Sie sind auf Seite 1von 23

JEE (Advanced), 2016

HALF COURSE TEST VII

ALL INDIA INTEGRATED TEST SERIES

FIITJEE Students From All Programs have bagged 33 in Top 100, 77 in Top 200 and 205 in Top 500 All India Ranks. FIITJEE Performance in JEE (Advanced), 2015:
4551 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.

FIITJEE

Paper 1
Time Allotted: 3 Hours

Maximum Marks: 246

Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .

INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.

Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part is further divided into three sections: Section-A, Section-B & Section-C
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.


1. Section A (01 07) contains 7 multiple choice questions which have only one correct answer.
Each question carries +3 marks for correct answer and 1 mark for wrong answer.
Section A (08 11) contains 4 multiple choice questions which have one or more than one
correct answer. Each question carries +3 marks for correct answer. There is no negative
marking.
Section-A (12 16) contains 2 paragraphs. Based upon paragraph, 2 and 3 multiple choice
questions have to be answered. Each question has only one correct answer and carries
+3 marks for correct answer and 1 mark for wrong answer.
2. Section B (01 02) contains 2 Matrix Match Type questions containing statements given in 2
columns. Statements in the first column have to be matched with statements in the second
column. Each question carries +8 marks for all correct answer. For each correct row +2 marks
will be awarded. There may be one or more than one correct matching. No marks will be given for
any wrong matching in any question. There is no negative marking.
3. Section-C (01 06) contains 6 Numerical based questions with answers as numerical value from
0 to 9 and each question carries +3 marks for correct answer. There is no negative marking.

Name of the Candidate

Enrolment No.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

2
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Useful Data

PHYSICS
Acceleration due to gravity

g = 10 m/s2

Planck constant

h = 6.6 1034 J-s

Charge of electron

e = 1.6 1019 C

Mass of electron

me = 9.1 1031 kg

Permittivity of free space

0 = 8.85 1012 C2/N-m2

Density of water

water = 103 kg/m3

Atmospheric pressure

Pa = 105 N/m2

Gas constant

R = 8.314 J K1 mol1
CHEMISTRY

Gas Constant

Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV

=
=
=
=
=
=
=
=
=
=

8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
6.023 1023
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
1.6 1019 J

Atomic No:

H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,


N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35,
Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

3
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Physics

PART I
SECTION A
Straight Objective Type

This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.

At the middle of the mercury barometer tube there is a little


column of air with the length l0 and there is vacuum at the top as
shown. Under the normal atmospheric pressure and the
temperature of 300 kelvin, l0 = 10 cm. Neglect expansion of the
tube. The length of the air column if the temperature rises to 330
Kelvin will be:
100
(A)
cm
(B) 11 cm
11
(C) 10 cm
(D) 12 cm

vacuum

air
column

l0

2.

Two cars A and B are moving towards each other with same speed 25 m/s. Wind is blowing with
speed 5 m/s in the direction of motion of car A. The car A blows horn of frequency 300 Hz and the
sound is reflected from car B. The wavelength of the reflected sound received by the driver of car A is
(velocity of sound in air = 330 m/s)
25
31
(A)
m
(B)
m
36
36
35
37
(C)
m
(D)
m
36
36

3.

A particle is moving along the x axis is acted upon by a single force F = F0ekx, where F0 and k are
constants. The particle is released from rest at x = 0. It will attain a maximum kinetic energy of :
F
F
(A) 0
(B) 0k
k
ke
kF0
(C) k
(D) kekF0
e
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

4
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

4.

First 10 cm piece of a uniform meter strick is cut and kept


on the other end as shown in figure. Find the shift in the
x-coordinate of center of mass
(A) 5 cm
(B) 10 cm
(C) 9 cm
(D) 45 cm

5.

A satellite is in a circular orbit very close to the surface of a planet with speed v 0. At some point it is
given an impulse along its direction of motion, causing its velocity to increase times (that is, its
speed becomes v 0). It now goes into an elliptical orbit. The maximum possible value of for
satellite to move in the elliptical orbit is:
(A) 2
(B) 2
1
(C) 2 + 1
(D)
2 1

6.

An elevator is moving upward with an acceleration a. It has velocity v at t = 0. A man inside the
elevator lifts a body of mass m through a height h in interval t = 0 to t = t0. The average power
developed by the man is in elevator ref. frame :
m(g a)h
1
(A)
(B) m(g + a) (v +
at0)
t0
2
mgh
1
(D) mg (v + at0)
t0
2
A thermally insulated vessel contains some water at 0C. The vessel is connected to a vacuum pump
to pump out water vapour. This results in some water getting frozen. It is given Latent heat of
5
5
vaporization of water at 0C = 21 10 J/kg and latent heat of freezing of water = 3.36 10 J/kg.
The maximum percentage amount of water that will be solidified in this manner will be :
(A) 86.2%
(B) 33.6%
(C) 21%
(D) 24.36%

(C)
7.

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

5
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Multiple Correct Choice Type


This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct
8.

As a wave propagates :
(A) The wave intensity remains constant for a plane wave
(B) The wave intensity decreases as the inverse of the distance from the source for a spherical wave
(C) The wave intensity decreases as the inverse square of the distance from the source for a
spherical wave
(D) Total power of the spherical wave over the spherical surface centered at the source decreases
with distance.

9.

A block of mass 2 kg is hanging over a smooth and light pulley through a light
string. The other end of the string is pulled by a constant force
F = 40 N. At t = 0 the system is at rest as shown. Then in the time interval from
2
t = 0 to t =
seconds, pick up the correct statement (s) : (g = 10 m/s2)
10
(A) tension in the string is 40 N
(B) work done by gravity is 20 J
(C) work done by tension on block is 80 J
(D) None of these

10.

11.

A solid cube of mass 5 kg is placed on a rough horizontal surface, in


xy-plane as shown. The friction coefficient between the surface and

the cube is 0.4. An external force F 3i 4j 20k N is applied on


2
the cube. (use g = 10 m/s
(A) The block starts slipping over the surface
(B) The friction force on the cube by the surface is 5 N.
(C) The friction force acts in xy-plane at angle 127 with the positive
x-axis in clockwise direction.
(D) The contact force exerted by the surface on the cube is 925 N

2kg

F=40N

x
An ideal monoatomic gas undergoes a processes in which P = 3V3. Choose the correct statements.
(A) If volume increases then temperature will also increase
(B) If temperature of the gas decreases, then pressure must also decrease.
(C) For expansion, heat will have to be supplied to the gas.
(D) If temperature increases then work done by gas is positive.

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

6
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Questions 12 and 13
In an organ pipe (may be closed or open) of 99 cm length standing wave is setup,
whose equation is given by longitudinal displacement
2
(y + 1 cm) cos 2(400) t
= (0.1 mm) cos
0.8
where y is measured from the top of the tube in meters and t in second.
Here 1 cm is the end correction.
12.

13.

The air column is vibrating in


(A) First overtone
(C) Third harmonic

(B) fifth harmonic


(D) Fundamental mode

Equation of the standing wave in terms of excess pressure is


(Bulk modulus of air B = 5 105 N/m2)
2
(A) Pex = (125 N/m2) sin
(y + 1 cm) cos 2(400t)
0.8
2
(B) Pex = (125 N/m2) cos
(y + 1 cm) sin 2(400t)
0.8
2
(C) Pex = (225 N/m2) sin
(y + 1 cm) cos 2(200t)
0.8
2
(D) Pex = (225 N/m2) cos
(y + 1 cm) sin 2(200t)
0.8
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

7
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Paragraph for Question Nos. 14 to 16

O
A rod of mass m and length l is free to rotate in a vertical plane about
fixed horizontal axis O passing through one end as shown in the figure. A
m
2l
sphere of mass
hits the rod elastically with horizontal speed v0 at a
4
3 m
4
2
distance
from O. Before collision, the rod is at rest in vertical position.
3
If we consider the sphere and the rod as a system, then gravity and force due to axis O are external forces.
For the rod alone, force exerted by O, gravity and impact force are all external forces. Similar conclusion can
be drawn for the sphere. Net external force on any system is equal to the product of the mass of the system
and the acceleration of the center of the mass of the system.
14.

The maximum angular deflection of the rod from the vertical after the collision is

5 v 20
3 v 20
(A) cos 1 1
(B) sin1 1

16 g
16 g

3 v 20
(C) cos 1 1
16 g

15.

16.

5 v 20
(D) sin1 1
16 g

The velocity of the sphere just after collision is


2v 0
(A)
7
2v
(C) 0
7

v0
2
v
(D) 0
2

(B)

Magnitude of the impulse on the rod exerted by the axis O during the collision is
3mv 0
(A) zero
(B)
8
3mv 0
3
(C)
(D) mv 0
14
7
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

8
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

SECTION B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given
in two columns which have to be matched. Statements (A, B, C, D) in column
I have to be matched with statements (p, q, r, s, t) in column II. The answers
to these questions have to be appropriately bubbled as illustrated in the
following example.
If the correct match are A-p, A-s, B-q, B-r, C-p, C-q and D-s, then the correctly
bubbled 4 4 matrix should be as follows:
1.

Match the following :


A block P of mass m placed on smooth horizontal surface and
connected with a spring. Another block Q of same mass is placed on
the block P.
The two blocks are pulled by a distance A and released. The blocks
oscillates without slipping on each other. Then match the matrix.
Column I
(A) Friction force on the block Q, When both block
coming towards equilibrium position form left.
(exclude the equilibrium position)
(B) Friction force at the block Q when both block
going right from equilibrium position. (exclude the
equilibrium position)
(C) Friction force will be maximum on Q.

Column II
(p) towards right

(D) Friction force on P when both block is coming


towards the equilibrium position from right.
(exclude the equilibrium position)

(s) at extreme position

Q
P

(q) towards left

(r) at equilibrium position

(t) none of these

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

9
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

2.

Match the following columns.


Column I

(A)

(p)

Column II
(Temperature T
in steady state)
50C

A spherical annular thermal resistor of


thermal conductivity K and inner and outer
radii 2R and 5R respectively, is in steady
state with its inner surface maintained at
100C and its outer surface maintained at
10C(heat flow is radially outwards). The
temperature of the concentric spherical
interface of radius 3R in steady state is T.

(q)

70C

A cylindrical and thermal resistor of inner


radius R and outer radius 8R is in steady
state with its inner surface maintained at
100C and its outer surface maintained at
10C(heat flow is radially outwards). The
temperature of the co-axial cylindrical
interface of radius 2R in steady state is T.

(r)

55C

(s)

25C

(t)

none of these

2K0

C
6K0

3K0

100C

10C

Three homogenous thermal resistors A, B and C, each of length ,


cross-sectional area A and thermal conductivity 2K0, 3K0 and 6K0
respectively are joined in series such that there is one dimensional
heat flow from left end (temperature 100C) to the right end
(temperature 10C). T is the temperature of the interface between
resistor B and C in the steady state.
(B)

5R

10C

100C
2R
3R
T

(C)

100C
2R

10C

T
R
8R

(D)

2L

6R

B
b

3R

100C

10C

A homogeneous thermal resistor whose outer surface is the frustom of


a solid cone, has the two base radii as 6R and 3R respectively and the
perpendicular distance between its, two bases is 3L. The two bases
are maintained at 100C and 10C. In the steady state(heat flows from
left end to the right end) the temperature of the interface at a distance
of 2L from the left end is T. Assume that L is very large in comparison
to R and the lateral surface of the cylinder is thermally insulated from
the surroundings. Find T.

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

10
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

SECTION C
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown

1.

Water at temperature 20 C flows from a tap T into a heated container C. The


container has a heating element (a resistor R) which is generating heat at the
rate of P, that may be varied. The rate of water in flow from trap is F = 0.16
cc/minute. The heat generated is sufficient so that the water in the container
is boiling and getting converted into steam at a steady rate. What is the
minimum power P (in watt) that must be generated as heat in the steady state
in resistor R so that the amount of liquid water in the container neither
increases nor decreases with time ? (Neglect other losses of heat, such as
conduction from the container to the air and heat capacity of container) For
water, specific heat c = 4.2 kJ.kg 1 K1, latent heat of vaporisation L vap=2.3
MJ.kg1 , density p = 1000 kg.m3.

2.

A cylinder of height h, diameter h/2 and mass M and with a


homogeneous mass distribution is placed on a horizontal
table. One end of a string running over a pulley is fastened
to the top of the cylinder, a body of mass m is hung from
the other end and the system is released. Friction is
negligible everywhere. At what minimum ratio m/M will the
cylinder tilt?

h/2
h M

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

11
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

3.

4.

Shown in the figure is a system of three particles connected by


two springs. The accelerations of A, B and C at any instant are A
1 m/sec 2, 2 m/sec 2 and (1/2) m/sec2, respectively, directed as
m1
shown in the figure. External force acting on the system is
(m 1 = 1kg, m 2 = 2kg and m 3 = 4kg)

a3

a2

a1
B

m2

m3

In a lawn a water sprinkler is sprinkling water in all the possible directions while rotating. What is
2
maximum area (in m ) on ground that can be sprinkled? The speed of water form nozzle is
1/ 4


400

2
m / s (g = 10 m/s )

5.

A horizontal board is being moved with a constant velocity v0 on a


smooth horizontal plane. A small block is projected on the block
with velocity v1 = 25 m/s at an angle = 37 relative to the
ground. The coefficient of friction between the block and the
board is = 0.3. If velocity of block (in m/s) relative to ground
after time t = 10 sec. is v than v/10 is equal to ..

6.

The 1/v versus displacement graph of a particle is shown in the


figure, where v is the speed of the particle. The particle is
moving in a straight line along positive x-axis. Calculate the time
taken (in seconds) by the particle to reach from the point A to B .

1/v (s/m)
B

x (m)

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

12
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Chemistry

PART II
SECTION A
Straight Objective Type

This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.

Find the equivalent weight of H3PO4 in the following reaction:

Ca OH 2 2H 3PO 4
Ca H2PO 4 2 2H2 O
(A) 98
(C) 32.7

(B) 49
(D) 37.2

2.

Which one of these does have greatest second ionization energy?


(A) B
(B) C
(C) Sr
(D) Ba

3.

Agaq 2NH3aq
Ag NH3 2 aq

What is the relationship between Kc and Ksp(AgCl)?


2

K sp NH3
1
(A)

K c Ag NH3 Cl

(C) K c

4.

Ag NH3 Cl

K sp Ag NH3 2

(D) K c
2

NH3 Cl

K sp Cl
Ag NH3 NH3 2
2

The shape of XeOF2 is similar to


(A) T
(C)

(B) K c

K sp NH3

(B)
(D)

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

13
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

5.

Find de Broglie wavelength of the electron in the first Bohrs orbit:


(A) 3 10 10 m
(B) 4 10 10 m
(C) 3 10 11m
(D) 4 10 11 m

6.

CH3
H3C

CH2 C

(A)

(C)

HBr / H2 O2
CH CH3

(B)

CH3
H3C

CH2 C

H3C

CH

Br
CH

Br

CH3

CH2 CH3

CH2 CH3

CH3
H3C

CH2 C

CH3

Br
CH3

(D)
H3C

CH2

CH

CH3

Br

7.

For the following reaction:

CO g

1
O2 g
CO2 g at 298K
2

The standard entropy change is 0.094 kJ mol1. The values of standard Gibbs free energy of
formation of CO2 and CO are 394.4 and 137.2 kJ mol1 respectively. The reaction is
(A) non-spontaneous, endothermic
(B) non spontaneous, exothermic
(C) spontaneous, endothermic
(D) spontaneous, exothermic
Multiple Correct Choice Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct
8.

Which of the following carbocation will be relatively more stable than benzyl carbocation?
(A)
(B)
CH2
Ph2CH
(C)

(D)

CH3
C
Ph

CH3

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

14
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

9.

Which of the following molecules/species contains atleast one atom with sp3 hybridization?
2
(A) ClO2
(B) SO3
3
(C) BO3
(D) H3PO3

10.

Which of the following is correct about the given reaction sequence?


H3 O
Hg OCOCH

/ THF, H O

Br2 / h
alc. KOH
NaOI
3 2
2

B
C
D E
A
NaBH , OH

(A)
(B)
(C)
(D)
11.

Molecular weight of (F) is nth multiple of weight of a methyl radical (where n = positive integer)
Compound (C) on heating with conc. H2SO4 gives (B)
Compound (B) can not exhibit position isomerism
Compound (A) can exhibit position isomerism

Chlorine gas is prepared in laboratory by the reaction:


K 2Cr2O7 HCl
KCl CrCl3 Cl2 H2O
If a 61.3 g sample of 96% K2Cr2O7 is allowed to react with 320 ml of hydrochloric acid solution having
density 1.15 g/ml and containing 30% HCl by mass. Now select the correct statement (s) among the
following:
(A) the mass of Cl2 generated is 42.63 g
(B) equivalent weight of K2Cr2O7 is 49 g
(C) equivalent weight of HCl is 85.16 g
(D) the stoichiometric coefficient of HCl is 14
Comprehension Type

This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 12 to 13
The decomposition of N2O5 is according to the equation:

2N2O5 g
4NO2 O2 g
is a first order reaction. After 30 minutes from the start of the decomposition in a closed vessel, the total
pressure is found to be 294.5 mm Hg. On complete decomposition the total pressure is 594.5 mm Hg. An
inert gas with partial pressure 10 mm Hg has always been present in vessel during decomposition of N 2O5.
12.

What is the pressure of the vessel before the beginning of decomposition of N2O5?
(A) 223.8 mm
(B) 233.8 mm
(C) 243.8 mm
(D) 253.8 mm

13.

What is the pressure of NO2 after 30 minutes?


(A) 67.6 mm
(B) 66.6 mm
(C) 65.6 mm
(D) 64.6 mm
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

15
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Paragraph for Question Nos. 14 to 16


Study following molecules before answering questions:
CH3

H
H3C

CH3

CH3

H3C

CH3

H
H3C

14.

What is the molecular formula of isomer of any of these molecules?


(A) C5H10
(B) C5H12
(C) C5H14
(D) C4H10

15.

The number of pairs of diastereomers are


(A) 1
(C) 3

16.

H
CH3

(B) 2
(D) 4

One of the seven cyclic isomers is missing. What is the number of C atom constituting the cyclic ring?
(A) 3 member ring, hence 3 C atoms
(B) 4 members ring, hence 4 C atoms
(C) 5 member ring, hence 5 C atoms
(D) 6 member ring, hence 6 C atoms
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

16
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

SECTION B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given in
two columns which have to be matched. Statements (A, B, C, D) in column I
have to be matched with statements (p, q, r, s, t) in column II. The answers to
these questions have to be appropriately bubbled as illustrated in the following
example.
If the correct match are A-p, A-s, B-q, B-r, C-p, C-q and D-s, then the correctly
bubbled 4 4 matrix should be as follows:
1.

2.

Match the following column I and column II:


Column I
(bond Order)
(A) 0
(p)
(B) 1.5
(q)
(C) 2.5
(r)
(D) 3
(s)
(t)
Match the following:
Column I
(Quantity)
(A)
(B)
(C)
(D)

Degree of dissociation
Pre-exponential factor
equation)
Rate of reaction
Activation energy

(Arrhenius

Column II
(Molecule)

N2
N2
CO
O2
He2

Column II
(Dimensions)
(T = Time, L = length, M = mol, W = mass)
(p)
T1
(q)
L0T0
(r)
(s)

M0L 0
M1L 3T1

(t)

W1L2T2

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

17
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

SECTION C
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown

1.

Number of possible cyclic alcohols with formula C 5H10O (excluding stereoisomer) is x than what is
x/2?

2.

The number of pure sigma bonds in Cr2O72 will be.

3.

Which number of hydrogen will be having least bond energy


with carbon in given below compound?

H (2)

H
(5)

H(1)

H (3)

H(4)

4.

Calculate the number of protons present in an acid whose 0.45 g requires 40 ml of N/2 KOH solution.
(MW = 90)

5.

The pH of blood stream is maintained by a proper balance of H2CO3 and NaHCO3 concentration. The
volume of 10 M NaHCO3 solution which is mixed with 10 mL sample of blood which is 4 M in H2CO3
in order to maintain a pH of 7.4 is x mL. Ka for H2CO3 in blood is 4 107. What will be the value of
x/10?

6.

If a mixture of 3 mol of H2 and 1 mole of N2 is completely converted in to NH 3, what would be the ratio
of the initial and final volume at same temperature and pressure?
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

18
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Mathematics

PART III
SECTION A
Straight Objective Type

This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.

Two consecutive sides of a parallelogram are 4x + 5y = 0 & 7x + 2y = 0. If one diagonal is


11x + 7y = 9, then equation of other diagonal is
(A) x + 2y = 0
(B) 2x + y = 0
(C) x y = 0
(D) none of these.

2.

The curve x + y = 3axy is symmetric about


(A) x-axis
(C) y = x

3.

4.

(B) y-axis
(D) none of these.

1
If mi , i = 1, 2, 3, 4 are con-cyclic points, then the value of m 1 m 2 m 3 m 4 is
mi
(A) 1
(B) 1
(C) 0
(D) none of these.
Coefficient of xr in the expansion of (1 2x) 1/2 is
2r !
(A)
(B)
2
r!
(C)

2r !
r! 2 22r

2r !
2
2r r!

(D) none of these.

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

19
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

1 3 9 27

...

2 8 32 128

5.

If w is a complex cube root of unity then w + w


(A) 1
(B) 0
(C) 9
(D) i.

is

6.

If 1 + a + a 2 + a3 + + ax = (1 + a)(1 + a2)(1 + a4) then x is


(A) 3
(B) 5
(C) 7
(D) 9.

7.

Ten persons, amongst whom are A, B and C to speak at a function. The number of ways in which it
can be done if A wants to speak before B and B wants to speak before C is
10!
(A)
(B) 3! 7!
6
(C) 10P3 . 7!
(D) none of these.
Multiple Correct Choice Type

This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct
8.

If (1+ x + x2) n = a 0 + a1 x + a 2x2 + +a 2n x2n, then the value of a0 + a 3 + a6 + .... is


(A) a 1+ a 4 +a 7 + ...
(B) a2+ a5 +a8 + ...
n-1
(C) 3
(D) none of these.

9.

One vertex of the triangle of maximum


|z 2 i| =2,is 2 +2i , remaining vertices is / are
(A) -1+ i( 2 + 3 )
(C) -1+ i( 2 3 )

area

that

can be inscribed

(B) 1 i( 2 + 3 )
(D) 1 i( 2 3 )

10.

If a, b, c be three unequal positive quantities in H.P. then


100
100
100
3
3
3
(A) a + c > 2b
(B) a +c > 2b
5
5
5
2
2
(C) a + c > 2b
(D) a + c > 2b2

11.

If

1 sin A = sin

(A) first
(C) third

in the curve

A
A
A
cos , then
could lie in quadrant
2
2
2 4
(B) second
(D) fourth

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

20
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 12 to 13
Read the following comprehension carefully:
Let f(n) denotes the number of different ways the positive integer n can be expressed as the sum of 1s and
2s. For example,
f(3) = 3, since 3 = 1 + 1 + 1 = 1 + 2 = 2 + 1
f(4) = 5, since 4 = 1 + 1 + 1 + 1 = 1 + 1 + 2 = 1 + 2 + 1 = 2 + 1 + 1 = 2 + 2.
Note that order of the appearance of 1s and 2s is important.
Now, answer the following questions:
12.

13.

The value of f(6) is


(A) 6
(C) 13

(B) 11
(D) 15

f{f(6)} is equal to
(A) 377
(C) 321

(B) 302
(D) 350
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

21
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

Paragraph for Question Nos. 14 to 16


Read the following comprehension carefully:
A coplanar beam of light emerging from a point source have equation x y + 2(1 + ) = 0, R. the rays of
the beam strike an elliptical surface and get reflected. The reflected rays form another convergent beam
having equation x y + 2(1 ) = 0, R. Further it is found that the foot of the perpendicular from the
2
2
point (2, 2) upon any tangent to the ellipse lies on the circle x + y 4y 5 = 0.
Now answer the following questions:
14.

The eccentricity of the ellipse is equal to


1
(A)
3
2
(C)
3

(B)

1
3

1
(D)
2

15.

The area of the largest triangle that an incident ray and the corresponding reflected ray can enclose
with the axis of the ellipse is equal to
(A) 4 5
(B) 2 5
(C) 5
(D) none of these

16.

Total distance travelled by an incident ray and the corresponding reflected ray is the least if the point
of incidence coincides with
(A) an end of the minor axis
(B) an end of the major axis
(C) an end of the latus rectum
(D) none of these
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

22
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

SECTION B
(Matching List Type)
This section contains 2 multiple choice questions. Each question has matching Column(s). The codes for
the Column(s) have choices (A), (B), (C) and (D) out of which only ONE OR MORE is/are correct
1.

Match the following Column-I with Column-II


(A)

(B)
(C)

(D)

2.

Column I
f(z) is a complex valued function f(z) = (a + ib)z where a, b R
1
and |a + ib| =
. It has the property that f(z) is always
2
equidistant from 0 and z, then a b =
The number of all positive integers n = 2a 3 b (a, b 0) such that
n 6 does not divide 6 n is
A is the region of the complex plane {z: z/4 and 4/ z have real
and imaginary part in (0, 1)}, then [p] (where p is the area of the
region A and [.] denotes the greatest integer function) is
2
If 3x + 4y + z = 5, where x, y, z R, then minimum value of26(x
2
2
+ y + z )is

Column II
(p)

(q)

(r)

(s)

25

(t)

10

Match the following Column-I with Column-II


Column I

Column II

sin cos x

(A)

cos sin x

(p)

xR

(q)

R n

(B)

(C)

tan( sinx)

(r)

(D)

ln(tanx)

(s)
(t)

x n, n

x 2n , 2n

2
2

x R n
8

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

23
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16

SECTION C
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown

1 1 1

... is .
4 8 16

1.

The value of alogb x when a = 0.2 b = 5 , x

2.

The value of c for which 2 2

3.

If coefficient of x7 in ax 2
bx

4.

In a ABC, a cos(B C) + b cos(C A) + c cos (A B) = (abc) k then k is

5.

The line L passes through the points of intersection of the circles x2 + y2 = 25 and
2
2
x + y 8x + 7 = 0. The length of perpendicular from centre of second circle onto the line L is .

6.

If the lines ax + y + 1 = 0, x + by + 1 = 0 and x + y + c = 0 are concurrent then

11

7
, where and are the roots of 2x2 + 7x + c = 0 is .
4
11

is equal to coefficient of x7 in ax 2 , then ab = ..


bx

1
1
1


1 a 1 b 1 c

(given a, b, c are distinct and different from 1)


Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

Das könnte Ihnen auch gefallen