Solutions

1
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ANSWERS, HINTS & SOLUTIONS
HALF COURSE TESTV
(MAIN)
Q. No.
1.
PHYSICS
A
CHEMISTRY
A
MATHEMATICS
A
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
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website: www.fiitjee.com
2
Physics
PART I
SECTION A
1.
2.
3.
4.
5.
6.
For isochoric process P T

P T
P
T
TP
1 100
T=
=
= 250 K.
P
0.4
1
P = 2 a2 v
2
T
2v
and v
2
P0(r ) + weight of liquid above sphere.
K
b2
m 4m2
Ishell + Ielement = 0
1
1 1
m2 (A 2 x 2 ) m2 x 2
2
3 2
'
3
A = A sin t
2
t = 2/3 sec
x
7.
20 6
(i)
2 m/s
7
1
1
1
1
(ii)
5(4)2 (2)(3)2 5v12 2v 22
2
2
2
2
5v 2v 2
(iii)
v CM 2 1
7
Solving (ii) and (iii), we lead to desired result.
v CM
8.
From centre of mass frame
9.
mv 2
T
r
3(4)2
T
120N , where x = 2/5
(2 / 5)
10 15
where, v CM
1 m/s
5
v 2 u2 = kt2/2m
10.
Momentum conservation
12i 6j 5 v
5m/s
cm
3kg
2kg
x
1x
5m/s
12i 6j
m/s
v
5
So, tan = 6/12
= tan1(1/2)
60
x
3
1
1 5(144 36) 1
1
2
2

3 4 2 3 = 180 (33) 15J
25
2
2
2
10
4m 2
2m2 when (m = )
3
11.
12.
13.
2F cos 60 = 3g + 2g
1
2FS 3g 2g
2
Fs = 50
2
So, a = 50/3 m/s

L r p
14.
a cos
a sin

av
v

av
29
1RT1
M1
2RT2
M2
30
P(x,t) F
y y
x t
4
Chemistry
PART II
SECTION A
1.
Velocity of electron in nth orbit of H like atom is given by:

2
2.18 10 6 m / s
n
For second orbit of He2+ ion:
Z = 2, n = 2
Velocity of electron = 2.18 106 m/s
2.
Cross Cannizzaro reaction will occur.
3.
Percentage of SN2 =
RateSN2
100
rate SN2 rate SN1
4.74 105 R X OH
4.74 10 5 R X OH 0.24 10 5 R X
100
= 1.93
4.
OH
CH2
CH3
O
H
CH2
H3 O
CH3
CH3
5.
OH
OH
CH3
n2 a 0
Z
r0 n2
rn
r3 9
r1 1
r3 9r1 9x
nh
2
nh
mv =
2 rn
mvrn
3h
h
2 9x 6x
h
6x
mv
6.
Because methanoic acid contain both aldehydic as well as carboxylic group.
7.
Si-F bond is stronger than C-F bond due to the donation of electron from F to Si gives rise to
p-d bonding.
5
8.
N2:
Bond order =
B.E A.B.E
2
10 4
3
2
CN is isoelectronic with N2 & hence same B.O.
9.
Bond length rNa rCl
10.
11.
13.
x y
2 2
+
The distance of closest approach between Cs & Cl.

i.e. the half of the body digonal.
a 3
=
2
a 3
1.69 1.81
2
3.50 2
7
a=
3
3
CaCO3 SiO 2
CaSiO3 CO2
flux
Impurity
slag
H3C
CH
CH CH2
H3C
CH
CH CH2
H3C
CH
Br
Br
H3C
cis
CH CH2
CH
CH CH2
trans
R
3+
S
2+
2+
14.
Except TiCl4 all other metal ion Fe , Cu & Mn contains unpaired electron & are coloured.
15.
CdS is yellow solid.
16.
Q=it
= 2 1.93 10 4
2 1.93 10 4
0.4F
96500
23.8
Number of moles of till will deposite =
0.2 mole
119
0.4
Oxidation state Sn
2
0.2
Number of Faraday
17.
In basic medium:
7
K MnO 4 K 2 MnO 4 ;
n factor 1
6
Let volume strength of H2O2 = x ml

Now meq of KMnO4 = meq of H2O2
7.9
x
1000 200
158 / 1
5.6
7.9 1000 200x
158
5.6
5.6
x=
1.4
4
18.
N Vbase = N Vacid
40 95 39 100
40
82 / n
95 82
n
2
39 100
19.
is inversely porportional to concentration.
20.
1 moles of C2H5OH = 1 mole of HCO2

= 1 4 eq of HCO2
n factor for C2H5OH = 4
M
EC2H5 OH
4
Also,
4 moles of I2 = 1 mole of CHI3
1
1 mole of I2 = mole of CHI3
4
1
8 eq CHI3 2 eq I2
4
21.
By using:
1.85 10 5
kb

0.136
c
0.001
Hence,
OH C 103 0.136 1.36 104 M
pOH log OH log 1.36 104
= log 1.36 + 4 = 3.86

pH + pOH = 14
pH = 14 pOH = 14 3.86 = 10.14
22.
Ionic compound are generally combination of metals & non metals example CaCl2, while molecule
compound are generally composed of non metals only as in N2O & PCl5.
23.
Cr H2 O 6
contains three unpaired electron when as Fe CN6
electron. All other complexes have one unpaired electron each.
24.
The percentage of
10
5
Then percentage of
contains zero unpaired
B =x
11
5
B = 100 x
7
10x 100 x 11
100
10.81
x = 19
The ratio of
10
5
11
5
B 19
B 81
25.
The fact that they are non stoichiometric is related to their structure, which are similar. The CCP
structure differ only in the arrangement of Fe2+ and Fe3+ in the holes in the octahedral & tetrahedral
crystal.
26.
Percentage of gold
27.
22
100
24
1
CH3 CH2 OH Na
CH3 CH2 ONa H2
2
(A)
CH3
CH3
P
H SO2 HCl
y
H SOCl2
Cl
H
D
D
(B)
CH3
A B
H
OC 2H 5
D
28.
30.
0.693
5.46 1010 year 1
9
1.27 10
If the mass of 40Ar is 3.6 times that of 40K, then the
3.6 + 1 = 4.6 times that now present.
2.303
4.6
t
log
2.8 109 year
10
1
1
5.46 10 year
K
original mass of
40
K must have been
n-factor of Cr2O72 = 6
2
+
Equivalent of Cr2O7 needed = equivalent of N2H5 = 0.136
0.136
2
moles of Cr2O7 =
0.0227
6
8
Mathematics
PART III
SECTION A
1.
7 4 3
B positive proper fraction
B + B = 1
1 B = B
B(P + B) 7 4 3
7 4 3
= (49 48) = 1.
n
2.
3 2n 9n 1 8
8
8
8
n
C0 n C1 8 n C2 82...n Cn 8n 1
int eger
8
8
2n
3 1

8 8
3.
2
3
1 1
1 1 1
2 2 1 2x
2 2 1 2 2 2x
1 2x 1 x
2!
3!
r
1 1 1
2 2 1 ... 2 r 1 2x
Tr+1 =
r!
1
r 1 1
1
1 1 2 ... r 1 2r xr
2 2 2
2
r!
r
r
r 1.3.5... 2r 1 2 x
1
2r r!
r
r 1.3.5... 2r 1 x
1
r!
7
7 1.3.5...13 x
T8 1
7!
1/2
A3
A4
4.
We know, in hexagon centres angle is
2n 4 6 2 180
2n
360
60 and each angle.
6
A2
60
radius r = A0 A1
In A0 A1 A2
A A 2 A1A 22 A 0 A 22 1 1 A 0 A 22
cos120 0 1
2A 0 A1 .A1A 2
2.1.1
A0 A2 3
A5
120
A0
A1
(i)
9
similar in A0A5A 4 are have A0A4 =

(A0A1) . (A0A2) . (A0A0)
3 3 3 unit.
5.
We have
2 x x x
2x x
x x x x x x x

2
2 x x 2 x
x
x 2x
2
2
x 2 x x 2 x x 2 x
x 2 x
x x .
2
0 x 1
x 1
0 x 2
2
x = 0 (not possible) [x] = 0
[x] = 1, {x} = x [x]
1
x
2
0
2 1
.
2
2
Equation of C.O.C from (2 cos, 2 sin )
C.O.C = T
2x cos 2 sin y
1
4
3
Let mid point (h1. k1)
equation of chord T = s1
hx ky
h2 k 2
1
4
3
4
3
hx ky h2 k 2
4
3
4
3
compare both (i) & (ii)
cos 2 sin
2
1
4 3
h
k
h2 k 2
4
3
4
3
x 1
6.
cos
sin
h 12
2 3h 4k
12k
3h
4k
(i)
(ii)
6h
3h
(a cos , a sin)
4k 2
6k
2
3h 4k 2
now for locus

2
2
2
2 2
36(h + k ) = (3h + 4k )
2
2
2
2 2
36(x + y ) = (3x + 4y )
10
7.
G.P.
1st term a
common ratio r
201
ai a ar ar 2 ...ar 200
i1
625
a 1 r 201
(i)
1 r
Now,
201
1 1
1
1
1 1 1
1
ai a a ... a a a ar ... ar 200
i1
1
2
200
201
1 1
a r
201
1
1 1 r 201 1
1 625
1
a 1 r r 200 a a r 200
1
r
625
625
1
2
a101 625
8.
x = sec cos
dx
sec tan sin tan sec cos
d
also y = sec3 cos3
dy
3 sec 2 sec tan 3cos2 sin
d
3
3
= 3 tan (sec + cos )
2
dy
9 tan2 sec 3 cos3
d
dy
dx
2

tan2 sec cos
dx
d
dy
dy

dx
x 0
dx at
9.
9
nnz
bx + ay = ab
(i)
equation of line r to (i) passing through origin is
ax by = 0
(ii)
from (i) &(ii)
x2
a
ay ab
y
b
Given
x2 y2
y
1
1
1
2 2
2
a
b
c
x2
y2
2
x2 y2
x2 y2
x 2 y2
x
1
c2
x +y =c.
11
10.
T = s1 (mid point h1 k1)

2
ky 2a(x + h) = k 4ah
2
ky 2ax = k 2ah
ky 2ax
1
k 2 2ah
parabola (homogenisation)
2
y = 4ax
ky 2ax
2
y =4ax(1) = 4a 2
x
k 2ah
8a2 x 2
4ak
y2 2
2
xy 0
k 2ah k 2ah
angle b/w two pair of straight line
tan
2 h2 ab
ab
4 h2 ab
tan
tan2
a b
2ak 2
8a2
4 2
1 2
k 2ah
k 2ah
2
8a2
1 2
k 2ah
(8a2 + y2 2x)2 tan2 = 16a2 (4ax y2)
compare with
(32 + y2 4x)2 tan2 = 64(8x y)2
a = 2.
11.
(x 1) k(x 1) = 0
(x 1) [x 2 + x + 1 k] = 0
x = 1 or x2 + x + (1 k) = 0
for exactly two distinct real solution
either D = 0 1 4(1 k) = 0 1 4 + 4k = 0
3
k
4
1 (one root)
or x 2 x 1 k
2 other root
3 k = 0 k = 3.
12.
= (a + b c)(a + c b)
= 2(s c)2(s b)
tan
s b s c s b s c 1
s s a
A
2
tan A
2 A
1 tan
2
2 tan
12
1
4 8 .
2
15
1
1
4
tan 3 tan 5 tan 7
tan
4
4
4

+
4
S
4
8
16
32
1 1 1
1
+

4 8 16 32
1
4 1 2 1.
1 4 3 6
1
2
2b
b
Minimum values of f(x) would occur at x
1 b2
2 1 b2
2
13.
14.
m(b) = 1 b2
2 2
1 b
2b
1
1 b2
m b
15.
b
1
varies from (0, 1] as b varies from ( , ).
1
2
1 b
1 b2
y=x+2
Area of triangle
0 2 1
1 8 14
1
2 3 3
8 6 1
(0, 2)
p1
135
2 69 64
2 3
3
64
3
64
3 = 21.

16.
log3 x 1
8 14
P2 ,
45 3 3
y = 2x+10
0
(8, -6)
1 3log3 x
20
2 log33
3
log3 x 1 log3 x 2 0
2
put log3 x 1 t 2 log3 x t 2 1
2|t| 3(1 + t2) + 4 > 0
2|t| 3 3t2 + 4 > 0
2
3t 3|t| + |t| 1 < 0
1
2
|t| ,1 t [0, 1)
3
x [3, 9) 6 integers i.e. 3, 4, 5, 6, 7, 8.
13
17.
|x + 3|
18.
19.
|x + 3|-2
AB=A
2
f(x) = x ax + 4
D 0 a2 16 0 a 4 or a 4
f(2) 0 4 + 2a + 4 0 a 4
f(4) 0 16 4a + 4 0 a 5
a
and 2 4 ; 4 a 8
2
Also, if B = 0 then also A B = A
a2 16 < 0, a (4, 4).
(i)
(ii)
(iii)
(-3, 2)
-2
cos 1 2cos 2 1
1
2 cos 2
apply C & D
1 cos 1 2 cos 2 2cos 2 1
1 cos 1 2 cos 2 2cos 2 1

1 3(1 cos 2 )
3 tan2 2
2
1 cos 2
2
tan2 1
2 3.
tan2 2
2
tan2
20.
x y2
y2
5
1 0
y + 20y + 40y + 79y2 + 74y + 23 = 0

g(x1) . g(x 2) . g(x 3) . g(x4) . g(x5) = product of roots = 23
g(x1) . g(x2) . g(x3) . g(x 4) . g(x5) 30g(x 1x 2x 3x 4x 5)
= 23 + 30 = 7.
21.
y2
3
(a + b + c) = a + b + c + 2(ab + bc + ca)
1
ab + bc + ca =
2
Now, (ab + bc + ca)2 = a2b2 + b2c2 + c2a 2 + 2abc (a + b + c)
1
a2b2 + b2c 2 + c2a2 =
4
Hence a4 + b4 + c4 = (a2 + b2 + c2)2 2(a2b 2 + b2c 2 + c2a2)
1
.
2
14
22.
23.
24.
25.
sin x sin x 0
3

2 sin x cos 0
(i)
6
2
6 2

Now sin x 1,1 for x R hence (i) will be true.

6
2
x R if 2k 1
6 6
2
possible k = 1
2

2 6 2
3
4 p
p + q = 7.
3
q
f(x) = 3x 2 + 2px + q < 0 x , 1

3
3x 2 + 2px + q = (3x + 5)(x + 1)

2p = 8; p = 4 & q = 5 p + q = 9.
-5/3
A B 1
A B
tan
tan
2 3
2
using Napiers analogy
c
A B a b
tan
cot
2
2 ab
1
c
A B ab
tan
cot
3
2
2 ab
1
c ab
c
cot
cot
3
2 ab
2
a + b = 3a 3b
a : b : : 2 : 1.
-1
(i)
If cos1 x cos1 y cos1 z 3

cos1x = , cos1y = , cos1z =
x = 1, y = 1, z = 1.
Now z2004 = 1
x2003 = 1
then
x 2004 y 2004 z2004
1 1 1
6
x
2003
2003
z 2003
6
3 2 1.
1 1 1
26.
The vertices 0(0, 0)

m
1
A
,
, B(0,1)
mn mn
are (parallel OABC = 2Ar( OAB))
y=nx
y=mx+1
y=nx+1
y=mx
15
1 m
1
m
0
1
1 0 0 0
2 mn mn
m n
1
.
mn
P
27.
28.
29.
RPS =
XPQ = 90
PQX = ( PXQ = 90)
PRS or QPR (AA similarity)
PR RS
QP PR
PR2 = PQ . RS
PR PQ RS 2r PQ . RS .
90-
C
r
R
a > 2b > 0
Therefore, the two given circles do not intersect each other
common tangents can be direct or indirect. As y = b are direct common tangents
given line should be indirect common tangent. Clearly line y mx b 1 m2 will pass from pt
(a/2, 0) (mid-point of the centres of the circles)
2b
m
.
2
a 4b 2
(pq,(p+1)(q+1))
AH BC then h = pq
A
BH AC then k = pq
h+k=0
x + y = 0 is straight line
h
B
(-p, 0)
30.
y=0
C
(-q, 0)
a1 = h1 = 2, a10 = h10 = 3
3 = a10 = 2 + 9d d = 1/9
a4= 2 + 3d = 7/3
1
1
1
1
3 = h10
9D D
3 h10 2
54
1 1
1 1 7
6D
h7 2
2 9 18
a4 h 7 =
7 18
6.
3 7

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1

For isochoric process P T

From centre of mass frame

Velocity of electron in nth orbit of H like atom is given by:

Cross Cannizzaro reaction will occur.

Because methanoic acid contain both aldehydic as well as carboxylic group.

Bond length rNa rCl

The distance of closest approach between Cs & Cl.

CdS is yellow solid.

Let volume strength of H2O2 = x ml

is inversely porportional to concentration.

1 moles of C2H5OH = 1 mole of HCO2

pOH log OH log 1.36 104

= log 1.36 + 4 = 3.86

contains zero unpaired

K must have been

B positive proper fraction

We know, in hexagon centres angle is

similar in A0A5A 4 are have A0A4 =

now for locus

T = s1 (mid point h1 k1)

x [3, 9) 6 integers i.e. 3, 4, 5, 6, 7, 8.

1 cos 1 2 cos 2 2cos 2 1

y + 20y + 40y + 79y2 + 74y + 23 = 0

Now sin x 1,1 for x R hence (i) will be true.

f(x) = 3x 2 + 2px + q < 0 x , 1

3x 2 + 2px + q = (3x + 5)(x + 1)

If cos1 x cos1 y cos1 z 3

The vertices 0(0, 0)

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