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R - butyrolactone 79-50-99.90% of 200 kg/barrels of imported 18000 yuan/ton Shan

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The basic information
English name gamma Butyrolactone. Alias 4 - Hydroxybutyric acid gamma - lactone; Bio. Endo - cis - 5 - Norbornene
- endo - 2, 3 - dicarboxylic anhydride
Product name gamma - butyl ester; 4 - hydroxy butyric acid lactone
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The molecular structure
Molecular formula C4H6O2
The molecular weight of 86.09
The CAS login number 96-48-0
EINECS registration number 202-509-5
FEMA login number 3291
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The chemical and physical properties

The density of 1.12

Melting point - 45 oC
The boiling point of 204-205 oC
The refractive index of 1.4355 to 1.4355
Flash point 98 oC
Water soluble MISCIBLE

descriptors

Colorless transparent oily liquid, has the certain moisture absorption and sligh
t odor. With water, alcohol, ester, ether, acetone and aromatics miscibility, sl
ightly soluble in straight-chain alkanes and naphthene. Freezing point 43.53 , the
boiling point of 206 (101.3 kPa), 89 (1.6 kPa), relative density 1.129 (20/4 ), th
refractive index of 1.4362. Flash point (cup) 98 , flash point 455 . Can with water
vapor volatilization, in thermal decomposition in alkaline solution.

Production methods

1. Maleic anhydride hydrogenation method, the method is advanced technology in t

he development of the 70 s, with a hydrogenation reaction, can be in any scale p
roduction of tetrahydrofuran and gamma butyrolactone, usually is the percentage
of four chlorine furan: gamma butyrolactone = 3-4:1. Production enterprise is mo
re, but the scale is small, an average of 300 t/a. The capacity of domestic tota
l capacity of up to 30%. 2.1, 4 - butyl glycol dehydrogenation reactor is shell
and tube type, packing sheet copper catalysts (in zinc oxide as a carrier). Cont
rol the reaction temperature 230-240 . Reaction product coarse gamma butyrolactone
by vacuum distillation and finished products, yield of above 77%.

use

Gamma butyrolactone is a kind of strong solubility, non-toxic, safe and convenie

nt to use the management of high boiling point solvents, used for butadiene, aro
matic hydrocarbons in petroleum processing, high-grade grease extraction agent;
Used for acrylic fiber spinning solvent in the chemical fiber industry, such as
wool, nylon, acrylonitrile fiber dyeing auxiliaries. In organic synthesis, GBL a
lso has a wide range of USES, it is a synthesis of alpha pyrrolidone, N - methyl
pyrrolidone, vinyl pyrrolidone, acetyl - gamma butyrolactone, ring and other ra
w materials, is a synthetic pesticides, herbicides, drugs within the brain, cipr
ofloxacin, vitamin B1, such as chlorophyll intermediates. Butyric acid is also u
sed in synthesis of chlorobenzene oxygen radicals class herbicides, plant growth
regulator.