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9 Bohr
1 ( )
.
.
En
2,18 10 18 J
n2
2 ( )
, .
f Ei
(n): (
). : n = 1, 2, 3 ,
:
(). : 0, 1, 2, , n - 1.
:
x, y, z. : -l, ..., 0, ..., +l.
spin (ms): .
: ms = +1\2.
Pauli
"
.
.
"
,
,
.
und
" ,
spin,
spin".
9 Moseley
"
"
( )
.. s, p, d f.
T s: ns1
ns2 s , 1 2.
T p: ns2
npx p , II V
13 18.
T d: ns2
n 1dx d , VB 3 12.
T f: ns2
n 2fx f , .
.
.
.
.
.
.
9
.
.
..
Ca(OH)2 o Ca
2
2OH
(..
) .
, .
..
HCl H2O o H3O Cl
HCN H2O R H 3O CN
9 - rrhenius
: 3+ ( +).
..
HF H2O R H 3O F
: .
..
NaOH o Na OH
9 - ronsted - Lowry
: .
: .
..
NH3 H2O R NH+
N
N
N
N 4 OH
9
2 2 R 3
9
9 -
: Cl, HBr, HJ, HNO3, HClO4, H2SO4 ( ).
: 3, (.. RNH2).
9 M -
()
mol mol
.
mol
mol
0<<1
( )
( )
( ).
(a Kb)
: 2 R 3
[H3O ] [OH ]
[HA]
: B H2O R BH OH
Kb
[BH ] [OH ]
[B]
( ).
9 Ostwald
Ka
2C
(1 )
a
A d 0,1 d 0,01 a = 2C.
C
-
a Kb = Kw
9
, .
.
..
3 2 R 4
4+.
4Cl o NH 4 Cl
9
pH , .
T (/)
(/+)
..
CN, NaCN
NH3, NH4Cl
pH
pH
pK a log
C
C
pOH=pK
log
pH , .
, ,
pH.
..
H
N
2 R 3
N
2
pH pKa H 1 .
pH ! pKa H 1 .
9
1. o
.
i) - (.. , Cl Cl, Br Br)
C2 + 2 o C2+2
C2 + 2 o C22
C2 + o C2+1
C2 + 2 o C2+1
Markovnikov: T
.
2.
.
i) (.. , Cl Cl, Br Br)
C22 + 22 o C2+2
C22 + 22 o C224
C22 + 2 o C22
3. (
) .
:
: 2, CN, RMgX.
M RMgX :
(HCH=O) (RCH2 OH)
, HCH=O, (
Grignard (RMgX) g
RX.
9
1. .
C2+1 + aO
C2 +NaX + H2O
2. .
C22 + 2aO
3. .
C2+1
C2 + H2O
2
.
9
1.
i) RX + gOH oROH + AgX
ii) RX + NaCN o RCN + NaX
RCN + 2H2O
RCOOH + NH3
( )
( )
( o)
iii)
iv)
v)
vi)
RX
RX
RX
RX
+
+
+
+
(
(
(
(
)
)
)
)
2.
R + SOCl2 o RCl + SO2 + HCl ( )
3.
RCOR + 2
RC + ROH
4.
CH4 + Cl2 o CH3Cl +
CH3Cl + Cl2 o CH2Cl2
CH2Cl2 + Cl2 o CHCl3
CH3Cl + Cl2 o CCl4 +
HCl
+ HCl
+ HCl
HCl
9
1. .
CH2=CH2
( CH2 CH2 )
CH3
CH3 CH=CH2
Cl
CN
2. 1,4
CH3 -
Cl -
H-
9 A
1.
n4
2Cr27. n4 .
i)
O
H2 O
O
R CH2OH
oR
CH
O o R
COOH
ii)
R1
R1
O
CH OH
C O
o
H2 O
R2
R2
..
5RCH2OH 4KMnO 4 6H 2SO 4 o 5RCOOH 2K 2SO 4 4MnSO 4 11H 2O
3
R1
R1
C O K SO Cr (SO ) 7H O
CHOH K Cr O 4H SO o3
2
4
2
4 3
2
2 2 7
2
4
R2
R2
2.
Fehling Tollens.
O
R
CH
O o R
COOH
..
RCHO 2CuSO 4 5NaOH o RCOONa Cu 2O p 2Na 2SO 4 + 32
RCHO 2AgNO 3 3NH 3 H 2O o RCOONH 4 2Ag p 2NH 4NO 3
HCOONa o CO
COOH
COOH
I
o CO 2,
I
o CO 2
COOH
COOH
..
5HCOOH 2KMnO 4 3H 2SO 4 o 5CO 2 2MnSO 4 K 2SO 4 8H 2O
9 A
i) 2
Ni, Pt, Pd
CH2 H2
o CH
CH2
CH
Ni, Pt, Pd
HCCH 2H 2
o CH 3 CH
ii) 2
Ni
R1
C
Ni
O H2 o
R
CH OH
iii) 2
CH3CN 22 o C 3C 2 2
9
RCOOH, C6H5OH, ROH, RC {CH.
: RCOOH > C6H5OH > ROH > RC { CH.
i) RCOOH
RCOOH NaOH o RCOONa H 2O
2RCOOH Na 2CO 3 o 2RCOONa CO 2 H 2O
1
RCOOH Na o RCOONa H 2
2
RCOOH NH 3 o RCOONH 4
ii)
C6H5OH
1
H
2
iii) ROH
ROH Na o RONa
1
H2
2
iv) RC { CH
1
RCCH Na o RCCNa H 2
2
9 A
:
RNH2, RCOO, RO, RC {C, R, C6H5O
..
RNH2 HCl o RNH 3Cl
R1
R1
R2
NH HCl o
R2
NH2Cl
9
1. 2
R CH CH 3 X 2 o R C CH 3 2HX
I
II
OH
O
2. CH3
R C CH3 3X 2 o R C CX 3 3HX
II
II
O
O
3. CX3 O
RCCX 3 OH o RCOO CHX 3
II
O
C 2 1 CH CH 3 t 0 :
I
OH
C 2 1 CH CH 3 4X 2 6NaOH o CHX 3 C 2 1COONa 5NaX 5H 2O
I
OH
C 2 1 C CH 3 t 0
II
: