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Michael P. Balogh
MS The Practical Art Editor
Glossary
The following list of terms is derived
from common usage throughout the
industry as an adjunct to the discussions in this primer and includes
terms and techniques no longer in
common usage.
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Collision-induced dissociation
(CID): Also referred to as collisionally activated dissociation (CAD), it
is a mechanism by which molecular
ions are fragmented in the gas phase
hy acceleration (using electrical
potential) to a high kinetic energy
in the vacuum region followed hy
collision with neutral gas molecules
such as helium, nitrogen or argon. A
portion of the kinetic energy is converted or internalized by the collision, which results in chemical bonds
breaking and the molecular ion is
reduced to smaller fragments. Some
similar "special purpose" fragmentation methods include electron transfer dissociation (ETD) and electroncapture dissociation (ECD). See the
MS Primer section on "Biomolecular
ionization methods."
Direct analysis real time (DART):
Developed by Robert Cody and others
in 2002, similar to desorption electrospray ionization (DESI) in application
although more closely related to APCI
in function. A sample is placed on a
substrate and bombarded by energized
particles formed in a process similar
to APCI. That is. metastable ions are
formed by a plasma and transported
by heated nitrogen gas directed at the
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Scanning: See also selected ion monitoring, quadrupole and ion current. Control voltages (DC and RF) are adjusted
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Michael P. Balogh
"MS The Practical
Art" Editor Michael
P. Balogh is principal
scientist. MS technology development,
at Waters Corp. (Mil\
ford, Massachusetts):
a former adjunct
professorand visiting scier)tist at Roger
Williams University (Bristol, Rhode Island);
cofounder and current president of the Society for Small Molecule Science (CoSMoS) and
a member of LCGC's editorial advisory board.