Name :

Class :.

Quiz 1

Chapter : Rate of Reaction

1

35

Diagram 1 shows a graph of the volume of gas produced against time for
the reaction between zinc granules and hydrochloric acid.
Rajah 1 menunjukkan graf isipadu gas yang dihasilkan melawan masa bagi
tindak balas antara ketulan zink dan asid hidroklorik .

Volume of gas,
cm3
Isipadu gas, cm3

Time, s
Masa, s
Diagram 1
Rajah 1
The gradient of the graph decreases with time because
Kecerunan graf berkurang dengan masa kerana
A
B
C
D

catalyst is not used

mangkin tidak digunakan
volume of mixture decreases
isipadu campuran berkurang
temperature of reaction decreases
suhu tindak balas berkurang
concentration of hydrochloric acid decreases
kepekatan asid hidroklorik berkurang

Magnesium reacts with acid to produce hydrogen gas, H 2.

Which solution would give the highest initial rate of reaction?
Magnesium bertindak balas dengan asid untuk menghasilkan gas hidrogen,
H2.
Larutan manakah akan memberikan kadar awal tindak balas yang
tertinggi?
A
B
C

100
100
100
100
100
100

cm3
cm3
cm3
cm3
cm3
cm3

of 1.0 mol dm-3 of nitric acid, HNO3

asid nitrik, HNO3 1.0 mol dm-3
of 1.0 mol dm-3 of hydrochloric acid, HCl
asid hidroklorik, HCl 1.0 mol dm-3
of 1.0 mol dm-3 of sulphuric acid, H2SO4
asid sulfurik, H2SO4 1.0 mol dm-3

1
QUIZ 1_CHEM/F5

100 cm3 of 1.0 mol dm-3 of ethanoic acid, CH3COOH

100 cm3 etanoik asid, CH3COOH 1.0 mol dm-3

Table 1 shows the experiments carried out to study the rate of reaction
between zinc carbonate and nitric acid.
Jadual 1 menunjukkan eksperimen yang dijalankan bagi mengkaji tindak
balas antara zink karbonat dengan asid nitrik.
Zinc carbonate, ZnCO3
Zink karbonat

Experimen
t
Eksperime
n

Mass (g)
Jisim

II

State
Keadaan

Nitric acid, HNO3

Asid nitrik
Volume(cm3 Concentratio
)
n (mol dm-3)
Isipadu
Kepekatan

Granule
Ketulan
Powder
Serbuk
Table 1
Jadual 1

50

0.1

25

0.2

Which of the following graph represents the two experiments?

Antara graf berikut yang manakah mewakili kedua-dua eksperimen itu?
A
Volume of
CO2/cm3
Isipadu CO2/cm3

B
Volume of
CO2/cm3
Isipadu CO2/cm3

II

I
II

I
Time/s
Masa/s

Time/s
Masa/s
C
Volume of
CO2/cm3
Isipadu CO2/cm3

D
Volume of
CO2/cm3
Isipadu CO2/cm3
I

II

II
Time/s
Masa/s

Time/s
Masa/s

2
QUIZ 1_CHEM/F5

Diagram 2 shows the graph of the volume of hydrogen gas against

time for the reaction between granulated zinc and 50 cm 3 1.0 mol
dm-3 sulphuric acid.
Rajah 2 menunjukkan graf isipadu gas hidrogen melawan masa untuk
tindak balas antara ketulan zink dan 50 cm3 asid sulfurik 1.0 mol dm-3

Volume/ cm3
Isipadu/ cm3

X
Y

Diagram 2

Time / s
Masa/ s

Rajah 2

Curve X is obtained when excess granulated zinc is reacted with 50

cm3 1.0 mol dm-3 sulphuric acid.
Which of the following must be done to produce curve Y?

Lengkung X diperoleh apabila ketulan zink yang berlebihan bertindak

balas dengan 50 cm3 asid sulfurik 1.0 mol dm-3.
Antara berikut yang manakah perlu dilakukan
untuk menghasilkan
lengkung Y?

Add distilled water to sulphuric acid

Replace granulated zinc with zinc powder

Add a few drops of copper (II) sulphate solution

Add sulphuric acid to the mixture

Tambahkan air suling ke dalam asid sulfurik

Gantikan ketulan zink dengan serbuk zink

Tambahkan beberapa titis larutan kuprum (II) sulfat

Tambahkan asid sulfurik ke dalam campuran

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QUIZ 1_CHEM/F5

STRUCTURE QUESTION (11 MARKS)

An experiment is carried out to study the effect of concentration on rate of
reaction.
50.0 cm3 of 0.5 mol dm-3 hydrochloric acid and excess granulated calcium
carbonate is put into a conical flask and is placed on an electronic balance as
shown in Diagram 1.
The mass of the conical flask and its contents is recorded at 60 seconds
intervals.
Satu eksperimen telah dijalankan untuk mengkaji kesan kepekatan ke atas kadar tindak
balas.
50.0 cm3 asid hidroklorik 0.5 mol dm -3 dan ketulan kalsium karbonat berlebihan
dimasukkan ke dalam kelalang kun diletakkan di atas neraca elektronik seperti dalam
Rajah 1.
Jisim kelalang kun dan kandungannya direkodkan pada sela masa 60 saat.

DIAGRAM 1
RAJAH 1

Table 1 shows the results.

Jadual 1 menunjukkan keputusan

Time/sec.
[Masa/saat]
Balance readings /g
[Bacaan neraca/g]

60

140.6
4

140.4
8

120

180

140.3 140.3
7
1
TABLE 1

240

300

360

420

480

140.2
6

140.2
2

140.2
0

140.2
0

140.20

JADUAL 1

(a)

Give the definition of rate of reaction.

Berikan maksud kadar tindak balas

......................................................................................................................
..................
[1 mark]
(b)
Explain why the mass of the conical flask and its content decreases with
time.
Terangkan mengapa jisim kelalang kun dan kandungannya berkurang dengan
masa

4
QUIZ 1_CHEM/F5

......................................................................................................................
..................
......................................................................................................................
..................
[1 mark]
(c)
Based on Table 1, plot a graph of the mass of the conical flask and its
content versus time on the graph paper below.
Berdasarkan Jadual 1, plotkan graf jisim kelalang kun dan kandungannya melawan
masa pada kertas graf di bawah.

Graph of mass of the conical flask and its content versus time
Graf jisim kelalang kun dan kandungannya melawan masa

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QUIZ 1_CHEM/F5

[3 marks]
(d) Based on the graph, calculate the instantaneous rate of reaction at 120
seconds.
Berdasarkan graf, hitungkan kadar tindak balas pada saat ke 120

[3 marks]
(e)

(i) Calculate the mass of carbon dioxide gas produced.

Hitungkan jisim gas karbon dioksida yang dihasilkan

[1 mark]
(ii) Calculate the expected volume of gas produced at room condition.
[1 mol of gas occupies 24 dm3 at room condition; relative molecular mass
of CO2 is 44 ]
Hitungkan isipadu gas yang dijangka akan terhasil pada keadaan bilik.
1 mol gas menempati 24 dm3 pada suhu bilik ; jisim molekul relatif CO2 ialah

44

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QUIZ 1_CHEM/F5

[2 marks]
ESSAY QUESTION (20 MARKS)
(a)
A student carried out an experiment to investigate the effect of catalyst on
the rate of reaction.
Diagram 2 shows the decomposition of hydrogen peroxide in the presence
of manganese(IV) oxide.
Seorang pelajar menjalankan satu eksperimen untuk mengkaji kesan
mangkin ke atas kadar tindak balas.
Rajah 8 menunjukkan penguraian hidrogen peroksida dengan kehadiran
mangan(IV) oksida.

Diagram 2
Rajah 2
Using Collision Theory, explain the effect of manganese(IV) oxide on the
decomposition of hydrogen peroxide.
Dengan menggunakan Teori Perlanggaran, terangkan kesan mangan(IV)
oksida ke atas penguraian hidrogen peroksida .
[5 marks]
[5 markah]
(b)

A student carried out two experiments to determine the time taken to

collect a maximum volume of 50 cm3 of gas.
Table 2 shows the result of the experiments.
Seorang pelajar menjalankan dua eksperimen untuk menentukan masa
yang diambil bagi mengumpul isipadu maksima gas sebanyak 50 cm 3.
Jadual 2 menunjukkan keputusan eksperimen tersebut.
Experime
nt
Eksperim
en

Reactant
Bahan tindak balas

Time,
s
Masa,
s

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QUIZ 1_CHEM/F5

50 cm3 of 1-volume hydrogen peroxide

solution and 1 g manganese(IV) oxide
50 cm3 larutan hidrogen peroksida 1-isipadu
dan 1g mangan(IV) oksida
25 cm3 of 2-volume hydrogen peroxide
solution and 1 g manganese(IV) oxide
25 cm3 larutan hidrogen peroksida 2-isipadu
dan 1g mangan(IV) oksida
Table 2
Jadual 2

II

(i)

(ii)

40

20

Draw a labelled diagram of the apparatus set up for the

experiment.
Lukiskan gambar rajah berlabel bagi susunan radas eksperimen
tersebut.
[2 marks]
[2 markah]
Sketch the graph for the gas liberated against time for Experiment
I and Experiment II on the same axes.
Lakarkan graf isipadu gas terbebas melawan masa pada paksi
yang sama bagi Eksperimen I dan Eksperimen II.
[2 marks]
[2 markah]

(iii)

Calculate the average rate of reaction for both experiments.

Tentukan kadar tindak balas purata bagi kedua-dua eksperimen.
[2 marks]
[2 markah]

(iv)

Compare the rate of reaction between Experiment I and

Experiment II. Explain the differences based on Collision Theory.
Bandingkan kadar tindak balas antara Eksperimen I dan
Eksperimen II. Terangkan perbezaan tersebut berdasarkan Teori
Perlanggaran.
[5 marks]
[5 markah]

(v)

Calculate the concentration in mol dm-3 hydrogen peroxide used in

Experiment I in order to produce 50 cm 3 of oxygen.
Hitung kepekatan hidrogen peroksida dalam mol dm -3 yang
digunakan dalam Eksperimen I untuk menghasilkan
50 cm 3
oksigen.
[Molar volume of gas = 24 dm3 mol-1 at room conditions]
[ Isipadu molar gas = 24 dm3 mol-1 pada keadaan bilik]
[4 marks]
8

QUIZ 1_CHEM/F5

[4 markah]

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QUIZ 1_CHEM/F5

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QUIZ 1_CHEM/F5