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FIITJEE
Paper 1
Time Allotted: 3 Hours
Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part is further divided into three sections: Section-A, Section-B & Section-C
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Enrolment No.
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
Useful Data
PHYSICS
Acceleration due to gravity
g = 10 m/s2
Planck constant
Charge of electron
e = 1.6 1019 C
Mass of electron
me = 9.1 1031 kg
Density of water
Atmospheric pressure
Pa = 105 N/m2
Gas constant
R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant
Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV
=
=
=
=
=
=
=
=
=
=
8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
6.023 1023
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
1.6 1019 J
Atomic No:
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
Physics
PART I
SECTION A
Straight Objective Type
This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.
vacuum
air
column
l0
2.
Two cars A and B are moving towards each other with same speed 25 m/s. Wind is blowing with
speed 5 m/s in the direction of motion of car A. The car A blows horn of frequency 300 Hz and the
sound is reflected from car B. The wavelength of the reflected sound received by the driver of car A is
(velocity of sound in air = 330 m/s)
25
31
(A)
m
(B)
m
36
36
35
37
(C)
m
(D)
m
36
36
3.
A particle is moving along the x axis is acted upon by a single force F = F0ekx, where F0 and k are
constants. The particle is released from rest at x = 0. It will attain a maximum kinetic energy of :
F
F
(A) 0
(B) 0k
k
ke
kF0
(C) k
(D) kekF0
e
Space for rough work
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
4.
5.
A satellite is in a circular orbit very close to the surface of a planet with speed v 0. At some point it is
given an impulse along its direction of motion, causing its velocity to increase times (that is, its
speed becomes v 0). It now goes into an elliptical orbit. The maximum possible value of for
satellite to move in the elliptical orbit is:
(A) 2
(B) 2
1
(C) 2 + 1
(D)
2 1
6.
An elevator is moving upward with an acceleration a. It has velocity v at t = 0. A man inside the
elevator lifts a body of mass m through a height h in interval t = 0 to t = t0. The average power
developed by the man is in elevator ref. frame :
m(g a)h
1
(A)
(B) m(g + a) (v +
at0)
t0
2
mgh
1
(D) mg (v + at0)
t0
2
A thermally insulated vessel contains some water at 0C. The vessel is connected to a vacuum pump
to pump out water vapour. This results in some water getting frozen. It is given Latent heat of
5
5
vaporization of water at 0C = 21 10 J/kg and latent heat of freezing of water = 3.36 10 J/kg.
The maximum percentage amount of water that will be solidified in this manner will be :
(A) 86.2%
(B) 33.6%
(C) 21%
(D) 24.36%
(C)
7.
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
As a wave propagates :
(A) The wave intensity remains constant for a plane wave
(B) The wave intensity decreases as the inverse of the distance from the source for a spherical wave
(C) The wave intensity decreases as the inverse square of the distance from the source for a
spherical wave
(D) Total power of the spherical wave over the spherical surface centered at the source decreases
with distance.
9.
A block of mass 2 kg is hanging over a smooth and light pulley through a light
string. The other end of the string is pulled by a constant force
F = 40 N. At t = 0 the system is at rest as shown. Then in the time interval from
2
t = 0 to t =
seconds, pick up the correct statement (s) : (g = 10 m/s2)
10
(A) tension in the string is 40 N
(B) work done by gravity is 20 J
(C) work done by tension on block is 80 J
(D) None of these
10.
11.
2kg
F=40N
x
An ideal monoatomic gas undergoes a processes in which P = 3V3. Choose the correct statements.
(A) If volume increases then temperature will also increase
(B) If temperature of the gas decreases, then pressure must also decrease.
(C) For expansion, heat will have to be supplied to the gas.
(D) If temperature increases then work done by gas is positive.
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Questions 12 and 13
In an organ pipe (may be closed or open) of 99 cm length standing wave is setup,
whose equation is given by longitudinal displacement
2
(y + 1 cm) cos 2(400) t
= (0.1 mm) cos
0.8
where y is measured from the top of the tube in meters and t in second.
Here 1 cm is the end correction.
12.
13.
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
O
A rod of mass m and length l is free to rotate in a vertical plane about
fixed horizontal axis O passing through one end as shown in the figure. A
m
2l
sphere of mass
hits the rod elastically with horizontal speed v0 at a
4
3 m
4
2
distance
from O. Before collision, the rod is at rest in vertical position.
3
If we consider the sphere and the rod as a system, then gravity and force due to axis O are external forces.
For the rod alone, force exerted by O, gravity and impact force are all external forces. Similar conclusion can
be drawn for the sphere. Net external force on any system is equal to the product of the mass of the system
and the acceleration of the center of the mass of the system.
14.
The maximum angular deflection of the rod from the vertical after the collision is
5 v 20
3 v 20
(A) cos 1 1
(B) sin1 1
16 g
16 g
3 v 20
(C) cos 1 1
16 g
15.
16.
5 v 20
(D) sin1 1
16 g
v0
2
v
(D) 0
2
(B)
Magnitude of the impulse on the rod exerted by the axis O during the collision is
3mv 0
(A) zero
(B)
8
3mv 0
3
(C)
(D) mv 0
14
7
Space for rough work
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
SECTION B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given
in two columns which have to be matched. Statements (A, B, C, D) in column
I have to be matched with statements (p, q, r, s, t) in column II. The answers
to these questions have to be appropriately bubbled as illustrated in the
following example.
If the correct match are A-p, A-s, B-q, B-r, C-p, C-q and D-s, then the correctly
bubbled 4 4 matrix should be as follows:
1.
Column II
(p) towards right
Q
P
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
2.
(A)
(p)
Column II
(Temperature T
in steady state)
50C
(q)
70C
(r)
55C
(s)
25C
(t)
none of these
2K0
C
6K0
3K0
100C
10C
5R
10C
100C
2R
3R
T
(C)
100C
2R
10C
T
R
8R
(D)
2L
6R
B
b
3R
100C
10C
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
SECTION C
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown
1.
2.
h/2
h M
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
3.
4.
a3
a2
a1
B
m2
m3
In a lawn a water sprinkler is sprinkling water in all the possible directions while rotating. What is
2
maximum area (in m ) on ground that can be sprinkled? The speed of water form nozzle is
1/ 4
400
2
m / s (g = 10 m/s )
5.
6.
1/v (s/m)
B
x (m)
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
Chemistry
PART II
SECTION A
Straight Objective Type
This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.
Ca OH 2 2H 3PO 4
Ca H2PO 4 2 2H2 O
(A) 98
(C) 32.7
(B) 49
(D) 37.2
2.
3.
Agaq 2NH3aq
Ag NH3 2 aq
K sp NH3
1
(A)
K c Ag NH3 Cl
(C) K c
4.
Ag NH3 Cl
K sp Ag NH3 2
(D) K c
2
NH3 Cl
K sp Cl
Ag NH3 NH3 2
2
(B) K c
K sp NH3
(B)
(D)
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
5.
6.
CH3
H3C
CH2 C
(A)
(C)
HBr / H2 O2
CH CH3
(B)
CH3
H3C
CH2 C
H3C
CH
Br
CH
Br
CH3
CH2 CH3
CH2 CH3
CH3
H3C
CH2 C
CH3
Br
CH3
(D)
H3C
CH2
CH
CH3
Br
7.
CO g
1
O2 g
CO2 g at 298K
2
The standard entropy change is 0.094 kJ mol1. The values of standard Gibbs free energy of
formation of CO2 and CO are 394.4 and 137.2 kJ mol1 respectively. The reaction is
(A) non-spontaneous, endothermic
(B) non spontaneous, exothermic
(C) spontaneous, endothermic
(D) spontaneous, exothermic
Multiple Correct Choice Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct
8.
Which of the following carbocation will be relatively more stable than benzyl carbocation?
(A)
(B)
CH2
Ph2CH
(C)
(D)
CH3
C
Ph
CH3
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
9.
Which of the following molecules/species contains atleast one atom with sp3 hybridization?
2
(A) ClO2
(B) SO3
3
(C) BO3
(D) H3PO3
10.
/ THF, H O
Br2 / h
alc. KOH
NaOI
3 2
2
B
C
D E
A
NaBH , OH
(A)
(B)
(C)
(D)
11.
Molecular weight of (F) is nth multiple of weight of a methyl radical (where n = positive integer)
Compound (C) on heating with conc. H2SO4 gives (B)
Compound (B) can not exhibit position isomerism
Compound (A) can exhibit position isomerism
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 12 to 13
The decomposition of N2O5 is according to the equation:
2N2O5 g
4NO2 O2 g
is a first order reaction. After 30 minutes from the start of the decomposition in a closed vessel, the total
pressure is found to be 294.5 mm Hg. On complete decomposition the total pressure is 594.5 mm Hg. An
inert gas with partial pressure 10 mm Hg has always been present in vessel during decomposition of N 2O5.
12.
What is the pressure of the vessel before the beginning of decomposition of N2O5?
(A) 223.8 mm
(B) 233.8 mm
(C) 243.8 mm
(D) 253.8 mm
13.
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
H
H3C
CH3
CH3
H3C
CH3
H
H3C
14.
15.
16.
H
CH3
(B) 2
(D) 4
One of the seven cyclic isomers is missing. What is the number of C atom constituting the cyclic ring?
(A) 3 member ring, hence 3 C atoms
(B) 4 members ring, hence 4 C atoms
(C) 5 member ring, hence 5 C atoms
(D) 6 member ring, hence 6 C atoms
Space for rough work
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
SECTION B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given in
two columns which have to be matched. Statements (A, B, C, D) in column I
have to be matched with statements (p, q, r, s, t) in column II. The answers to
these questions have to be appropriately bubbled as illustrated in the following
example.
If the correct match are A-p, A-s, B-q, B-r, C-p, C-q and D-s, then the correctly
bubbled 4 4 matrix should be as follows:
1.
2.
Degree of dissociation
Pre-exponential factor
equation)
Rate of reaction
Activation energy
(Arrhenius
Column II
(Molecule)
N2
N2
CO
O2
He2
Column II
(Dimensions)
(T = Time, L = length, M = mol, W = mass)
(p)
T1
(q)
L0T0
(r)
(s)
M0L 0
M1L 3T1
(t)
W1L2T2
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
SECTION C
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown
1.
Number of possible cyclic alcohols with formula C 5H10O (excluding stereoisomer) is x than what is
x/2?
2.
3.
H (2)
H
(5)
H(1)
H (3)
H(4)
4.
Calculate the number of protons present in an acid whose 0.45 g requires 40 ml of N/2 KOH solution.
(MW = 90)
5.
The pH of blood stream is maintained by a proper balance of H2CO3 and NaHCO3 concentration. The
volume of 10 M NaHCO3 solution which is mixed with 10 mL sample of blood which is 4 M in H2CO3
in order to maintain a pH of 7.4 is x mL. Ka for H2CO3 in blood is 4 107. What will be the value of
x/10?
6.
If a mixture of 3 mol of H2 and 1 mole of N2 is completely converted in to NH 3, what would be the ratio
of the initial and final volume at same temperature and pressure?
Space for rough work
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
Mathematics
PART III
SECTION A
Straight Objective Type
This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.
2.
3.
4.
(B) y-axis
(D) none of these.
1
If mi , i = 1, 2, 3, 4 are con-cyclic points, then the value of m 1 m 2 m 3 m 4 is
mi
(A) 1
(B) 1
(C) 0
(D) none of these.
Coefficient of xr in the expansion of (1 2x) 1/2 is
2r !
(A)
(B)
2
r!
(C)
2r !
r! 2 22r
2r !
2
2r r!
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
1 3 9 27
...
2 8 32 128
5.
is
6.
7.
Ten persons, amongst whom are A, B and C to speak at a function. The number of ways in which it
can be done if A wants to speak before B and B wants to speak before C is
10!
(A)
(B) 3! 7!
6
(C) 10P3 . 7!
(D) none of these.
Multiple Correct Choice Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct
8.
9.
area
that
can be inscribed
(B) 1 i( 2 + 3 )
(D) 1 i( 2 3 )
10.
11.
If
1 sin A = sin
(A) first
(C) third
in the curve
A
A
A
cos , then
could lie in quadrant
2
2
2 4
(B) second
(D) fourth
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 12 to 13
Read the following comprehension carefully:
Let f(n) denotes the number of different ways the positive integer n can be expressed as the sum of 1s and
2s. For example,
f(3) = 3, since 3 = 1 + 1 + 1 = 1 + 2 = 2 + 1
f(4) = 5, since 4 = 1 + 1 + 1 + 1 = 1 + 1 + 2 = 1 + 2 + 1 = 2 + 1 + 1 = 2 + 2.
Note that order of the appearance of 1s and 2s is important.
Now, answer the following questions:
12.
13.
(B) 11
(D) 15
f{f(6)} is equal to
(A) 377
(C) 321
(B) 302
(D) 350
Space for rough work
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
(B)
1
3
1
(D)
2
15.
The area of the largest triangle that an incident ray and the corresponding reflected ray can enclose
with the axis of the ellipse is equal to
(A) 4 5
(B) 2 5
(C) 5
(D) none of these
16.
Total distance travelled by an incident ray and the corresponding reflected ray is the least if the point
of incidence coincides with
(A) an end of the minor axis
(B) an end of the major axis
(C) an end of the latus rectum
(D) none of these
Space for rough work
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AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
SECTION B
(Matching List Type)
This section contains 2 multiple choice questions. Each question has matching Column(s). The codes for
the Column(s) have choices (A), (B), (C) and (D) out of which only ONE OR MORE is/are correct
1.
(B)
(C)
(D)
2.
Column I
f(z) is a complex valued function f(z) = (a + ib)z where a, b R
1
and |a + ib| =
. It has the property that f(z) is always
2
equidistant from 0 and z, then a b =
The number of all positive integers n = 2a 3 b (a, b 0) such that
n 6 does not divide 6 n is
A is the region of the complex plane {z: z/4 and 4/ z have real
and imaginary part in (0, 1)}, then [p] (where p is the area of the
region A and [.] denotes the greatest integer function) is
2
If 3x + 4y + z = 5, where x, y, z R, then minimum value of26(x
2
2
+ y + z )is
Column II
(p)
(q)
(r)
(s)
25
(t)
10
Column II
sin cos x
(A)
cos sin x
(p)
xR
(q)
R n
(B)
(C)
tan( sinx)
(r)
(D)
ln(tanx)
(s)
(t)
x n, n
x 2n , 2n
2
2
x R n
8
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23
AIITS-HCT-VII (Paper-1)-PCM-JEE(Advanced)/16
SECTION C
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown
1 1 1
... is .
4 8 16
1.
2.
3.
If coefficient of x7 in ax 2
bx
4.
5.
The line L passes through the points of intersection of the circles x2 + y2 = 25 and
2
2
x + y 8x + 7 = 0. The length of perpendicular from centre of second circle onto the line L is .
6.
11
7
, where and are the roots of 2x2 + 7x + c = 0 is .
4
11
1
1
1
1 a 1 b 1 c
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