Beruflich Dokumente
Kultur Dokumente
6-1
D=
Xd =
53.85
0.91
R=
q=
E(ML) =
0.288
0.45
1
lb mol/hr
2000 0.0
1. 0
H or h
Axis Title
0. 8
100
0.5
lb mol/hr
0. 4
500 0.0
0. 2
0.0
0. 0
0.0
0.2
0.4
0.6
Axis Title
Qr = 927826.4567 BTU/hr
Qc = -97849.459
1500 0.0
1000 0.0
0. 6
F=
Xf =
0.8
1.0
Y or X
W = 46.15 lbmol/hr
Xw = 0.0215
Number of Stages Required13
BTU/hr
Ponchon-Savarit Diagram >>>>>>>>
Equilibrium and Enthalpy Data
Equilibrium
Point #
X
Y
0
0.000
0.000
1
0.010
0.253
2
0.020
0.425
3
0.050
0.624
4
0.100
0.755
5
0.150
0.798
6
0.200
0.815
7
0.300
0.830
8
0.400
0.839
9
0.500
0.849
10
0.600
0.859
11
0.700
0.874
12
0.800
0.898
13
0.900
0.935
14
1.000
1.000
Enthalpy
X or Y
0.000
0.020
0.050
0.100
0.300
0.500
0.600
1.000
1.000
1.000
1.000
units= BTU/lb-mol
h
H
0
17510
-433
17210
-776
16950
-1047
16650
-840
15690
-391
14975
-262
14600
0
12980
0
12980
0
12980
0
12980
Feed
100
0.5
hF(sat liq)
-391
HF(sat vap)
14975
h'F
8060.3
mol/hr
Xf
Qr
927826.46
Qc
-97849.459
R=
q=
E(ML) =
# of Stages
0.288
0.45
1
13
Tray
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
0.83243
0.77933
0.73267
0.68836
0.62905
0.52738
0.32794
0.14876
0.11377
0.10713
0.09144
0.04886
0.01111
-
0.91
0.89304
0.88184
0.87225
0.86336
0.85174
0.83251
0.79694
0.76684
0.76113
0.73258
0.61642
0.27216
done
-
McCabe-Thiele Plot
Distillate
53.85 mol/hr
0.91 Desired Xd Enriching Line
y =
0.224
Ponchon-Savarit Plot
x +0.707
Stripping Line
y =
4.212
x +-0.069
q line
y =
x +0.909
-0.818
Intersection (q,enriching)
x =
0.194
y =
0.750
Bottoms
46.15 mol/hr
0.0215 Desired Xw
Determine Quadratic Least Squares Fit for the Enthalpy Curves
Saturated Liquid
X_1 =
1
1
1
1
1
1
1
1
1
1
1
0.00
0.02
0.05
0.10
0.30
0.50
0.60
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.01
0.09
0.25
0.36
1.00
1.00
1.00
1.00
XT_1 =
1
0.00
0.00
1
0.02
0.00
1
0.05
0.00
f_1 =
1
0.10
0.01
1
0.30
0.09
0
-433
-776
-1047
-840
-391
-262
0
0
0
0
1
0.50
0.25
1
0.60
0.36
1
1.00
1.00
1
1.00
1.00
1
1.00
1.00
1
1.00
1.00
1
0.60
0.36
1
1.00
1.00
1
1.00
1.00
1
1.00
1.00
1
1.00
1.00
a_6 = -518.42945179
a_5 = -708.88566906
a_4 = 1252.35357133
Saturated Vapor
X_2 =
1
1
1
1
1
1
1
1
1
1
1
0.00
0.02
0.05
0.10
0.30
0.50
0.60
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.01
0.09
0.25
0.36
1.00
1.00
1.00
1.00
XT_2 =
1
0.00
0.00
1
0.02
0.00
1
0.05
0.00
f_2 =
1
0.10
0.01
1
0.30
0.09
17510
17210
16950
16650
15690
14975
14600
12980
12980
12980
12980
1
0.50
0.25
a_3 = 17301.9993582
a_2 = -5247.9716308
a_1 = 936.622683233
Data points for use on McCabe-Thiele (MT) plot - Only one decimal place used for the sake of clarity
x
45 Degree line
Equilibrium line
Stripping line
Enriching line
q line
0.0
0.0
0.0
0.0
0.0
0.3
0.0
0.0
0.4
0.1
0.1
0.6
0.1
0.1
0.8
0.2
0.2
0.8
0.2
0.2
0.8
0.3
0.3
0.8
0.4
0.4
0.8
0.5
0.5
0.8
0.6
0.6
0.9
0.7
0.7
0.9
0.8
0.8
0.9
0.9
0.9
0.9
1.0
1.0
1.0
0.2
0.7
0.0
0.0
0.2
0.8
0.9
0.9
0.5
0.5
0.2
0.8
equil
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.3
0.3
0.6
0.6
0.7
0.7
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
Data points for use on enthalpy-concentration plot - Only one decimal place used for the sake of clarity
x
Sat. liquid data Sat. vapor data Sat. liquid correlation
Sat. vapor correlation
Equil. (PS) h
0.0
0.0
17510.0
-518.4
17302.0
0.0
0.0
-433.0
17210.0
-532.1
17197.4
0.0
0.1
-776.0
16950.0
-550.7
17041.9
0.0
0.1
-1047.0
16650.0
-576.8
16786.6
0.0
0.3
-840.0
15690.0
-618.4
15811.9
0.0
0.5
-391.0
14975.0
-559.8
14912.2
0.0
0.6
-262.0
14600.0
-492.9
14490.4
0.0
1.0
0.0
12980.0
25.0
12990.7
0.0
1.0
0.0
12980.0
25.0
12990.7
0.0
1.0
0.0
12980.0
25.0
12990.7
0.0
1.0
0.0
12980.0
25.0
12990.7
0.0
0.0
0.0
0.0
0.0
0.3
0.0
0.6
0.1
0.7
0.1
0.8
0.1
0.8
0.1
0.8
0.3
0.8
0.5
0.9
0.6
0.9
0.7
0.9
0.7
0.9
0.8
0.9
0.8
0.9
H
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
-526.2
15943.1
-550.1
14423.0
-572.8
13960.1
-580.0
13850.2
-582.9
13828.4
-596.2
13714.6
-616.2
13582.1
-544.0
13511.6
-468.8
13469.3
-413.0
13437.0
-365.5
13402.5
-310.3
13362.3
-240.7
13302.0
Mass balance
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.3
0.0
0.6
0.0
0.7
0.9
0.1
0.9
0.1
0.9
0.3
0.9
0.5
0.9
0.6
0.9
0.7
0.9
0.7
0.9
0.8
0.9
0.8
0.9
0.9
H
-2570.6
17189.6
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
-2570.6
15943.1
-2570.6
14423.0
-2570.6
13960.1
17169.3
-582.9
17169.3
-596.2
17169.3
-616.2
17169.3
-544.0
17169.3
-468.8
17169.3
-413.0
17169.3
-365.5
17169.3
-310.3
17169.3
-240.7
17169.3
-126.4
Feed line
0.0
0.5
0.9
-2570.6
8060.3
17169.3
Notation
(1) Color convention
Black line in McCabe-Thiele plot denotes y=x line
Black lines in Ponchon-Savarit plot denote enthalpy-concentration lines
Blue-colored values denote spreadsheet-calculated values
Blue line in McCabe-Thiele and Ponchon-Savarit plots denote stage steps
Green line in McCabe-Thiele plot denotes equilibrium line
Magenta line in McCabe-Thiele plot denotes q line
Red line in McCabe-Thiele and Ponchon-Savarit plots denote operating lines
Yellow boxes denote required data entry
(2) Variable Descriptions
a_i
alpha
b_e
b_q
b_sat_liq
b_sat_vap
D
E(ML)
enth_h_i
enth_Hi
equil_x_i
enth_xy_i
equil_y_i
F
f_1,2
H_del_D
H_del_W
h_i
hF
hF_sat_liq
HF_sat_vap
liq_hA
liq_hB
m_e
m_i,b_i,y1_i,y2_i
m_q1
m_q2
m_sat_liq
m_sat_vap
mintray_op_i
mintray_equil_i
ps_equil_hi
ps_equil_Hi
ps_massbal_hi
ps_massbal_Hi
q
Qc
Qr
R
root_i
sat_liq_constant_term
sat_liq_x_term
sat_liq_xsquared_term
slope,m
stage_number
stages
step_equil_i
step_op_i
W
vap_HA
vap_HB
X_1,2
X_del_D
X_del_W
Xd
Xf
Xint_q_enrich
Xint_q_equ
Xs
XT_1,2
Xw
xx_i
y_i
Yint_q_enrich
Yint_q_equ
Equilibrium (tie line) point i on saturated vapor line on Ponchon-Savarit stage steps
Equilibrium (tie line) point i on saturated liquid line on Ponchon-Savarit stage steps
Mass balance point i on saturated vapor line on Ponchon-Savarit stage steps
Mass balance point i on saturated liquid line on Ponchon-Savarit stage steps