Beruflich Dokumente
Kultur Dokumente
Vol:6 2012-07-28
(1)
271
Pg
(3)
:KHUH g is the gas density in g/cc, and D1, D2, and D3 are
dependent parameter as a function of temperature and
molecular weight. This proposed modification results in
correcting the original correlation to account for the presence
of high content of heptane plus fraction, hydrogen sulfide and
carbon dioxide in natural gases. These corrections are
calculated by the following equations.
>
y.CO >6.4366u10
y.C > 3.2875u10
'P g
'P g
3
7
log J g 6.7255u103
1
log J g 1.2885u101
Where
@
@
@
(4)
P h is calculated as follow:
A( p pr ) B(T pr )
C ( p pr ) D(T pr )
a1 a2 pr a3 pr2 a4 ln( pr ) a5 ln 2 ( pr )
(6)
a6
a7 ln 2 (Tr )
Tr
1 a8 p r2
a9 a10 a11
Tr Tr2 Tr3
(10)
Pg
ln 7pr a0 a15pr a2 5pr2 a35pr3 7pr (a4 a55pr a6 5pr2 a7 5pr2 )
P1
(7)
7pr2 (a8 a9 5pr a105pr2 a115pr3 ) 7pr3 (a12 a135pr a145pr2 a155pr3 )
(5)
(8)
Ph 1.709 u105 2.062 u106 S g 7 460 8.188 u103 6.15 u103 log S g (9)
(2)
P1
>
U g 8
4
10 . exp &
62.4
(2)
:KHUHHDFKRI.;DQG
<DUHDIXQFWLRQRIWHPSHUDWXUH
and molecular ZHLJKW DQG g is the gas density at reservoir
pressure and temperature in lb/ft3.
Pg
reduced temperature and pressure, over ranges of 1-3, and 120, respectively, as:
(11)
(12)
(13)
(14)
(15)
272
D jk
N k 1
Fk wijk D i ( k 1) E jk
i1
(16)
AARD%
1 N z exp z calc
u 100
z
N i1
exp
(17)
273
TABLE I
PROPERTIES OF NATURAL GASES USED IN THIS STUDY
Minimum
Composition
%)
Methane
Average
66.25
100
97.2421
Carbon dioxide
2.19
0.2941
Ethane
9.306
1.3825
Propane
4.963
0.2908
i-butane
0.719
0.0596
n-butane
1.279
0.0534
i-pentane
0.226
0.0436
n-pentane
0.249
0.0431
Hexane
0.179
0.0464
Heptane plus
0.136
0.0095
Argon
0.042
0.0010
Nitrogen
9.752
1.0634
Hydrogen
33.75
0.1854
Helium
0.052
0.0012
Pressure (Mpa)
0.1
97.3
10.96
Temperature (K)
250
570
371.45
95.93
586.63
165.26
9LVFRVLW\3
700
600
3UHGLFWHG9LVFRVLW\3
4.5
4
3.5
AARD%
Maximum
(mol
3
2.5
2
1.5
500
400
300
200
1
100
0.5
0
3
9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41
Number of neurons
100
200
300
400
500
600
700
([SHULPHQWDO9LVFRVLW\3
274
TABLE III
AVERAGE ABSOLUTE RELATIVE DEVIATION OF ANN COMPARED TO EMPIRICAL
MODELS
Ref
1
ANN
HMS
LGE
CKB
ADEL
SNP
0.9
Cumulative frequancy %
0.8
0.7
0.6
0.5
ADEL
LGE
HMS
CKB
SNP
ANN
No.2
2.0279
No.3
8.6979
9.5845
17.407
3.7626
2.4761
0.2274
[14]
3.5062
18.1899
9.2737
1.9253
0.0994
[15]
No.4
No.5
4.3753
7.2971
19.8208
9.6398
2.9619
0.1162
[15]
4.2072
7.5699
19.9511
9.4248
2.487
0.1523
[15]
8.9967
2.9721
2.0496
[16]
No.6
2.4419
3.5954
O.R.
0.4
No.7
1.5459
7.7279
O.R.
7.7456
4.7911
0.7616
[17]
0.3
No.8
1.3918
10.770
4
O.R.
28.2663
4.2566
0.6745
[17]
0.2
No.9
1.0207
7.1625
O.R.
7.4375
5.2335
0.4739
[17]
0.1
No.10
1.8347
1.9373
O.R.
9.151
2.8555
0.3435
[18]
No.11
4.4431
5.9219
O.R.
12.8676
2.1231
0.139
[18]
No.12
4.9279
4.0761
14.3019
3.545
1.7427
0.1931
[19]-[20]
4.5509
4.9428
18.8399
5.9401
2.1269
0.2208
Gas type
0.5
1.5
2.5
AARD%
Methods
AARD%
RMSD%
LGE
4.9428
5.9265
CKB
5.9401
8.1976
ADEL
4.5509
5.7361
HMS
18.8399
28.4532
SNP
ANN
2.1269
0.2208
3.3233
0.0171
275
450
600
550
400
Viscosity (P)
Viscosity (P)
500
450
400
350
ANN
350
300
ANN
250
SNP
SNP
300
ADEL
ADEL
250
CKB
LGE
LGE
200
Experimental
150
Experimental
150
11
13
10
11
12
13
Fig. 6 Experimental data and results of ANN and other method for
sample mixture in 330K
Fig. 4 Experimental data and results of ANN and other method for
sample mixture in 270K
Pr
15
Pr
520
470
420
Viscosity (P)
CKB
200
TABLE IV
COMPOSITION OF SAMPLE GAS
370
320
ANN
270
SNP
ADEL
220
CKB
LGE
170
Component
mol%
methane
0.84990
ethane
0.05529
propane
0.02008
isobutane
0.00401
n-butane
0.00585
isopentane
0.00169
n-pentane
0.00147
n-octane
0.00152
Experimental
120
1
11
13
15
Pr
Fig. 5 Experimental data and results of ANN and other method for
sample mixture in 300K
276
toluene
0.00090
methylcyclopentane
0.00102
nitrogen
0.03496
carbon dioxide
0.02331
[21]
[22]
ACKNOWLEDGMENT
The authors are grateful to University of Kashan for
supporting this work by Grant No. 158484.
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277