aekyung
Korea
China
NanYa
Taiwan
Hanwa
Korea
Wuxi Coking
China
BASF SE
Germany
Mistubishi Gas
Chemical
Japan
China
Oltchim
Romania
Shanghai Coking
China
Petrom
Brasil
Panimex
Chile
PetroChina Jinzhou
Petrochemical
China
Gadiv
Israel
Dongguan
Shenghe
China
UPC Zhenjiang
China
Changzhou
New Solar
China
Zhejiang GST
China
Description:
5-Layer Catalyst
(CL0, CL1, CL2, CL3, CL4)
Phthalic Anhydride
Maleic Anhydride
o-Xylene Load:
Benzoic Acid
max. 4.0 Nm /h
Composition:
Phthalide
Shape:
Rings, 7 x 7 x 4 mm
o-Toluic Aldehyde
Filling Density:
o-Xylene
Filling Height:
3.0 3.7 m
(at 100 g/Nm3 OX Loading and 4.0 Nm3 Air per Tube and Hour)
16
345 350C
Phthalic
Anhydride Yield:
115.5 116.5 %
PD Content:
0.02% in CPA
SO2:
no need
Solidification Point:
> 131.0C
Colour (Hazen):
5 10 APHA
Heat Stability:
Reference List
Company
Country
Company
Country
UPC Zhenjiang
China
Deza
Czech Republic
CL0
CL1
CL2
CL3
CL4
17
Application:
Composition:
Description:
Shape:
Rings, 8 x 6 x 5 mm
Feed Ratio
O4-29:
Filling Density:
Feed Ratio
O4-29 HiFlex:
Filling Height:
2.9 3.4 m
Load O4-29:
max. 80 g/Nm
355 365C
Load
O4-29 HiFlex:
max. 85 g/Nm
Phthalic
Anhydride Yield
O4-29:
109 110%
Phthalic
Anhydride Yield
O4-29 HiFlex:
110 111%
in Mixed Feed Operations (50:50)
NQ Content:
max. 4.0 Nm /h
Phthalic Anhydride
Catalyst
O429/O4-29 HiFlex
Phthalic Anhydride:
Maleic Anhydride
Benzoic Acid
Naphthoquinone:
18
O4-29/O4-29 HiFlex
Expected Quality of Pure Phthalic Anhydride
Phthalic Anhydride
Catalyst
O4-29/O4-29 HiFlex
Purity:
Solidification Point:
> 131.0C
Colour (Hazen):
5 10 APHA
Heat Stability:
Reference List
Company
Country
Shijiazhuang Bailong
China
DEZA
Czech Republic
DCC Pohang
Korea
ISEGEN
South Africa
KOPPERS
USA
19
About Us
BASFs Catalysts division is the worlds
leading supplier of environmental and
process catalysts. The group offers
exceptional expertise in the development of technologies that protect the
air we breathe, produce the fuels that
power our world and ensure efficient
production of a wide variety of chemicals, plastics and other products,
including advanced battery materials.
By leveraging our industry-leading
R&Dplatforms, passion for innovation
and deep knowledge of precious and
base metals, BASFs Catalysts division
develops unique, proprietary solutions
that drive customer success.
Americas
BASF Corporation
25 Middlesex/Essex Turnpike
Iselin, NJ 08830, USA
Tel: +1-732-205-5000
Fax: +1-732-205-5687
Email: catalysts-americas@basf.com
Asia Pacific
BASF East Asia Regional HQ Ltd.
45th Floor, Jardine House
No. 1 Connaught Place
Central, Hong Kong
Tel: +852-2731-0191
Fax: +852-2731-5634
Email: catalysts-asia@basf.com
Europe, Middle East, Africa
Customer Service
BASF Nederland B.V.
Tel: +31-30-6669555
Fax: +31-30-6669340
Email: catalysts-europe@basf.com
Although all statements and information in this publication are belived to be accurate and reliable, they
are presented gratis and for guidance only, and risks
and liability for results obtained by use of the products or application of the suggestions described are
assumed by the user. NO WARRANTIES OF ANY
KIND, EITHER EXPRESS OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBEDOR DESIGNS,
DATA OR INFORMATION SET FORTH. Statements
or suggestions concerning possible use of the products are made without representation or warranty
that any such use is free of patent infringement and
are not recommendations to infringe any patent. The
user should not assume that toxicity data and safety
measuresare indicated or that other measures may
not be required.
www.catalysts.basf.com/chemicals