Beruflich Dokumente
Kultur Dokumente
After the completion of my in plant training I intend to thank all the staff of GAIL (INDIA) Ltd.
who directly or indirectly was responsible for making mystay(during the training period) fruitful.
I am very grateful to the staff of GAIL who cooperated with me during the entire training period.
First and foremost, I would like to thank Mr. P.K. Jain Chief Manager (training) for making it
possible for me to come to GAIL and undergo the training.
The people of IOP&S Unit( where we were deputed) deserve special mention. I extend my
sincere gratitude to
Mr. A.K. Nashkar, HOD(IOP&S)
Mrs. Sweta Rani, Dy Manager( PC Operation), (IOP&S)
Finally, I would like to thank the field Engineers& GAIL family, who were in some way or
other related to our successful training.
1 | Page
ABSTRACT
In plant training is a vital part in the progress of fledgling engineers. For me this was the first
rendezvous of practical knowledge with the theoretical concepts acquired during the years in
college. I am very fortunate that I got the opportunity of undergoing training in one of the most
sophisticated and modern petrochemical plant, GAIL. The experience gained during the short
stay here was fascinating to say the least. It was tremendous feeling to see the practical operation
of different equipment and processes, which until now existed for me only in books. I was
deputed in IOP&S unit for my training. I was overwhelmed by the sheer size and complexity of
the plant. What still fascinates me, how such a big unit is being monitored and operated with the
desired results.
In this short stay it was possible for me to wholly decipher the detailed functioning of the
plants; but still I was fortunate enough to get a sound overview of the unit.
Thanks
2 | Page
CONTENT
CERTIFICATE
ABSTRACT
ACKNOWLEDGEMENT
LIST OF FIGURES
LIST OF TABLES
3 | Page
5-6
5-6
6
6
7-8
9
10-18
10-15
10-12
13
14
15
16-18
16
17
18
19-42
19
19-24
25-31
32-37
38-42
43
fig 1.1
Gas demand in india is dominated by the power and fertilizer sectors which account for
66 per cent of the current consumption. In 2006, the total gas demand was around 152
MSCMD. The gas demand is expected to increase to 320 MSCMD, according to a report
by Ernst & Young. Significantly, the share of natural gas in the overall fuel mix is
expected to increase from 8 per cent in 2006 to 20 per cent by 2025.
Reliance industries plans to invest between US$ 5.45 billion to US$ 6.54 billion over the
next three years to lay a 10,000 km pipeline.
Production:
4 | Page
1.
Consumption:
Indias domestic demand for oil and gas is on the rise . As per the Ministry of Petroleum,
demand for oil and gas is likely to increase from 176.40 million tons of oil equivalent
( mmton ) in 2007-08 to 233.58( mmton ) in 2011-12
INTRODUCTION TO GAIL
GAS AUTHORITY OF INDIA LTD. (GAIL) is one of the outstanding public enterprises
within the country today. It is one of the MAHARATNA Company in INDIA.
The setting up GAIL(India) LTD., in august 1984, heralded a new era of natural gas in
the country. GAIL is now 29 glorious years of service to the nation.
5 | Page
Since 1984, GAIL has made significant contribution to the nations economy by supplying
natural gas through its pipeline network for
1. Generation of over 87,000 MW of power
2. Production of over 145 million tons of urea
3. Production of LPG for over 7 cr. households in the country
4. Over 5.7 lakhs vehicles in the country today running on CNG supplied by GAIL and
over 7 lakhs households on piped natural gas(PNG) in the country.
5. Production of petrochemicals of around 4 lakhs mts which is used in the plastic
industry.
The natural gas infrastructure of around 7,000 km. accounting for over 82% of total
pipeline infrastructure in india , set up so far by gail has contributed enormously to the
economically and socially critical sectors such as fertilizers and power.
GAIL has the distinction of pioneering the clean fuel revolution for transport sector in the
country with the introduction of CNG in Delhi and Mumbai which has significantly
helped in reducing pollution levels in these two cities.
It provides ready market access to the domestic gas producers, making gas available to
the customers including those remotely located and devoid of market access. It has
provided cheaper, environment friendly alternative fuel and has reduced import
dependency as natural gas has substituted liquid fuel such as naphtha, fuel oil, etc.
GAILs pipeline network to the gas consumers in the states of:
1. Gujarat
2. Maharashtra
3. Rajasthan
4. Madhya Pradesh
5. Delhi
6. Haryana
7. Uttar Pradesh
8. Andhra Pradesh
9. Tamilnadu
10. Assam
11. Tripura
In addition to supplying natural gas to various consumers, GAIL has also setup 7 LPG
plants and a petrochemical plant to extract value added products from gas. Gail today
handles about 95% of natural gas business in India , through its 3900km of pipelines in
country. Gail is also one of the largest LPG producers in India with a liquid hydrocarbon
production. It produces around 1.35 MMTPA of liquid hydrocarbon including LPG for
domestic consumption. It has emerged as the no. 1 gas company in India. It has won the
excellent performance award for past several years, as well as safety award. It has
ISO 900 certificate for its pipeline system and also ISO 14001 for HVJ pipeline.
6 | Page
Entering into the field of petrochemical, GAIL has set up petrochemical complex at
PATA(UP).
The natural gas to the complex is coming from vijaipur through HVJ pipeline for
producing petrochemical conversion of ethane, propane& LPG from natural gas. The
ethane& propane are recovered from natural gas in GPU & set to gas company unit to
produce ethylene& propylene while LPG is recovered in LPG is recovered in LPG
recovery unit. Ethylene is converted to final products HDPE& LLDPE.
Project configuration:
S.no
1
2
3
4
5
6
7
unit
Gas cracker unit
Gas sweetening
agent
C2/C3 Recovery
LLDPE
HDPE 1& 2
LPG&
PROPANE
BUTENE
PLANT
capacity
licencor
4,00,000 TPA
U.S.A.
12.66 MMSCMD TOTAL
FINAEIF
4,00,800 TPA
E.I.L.
2,10,000 TPA
NOVACOR
1,00,000 TPA
MITSUI,JAPAN
2,98,480 TPA
E.I.L
10,000 TPA
I.F.P., FRANCE
Various utilities and offsite facilities have been provided in the complex. These include
raw water, cooling tower, compressed air, DM water, nitrogen flare, storage system are
provided.
GAS
Rich gas from
SWEETNING
UNIT LIC: TOTAL
FINAEIF
7 | Page
LLDPE/ HDPE
SWING UNIT LIC:
NOVACOR
vijaipur
C2/C3
GAS
CRACKING
UNIT LIC:
USA
GAS
PROCESSING
UNIT
LPG UNIT
LIC: E.I.L.
BUTENE 1 LIC:
I.F.P., FRANCE
PROPYLENE
LPG
PROPANE
UPSTREAM OPERATION
GAS SWEETENING UNIT
Amine gas treating also known as gas sweetening and acid gas removal, refers to a group of
processes that use aqueous solutions of various alkyl amines( commonly referred to simply as
amines) to remove hydrogen sulfides and carbon dioxide from gases. It is a common unit process
used in refineries and is also used in petrochemical plants, natural gas processing plants and
other industries.
Processes within oil refineries or chemical processing plants that remove hydrogen sulfides or
mercaptans are commonly referred to as sweetening processes because they result in products
which no longer have the sour, foul odour of mercaptan and hydrogen sulfide.
8 | Page
RNH3 + SH-
A typical amine gas treating process (as shown in the flow diagram below)
includesan absorber unit and a regenerator unit as well as accessory equipment. In theabsorber,
the downflowing amine solution absorbs H2S and CO2 from the upflowing sour gas to produce a
sweetened gas stream (i.e., a gas free of hydrogen sulfide and carbon dioxide) as a product andan
amine solution rich in the absorbed acid gases. The resultant "rich" amine is then routed into the
regenerator (a stripper with a reboiler) to produce regenerated or "lean" amine that is recycled for
reuse in the absorber. The stripped overhead gas from the regenerator is concentrated H2S and
CO2. In oil refineries, that stripped gas is mostly H2S, much of which often comes from a sulfur9 | Page
removing process called hydrodesulfurization. This H2S-rich stripped gas stream is then usually
routed into a Claus processto convert it into elemental sulfur. In fact, the vast majority of the
64,000,000 metric tons of sulfur produced worldwide in 2005 was byproduct sulfur
fromrefineries and other hydrocarbon processing plants. Another sulfur-removing process is
the WSA Process which recovers sulfur in any form as concentrated sulfuric acid. In some
plants, more than one amine absorber unit may share a common regenerator unit.
fig 1.2
Process flow diagram of a typical amine treating process used in petroleum refineries, natural
gas processing plants and other industrial facilities.
The amine concentration in the absorbent aqueous solution is an important parameter in the
design and operation of an amine gas treating process. Depending on which one of the
following four amines the unit was designed to use and what gases it was designed to
remove, these are some typical amine concentrations, expressed as weight percent of pure
amine in the aqueous solution:
Monoethanolamine: About 20 % for removing H2S and CO2, and about 32 % for
removing only CO2.
10 | P a g e
The choice of amine concentration in the circulating aqueous solution depends upon a
number of factors and may be quite arbitrary. It is usually made simply on the basis of
experience. The factors involved include whether the amine unit is treating raw natural
gas or petroleum refinery by-product gases that contain relatively low concentrations of
both H2S and CO2 or whether the unit is treating gases with a high percentageofCO2 such
as the offgas from the steam reforming process used in ammonia production or theflue
gases from power plants. Both H2S and CO2 are acid gases and hence corrosive to carbon
steel. However, in an amine treating unit, CO2 is the stronger acid of the two. H2S formsa
film of iron sulfide on the surface of the steel that acts to protect the steel. When treating
gases with a high percentage of CO2, corrosion inhibitors are often used and that permits
the use of higher concentrations of amine in the circulating solution. Another factor
involved in choosing an amine concentration is the relative solubility of H2S and CO2 in
the selected amine. For more information about selecting the amine concentration, the
reader is referred to Kohl and Nielsen's book.
The choice of the type of amine will affect the required circulation rate of amine
solution, the energy consumption for the regeneration and the ability to selectively
remove either H2S alone or CO2 alone if desired.
The current emphasis on removing CO2 from the flue gases emitted by fossil fuel power
plants has led to much interest in using amines for that purpose.
In the specific case of the industrial synthesis of ammonia, for the steam
reforming process of hydrocarbons to produce gaseous hydrogen, amine treating is one
of the commonly used processes for removing excess carbon dioxide in the final
purification of the gaseous hydrogen
Naphtha is primarily used by power, fertilizer, steel and petrochemical units. In power and steel
it is used as a fuel, whereas in petrochemical , chemical, fertilizer units it is used as a feedstock.
GAIL is presently operating 7 GPU located at Vijaipur (2 units), Auraiya, Vaghodia, Usar, Lakwa
& Gandhar plant for production of main products viz. LPG & Polymer through GPU/GCU
except usar, the following by products liquid hydrocarbons (LHC) are produced:
Plants
byproducts
Vijaipur
Auraiya
Vaghodia
naphtha
Gandhar
pentane, naphtha
Lakwa
sources. Thus natural gas is one of the most wanted feed stocks for petrochemical production.
The thermal cracking of natural gas proceeds at very high temp. resulting in olefins( mostly
ethylene/propylene). The temp. in a gas cracker exceeds 1000 degree C. For
ultimatedecomposition of gas into elements more than 1500 degree C is required. Thus ,
acetylene/carbon black production encounters such high temperatures. Usually oxy combustion
methods are used for attaining such high temp.. BASF burners/kellogs burners are available in
market
fig 1.3
Downstream operation
Petrochemicals
Gails the countrys premier natural gas marketer& transporter, diversified into the
manufacturing and marketing of downstream HDPE& LLDPE from natural gas cracking at its
pata unit from 19th april 1999. The beginning was with a name plate capacity of 2,60,000 MTPA
of HDPE & LLDPE. In FY 2009-10, the petrochemical business portfolio contributed over 28%
of the segment gross profit.
14 | P a g e
Gail is the only HDPE/ LLDPE plant operating in northern India and has a dominant market
share in north India. The primary thrust markets for the polymer had been western India, but with
the entry of Gail in the HDPE&LLDPE market verticals, today north India has also witnessed a
rapid and significant growth in the polymer downstream processing verticals. In a successful
span of about a decades of establishing and marketing its grades under the brand names Glex&
Glene, Gail has alongside augmented its name plate capacity of HDPE&LLDPE to 4,10,000
MTPA by adding another dedicated HDPE downstream polymerization unit of 1,00,000 MTPA.
GAIL has two trains of dedicated HDPE units of the Mitsui slurry technology license( capacity
2* 1,00,000 MTPA) and marketing the grades under the brand name of G lex and one train of the
HDPE&LLDPE swing plant under the NOVACOR solution based technology license( capacity
2,10,000 MTPA).
Further by adding 6th furnace & de bottlenecking of the plant, the Gails pata plant capacity will
reach to 5,00,000 mts of ethylene & 5,00,000 MTs of HDPE&LLDPE producing capacity by
FY 2011-12.
GAIL has also formed a joint venture company by the name of M/s Bhramaputra cracker and
petrochemicals ltd.( BCPL) to accelerate the GoIs only authorized petrochemical project in the
north east of India( at Assam ,India). The bcpl is a JV between the government of Assam , GAIL
INDIA ltd. OIL INDIA ltd.& NRL.
Further Gail has plans to augment the installed capacity further by putting up new plants of
HDPE/LLDPE by 500 KTA at pata, which is targeted to the operational by FY 2013-14
4. Prepolymerization
5. Polymer drying
6. Extrusion
7. Product homogenization
8. Product storage and bagging
Different section:
1. Catalyst, co catalyst handling and metering
2. Polymerization
16 | P a g e
fig 1.4
Storage vessels:
TYPES OF STORAGE VESSELS IN IOP&S:
Following are the types of vessels used in Storage area :
1.) Cylindrical vessels
2.) Spherical vessels (HORTON SPHERES)
3.) Double Walled Ethylene tanks
4.) Bullets
5.) Mounded Bullets
Spherical Vessels are generally preferred as its ratio of volume to surface area is less . Therefore
large amount of material can be stored in less space. There are 14 Horton Spheres, 9 cylindrical
storage vessels and 2 double walled ethylene tanks. Horton spheres present in storage area are of
different fixed designed diameters such as 11.5m, 13m and 15m. There are 8 spheres of diameter
equal to 15 m to store C2/C3 having their tag no. from TS - 101 to TS - 108 . Fire coating of
thermolag is required in these C2/C3 storage vessels as temp conditions are very low. There are 2
Horton spheres of diameter equal to 11.5 m to store Propylene with their tag no. as TS 109 and
TS 110 . There are 2 Horton spheres of diameter 13m to store Butene -1 having tag no. TS
112 and TS 113 . And there is a Horton sphere each for C4 mix ( tag no. TS - 111) and
ethylene (TS -114) as well. Likewise C2/C3 Horton sphere, insulation is required in ethylene
sphere also as its temp conditions are very low.
There are 2 Double walled Ethylene tanks to store ethylene ( from GCU ) at -104c and 0.7-0.8
kg/cm2. As temp conditions are very low so insulation with perlite is done in the annular space.
There are 9 cylindrical vessels in storage area . one for xylene , one for wash oil, one for hexane ,
one for cyclohexane , two for mixed fuel oil and two for SBP.
There are 7 mounded storage bullets to store LPG as it is heavier than air. And there are 2
mounded bullets for storage of propane also.
There are 2 storage bullets to store hydrogen also.
PROPYLENE STORAGE
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In UPPC propylene will be produced in the Gas Cracker as a product. For storing this propylene,
two Horton spheres 44-TS-00-109/110 have been provided in the Offsite area. The spheres are
11.5m diameter and elevated by 5.5 m to cater to the transfer pump NPSH requirement.
44-TS-00-109/110
Number of spheres
Two
C 9.4 to 40
C -40/+55
M 11.5
Insulation
19 | P a g e
i.e. 70%. Similarly propane percentage is low in the former case (15%) than the latter case
(26%). This is the feed stock to the Gas Cracker.
The C2C3 comes through a 8 line from the C 2C3 plant for storage at Offsites. Eight spheres each
of 1500M3 capacity (15 M diameter) have been provided for this storage. This storage capacity
is equivalent to 3 days production of C2C3 corresponding to 4,10,000 TPA ethylene production.
Under normal conditions cracker will receive C2C3 directly from C2C3 plant and a small slip ream
of 7 T/hr will be diverted to the offsite storage. Three pumps (41-PA-CF-004 A/B/C) of 100
M3/hr capacity each are provided to transfer C 2C3 to GCU. Under normal condition (when C 2C3
plant is running) this 7 T/hr will be pumped out of the storage spheres and is routed to join the
main C2C3 rundown line leading to the GCU. Thus the entire system is kept chilled at a
temperature of -2 to 5 0C. This is to ensure that the system can be taken in line immediately
whenever required. The sphere is provided with facility to measure average temperature of the
fluid by the probe mounted with servo type level transmitter on sphere top. C 2C3 will be stored in
the sphere at a temperature of -20C to 50C and a pressure of 22.5 Kg/cm2g.
fig 1.5
HORTONS SPHERE
20 | P a g e
fig 1.6
STORAGE TANK
HYDROGEN STORAGE AND TRANSFER
Receipt & Storage:
Hydrogen is used as a chain terminator in polymeric reactions. So a continuous supply of H 2 has
to be ensured for the safe running of the polymer plants. Under normal conditions, Hydrogen
coming from the PSA unit at GCU (at 19 Kg/cm2g) will be compressed by a MP compressor
(41-KA RP-001) to 50Kg/cm2g and will be routed to the consumer. The balance hydrogen will
be compressed in a HP compressor (41-KA-RP-002) up to 137 Kg/cm2g and stored in two H2
bullets (41-VV-00-118 A/B) of 70M3 capacity each. These bullets store H2 at a pressure of 137
Kg/cm2g. These will be in use when H2 is not available from GCU-PSA. The HP compressor
can also be used as a standby of the MP compressor whenever required. PCV-2103 has been
provided to let down HP hydrogen pressure to MP level for consumption. Provision is also there
to evacuate the bullets by the same compressor whenever required.
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Two
Ambient
C 55
Stored Capacity M3 70
MOC
Carbon Steel
Insulation
Nil
Each bullet is provided with the following instruments:- One pressure transmitter
- One temperature gauge
- One pressure gauge
- Two safety valves (one in operation + one spare) Designed for fire case.
Each bullet is provided with two process line, one fill-in and one line grouted to the consumer.
All the process lines are provided with remote operated valve for isolation in case of any
emergency i.e. fire, leakage, etc. Thus on closure of these valves, the bullet gets isolated from
rest of the system. Both open and close push buttons and status indications of these ROVs are
available in the control room. Each bullet is protected with a pair of safety valves (one operating
+ one standby) designed for fire case discharge capacity.
FIRE:
Spheres are protected against external fire by a layer of fire proofing paint which can
stand fire for 2 hrs. Apart from this over this layer, there are networks of thermal fuses
and water spray. Thermal fuses are small glass bulbs filled with a liquid set to break when
it gets heated upto 790C and are located at the tip of an instrument air network. Thermal
fuses seal the network thus pressurizing the entire network to level of instrument air
pressure. The second network is that of fie water with a spray on the tips. Water is
supplied to this network through a solenoid operated valve which normally remains
closed. When the bulb breaks instrument air leaks out causing a drop in air pressure. A
low pressure switch located on instrument air line to each sphere is actuated when
pressure falls to 2.5 Kg/cm2g. This in turn actuates solenoid valves thereby closing
ROVs of respective sphere and simultaneously opening solenoid operated valve on fire
water line to the sphere. The sprays will drench the sphere at a rate of 10 LPM/M2 of
sphere surface area. Instrument air is supplied through a restriction orifice so that when a
bulb breaks only PSL of the affected sphere is actuated while instrument air network on
other two spheres remain pressurized. ROVs on hydrocarbon lines and those on fire
water lines are operate as described for the case of propylene storage. Instrument air to
only bottom ROV is supplied through a volume bottle with capacity sufficient for two
operations
In the event of fire in the sphere area, the sphere is provided with security system to
isolated the affected sphere from the others. All the spheres are provided with two nos. of
safety valves sized for fire case (1+1). This safety valve will be protecting the sphere
from over pressure by dumping the vapour generated due to fire.
High expansion foam can also be applied on the ethylene tank. Around 5000 lpm of foam
solution can be applied on the tank
All the ROVs of the spheres are provided with close facility from field.
The deluge valves on fire water sprinkler lines for adjacent tanks in the dyke shall get
opened.
All the ROVs of the spheres are provided with close facility from the local control panel.
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All the deluge valves for the water sprinkler is provided with push buttons in the control
room to open them manually.
Gas detectors are provided near each ROV and one on the top of the sphere to alert the
operator from gas leakage
Dm plant
INTRODUCTION:
De-mineralized water is required in GAIL, Pata complex to generate steam as well as for process
use for injection, dilution, washing etc. in units like GCU, LLDPE/ HDPE (Swing), HDPE
(Slurry). Treated raw water is fed to DM water plant to produce DM water of required quality.
DM water is distributed to various users from DM water storage tanks (three in number) which
can meet 6 hours normal requirement each. Three DM water pumps (2 Oper + 1 Standby) in D.
M. Plant-1 and two DM water pumps (1 Oper + 1 Standby) in D. M. Plant-2 are provided to feed
DM water to Power plant and process units.
Brief description of DM plant is given in this section. For detailed description of DM plant, start
up and shut down procedure. Vendors manual shall be referred.
DM WATER REQUIREMENT:
The estimated requirement of DM water for GAIL, Pata is given below:
Normal
Maximum
(T/hr)
(T/hr)
20
5.0
10
10
20
Butene 1
Caustic dilution
7.0
GCU
LLDPE/ HDPE
HDPE-I&II
3.0
120
130
Generation
HRSG
70
TOTAL DM WATER
90
210
275
DM WATER CHARACTERISTICS:
pH
6.5 7.0
Conductivity micromho/cm
0.2
0.02
Turbidity
NIL
Iron as Fe
0.005
TDS
0.1
Copper as Cu
<0.005
Hardness
Nil
CAPACITY:
To meet DM water requirement at GAIL, Pata, two chains each capable of producing 125 M3/hr
(2500 m3/day) DM water are provided. One more chain having capacity of 200 M3/hr (4000
M3/day) was installed in 2002 with installation of LPG plant. Chains are run as per D. M. Water
requirement in the plant.
25 | P a g e
pH
7.5-8.3
Turbidity
NTU
<2
M alkalinity as CaCO2
mg/l
80
Ca hardness as CaCO3
mg/l
80
mg/l
110
Chloride as Cl
mg/l
20
Sulphate as SO4
mg/l
60
mg/l
20
Total Iron as Fe
mg/l
<0.1
mg/l
<65
PROCESS DESCRIPTION:
Treatment Scheme:
1)
The water as delivered at the de-mineralizing plant is clarified and filtered by other. It has
little turbidity, organic matter (KMnO4 value) free chlorine and iron. The Activated Carbon
26 | P a g e
Filters (ACF) is installed to effectively eliminate these from the de-mineralized water. To
produce de-mineralized water quality specified above, the water is passed through successive
fixed beds of ion exchange resins. The resin columns are arranged serially as follows:
a)
b)
c)
d)
e)
Mixed bed
II)
Column Description:
a)
i)
This ion exchange resin exchanges the calcium, magnesium, (i.e. hardness) and sodium
ions present in feed water with Hydrogen ions. This exchange is represented as follows:
RH + NaCl R Na + H+ + Cl
where R represents resin. H+ and Na+ (or Ca or Mg) are cations and Cl- (or SO4- or HCO3- etc.) is
anion.
ii)
The water leaving the cation exchanger column will thus contain HCl (Hydrochloric
acid). H2SO4 (Sulphuric acid) and H2CO3 (Carbonic acid) in quantities equivalent to the cations
removed from the water. The decationised water is thus acidic (pH approx. 4).
iii)
The fixed resin bed has finite quantity of H + ions. Once these have been exchanged for
Ca. Mg and Na ions, the treatment is stopped and the resin is regenerated to replenish the H +
ions. This is done by passing a solution of HCl (Hydrochloric acid) through the column. The
exchange is represented as follows:
RNa + HCl RH + NaCl
The exchange process is thus reversible. The strength of the solution passing through the bed
shall be 4-5%.
iv) The strongly acidic cation exchange resin will exchange all the Ca ++ and Mg++ ions in the
water till the bed is exhausted. Howerver, its affinity to Na + ions is not as strong and therefore
decationized water is hardness free but contains Na+ ions as leakage.
v) The sodium ion leakage is controlled by the quantity of Acid used for regeneration
(Regeneration level). Higher regeneration level reduces Na+ ion leakage.
27 | P a g e
vi) The sodium ion leakage is also regulated by the method of regeneration. Injection of acid in a
direction opposite to the direction of treatment flow (counter current) produces consistently
lower Na+ leakages for the same regeneration level than passing the acid in the direction of
treatment flow. Air pressure from the top is applied to hold the resin without lifting during
counter current regeneration and displacement rinse.
vii) Na+ ion leakage contributes to
viii)
a)
Conductivity of Dematerialized water.
b)
Silica leakage in De-mineralized water and hence must be controlled.
After regeneration, the resin is rinsed with water to waste away the excess acid and the
b)
Degasser System:
i) The de cationised water contains strong and weak acids (see (a) ii). The carbonic acid is a
weak acid which is easily driven out of water in the form of carbon di oxide by passing a current
of air through cascading water.
ii) This reduces the exchange load on the following anion exchangers. This is accomplished
mechanically and does not require regenerate chemical.
iii) Water is allowed to fall down in a cylinder filled with raschig rings. The rasching rings
increase the surface area on which water film is formed.
iv) Air is blown into the cylinder from the bottom and passes out at the top with the carbon di
oxide disassociated from the carbonic acid present in the water. Air flow rate is 1080 m3/hr/m2.
v) The water thus stripped of CO2 is collected in a degassed water storage tank and pumped
from there to the anion exchanger.
vi) There is a minimum amount of carbon di oxide retained in the water even after degassing.
This amount is 5.7 mg/ltr as CaCO3 (5ppm as CO2) considered as maximum.
ii) The water leaving the weak base anion column will thus contain only silica and the leakage
CO2 of degasser tower in the form of respective acids along with sodium leakage of cation
exchanger.
iii) As with cation exchanger the fixed resin bed has finite quantity of hydroxyl ions and once
these have been exchanged for chloride and sulphate ions the treatment is stopped and the resin
is regenerated to replenish the OH- ions. This is done by passing a solution of NaOH (sodium
hydroxide) through the column. The exchange process is thus reverse.
iv) The weak base anion resins have very high regeneration efficiency and can be regenerated
with slight excess of caustic soda over the exchanged load. Also weak base resin can be
regenerated with very dilute solutions of caustic soda. Also weak base anion exchanger can
contain up to 1 mg/ltr as CaCO3 of chloride ions as leakage.
v) To economize on the consumption of caustic soda for regeneration, the weak base anion is
regenerated in Thoroughfare, with the following strong base anion. This gives the advantage of
passing the total quantity of caustic soda required for both strong base and weak base anion
exchangers through the strong base anion exchanger first and then passing it through the weak
base anion exchanger.
vii) After regeneration the resin is rinsed with degassed water to wash away the excess caustic
soda and the column can be used again to exchange.
d)
i) This ion exchange resin exchanges anions of both strong and weak acids. In the present case,
since the anions of strong acid are exchanged in the preceding weak base anion column the feed
to the strong base exchanger contains mainly silica, carbon dioxide, and chloride in the form of
acids. The later two being leakages from degasser and weak base anion. Besides it contains the
sodium leakage of cation exchanger.
ii) In the strong base anion exchanger, the silica, chlorides and bicarbonates, all anions, are
exchanged with hydroxyl ions. The water leaving the strong base anion exchanger will thus
contain equivalent quantity of NaOH as an exchange product of sodium leakage from cation
exchanger and silica as leakage of the strong base anion exchanger.
iii) The fixed resin bed after being exhausted is regenerated with sodium hydroxide to replenish
the OH ions: the process is thus reversible.
iv) The strong base anion exchanger will exchange all anions but its affinity for silica is not as
strong and therefore the anion treated water will contain some silica as leakage. This leakage is
increased due to the presence of sodium ions in water which is converted into sodium hydroxide.
29 | P a g e
e)
I) This ion exchange resin exchanges both Anions as well as Cations. In the present case, the
slippage of Anions from WBA and then SBA and slippage of Cations from SAC is taken care of
by this exchanger.
II) This exchanger consists of Strong Acid Cations resin and Strong Base Anion resin. Both
resins are mixed with each other for the purpose of final polishing of the water.
III) For regeneration of both the resins, both beds are required to be separated. For that the mixed
bed is fluidized by counter current water flow. Both beds are separated with water layer is seen in
between both the beds. Because of difference in specific gravity of both types of resins, Strong
Base Anion resin bed settles at the bottom and Strong Acid Cations settled at the top.
IV) As usual SBA resin is regenerated by 4-5% conc. Solution of NaOH and SAC resin is
regenerated with 4-5% conc. of HCL.
v) After regeneration the resins are mixed by passing a current of air from bottom of the vessel.
After mixing the mixed resins are rinsed and can be put back to exchange.
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History:
Cooling towers originated out of the development in the 19th century of condensers for use with
the steam engine. Condensers use relatively cool water, via various means, to condense the steam
coming out of the pistons or turbines. This reduces the back pressure, which in turn reduces the
steam consumption, and thus the fuel consumption, while at the same time increasing power and
recycling boiler-water. However the condensers require an ample supply of cooling water,
without which they are impracticalthe cost of the water exceeds the savings on fuel. While this
was not an issue with marine engines, it formed a significant limitation for many land-based
systems. By the turn of the 20th century, several evaporative methods of recycling cooling water
were in use in areas without a suitable water supply, such as urban locations relying on municipal
water mains. In areas with available land, the systems took the form of cooling ponds; in areas
with limited land, such as in cities, it took the form of cooling towers. These early towers were
positioned either on the rooftops of buildings or as free-standing structures, supplied with air by
fans or relying on natural airflow. An American engineering textbook from 1911 described one
design as "a circular or rectangular shell of light plate in effect, a chimney stack much
shortened vertically (20 to 40 ft. high) and very much enlarged laterally. At the top is a set of
distributing troughs, to which the water from the condenser must be pumped; from these it
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trickles down over "mats" made of wooden slats or woven wire screens, which fill the space
within the tower.
A hyperboloid cooling tower was patented by the Dutch engineers Frederik van
Iterson and Gerard Kuypers in 1918.[7] The first hyperboloid cooling towers were built in 1918
near Heerlen. The first ones in the United Kingdom were built prior to 1930 in Liverpool,
England to cool water used at a coal-fired electrical power station
make use of once-through ocean water. But even there, the offshore discharge water outlet
requires very careful design to avoid environmental problems.
Petroleum refineries also have very large cooling tower systems. A typical large refinery
processing 40,000 metric tonnes of crude oil per day (300,000 barrels (48,000 m3) per day)
circulates about 80,000 cubic metres of water per hour through its cooling tower system.The
world's tallest cooling tower is the 202 metres (663 ft) tall cooling tower of Kalisindh Thermal
Power Plant in Jhalawar, Rajasthan, India.
dry cooling towers operate by heat transfer through a surface that separates the working
fluid from ambient air, such as in a tube to air heat exchanger, utilizing convective heat
transfer. They do not use evaporation.
wet cooling towers (or open circuit cooling towers) operate on the principle
of evaporative cooling. The working fluid and the evaporated fluid (usually water) are one
and the same.
fluid coolers (or closed circuit cooling towers) are hybrids that pass the working fluid
through a tube bundle, upon which clean water is sprayed and a fan-induced draft applied.
The resulting heat transfer performance is much closer to that of a wet cooling tower, with
the advantage provided by a dry cooler of protecting the working fluid from environmental
exposure and contamination.
In a wet cooling tower (or open circuit cooling tower), the warm water can be cooled to a
temperature lower than the ambient air dry-bulb temperature, if the air is relatively dry (seedew
point and psychrometrics). As ambient air is drawn past a flow of water, a small portion of the
water evaporates, and the energy required to evaporate that portion of the water is taken from the
remaining mass of water, thus reducing its temperature. Approximately 970 BTU of heat energy
is absorbed for each pound of evaporated water. Evaporation results in saturated air conditions,
lowering the temperature of the water processed by the tower to a value close to wet-bulb
temperature, which is lower than the ambient dry-bulb temperature, the difference determined by
the initial humidity of the ambient air.
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To achieve better performance (more cooling), a medium called fill is used to increase the
surface area and the time of contact between the air and water flows. Splash fill consists of
material placed to interrupt the water flow causing splashing. Film fill is composed of thin sheets
of material (usually PVC) upon which the water flows. Both methods create increased surface
area and time of contact between the fluid (water) and the gas (air), to improve heat transfer.
Natural draft Utilizes buoyancy via a tall chimney. Warm, moist air naturally rises
due to the density differential compared to the dry, cooler outside air. Warm moist air is less
dense than drier air at the same pressure. This moist air buoyancy produces an upwards
current of air through the tower.
Mechanical draft Uses power-driven fan motors to force or draw air through the
tower.
Induced draft A mechanical draft tower with a fan at the discharge (at the top)
which pulls air up through the tower. The fan induces hot moist air out the discharge.
This produces low entering and high exiting air velocities, reducing the possibility of
recirculation in which discharged air flows back into the air intake. This fan/fin
arrangement is also known as draw-through.
Forced draft A mechanical draft tower with a blower type fan at the intake.
The fan forces air into the tower, creating high entering and low exiting air velocities.
The low exiting velocity is much more susceptible to recirculation. With the fan on the
air intake, the fan is more susceptible to complications due to freezing conditions.
Another disadvantage is that a forced draft design typically requires more motor
horsepower than an equivalent induced draft design. The benefit of the forced draft
design is its ability to work with high static pressure. Such setups can be installed in
more-confined spaces and even in some indoor situations. This fan/fill geometry is also
known as blow-through.
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Fan assisted natural draft A hybrid type that appears like a natural draft setup,
though airflow is assisted by a fan.
Hyperboloid (sometimes incorrectly known as hyperbolic) cooling towers have become the
design standard for all natural-draft cooling towers because of their structural strength and
minimum usage of material. The hyperboloid shape also aids in accelerating the
upward convective air flow, improving cooling efficiency. These designs are popularly
associated with nuclear power plants. However, this association is misleading, as the same kind
of cooling towers are often used at large coal-fired power plants as well. Conversely, not all
nuclear power plants have cooling towers, and some instead cool their heat exchangers with lake,
river or ocean water
temperature
return
30.98
41.12
10.14
31.42
42.00
10.58
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31.00
41.98
10.98
31.61
41.24
9.63
29.60
37.62
8.02
29.88
40.17
10.29
31.18
38.46
7.28
For efficiency:
Range= hot water temp. inlet- cold water temp. outlet
Approach= cold water temp. outlet- ambient air wet bulb temp.
Efficiency= range/ hot water temp. inlet- ambient air wet bulb temp.
Cooling tower
RAW WATER
INTR0DUCTION:
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QUANTITY M3/Hr
NORMAL
MAXIMUM
A)
DM Water make up
250
450
B)
600
700
B)
20
30
43
C)
02
03
D)
Miscellaneous Water
25
27
E)
75
75
TOTAL
1015
1340
55
QUANTITY M3/Hr
NORMAL
Fire water make up
MAXIMUM
0-50
Horticulture
100
0-30
30
pH
7.9-8.6
8.1
Turbidity NTU
20-30
20
0-3
85-95
65-70
90-100
Chloride as Cl.mg/l
82
162
10-12
Sulphate as SO4,mg/l
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310
215
25-30
30-35
167
20
TDS, mg/l
170-190
985
0.15-0.2
0.2
Cu, mg/l
Nil
Colloidal SiO2
10
5-10
Nil
--
SYSTEM DESCRIPTION:
RAW WATER RECEIPT AND STORAGE:
Canal water is received in the complex through an open channel and stored in Canal Water
reservoirs. There are three reservoirs having a capacity of 20000 m3 each and one reservoir
having the capacity of 80000 m3. Total design capacity to store canal water is 680000 m3.
However, in year 2007, for using the free board of the dyke of the reservoirs, overflow points
were raised by 20 cm, whereby we can now store up to 750000 m3. For lifting canal water
beyond its canal natural level to uplifted level of reservoirs, two centrifugal pumps having
capacity of 700 m3/hr each were installed in 2007 on feeder channel.
This storage canal water caters to 30 days normal requirement or 25 days of maximum water
requirement of the complex. This water is then sent to Raw Water Treatment Plant RWTP-1 and
RWTP-2 (each having the capacity of 550m3/hr). Here the water is subjected to the following
continuous treatment:
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Two are for normal operation and the third will be used as a stand by (275 M3/hr capacity each).
The clarified water from the CLF enter the RSGF through inlet channels provided for the
purpose. From these channels through entry valves at the top the water flow into the RSGF.
Filtration is effective through the granular sand and supporting gravel media in a vertically
downward direction and flow out into the Filtered Water Channel (FWC). In the sand filters, the
turbidity of water is reduced to <2 NTU. During the course of filtration sediments / flocs that
have been carried over from the CLF will deposit on the surface of the RSGH beds and penetrate
upto a certain depth in the sand layers only. With time (may be in 24 hrs.) the rate of filtration
may reduce and there will be head loss within the filter media. This head loss can be read from
the Loss of Head (LOH-1101 A/B/C) gauge provided. When the head loss is sufficiently high it
is an indication that the filters need to be cleaned. After cleaning the filters can be brought back
to normal use. Filter cleaning is done with water backwash from a wash water tank (330 M3
capacity) backwashing is done at the rate of 0.4 M3/min/M2 and air scouring from air
compressor/ blowers (23-BF-1 A/B for RWTP-1 & 35-KA-1005 A/B for RWTP-2) provided for
the purpose. These blowers have a capacity of 1555 M3/hr each and developing a pressure of
0.35 Kg/cm2g. The air scouring rate is 0.9 M3/min/M2. This backwash/ air scouring is done in
the reverse direction to filtration i.e. vertically upwards through the under drain pipes at the
bottom of the RSGF. This filter cleaning generally takes about 10-15 minutes. Once the filters
are cleaned normal operation can be resumed. The RSGF has been designed for a flow of 275
M3/hr/ each. The rate of filtration is 80 LPM/M2. The backwash waste water in RWTP-1 is
collected through a channel into the waste water tank adjacent to the filter beds which is pumped
by Dirty backwash pumps (23-PC-01 A/B) to the sludge lagoons which in turn again pumped
back to the inlet feeder canal channel of raw water reservoir R-3. The Back wash water in
RWTP-2 directly goes to sludge lagoons by gravity. The treated water is now sent to Treated &
Filtered water reservoirs tanks through underground pipe line
References:
1. www.Wikipedia.org
2. www.google.co.in
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3. www. Gail.nic.in
4. www. slideshare.com
5. books and referrences
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