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Alkanes [1.6]
Cracking
- Shorter chained hydrocarbons are more in demand so cracking is used to break down less useful
hydrocarbons into more useful, shorter chained hydrocarbons.
- Generally: Long Chained Alkanes -> Shorter Chained Alkanes + Alkenes + H2
- Shorter alkanes have use as fuels and petrochemicals.
- Alkenes are used in the manufacture of polymers.
- Thermal Cracking
> High temperatures (900oC) and pressures (70atm).
> The higher the temperature, the lower Mr alkenes.
> The reaction has a free radical mechanism.
- Catalytic Cracking
> Cracking can occur in the presence of a catalyst at 450oC.
> The catalysts are zeolites.
> Catalytic cracking produces alkanes, cycloalkanes and aromatics.
> The mechanism involves the formation of carbocations.
Joel Biffin
Alkanes [1.6]
Combustion of Alkanes
- Complete combustion occurs in the presence of oxygen, the combustion of alkanes is highly exothermic
Definitions
Fractional Distillation
Cracking
Fuel which has been formed over millions of years and which is a finite
resource
Any gas which contributes to global warming by absorption of infra-red
radiation by their bonds (polar)
Joel Biffin