Beruflich Dokumente
Kultur Dokumente
Version 3
Product name:
Product code:
1671542
Identified uses
Chemical plating of metals / Surface treatment
Uses advised against
No information available
Prepared By:
Product Safety Department (PSD), email: HES-Berlin@atotech.com
Category 2
Category 2A
Category 2
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Signal word:
Warning
Hazard statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements
P273 - Avoid release to the environment
P280 - Wear protective gloves/eye protection/face protection
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing
Other hazards
None known
Description:
Components
sulphuric acid
Weight %
1-2.5
CAS-No
7664-93-9
INDEX No
016-020-00-8
EC-No.
231-639-5
copper sulphate
0.1-1
7758-98-7
029-004-00-0
231-847-6
0.1-1
27206-35-5
248-324-3
REACH No.
01211945883820
01211952056640
GHS Classification
Skin Corr. 1A (H314)
Acute Tox. 5 (H303)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
Acute Tox. 3 (H301)
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)
Skin Sens. 1 (H317)
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For the full text of the H-Statements mentioned in this Section, see Section 16
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Components
sulphuric acid
Austria
TWA: 0.1 mg/m3
STEL: 0.2 mg/m3
copper sulphate
Australia
STEL: 3 mg/m3
TWA: 1 mg/m3
Bahrain
TWA: 1 mg/m3
STEL: 3 mg/m3
China
Carcinogenic to
humans
STEL: 2 mg/m3
TWA: 1 mg/m3
Czech Republic
TWA: 1 mg/m3
Ceiling: 2 mg/m3
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Denmark
TWA: 1 mg/m3
Finland
TWA: 0.2 mg/m3
STEL: 1 mg/m3
France
TWA: 0.05 mg/m3
STEL: 3 mg/m3
Germany
MAK: 0.1 mg/m3
Carcinogen: Category
4
Peak: 0.1 mg/m3
inhalable fraction
Pregnancy: no risk to
embryo/fetus if
exposure limits
adhered to
MAK: 0.1 mg/m3
Peak: 0.2 mg/m3
inhalable fraction
Pregnancy: no risk to
embryo/fetus if
exposure limits
adhered to
Hong Kong
TWA: 1 mg/m3
STEL: 3 mg/m3
TWA: 1 mg/m3
copper sulphate
Components
sulphuric acid
copper sulphate
Components
sulphuric acid
Hungary
TWA: 1 mg/m3
STEL: 1 mg/m3
STEL: 4 mg/m3
India
TWA: 1 mg/m3
Indonesia
NAB: 1 mg/m3
Ireland
TWA: 1 mg/m3
Italy
Japan
Korea
STEL: 0.6 mg/m3
TWA: 0.2 mg/m3
1A - Known Human
Carcinogen based on
human evidence,
limited to strong acid
mist
Lithuania
TWA: 1 mg/m3
STEL: 3 mg/m3
Malaysia
TWA: 1 mg/m3
The Netherlands
copper sulphate
Components
sulphuric acid
Norway
TWA: 0.1 mg/m3
Carcinogen
STEL: 0.3 mg/m3
Philippines
TWA: 1 mg/m3
Poland
TWA: 1 mg/m3
NDSCh: 3 mg/m3
Corrosive substance
Fetotoxicity
TWA: 0.2 mg/m3
Portugal
A2 - Suspected
Human Carcinogen
TWA: 0.2 mg/m3
Singapore
1 mg/m3 PEL
STEL: 3 mg/m3
Components
sulphuric acid
Slovakia
TWA: 0.1 mg/m3
Ceiling: 0.1 mg/m3
Slovenia
TWA: 0.05 mg/m3
Sweden
LLV: 1 mg/m3
STEL: 3 mg/m3
Spain
VLA ED: 1 mg/m3
VLA EC: 3 mg/m3
Taiwan
TWA: 1 mg/m3
STEL: 2 mg/m3
Components
Thailand
Turkey
United Arab
Emirates
TWA: 1 mg/m3
STEL: 3 mg/m3
United Kingdom
Vietnam
TWA: 1 mg/m3
TWA: 1 mg/m3
STEL: 2 mg/m3
TWA: 0.5 mg/m3
STEL: 1 mg/m3
copper sulphate
sulphuric acid
copper sulphate
Exposure controls
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liquid
Colour:
light blue
light green
Odour:
No information available
Odour Threshold
No information available
No information available
> 100
Not applicable
Evaporation rate:
No information available
Flammability
No information available
No information available
No information available
Vapour pressure:
ca. 23 hPa
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No information available
Water solubility
miscible
No information available
No information available
No information available
Viscosity:
No information available
Explosive properties:
Not applicable
oxidising properties
No information available
pH:
0.00 - 2.00
Relative density
1.010 - 1.030
Other information
VOC Content(%):
Not applicable
Solubility in other solvents:
No information available
Bulk density
No information available
Ignition temperature (C):
No information available
Solidification point (C):
Not required
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LD50/oral/rat
2140 mg/kg
300 mg/kg
> 2000 mg/kg
LC50/inhalation/rat
510 mg/m3 2h
No information available
-
LD50/dermal/rabbit
No information available
1000 mg/kg
-
Other information
Irritation
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Freshwater Algae
Components
copper sulphate
7758-98-7
bis-(3-sulfopropyl)-disulfide, disodium salt
27206-35-5
Water Flea
48 h EC50 0.02 mg/L
Log Pow
- 3.68
Mobility in soil
No known effect based on information supplied
Results of PBT and vPvB assessment
No information available
Other adverse effects
None known based on information supplied
IMDG
UN-No (IMO/IMDG):
Proper shipping name (IMDG):
Technical Name (IMDG):
Ems no.:
Hazard Class (IMO/IMDG):
Packing group (IMO/IMDG):
Marine pollutant:
Hazard Label (IMO/IMDG):
ADR/RID
UN-No:
Proper shipping name:
Technical Name (ADR):
Hazard Class:
UN3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
copper sulfate
F-A,S-F
9
III
P
9
3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
copper sulphate
9
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Packing group:
Classification Code:
Kemler Number (ADR):
ADR/RID-Labels
ICAO/IATA
UN3082
UN-No (IATA):
Proper shipping name (IATA): ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
copper sulfate
Technical Name (IATA):
9
Hazard Class (IATA):
III
Packing group (IATA):
9
Hazard Label:
Environmentally hazardous
Marine pollutant
Special precautions for users
None known
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
Further Information:
10-13
Substances currently restricted by WEEE/RoHS (European Directive 2012/19/EC , 2011/65/EC) or ELV (European Directive
2000/53/EC):
PBDE
-
PBB
-
CrVI
-
Hg
-
Pb
-
Cd
-
Please note: Current legislation restricting the use of certain substances applies to homogeneous material in finished
articles being supplied to the market. Substances deposited during surface finishing may have a composition (weight
percent) higher than the weight percent of the substance in the operating solution from which the deposit is made.
Atotech encourages its customers to implement systems to ensure their finished products comply with the regulations in
force.
All of the components in this product are on or exempt from the following inventories:
US TSCA, CANADA DSL / NDSL, Europe (EINECS/ELINCS/NLP), Australia, Korea, China, Japan.
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Revision
This data sheet contains changes from the previous version in section(s) - 3
Revision Date:
26.02.2014
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal
and release and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in
the text
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