Beruflich Dokumente
Kultur Dokumente
======================================
EMERGENCY PREPAEDNESS
AND RESPONSE PLAN
Name of Employee
Designation
Signature
Date
Prepared By:
Reviewed by :
Approved by:
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TABLE OF CONTENTS
S. No
Description
Page. No
1.
Preface
2.
Introduction
8-9
4.
5.
10
6.
Definition of an Emergency
10
7.
10-11
8.
11
9.
10.
11-12
12
i.
Warehouse-I
12-13
ii.
Warehouse-II
14
iii.
14-15
11.
Process Description
15
12.
15-16
13.
Approach Roads
16-17
14.
17
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15.
16.
17.
Assembly Points
18
18.
18
19.
19
20.
19
21.
22.
23.
20-21
24.
21-22
25.
22
26.
Categorization of Emergencies
22-24
27.
24-25
28.
Declaration of Emergency
25
29.
25-26
30.
26
31.
26-27
32.
33.
27-28
34.
28-29
35.
36.
Incident Notice
37.
34
38.
35
i) Site Controller
17
17-18
19-20
20
27
29
30-33
35
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36
iii)
36
iv)
v) Medical Coordinator
vi)
Communications Coordinator
36-37
37
37
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vii)
Fire Coordinator
37
viii)
37
ix)
Security Coordinator
38
x)
38
xi)
38
xii)
Shift Electrician/Supervisor
38
xiii)
Ambulance Driver
39
xiv)
Manager Administration
39
xv)
39
39.
40
40.
Environmental Emergencies
41
41.
41
42.
41-42
43.
42-43
i.
ii.
44.
43
43
iii.
44
iv.
44
44
44
ii. Emergency Procedure for Handling Fire in Solvent Storage tank farm
44-45
45
46
46
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46
46-47
47
47-48
48
48
49
49-51
51-52
52-54
xviii.
55
55-57
57
57-58
58
58-59
xxii.
59
xxiii.
59
xxiv.
59
xxv.
60
xxvi.
60
xxvii.
xxviii.
60
60-61
xxix.
61
xxx.
61
xxxi.
61
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xxxii.
61-62
xxxiii.
62
xxxiv.
62
xxxv.
xxxvi.
62
62
xxxvii.
63
xxxviii.
63
xxxix.
63
63
64
64-65
xliii.
65-66
xliv.
67
45.
67-68
46.
Evacuation Procedure
68-69
47.
48.
49.
71
50.
72
51.
73-74
52.
75-76
53.
76
54.
77
55.
78
56.
79
57.
69
70-71
79-80
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58.
81-82
59.
List of Abbreviations
83
60.
--
61.
--
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PREFACE:
A Totally safe chemical plant could exist only in theory. The best available design of plants and
procedures notwithstanding there is in practice, always a certain probability of circumstances
combining to make things go wrong, the unexpected to happen and an accident to occur and an
emergency can occur in any chemical industry. Numerous instances are known, whereby timely and
effective action after the event, has greatly contributed towards minimizing the damage to plant and
property and loss of lives.
Chemical industries have an onerous responsibility to preserve and protect the environment and ensure
that whatever happens within their premises does not affect the surrounds.
With the above in view, an Onsite Emergency Control Plan has been prepared for our factory at
Mekaguda. All concerned are hereby requested to carefully study and thoroughly familiarize themselves
with it, in order to ensure its effective use in times of emergency.
It is sincerely hoped that his Emergency Preparedness & Response Plan will help all NPCD
employees to prepare themselves to contain, control, mitigate, and neutralize the consequences of any
emergency that may arise.
INTRODUCTION:
xxxx PHARMA LIMITED, Chemical Division (NPCD) at Mekaguda Village, Kothur Mandal,
Mahaboob Nagar District, and Andhra Pradesh has taken steps to assess, minimize and wherever
feasible eliminate risks. In spite of its best efforts, an emergency may still occur which may affect life
and property within the plant and its neighborhood. Therefore, an Onsite Emergency Plan has been
prepared for mitigating the effects of a major emergency.
In the interest of all the employees this plan should be put into practice during an emergency. Mock
drills and rehearsals are conducted periodically to ensure preparedness of all the concerned for effective
implementation of the plan. The Onsite Emergency Plan will be upgraded as and when there are
changes in the facilities.
The success of this plan in accomplishing its purpose depends largely upon each individual carrying out
his/her designated duties effectively and promptly.
THE CONCEPT:
Emergency in Plant Parlance is fire, explosion and toxic release and has the potential to cause serious
injury/loss of life and damage to property and which tends to cause disruption inside and sometimes
extends outside the plant. Emergency could also set- in due to external situations like natural calamities,
sabotage etc.
It is the preparedness of the plant that differentiates the impact. Almost all emergencies start from small
events and lead to emergency and then to disaster. It is the response in the first five minutes that makes
an event small or big. This can happen only if exigencies have been identified and procedures properly
planned, practiced, evaluated and improved.
The Emergency plan is a statutory requirement as per provision of sub section 4B of the Factories
(Amendment) Act, 1987. The purpose of this on-site emergency plan is to ensure the life and
properties of all concerned and minimize the damage to the maximum possible extent, in case of any
emergency.
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Preparation of Onsite Emergency Plan is mandatory under Rule 13 of Manufacture, Storage and
Handling of Hazardous Chemicals, 1989. Schedule 11 under Rule 13.1 of Manufacture, Storage and
Handling of Hazardous Chemical provide guidelines for preparation of onsite Emergency Plan. Based
on the concepts and guidelines provided, an action plan indicating clearly, the duties to be performed by
different persons in the factory during an emergency is laid down in the form `On site Emergency
Plan.
This " ON-SITE EMERGENCY MANAGEMENT PLAN has been prepared to outline the response
of the Management to control emergencies in the M/S. XXXX PHARMA LIMITED, MEKAGUDA.
This plan will explains basic requirements, definitions, objectives, manufacturing process and plant
facility details as called for under schedule 13 of Manufacture, storage and handling of hazardous
chemicals. This includes key elements, organization chart, roles and responsibilities, hazard analysis
details, possible emergencies, contents of emergency control centre etc.
OBJECTIVES OF THE EMERGENCY PLAN:
To define the hazards and assess the risks and identify the Maximum Credible Loss Scenario
(MCLS)
To outline the responsibilities and functions of the key members of the emergency response team, to
Safeguard other employees and environment.
To inform authorities and mutual aid centers to come for help.
To effect rescue and treatment of casualties. To count injured.
To identify and list any fatal accident.
To inform and help relatives.
To secure the safe rehabilitation of affected areas and to restore normalcy.
To preserve records, equipments etc., and to organize investigation into the cause of the emergency
and preventive measure to stop its recurrence.
Purpose of the plan: This plan is developed to:
Control or limit any effect arising out of an emergency or potential emergency that may arise at the
plant.
To ensure communication of all vital information to appropriate internal and external bodies as
soon as possible.
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Date: 29-09-2011
Rev: 03
Chairman and Managing Director
DEFINITION OF AN EMERGENCY:
Emergency means a situation or condition leading to circumstances or set of circumstances in which
there is a danger to life or health of persons or which could result in big fire or explosion to the work
and outside environment affecting the workers or neighborhood in a serious manner, demanding
immediate action.
OR
An emergency occurring in a factory is one that may affect several departments within it and may cause
serious injuries, loss of life, damage to the property and the community beyond the factory premises. It
may require assistance from external agencies such as fire brigade, local hospitals, Road Transport
Authority (RTA), Police, District Emergency Authority (DEA) etc. to manage it effectively.
BRIEF DESCRIPTION OF THE PLANT:
S.N
O
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Mr Venkata Rao
Vice President Production
Mobile :9866005196
Mr. M. Nageswara Rao
Sr. Manager - WH
Mobile:9550240469
Mr N. Satya Narayana
Sr Manager- HRD
Mobile :9949533374
Mr P. Chiranjeevi Rao
Dy General Manager- Environment
Mobile :9848196822
Shifts:
1st Shift: 6.00 to 14.00 Hrs
No of employees
110
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110
110
255
Total
575
Working hours:
A Shift
B Shift
C Shift
General Shift
:
:
:
:
06.00Hrs To 14.00Hrs
14.00Hrs To 22.00 Hrs
22.00Hrs To 06.00Hrs
08.305Hrs To 17.30Hrs
Type of Storage
Drums
Drums
Tins
Tins
Tins
Drums
Drums
Bags
Tins
Carboys
Drums
Bags
Tins
Drums
Drums
Drums
Drums
Drums
Shippers
Drums
Drums
Drums
Carboys
Drums
Drums
Tins
Carboy
Drums
Drums
Drums
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31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
Tins
Bags
Carboys
Drums
Tins
Drums
Drums
Containers
Drums
Drums
Drums
Carboys
Carboys
Drums
Carboys
Drums
Bags
Drums
Tins
Drums
Box
Carboys
Bags
Drums
Drums
Drum
Drums
Drums
Tins
Drum
Carboys
10.
Type of Storage
1-Bromo-3-Chloro Propane
Aceto Nitrile
Benzoic Acid
Copper Cyanide
Dimethyl Amine
Dimethyl Formamide
Dimethyl Sulfoxide
Hydro Bromic acid CP
Magnesium Turnings
Para Bromo Fluoro Benzene
Drums
Drums
Drums
G.I Tins (25 Kg)
Drums
Drums
Drums
Drums
Tins
Drums
Nature of the
Material
Corrosive
Flammable
Flammable
Toxic
Flammable
Flammable
Flammable
Corrosive
Flammable
Flammable
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11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
Phosphorous Pentoxide
Phosphorous Pentoxide
PTS Acid
Raney Nickel
Sodium Boro Hydride
Sodium Cyanide
Sodium Hydride
Solvent Ether
Stannous Chloride
Tetra Hydro Furan
Tri Ethyl Ortho Formate
Corrosive
Corrosive
Flammable
Flammable
Flammable
Toxic
Flammable
Flammable
Harmful
Flammable
Flammable
Storage Tank No
Capacity
ST-801
Ethyl Acetate
20KL
Flammable
ST-802
Acetic Acid
30KL
Corrosive
ST-803/1
Chloroform
30KL
Flammable
ST-804
MCL
30KL
Toxic
ST-805
MCL
30KL
Toxic
ST-806
Diesel
30KL
Flammable
ST-807
Diesel
30KL
Flammable
ST-808
Acetone
30KL
Flammable
ST-809/1
Hexane
30KL
Flammable
ST-810/1
Toluene
30KL
Flammable
ST-811/1
Toluene
30KL
Flammable
ST-812/1
Acetone
19 KL
Flammable
ST-813
Methanol
100KL
Flammable
ST-814
IPA
30KL
Flammable
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15.
16.
17.
18.
ST-815
IPA
20 KL
Toxic
ST 822
Methanol
30 KL
Flammable
ST-835
Hexane
30 KL
Flammable
ST-808/1
Cyclo hexane
30 KL
Flammable
PROCESS DESCRIPTION:
In Production department, Reactors, Centrifuges, Nutsch filters, Leaf filters, Dryers, Millers, Sifters,
Micronizers & Blenders are the main equipments.
Reactors: Reaction shall be carried out in reactors. Different capacity Stainless Steel Reactors and
Glass Lined Reactors are used in Production and selection of reactor is to be done based on the nature
of the chemical. All the reactors will have jacket provision. The contents of the reactors can be heated /
cooled by passing steam / cooling tower water. Based on the process requirement, different type of
stirrers like anchor, propeller, turbine etc will be used with variable RPM. The chemical reactions
carried out in the reactors are mostly distillation, chlorination, nitration, Bromination, Friedel craft
alkylation and hydrogenation.
Centrifuges / Nutch filter: will be used for wet material isolation from reaction mass based on the
material nature.
Leaf filters: Leaf filters are used to remove the activated carbon used in the reaction mass for colour
improvement or to remove the spent sodium sulphate used for moisture removal.
Driers: Isolated wet materials shall be dried using different driers
Multi miller: Dried material shall be milled to de-lump the lumps formed during drying.
Sifters: Sifters are used to control the particle size of the material.
Micronizers: Micronizer is used to reduce the particle size of the API as per customer requirement.
Blenders: Two or more production lots shall be blended to increase the commercial batch size.
MAIN PRODUCTS MANUFACTURED:
S. No.
1
2
3
4
5
6
7
8
Block
Kilo Lab
Kilo Lab
Kilo Lab
Kilo Lab
Kilo Lab
Kilo Lab
Kilo Lab
Kilo Lab
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S. No.
Name of the Product
9
Tolterodine tartrate
10
Trihexyphenidyl HCl
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Block
Kilo Lab
Kilo Lab
Zoledronic Acid
Kilo Lab
Zolmitriptan
Kilo Lab
Pilot Plant
S-Citalopram Oxalate
Pilot Plant
Sumatriptan succinate
Pilot Plant
Terbinafine Hydrochloride
Pilot Plant
Isosorbide- 5-Mononitrate
Production Block-II
Isosorbide Dinitrate
Production Block-II
Citalopram Hydrobromide
Production Block-III
Erlotinib Hydrochloride
Production Block-III
Production Block-III
Ondansetron Hydrochloride
Production Block-III
Imatinib Mesylate
MPB A
Sertraline Hydrochloride
MPB A
Fluoxetine Hydrochloride
MPB B
Lansoprazole
MPB B
Lanthanum Carbonate
MPB B
Omeprazole
MPB B
Pantoprazole sodium
MPB B
Glatiramer Acetate
MPB CK
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APPROACH ROADS:
A well-laid and wide road runs all around all the buildings/production blocks and solvent storage tank
farm area. Two gates are ends of the road lead to the National Highway No. 7, which connects
Hyderabad & Bangalore. The same road leads to Mekaguda village towards North side.
There is one main gate at Security office on East side, one gate on South West Boundary wall the site.
(Gate 1: Main Security-Time office, Gate: 2: checking). The first gate is used for allowing Emergency
Vehicles like Fire Brigade, Ambulance vans etc., to enter. The gate 1 & 2 are manned round the clock
by Security Officer and Security Guards.
Security Setup:
February to April
May to September
October to January
Average Wind Velocity
:
:
:
:
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ASSEMBLY POINTS:
All employees in the block where the emergency occurs shall evacuate the work place and assemble at
the locations identified as assembly points. Site Plan showing the Evacuation Routes & Assembly Points.
Depending upon the wind direction the following are the assembly points
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First Aid Training is given to the First Aiders during Safety Training Programmes.
Recognised Hospitals and Eye Specialist at Hyderabad are located at a Distance of 50 km from the
factory.
Government Hospital is available at Hyderabad and nearby Doctors and Hospitals are contacted in
Emergency by our FMO.
Critical Cases are referred to Govt Hospitals/Specialised Hospital at Hyderabad Secunderabad,Bidar
under the guidance our Factory medical Officer
Emergency showers/eye wash fountains are provided in each block & Storage areas and at strategic
locations for thorough washing in case of chemical splashes/hot burns / chemical burns.
A wheeled stretcher with folding and adjusting devices, with the head of the stretcher capable of
being fitted upward.
Insulated gauntlets.
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Roll of Aluminium foils, soft roller bandages 6" x 5 yards adhesive tape in 3" roll, safety pins
Poisoning : Syrup of Ipecac, Activated charcoal pre-packed in doses, snake bite kit, drinking waterpre-packed in doses
Emergency medicines: As per requirement under the advice of medical officer.
By continuous whistle: The Security will alert the persons soon after receiving the
information about the emergency.
For communicating the declaration of emergency and evacuation decision to the plant
personnel, the electrical siren is used by the security officer upon getting instructions from site
incident controller / Incident controller / Emergency coordinator / HOD (Safety & Health)
Tel.Ph.No.282101
Tel.Ph.No.252101
Tel.Ph.No.252361
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In consultation with Site Controller / Incident controller, the Manager- Administration communicates
The information to the following department, depending on the nature of the disaster/emergency:
Escape routes are those that allow reasonably safe passage of persons from the work area to the
Assembly Points.
The emergency exits boards/marking with the arrow directions are provided in all production
Blocks/rooms, QC buildings, Raw Material Stores. The Way to Assembly Point signage boards
Are provided at various strategic locations so as to reach the desired Assembly Point depending
Upon the wind direction
WIND SACKS:
During an emergency, the knowledge of exact wind direction helps the plant Personnel to decide
on the selection of right escape route for safe evacuation of Personnel and also the safe assembly
point.
The wind sacks are provided at the following locations and the locations of wind sacks are marked
in the site plan
S.No Block/Location
PB-I Building
PB-II Building
PB-V Building
PB-VII Building
SRP column
MPB-E& F
MPB-G
P&A Building
Stripper column
Depending on the wind direction, the escape route is chosen and personnel are given guidance for
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Escape through these routes. Refer site plan for escape route.
SAFETY SHOWERS AND BODY WASHERS:
[
Readily accessible means of drenching water for workers, parts of body of workers and, clothing of
workers who have been contaminated with hazardous and corrosive substance; and such means shall be
as per the scale shown in the Table below.
S.No
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
Block/Location
PILOT PLANT
PB-I
PB-I
PB-II
PB-II
PB-III
PB-III
PB-III
PB-IV&VI
PB-VII
PB-V
PB-V
SRP
ETP
ETP
INCINERATOR
RO PLANT
DM PLANT
WH-I
WH-II
WH-II
SOLVENT YARD
WH-III
WH-IV
WH-IV
MPB-A
MPB-A
MPB-B
MPB-B
MPB-C
MPB-D
MPB-D
QC-LAB
MPB-E
MPB-E
MPB-E
MPB-F
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38.
39.
40.
MPB-F
MPB-F
MPB-J
SFT-ESBS-38
SFT-ESBS-39
SFT-ESBS-40
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Examples:
Day storage tanks for ML, Spent Solvent, and Fresh solvent
Fire in Incinerator
Toxic gas release from bulk storage tanks in tank farm (Bromine /Chlorine gas leak).
Toxic gas release from Dry HCl cylinders storage shed and battery at production block
Earthquake
Flooding
Food poisoning
Cyclone
Category V Emergency:
Major Emergencies that can occur outside the factory premises during transportation of flammable
Toxic Materials like Methanol, Toluene, Ethyl Acetate, etc., which are procured by NPCD fall
Under this Category.
Emergency situations may also arise during transportation of treated effluent to PETL (as and when
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Required), hazardous wastes & spent solvents from our sites to TSDF & authorized agencies as the
Case May be. Emergency arising due to transportation of finished goods & intermediates from our
Site to suppliers are Co-ordinate by Safety, Commercial, Marketing & Quality Assurance Team.
Assistance from suppliers, Transporters, police and fire services may be required to control such
Emergencies. The NPCD Management has also to co-ordinate with the District Emergency
Authority to initiate actions as per the Off site Emergency Plan prepared by the District
Emergency authority.
Examples:
Major Fire Emergency of Road tankers transporting flammable solvent/corrosive chemicals in bulk
toxic chemicals/gases in bulk.
Major spillage of treated effluent & hazardous wastes (solid & liquid)
Fire incidents of trucks/vehicles during transportation of hazardous wastes from our site to PETL
(for Effluent), TSDF (for Hazardous wastes) & authorized agencies (for hazardous by products,
spent solvents & wastes)
Emergency situations due to accident of vehicles/trucks carrying & transporting finished goods
& intermediates.
NOTICING Of FIRE/ EXPLOSION OR TOXIC RELEASE EMERGENCY:
Any person noticing an unusual occurrence or toxic release must break the manual call point which is
provided for all the buildings and blocks. He also communicates the emergency on Intercom No.335
which is available with second gate security gate
If any person notices fire he should start shouting "FIREFIRE-- FIRE". and break the manual call
point which is provided for all the buildings and blocks. Or raise the FIREBELL for a one minute.
He also communicates the emergency situation to security on Intercom No.335 which is available with
second gate security.
'HOOTER SOUND SHOULD. (Fire /toxic release any other emergency) first
inform the Section In charge or concerned Department Head immediately through intercom or
Walky talky.
Rush to the scene of Fire and help others in Fire fighting if he is trained in fire fighting
The Section In charge rushes to the incident spot and assess the situation. If the emergency is a
Major one falling under any of the categories other than category-1 will inform to the site
Controller through Intercom phone No 301 or through massager.
Incident controller immediately takes the charge of site and does all necessary actions with ERT
Team.
Incident controller give the information to Site Controller and Security department on Intercom
Phone no.335 or 333 or walky talky about place of Fire, material involved etc.
Arrange for the evacuation of the persons of the endangered block/area by using the emergency
Escape Routes to reach to the Assembly Point.
In absence of Site controller-Executive Vice President (CES), The Vice President (production) will
Take charge of site controller,
The Vice President-Production, is the Incident Controller, in case of absence of Incident
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Controller, Immediate subordinate at site will act as an Incident Controller during working hours
DECLARATION OF EMERGENCY:
During the General Shift from 8.45 AM. to 5.30 PM. the Site Controller has the authority to
Declare the emergency for all Categories.
During the working hours when the Site Controller/Incident Controller is not available at plant, the
Emergency Coordinator (Block In charges) has the responsibility and authority to declare a major
Emergency based on his assessment.
Production In charges of respective block is the Emergency Co-ordinator after the General shift
Hour from 6.00PM to 9.00AM and on Holidays.
On Sunday or on holidays the Emergency Coordinator (Block In charges) has the responsibility
And Authority to declare a major emergency based on his assessment.
Other than general shift, the duty officer who is available at site will be acts as a site controller
And Authority to declare a major emergency based on block in charges information. Information
Should be give to NDO on walky talky or intercom number 335.
The Night duty officer who is present on duty will take the charge of the ECC and do the
Announcement for evacuation of plant.
EMERGENCY IN NIGHT TIME:
The Night duty officer who is present on duty will take the charge of the ECC and do the
Announcement for evacuation of plant.
The NDO should contact all Emergency key personnel for providing the necessary resources in
Controlling an Emergency coordinator.
The NDO alerts Security Personnel to give Emergency Siren as per code, after assessing the
Gravity of the situation.
Block in charge will give instruction and guides his staff to tackle the situation, with the help of
Executive- Production & Executive Maintenance.
Block in charge will alerts Mechanical, Electrical, Security, Quality Assurance and other
Departments by lashing the news about the emergency and seeks their help.
Block in charge will alerts the Shift-in-charges of other blocks to be prepared for emergency action
i.e., to bring all the processes to safe position or to stop as the situation warrants and to take
Preventive measures to stop spread of Fire etc., and for orderly evacuation.
Block in charge will directs for the removal of other material from the vicinity of the incident.
Block in charge will arranges for evacuation of other staff, other than persons attending the
Emergency.
Block in charge will arranges for necessary Fire Extinguishers and Personal Protective appliances
For the persons with the help of emergency core team members for attending the emergency.
With the help of Occupational Health Centre, he arranges Medical Aid/First Aid to the injured.
He arranges for taking roll call at the assembly points to verify a find out any missing person and
Arranges to rescue the trapped persons if any.
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He communicates the information to the key persons i.e., Site Controller, Incident Controller,
DGM.-EHS, GM-P&A, Manager-Administration, through Security and after their arrival, he hands
Over the Charge to the Site controller / Incident Controller and helps them.
Major Emergency is declared by sounding the emergency siren as per the siren code to indicate the
Emergency.
Manual call point / Fire bell is operated for alerting the local area personnel for initiate the
Emergency.
CENTRALIZED ELECTRICAL SIREN:
This Electric siren gives an indication that an emergency exists in any part of the factory and this siren
gives wailing siren for Three minute pulsating tone (Long run siren with ON & OFF) & is raised by
the security officer upon receiving instructions from Site Controller/ Incident controller/DGM-EHS
who is Emergency Coordinator. The emergency siren code is given below.
The sounding of an emergency siren is an indication to the personnel in the factory that an
emergency has arisen and if so directed, they have to shut down the plant to a safe position and move
towards the Assembly Point using the appropriate escape routes.
In case of Category IV & V emergencies, which are Off-site nature, the Site Controller has to
inform the District Emergency Authority (DEA) i.e. the District Collector of Mahaboob nagar
district.
The emergency operations are controlled from the emergency control center.
The emergency operations are controlled by the Site Controller with the coordination of incident
controller and DGM-EHS
There will be an emergency Siren for the entire Factory premises and same will be raised by the
security Officer/guard who sits in second gate after receiving the instruction from site incident
controller/ incident controller.
After raising the emergency siren, security guard shall open the Emergency control center for
occupying the site controller. And red flag shall be shown as emergency.
Site controller takes the charge of ECC and does the announcement through public address system
for total plant evacuation or partial evacuation of plant depending on the emergency.
Site controller also does the announcement for evacuation route and location assembly point etc.
All employees are trained in Fire Prevention and Basic Fire Fighting and also refresher courses are
Conducted at a regular interval.
A well-trained Security team is working round the clock in shifts to meet any emergency and rescue
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Proper storage methods are developed and incompatible chemicals are segregated and
stored
Separately to prevent fires.
PLANT LAYOUT AND FACILITIES:
The facilities of the plant are provided in a plot of 100 acres. It is having approach roads all around
the Plant.
Production area mainly consists of reactors, coolers, condensers, associated ancillary equipment,
fitters, pumps, driers, distillation set up, scrubbers etc.
Production block and dry shed have been allocated for the production of drugs and intermediate.
Warehouse will hold material received in barrels carbuoys, solid bags and in fiber drums.
Apart from the above storages, solvents are received and stored for operation in tanks and approval
from CCOE.
Boiler steam generation is based on furnace oil/coal for which a separate storage facility is
available.
Utility section consists of cooling towers and connected pumps, refrigerated salt-water circulation
system and one boiler for steam generation.
Since most of the reactions are carried out in the presence of Nitrogen to ensure inert atmosphere
and for purging equipment before commencing reaction a separate liquid Nitrogen Storage Tank is
provided with necessary safety precaution.
Production areas, storage yard, warehouse, peripheral area and utility yards have hydrants,
monitors, manual call points, landing hydrants and first aid firefighting equipment.
Fire protection system provided for all production block and storage area as per TAC norms.
Fire water storage is 600M3 an exclusive storage facility.
All supply lines are laid over ground; underground lines are with protective and anticorrosive
layers.
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Speed is essential
Use the best presence of mind.
Raise the manual call point in case of fire/Explosion/toxic gas release etc.
Telephone /walky-talky systems are to be used for essential communication to combat the
emergency.
Rush to the spot of fire and attempt to put out the fire with suitable things within his reach, if he is
trained in Fire Fighting, otherwise informs the concerned Section In charge and evacuate using the
Emergency Escape Route to Assembly Point.
Extinguish and Tackle the fire with suitable fire extinguishers available in the area.
If extinguishing fire is not possible, he should see that fire does not spread to nearby
materials/areas.
Use fire hydrant hose from the nearest Fire Hydrant Hose Boxes if trained in use of Fire Hydrant.
Operate the quick opening valve for the Medium Velocity Water spray system, if the fire is in on
solvent tanks, if trained in the operation.
Only Trucks and Tankers with flame trap, spark arrestors is allowed inside the plant.
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Alternative
T. Venkata Rao- 304
Security Supervisor
Alternative
K.S.C.Sekhar
P.Sudhakar
D Srinivas
Venkateswara Rao
Venkateswara Rao
Raghu Ram
K. Vinu Kondaiah
K. Vinu Kondaiah
Brahmaiah
Ch. Srinivasa Rao
Mr. Rama Krishna
Mr Venkateswara rao403 - 101
Mr. Nannapenai Srinivas392/393 -201,202
Mr. Krishna Prasad
Mr. G. Srinivas
S.M. Nazeer
K. Srihari- 313
Satyanarayana
M.C.V. Reddy
Rangarao- 381
MPB- F block
MPB- G block
MPB- J block
Warehouse I, II, III and IV
Maintenance
E.T.P and ATFD and MEE
Q.C Building
Administration Building
========================================================
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Once receive the call from security or incident controller of any incident, he shall assess the
Situation quickly if possible and decide, if a major emergency is to be declared. If so, advice
Incident Controller /security (phone no. 335) to raise emergency siren accordingly.
On declaration of Major Emergency, ensure that outside help is called (Police, Fire Brigade, and
Ambulances) and if necessary NPCD is inform.
Ensure co-ordination between the Incident Controller and all the emergency team viz. Control
Team, Fire Fighting Team and Rescue Team First Aid and Medical Team, Stores, Transport,
Security, Engineering, Production etc.
In consultation with the incident controller direct the shutting down of the plant and evacuation of
the Personnel to safe locations, if required.
He declares emergency, directing other areas/blocks/section to stop processes
Ensure that any casualties are receiving attention, get additional help if required and ensure that
Relatives are informed.
Liaise with fire and police officers and advise them on effect outside the factory.
Ensure accounting of personnel.
Maintain continuous communication with Incident Controller and review the situation.
He is over all in charge of the emergency situation and spoke person for carrying out
Communication with Media / Press / Govt. Officials / NGOs, etc.
His task is to co-ordinate all the internal and external activities from the emergency control center
Located at Main Security Gate
Keep liaison with Government Officials viz. Factory Inspector, Director, Factories, Superintendent
of Police, Additional Fire Officer, and Pollution Control Board with assistance from Dy General
Manger EHS and Manager-Administration
Arrange for relief of personnel where emergency is prolonged with assistance from Manager(P&A)
If the toxic release extends to areas outside the factory premises and the emergency falls in the
Category IV, then inform the Police, Local Authorities like Gram Panchayat and the District
Emergency Authority specifically about such development and arrange evacuation, transportation
and Medical attention as required by the authorities.
Decide on termination of emergency, advice Incident Controller/security accordingly, and
Authorize the sounding of all clear siren.
Direct rehabilitation work on termination of emergency Ensure preservation of evidence.
========================================================
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Once receive the information from workmen / any other regarding incident, he shall rush to the
Spot and assess the situation quickly.
Communicate the emergency to the Site Controller immediately.
Give information to ECC security personnel (Phone 335) to raise emergency siren accordingly.
Incident Controller is the person directly responsible for controlling the disaster. He reports to Site
Incident Controller.
He handles the situation by arresting or containing the chemical release, or containment or
Suppression of Fire spread.
He advises Site Incident Controller about the magnitude of risk.
He arranges to segregate the material available in incident spot and arrange for its safe storage.
He brings the processes of the section to a safe position by stopping the process as situation warrants.
He ensures all his people are present at the assembly point and helps Security and Time Office in
Accounting the missing/trapped person, if any by taking roll call and recording.
He ensures that the injured persons are removed from the area of incident and brought to the safe
Place.
He guides the Core Team Members about type of reactions involved, the type of material in use
And in Stock around the hazard area, and controlling operations.
He Co-ordinates in arranging required personal protective appliances and ensures that fire
Extinguishers are available to the Fire Fighting team and Core Team Members tackling emergency
Situations.
He Co-ordinates with Safety & Security in incident control and in sending the injured for
Medical Aid.
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Invalidate all safety permits issued in the affected and near-by areas
Arranging replacement of used or exhausted safety items
To report accidents and emergencies to Government authorities as per legal requirements
Ensures the necessary PPE is available for emergency team
v) Medical Coordinator:
Maintaining a primary backup communications between the ECC and the blocks/sections
Communicate with external agencies like fire-brigades and hospitals
Alert neighboring areas
Arrangement of external medical treatment through factory medical officer
Sends messages to the key persons or to any plant persons, if required by a messenger
(Two vehicles are available at his command for this purpose.)
Providing services of his staff to the incident controller for closing down the services
Isolate the power supply where ever required
Arrange to carry out assigned duties pertaining to salvage of all engineering services including
water supply, power supply, telephone systems and fire pump operations
Providing emergency repair / power services as necessary
Erecting barricades and other vehicle movement control devices as necessary
Providing for debris clearance and effected site clean up as necessary
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Controlling the movement of employees and vehicles at the site and maintaining the access lines
for emergency vehicles and personnel
Security Officer shall communicate with Site Emergency Team about the Incident.
Preventing unauthorized entry into hazardous or secured areas
Assisting with the Medicare and handling of injured persons
Assisting with fire combat team if necessary
x) Supervisor/ Officer of the affected area /Block: He will carry out the following jobs.
Under the leadership of Senior Supervisor the fire fighting team will work promptly to arrest the
fire with the aid of the Fire extinguishers available there if
Emergency is of category I use fire extinguishers and if emergency of category II & III using fire
Hydrant, water monitor, foam monitor, fire extinguisher DCP trolley for extinguish the fire.
All helpers, operators and other supervisors who are trained in fire fighting and operational safety
will assist him in fighting the fire.
On arrival of the shift in charge/Block In charge to the spot, all the personnel will work under his
instructions.
xi) Executive - Production/QA-QC /Maintenance / Stores Executive/Shift In charges / Managers:
Execute all the jobs to stop spreading of fire
Instruct for closure of all valves on pipe lines carrying inflammable material entering into the section
The shift electrician / supervisor must always available in his work area so that he can contact /
instructed to switch off power supply to be affected block / section.
In case of Fire / Toxic release the ventilation system of the affected section / block should be
Switched off
AHU should be restarted after ensuring the people have been evacuated
The person should be allow to enter into section / block by the section in-charge after ensuring the
toxic gas / obnoxious gas is absent
Remain alert on duty for any electrical isolation of equipment during the emergency.
Ensure that adequate power supply is available for sensitive plant operations.
Keep the generators in readiness, in case of power failure during emergency.
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The ambulance driver on duty shall rush to the Parking Area, take over the ambulance, and await
instructions from the Site controller or Factory Medical Officer or Male Nurse and then rushes to
the incident spot.
He should park the ambulance in such a way that it is not very near to the affected area.
Ambulance should be parked in the opposite wind direction in case of toxic release
He should park ambulance in reverse direction, so that the victim can be put in ambulance easily.
On hearing the emergency siren, contact the section in charge for necessary action.
Do not leave your work area or go to the site of emergency and wait for the instructions for
evacuation.
If you are an employee of unaffected area, be ready to close down (shutdown) Operations / plant /
equipment in your work area.
Be ready to go to the nearby assembly point.
If you are present in an area, which is not your regular work place, inform the section in charge of
that area about your presence and follow his advice.
If you do not get any directions from the section in charge and if you happen to get affected at any
stage by the spreading toxic gas or fire, then act as indicated below:
In case you notice/smell leakage of toxic gas like chlorine then leave the place in cross wind
direction and precede the assembly point located in that direction.
Warn nearby employees, if possibly by shouting.
All hot work in progress within the factory limits must stop.
Affected Areas: The following factors should be checked off before normal operations may be
resumed. Permission from the authorities has been obtained.
Absence of explosive or toxic gases has been verified
The causes of the incident have been identified.
No new hazards have been created by the Incident.
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Location
Production
blocks
Ware house
area.
&Bulk
storage
yard.
2.
Services
Power
House
area.
Hazard
Fire
&
Explosion,
Property damage, injury
to human beings, Land
contamination
Burn and thermal heat
Fire
&
Explosion,
Property damage, injury
to human beings, Land
contamination.
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S.NO
Location
Q.C
Laboratory
Hazard
Fire & Explosion, air
pollution,
Property
while damage, injury to human
beings.
ENVIRONMENTAL EMERGENCIES:
S.NO
1
2
3
Location
Failure of water
pollution control
equipment
Dust collector at
boiler
Process scrubbers
Hazard
Water pollution and
contamination
Land
High
Location
Production
area
Hazard
1.
2.
3.
4.
1.
2.
3.
4.
1.
2.
3.
4.
Air pollution
Water pollution
Land contamination
Resource depletion
Air pollution
Water pollution
Land contamination
Resource depletion
Air pollution
Water pollution
Land contamination
Resource depletion
Any employee who notices a fire will shout FIRE-FIRE-FIRE to raise an alarm/to ring the
Fire bell at least 60 seconds. He will analyze the fire and immediately start the fire fighting
Operation with the use of fire extinguishers / buckets available in the department.
The person who hears him, he will then report the matter to his HOD/ In-charge.
HOD /In-charge of the department will immediately rush to the location of fire and inform
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regarding the type and nature of fire to Security, Safety department and to the plant manger
On the intercom phones, and for further action.
Shut-down & Leak Control Coordinator shall switch off the power supply to that area
Immediately to avoid further hazards.
The in-charge of that section informs the same to the Site controller.
Immediately after receiving the fire call, the fire combat will rush to the spot for fighting the fire
The Communications Coordinator asks the nearby fire station for further help in case of
Necessity.
Simultaneously while fighting the flammable, combustible materials, oxidants or explosives
Are removed to safer place wherever possible. If shifting of the above materials is not
Possible, the adjacent area also is sprayed with water as an additional precaution.
In case of any emission of toxic/ poisonous fumes while fighting the fire, the working
personnel shall use the mask with compressed air line / Self Contained Breathing Apparatus
(SCBA) set.
The Block / Section Coordinator shall bring all other process & activities to safe position or
Stopped.
The security department will instruct the guards to carry extra fire extinguishers and rush to
The location to take charges of the fire fighting operation.
If the fire is out of control, the safety officer arranges to start fire pump. Then he will rush
to the location and try to control the situation with the help of security guards, employees and
HOD.
The Safety officer and Factory Manger will assess the situation and call external agencies,
(Fire brigades), through phone calls for help if necessary. They will also inform all other
HODs concerned regarding the emergency.
In case of major fire, Security officer will give signal of alarm by operating the siren. When
the siren is given, evacuation of persons form the location of fire will be taken up as per
Instructions from the HOD. These persons shall assemble at locations identified as
Evacuation & Assembly points.
On the arrival of fire brigade, the in-charge of fire brigade will take charge of fire fighting
Operation and security officer with his team will assist him in the fire fighting operation.
The medical Coordinator will send ambulance and necessary stretchers to the scene and
Arrange for transportation and treatment of injured persons.
The Safety officer will give the information of the emergency to Government Authorities as
Per legal requirements. The Factory Manger will prepare written report of the incidence with
Help of Safety officer and send it to Government authorities and superiors.
FIRE AND EXPLOSION EMERGENCY IN SOLVENT TANK FARM AREA:
Solvent storage pool fire:
Methanol, Acetone, toluene, IPA Cyclohexene, and Hexane is a flammable liquid and having
flashpoint of less than 23 deg C. It is stored in horizontal tanks.
It takes approximately 2 hours for the leakage of 30 KL solvent from the tanks
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It takes approximately 14 hours for the vaporization of 1000 Kg of flammable solvent in a bund.
In the event of rupture of any solvent bulk storage tank, the entire quantity may spill into the dyke
area. If this dyke catches fire, the radiation effects will be higher than the tank fire.
The effect of radiation intensity levels from fires is given in Table No.1
The typical value and associated damage levels of thermal flux is given in Table No. 2
The consequence contour for Methanol Pool Fire is given in Drawing No.1
In case of pool fire, there will not be any harmful effect to the people up to a separation distance of
22 meter. The lower flammability limit distance for methanol vapour is 10 meter before it safely
disperses. If this vapour meets with an ignition source within the lower flammability limit distance
of 10 meter it will lead to a flash fire and pool fire as shown in the drawing No.1.
i) Solvent storage pool fire Damage caused at different incident levels of thermal radiation
S. No.
Incident
Flux KW/m2
1.
37.5
2.
25.0
3.
12.5
4.
4.0
5.
1.6
Harmful Effects
Strong sunlight
Related to a Safe exposure assuming that shelter is found within one
minute.
Related to the flux required to weaken structural steel within tens of
minutes.
Related to the flux required to weaken heavy structural steel within tens of
minutes
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28
4.0
18.0
37.5
12.5
12
1.
2.
3.
iv) Solvent storage pool fire: consequence contour for methanol storage pool fire:
The operator/technician after noticing fire/leakage in tank farm area informs 335/333 and
department in charges immediately.
Break the nearest manual call point immediately to alert the people.
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Take the nearest fire extinguisher to extinguish the fire if possible. Shout FIRE, FIRE / MANTA,
MANTA to alert the nearest person.
Emergency is declared by activating the siren, after noticing fire or explosion in tank farm area
Start using the fire hydrant points, water sprinkler, water monitor and foam gun kept near the tank
farm area.
Evacuate all the personnel in the tank farm area.
Stop all activities/loading unloading in the tank farm area
Cordon off the area and do not allow any person inside tank farm.
Inform Fire Station Shad Nagar/ Mahaboob Nagar about the Fire, if required.
Inform Chief Inspector of Factories and police station.
ii) Emergency procedure for Fire protection measures in solvent storage tank farm:
Following protective measures are provided for the solvent Storage Pool Fire Emergency.
Automatic deluge valve with MVWS (medium velocity water sprinkler) provided for all solvent
tanks.
Manual operated foam monitor system is installed over Solvent Storage Tank
Public address system available in tank farm area for communication
Portable Fire Extinguishers are kept in the solvent Storage Area.
The Fire Hydrant System surrounds the Solvent Storage Area.
Sand Buckets (12 Nos) are kept in the Solvent Storage Area.
Water monitors are installed at Solvent Storage tank farm area
300 Liters of foam Compound with a foam making branch is kept at solvent storage tank farm
All solvent tanks having condenser cooling with Flame arrestor provided.
Lightening arrestors provided to nearby area
Breather valves facility with Nitrogen blanketing provided to all flammable chemical storage tanks
MCP provided inside the solvent tank farm area
Hydrogen is highly flammable (2H2 + O2 2H2O). It can ignite in combination with as little as 23%
air (5% oxygen). Even small amounts of air in lines or storage tanks are potentially dangerous. In
addition, the friction caused by high-pressure gas passing through a narrow valve could theoretically
create enough heat to ignite hydrogen. Therefore, it is vital that no air be in lines. Before opening the
hydrogen gas valve, purge the line with nitrogen gas to eliminate air. On loss of containment, a harmful
concentration of hydrogen gas in the air will be reached very quickly. Hydrogen gas detectors have
been installed in the Storage and Reactor area.
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Fire: Extremely flammable. Many reactions may cause fire or explosion due to Gas/air mixtures.
Inhalation: High concentrations of this gas can cause an oxygen-deficient environment. The symptoms
of exposure to hydrogen are headaches, ringing in ears, dizziness, drowsiness, unconsciousness, nausea,
vomiting and depression of all the senses. The skin of a victim may have a blue color. Pre-existing
respiratory conditions may be aggravated by overexposure to hydrogen. Ensure fresh air and rest to the
victim. Artificial respiration may be needed. Inform OHC.
Detection of Hydrogen flame: Hydrogen also burns with an invisible flame, which creates the risk of
discovering a fire by walking into it. Before entering the suspected hydrogen leakage/fire area, detect
hot spot using Infrared Gun. As an alternative, use a straw broom attached to 15 feet stick to find
suspected flames. Burning of broom indicates presence of hydrogen flame.
Fire: Shut off supply / depressurize the line / equipment. If not possible and no risk to surroundings.
Let the fire burn itself out. In other cases extinguish with water spray, powder, carbon dioxide or
Nitrogen gas. Keep cylinder cool by spraying with water. Combat fire from a sheltered position to
prevent explosion. Evacuate personnel from the area.
The operator/technician after noticing fire or explosion in reactor break the nearest manual call
point and informs 335/333 and department in charge
Emergency is declared by activating the siren, after noticing fire or explosion in Reactor.
Start using the fire hydrant points near the Production block.
Evacuate all the personnel in the production block. After announcement in the public address
system
Stop all activities in the production block
Stop all addition immediately in the production block
Cordon off the area and do not allow any person inside tank farm.
Inform Fire Station Shad Nagar/ Mahaboob Nagar about the Fire, if required.
Inform Chief Inspector of Factories & Boilers on Phone
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The operator/technician after noticing fire or explosion in centrifuge break the nearest manual
call point and informs 335/333 and department in charge
Emergency is declared by activating the siren, after noticing fire or explosion in Centrifuge.
Start using the fire hydrant points near the Production block.
Evacuate all the personnel in the production block. After announcement in the public address system
Stop all activities in the production block
Stop all additions immediately in the production block
Cordon off the area and do not allow any person inside tank farm.
The operator/technician after noticing fire or explosion in Boiler break the nearest manual call
point and informs 335/333 and department in charge
Emergency is declared by activating the siren, after noticing fire or explosion in Boiler.
Start using the fire hydrant points near the boiler House.
Evacuate all the personnel near the boiler area to assembly area. After announcement in the
public address system
Cordon off the area and do not allow any person inside tank farm.
Inform Fire Station Shad Nagar/Mahaboob nagar about the Fire, if required.
The operator/technician after noticing fire or explosion in ETP break the nearest manual call
point and informs 335/333 and department in charge
Emergency is declared by activating the siren, after noticing fire or explosion in ETP.
Start using the fire hydrant points near the boiler House.
Evacuate all the personnel near the ETP area to assembly area. After announcement in the
public address system
Cordon off the area and do not allow any person inside tank farm.
Inform to Fire Station Shad nagar/Mahaboob nagar about the Fire.
Inform Chief Inspector of Factories & PCB, Hyderabad.
Clean up the area with water.
The operator/technician after noticing fire or explosion in DG break the nearest manual call
point and informs 335/333 and department in charge.
Emergency is declared by activating the siren, after noticing fire or explosion in DG.
Start using the fire hydrant points near the DG area.
Evacuate all the personnel near the DG area to assembly area. After announcement in the
public address system
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Cordon off the area and do not allow any person near D.G. House.
Inform Chief Inspector of Factories & Boilers on Phone
Inform Police Station
Clean up the area with water.
In case of Fire:
Sodium hydride (NaH) in the dry state is pyrophoric. The product is purchased as relatively safe
dispersion in Paraffin oil. Ignites spontaneously at room temperature in moist air. Reacts violently with
water, liberating highly flammable hydrogen gas; causes severe burns on eye or skin contact. Sodium
hydride reacts with the moisture on skin and other tissues to form highly corrosive sodium and
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potassium hydroxide. Contact of these hydrides with the skin, eyes, or mucous membranes causes
severe burns; thermal burns may also occur due to ignition of the liberated hydrogen gas.
In case of Fire:
Reacts violently with water, liberating highly flammable hydrogen gas; causes severe burns on eye or
skin contact. Sodium reacts with the moisture on skin and other tissues to form highly corrosive sodium
hydroxide. Contact of metallic sodium with the skin, eyes, or mucous membranes causes severe burns;
thermal burns may also occur due to ignition of the metal and liberated hydrogen.
Sodium spontaneously ignites when heated above 115 C in air that has even modest moisture content,
and any sodium vapor generated is even more flammable. Sodium reacts violently on contact with
water and often ignites or explodes the hydrogen formed.
In case of Fire:
If anybody noticed, break the nearest manual call point.( Red colour)
Call 333 or walky talky to inform security gate.
Break the MCP of power shut down.( Blue colour)
Evacuate personnel from the area. Follow public address instructions.
Sodium fires must be extinguished with a class D dry chemical extinguisher or by the use of
sand,
Ground limestone, dry clay or graphite.
Water or CO2 extinguishers must never be used on sodium fires.
Use Self Contained Breathing Apparatus while fighting sodium metal fire. Use Nomex Suit.
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Use full PVC suit, Breathing apparatus, Rubber hand gloves, safety Shoes.
Use PVC apron, Rubber hand gloves, safety goggles and face shield (8 inch a Minimum.)
If anybody smell or small leakage observed, inform to PB-V production block in charges
immediately.
If major leakage observed, break the nearest manual call point.
Call 333 or walky talky to inform security gate.
In case of leak Evacuate the people to safe area
Responders must wear SCBA and PVC suit, never direct water jet on liquid.
Use emergency kit for arresting leaks.
The emergency kit provided for chlorine leak from toner can also be used.
Always stand in up wind direction while attending to chlorine leak.
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a)
b)
Human Effects
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Source: Chlorine Toxicity Monograph, Revised Edition 1989 institution of Chemical Engineers, UK
Safety measures for chlorine tonner storage area: Following safety measures available in chlorine
Shed.
Hydrogen Chloride is released in different reactions in the plant. The gas so released is drawn
through suction blowers and is neutralized through a scrubbing mechanism. The Maximum release
rate is assumed as 20 kg/hour, considering power failure, scrubber failure (for reasons of operational
failure or mechanical failures)
It is assumed that there could be a failure to draw so released Hydrogen Chloride gas for
various reasons like a mechanical failure of blower, power failure, no scrubbing medium in scrubber
tank etc. Out of all the processes considered in this analysis, IDLH: 50 ppm
Effects of HCL at various concentrations:
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S.No
1
2
3
4
Effects
Barely Tolerable
Throat Irritation
Tolerable
Immediate Irritation
Dry hydrogen chloride is a toxic, colorless, liquefied compressed gas with sharp pungent odor.
Corrosive and irritating to the eyes, skin, and mucous membranes. Inhalation may result in
chemical pneumonitis, pulmonary edema.
Reacts with water or moisture in the air yielding dense, acrid HCL fumes. Reacts with fluorine,
calcium carbide, cesium carbide, rubidium carbide, and lithium silicide. Reacts vigorously with
alkalis and many organic materials with liberation of heat. Strong oxidizers cause release of
chlorine.
The operators engaged on handling of dry HCl gas cylinders must wear clean Gloves, ABM
and safety shoes.
While handling, cylinders must not be allowed to be dropped or permitted to strike against each
other.
Cylinders should be protected against direct sun (< 52C) when in use or under storage.
Transporting of dry HCL cylinders must be done by means of a cylinder trolley etc.,
Specially meant for cylinder transport. It is strictly prohibited to carry on shoulders or rolling
on the ground.
The safety devices provided on the cylinders must not be tampered with. Ensure availability of
Valve protective cap.
Cylinders should not be used as rollers, supporters or any other purpose than to contain gas.
Never strike an arc on a gas cylinder. Never allow a cylinder to contact Electric lines or wires.
In case of HCL Gas leak:
If small leakage observed, inform to ware house in charges immediately.
If major leakage observed, break the nearest manual call point.
Call 333 or walky talky to inform security gate.
In case of leak Evacuate the people to safe area
Responders must wear SCBA and PVC suit, never direct water jet on liquid.
Remove gas with fine water spray.
Stay in the upwind direction
Use emergency kit for arresting leaks. The emergency kit provided for chlorine leak from toner can
also be used.
xv) EMERGENCY PROCEDURE FOR HANDLING AMMONIA LEAK:
Ammonia is handled in cylinder in the plant. Assuming that one cylinder of Ammonia (50 kg). The
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Vapour concentrations over a period of one hour are computed for day and night conditions for IDLH
Level of exposure.
The following is result of such modeling: Day Condition
Wind: 1.5 meters/second from s at 3 meters
Ground Roughness: open country cloud Cover: 5 tenths
Air Temperature: 42 C
Stability Class: B
Direct Source: 50 kilograms
Source Height: 0
Release Duration: 1 minute
Red : 217 meters --(300 ppm = IDLH)
Night
condition:
Air Temperature: 12 C
Red: 736 meters ---
Stability Class: F
(300 ppm = IDLH)
Toxic effects
of ammonia release at different concentrations:
Concentration
General Effects
25 ppm
Odour detectable normally
100 ppm
No adverse effect on average
workers
400 ppm
Nose and Throat Irritation
700 ppm
1700 ppm
2400 ppm
5000 ppm
Exposure Period
Maximum 8 hours
Deliberate exposure for long periods not
allowed
No serious effects after immediately 30 to 60
mts
No serious effects after 30 to 60 mts
Could be fatal after 30 mts
Fatal after 30 mts
Fatal within minutes
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10000ppm
Rapid asphyxia
Ammonia is a Corrosive liquid and gas under pressure. Harmful if inhaled. Causes eye, skin, and
Respiratory tract burns. May cause kidney and respiratory system damage, Can catch fire. It is
Colorless liquefied compressed gas packaged under its own vapor pressure of 114 psig at 70 F.
Ammonia can cause severe eye, skin and respiratory tract burns. Overexposure may also cause
Central nervous system effects including unconsciousness and convulsions. Upper airway damage is
More likely to occur.
It poses an immediate fire and explosion hazard when concentration is in between 16% - 25 %,
Therefore, area must be ventilated.
Hand Gloves, ABM and safety shoes must be worn while handling of Ammonia gas cylinders.
Cylinders must not be allowed to be dropped or permitted to strike against each other.
Cylinders should be protected against direct sun (< 52C) when in use or under storage.
Transporting of Ammonia cylinders must be done by means of a cylinder trolley etc. specially
Meant for cylinder transport. It is strictly prohibited to carry on shoulders or rolling on the ground.
Responders must wear SCBA and PVC suit, never direct water jet on liquid.
Carefully throws polypropylene booms / pillows around and on the spill to prevent the spread
of
The spill.
Absorb the spill with polypropylene pads and squeeze the pads into disposable container.
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Pour dry sand on the spill and collect into disposable container. Neutralize the contaminated
area with about 5% Hydrochloric acid.
Flush the contaminated area with water to ETP till washings pH on pH paper is 6.0
7.5.
Send the disposable container containing Base liquid to effluent treatment plant,
disposable container containing Polypropylene pads, Booms to Incinerator and disposable
container containing contaminated sand to ETP Sludge drying beds for proper
detoxification.
(THE SULPHURIC ACID, NITRIC ACID AND HYDROCHLORIC ACID AND SODIUM
HYDROXIDE):
Spillage may cause disaster due to spreading and contaminating with other incompatible
materials.Hence, the following measures are planned to control & contain such situations.
Adsorbents pads are used for small quantity spills.
The corrosive effect of these acids & bases either on metals or human tissues is due to their
affinity towards moisture. Hence to prevent corrosion with moist acid& base the vent lines are
provided with moisture free traps. At the time of emptying it is only dry air that fills the tanks.
In case of spillage of the acid & base plenty of dry sand is kept for dumping followed by de
harming with soda ash etc., wearing air mask, rubber gloves, full body PVC suit and gumboots.
Suitable bunds are provided around storage tanks to prevent the spreading and thereby isolating
and de harming.
Medical officer, First Aid, emergency team and fire departments are kept informed for rescue
operations.
The affected persons are removed to fresh air for instituting artificial respiration. Transfer the
injured persons if any, to Occupational Health Center for medical help.
In case spillage of the material, plenty of dry sand is kept for dumping around spills, followed
by wearing, rubber gloves, full PVC suit and gum boots etc.
Suitable bunds are provided around storage tanks to prevent the spreading and contaminating
the surrounding land.
People are evacuated and affected persons are removed to fresh air for giving artificial
respiration.
Dont use water to dilute the acid or flushing the spillage to drain
Wear full body suit/SCBA for handling emergency
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The corrosive effect of these acids either on metals or human tissues is due to their affinity
towards moisture. Hence to prevent corrosion with moist acid the vent lines are provided with conc.
Sulphuric acid traps. At the time of emptying it is only dry air that fills the tanks.
In case of spillage of the acid plenty of dry sand is kept for dumping followed by de harming
with soda ash etc., wearing air mask, rubber gloves, full apron and gumboots.
Suitable bunds are provided around storage tanks to prevent the spreading and thereby isolating
and de-harming
The affected persons are removed to fresh air for instituting artificial respiration
========================================================
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The area should be immediately evacuated particularly downwind area and Restrict access to the
area until completion of recovery and cleanup.
Eliminate all ignition sources and provide adequate ventilation depending upon the nature of the
chemical.
Stop or reduce leak if safe to do so.
Contain the material with earth sand or absorbent material which does not Reactive with spilled
material.
Recovery and cleanup should be done the trained personnel only. The person cleaning the spilled
material should wear required Personal Protective Equipment (PPE) such as respiratory cartridge
mask, safety goggles, gumboots, PVC Suit and rubber hand gloves etc
Do not touch the spilled material and avoid prolonged and repeat exposure to Toxic chemicals.
Prevent spilled material entering waterways, sewers or drainages.
Ground the containers if the spilled materials generate the static electricity.
Vacuum / sweep up the spilled material in an approved, portable and suitable containers as mentioned
the MSDS.
Place the containers with covers, labels and in suitable locations.
After recovering the material, cleanup the area with suitable absorbent Material as mentioned in
the MSDS.
Flush the area with water if it is required.
========================================================
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The chemical spillage occurring in open ground not having secondary containment is first
retained at the spilled area by making a containment bund by using sand or murram (sand) around
spills.
If the spill is small. The spillage is then absorbed using absorbent pads and collected in a
double poly liner bags using PPE as per spill control procedure.
Sealed properly and sent to ETP department along with a waste transfer note for further
disposal.
If the spillage has entered into nearby storm water drains, then efforts must be made to retain in
storm water drains by putting sand bags.
If possible. If this cannot be achieved, then divert the spillages to fire water collection pit by
operating the valve towards firewater collection chamber.
This spill then will be pumped to drums/tanker for disposal to waste disposal site or to our
Incinerator.
All close rooms are installed with oxygen sensors for monitoring oxygen. Normal oxygen will be
showing in sensor is 21 - 21.9% all the time.
In case of oxygen concentration reduced by less than 18.5% v/v due to nitrogen leakage, oxygen
sensor will activate and give buzzer sound.
Once hear the buzzer sound evacuate the place immediately.
Information should be given to block in charge for leakage of nitrogen
Block in charges will rush to the area and keep close the inlet of nitrogen line and open the door
and windows to increase the oxygen level.
After 20-30 minute, safety department will check the oxygen concentration in the area by portable
meter.
If oxygen is found more than 18.5%, then rectify the pipeline leakage and correct the same.
Check the leak test with pressure if found no leakage then hand over to production department
Again calibrate the oxygen analyzer then keep in ON.
Call immediately to 333/335 or
Contact immediately on walky talky
Evacuate the people from the affected area. If required
After 20-30 minute, safety department will check the Oxygen level concentration in the area by
portable meter
xx) EMERGENCY PROCEDURE FOR HANDLING LPG GAS LEAK IN CANTEEN AREA
LPG sensors installed for monitoring LPG in the canteen. Normal LPG level will be showing in
sensor is ZERO all the time.
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In case of LPG leakage and concentration reaches to 20% of LEL sensor will activate and give buzzer
sound.
Once hear the buzzer sound close the cylinder valve immediately.
Information should be given to canteen in charges for leakage of LPG
Canteen in charges will rush to the area and keep open the door and windows to dilute the LPG.
After 20-30 minute, safety department will check the LEL concentration in the area by portable meter.
If LEL is found ZERO then rectify the pipeline leak/cylinder leak and correct the same.
Check the leak test with pressure if found no leakage then hand over to canteen
Again calibrate the LEL sensor and keep in ON.
If observed the cylinder leakage disconnect the cylinder and bring cylinder to outer atmosphere
Break the nearest MCP, inform his supervisor about incident
Call immediately to 333/335 or
Contact immediately on walky talky
Evacuate the people from the affected area. If required
Inform power house to switch off the main switch
If anybody notice the fire in canteen, break the nearest manual call point immediately.
Extinguish the fire with portable fire extinguisher if possible immediately
Call immediately to 333/335
Contact immediately on walky talky
Break the nearest MCP, inform his supervisor about incident
Inform to canteen in charges about fire
Evacuate the people from the canteen. If required
Start fire hydrant system to extinguish the fire if required.
Evacuate the people from the affected area. If required
Inform power house to switch off the main switch
After 20-30 minute, safety department will check the LEL concentration in the area by
Portable meter
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If phosgene leakage sensor will activate and give the local alarm
Break the MCP if necessary (multi inhalation), inform supervisor about incident
Call immediately to 333/335 or
Contact immediately on walky talky
Inform to Block in charges about leakage
Evacuate the people from the affected area. If required
Inform to medical officer for HCl about inhalation.
Send affected personnel to hospital for treatment
========================================================
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Stop all operations immediately. Close all valves of solvent storage tank
Switch off power supply to avoid electrocution due to short circuit.
Evaluated information will be disseminated to personnel.
Shift the water reactive material to elevated places like racks / building as appropriate.
Activate the onsite warning and instructional system as necessary.
Follow unit shut down procedures and Shutdown Electrical power.
Control water flow by dike arrangement using sandbags, and or pumping.
Start up after checking and clearing water from each and every unit.
The factory premises is situated in Hyderabad which falls under Zone II under Seismic zone
classification and accordingly the probability and impact will be least to moderate.
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DROP to the ground; take COVER by getting under a sturdy table or other piece of furniture; and
HOLD ON until the shaking stops. If there isnt a table or desk near you, cover your face and head with
your arms and crouch in an inside corner of the building.
Stay away from glass, windows, outside doors and walls, and anything that could fall, such
as lighting fixtures or furniture.
Stay inside until the shaking stops after that it is safe to go outside.
Do not attempt to move to a different location inside the building or try to leave.
Be aware that the electricity may go out or the sprinkler systems or fire alarms may turn on.
DO NOT use the elevators.
If staying outside the building move away from buildings, streetlights, utility wires. And stay there
Until the shaking stops.
If in a moving vehicle stay in the vehicle. Proceed cautiously once the earthquake has stopped
The information is passed on to plant manager and he will immediately coordinate with all the
internal and external agencies for necessary action / help.
The Occupational Health Center / medical officer is informed to meet the emergency. The
ambulance is kept ready to take the injured persons.
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Nearby hospitals are informed explaining the nature of the accident for keeping necessary medical
facilities.
The concerned team will act according to the situation to avoid confusion and panic.
There is public address system in administrative building connecting all the areas, through which
all the concerned are alerted.
Nearest police station is informed explaining the nature of accident and precautions to be taken by
the people in the surrounding area.
The responsible officers inform the families of the injured persons and transport is provided for the
families of the injured persons.
========================================================
======================================
manual bag with pure O2. If neither is immediately available then the prone pressure method of
mouth-to-mouth resuscitation may be used.
Note: Maintaining an adequate airway is mandatory.
Have an assistant, break a Durule Amyl Nitrite Inhalant in a handkerchief and hold it in front of the
patients mouth for 15 seconds followed by a rest for 15 seconds. Then reapply.
Wash off any cyanide present on the skin. Remove any clothing that is contaminated by cyanide.
Keep the patient warm.
Specific Therapy (To be used at the discretion of doctor, nurse, or paramedic)
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the hospital. In addition to the ambulance, fleets of other vehicles like jeeps and pickup vans are
also available if the situation demands.
Statutory obligations:
Necessary information is sent to the following authorities as required by statute.
Local health authority.
Inspector of factories, Mahaboob Nagar Dist
The station house officer of nearest police station, Kothur and District Medical officer
Mahaboob Nagar Dist
Once the incidence of food poisoning is confirmed, the matter is communicating immediately
to the nearest Hospitals and Police Station.
Communicate Immediately to the Inspector of factories and Dy. Chief Inspector of Factories
Mahaboob nagar
Vehicles are kept ready for quick transportation.
Meanwhile First Aid is given to the affected persons.
The source of the poisoning may generally be canteen. Hence, the contaminated food is kept
Separately to avoid others getting affected.
Necessary information is sent to the following statutory authorities by the Incident Controller
As given below:
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After the emergency comes under control, Site controller (SC) along with fire and safety
coordinator will go around all the areas and confirm total control of the situation.
Communication coordinator will check for head count and tally employees and organize further
efforts through incident controller for search of missing persons.
After ensuring tally of head count and confirming control of emergency incident controller will
communicate end of emergency to site Controller who in turn assess the situation and inform
security to go on long-siren to declare End of Emergency.
At the sounding of All Clear Siren (three minute long siren)
Also site controller will do the announcement through the public address system for cease of the
Emergency.
Work in the unaffected areas of the factory shall resume.
EVACUATION PROCEDURE
For the purpose of this procedure, evacuation means withdrawal of personnel form places of work
in an Emergency.
All fires or dangers occurrences need not necessarily be followed by an evacuation.
If a fire or a dangerous occurrence is of a minor nature (i.e., very easily and quickly controllable),
Evacuation is not necessary.
If a fire or dangerous occurrence is likely to spread over a large area, goes out of control and is
likely to endanger the lives of the staff of the factory.
Evacuation of the employees of the entire factory is necessary.
The following procedures have been drawn mainly with a view to moving personnel form their
place of work to a safe place as quickly as possible and in an orderly manner, when a situation
arises where evacuation becomes necessary.
a) Sectional / Departmental Evacuation
When a fire or a dangerous occurrence (explosion, spread of fumes / vapors etc.) takes place, the
block in-charge or the section head or the production officer will immediately:
Make an on-the-spot assessment whether the situation warrants evacuation by the staff
Ensure that all operations have been brought to a satisfactory STANDSTILL STATE.
Order evacuation either orally or by blowing the whistle long blasts with short breaks in between.
Ensure that the visitors / contractors also evacuated.
Follow the public address system instructions.
b) Department head or the production manger or the production officer will immediately
Ensure that all operations have been brought to a satisfactory STANDSTILL STATE.
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Ensure an order has been given to evacuate, move quickly to the assembly point through the safe
exit in an orderly manner by the route.
Follow the instructions through public address system.
Ensure that no one exists in the section / department which is to be evacuated.
After the evacuation, take a roll call of the members of the concerned department in the assembly
points from the muster roll.
Report the missing names to the department head / security in charge / security guard.
Members of staff working in another department when an evacuation is announced will join the
staff of that department and proceed along with them to the evacuation assembly point of the
department where dangerous incident fire has occurred.
Staffs who are temporarily away from their place of workman evacuation has been ordered should
proceed to the evacuation assembly points and report about their safety to the department head or
their supervisor.
When staffs are away from their department, their department heads should be kept informed about
their whereabouts.
Block In-charge
Incident controller
Security gate
Main Gate & Other Production Blocks:
One person in each block will be available near the department Internal telephone, to receive all
communications from Incident Controller. / follow the instructions through Public address system.
Security Officer shall communicate the Emergency to the following Persons:
Site Controller
Incident Controller
Emergency Coordinator
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The Communication Co-Ordinator through Site Controller will communicate with the required external
emergency services like fire brigade, hospitals and ambulance services etc. He will be in continuous
contact with incident spot, other production blocks, Assembly points and alert neighboring areas. Also he
will be responsible for updating the higher authorities.
Post-Emergency Procedure:
Review the incident; identify the remedial measures and implement. Disseminate the information within
the unit to prevent recurrence. Report to statutory authorities as applicable.
RECOVERY PROCESS PLAN
Introduction: Towards re-establishing normal operations at the earliest after an emergency the
following procedure will be followed. The section is divided into five parts:
1. Reconstruction of the accident scenario
2. Incident investigation
3. Establishing a recovery team
4. Damage assessment
5. Clean-up and Restoration
Post-Emergency and Recovery reporting after the major emergency has been cleared the scene needs
reconstruction with the help of persons who were associated with the scenario.
Incident investigation: To investigate the cause of the emergency and to prevent recurrence of the
incident requires thorough investigation. The investigation team should immediately seal off the
incident scene and commence its investigation to minimize the loss of any physical evidence.
The investigation of the scene should include photographing the area, identifying equipment from
fragments and note unusual items.
Written or recorded statements are to be taken from all operators involved, potential witnesses and
others who might have pertinent knowledge about the incident.
Report: A final report will be prepared giving details about the basic reason for the accident and will
work as a failure report covering equipment, maintenance, procedure, training, human error etc.
Recovery Team: In order to facilitate the restoration of normal operations of the company after an
emergency, a team is to be constituted by Chief Emergency Controller to manage recovery activities,
including damage assessment.
As a general rule, however, individuals representing Maintenance, Production, safety, Quality Control,
Accounts, Engineering etc., will be involved.
The recovery team is responsible for damage assessment, Clean-up and salvage operations and the
restoration of normal operations. A primary function of the recovery team will be to assess the damage
to structures, equipment and materials.
Clean-up and restoration operations:
As soon as incident investigations are completed and restoration plans have been made, clean-up and
restoration activities will commence.
Damaged equipment:
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Prior to restoration of normal operations, all affected equipments are to be tested and checked according
to procedures established.
Post-emergency recovery reports:
The officer-in-charge of Safety will hold review sessions with emergency response personnel to
evaluate: The adequacy of emergency response procedures.
1.
2.
Mitigation measures:
Following are safety measures and also the mitigation measures recommended to prevent any disastrous
situation listed under consequence scenario.
Fire fighting system (Fire extinguishers) is provided and the adequacy of the fire fighting system
may be assessed from consideration of minimizing the heat radiation effects due to jet fire, fireball
and flash fire.
Fire fighting system, Hydrant system, is introduced to mitigate the fire and exposure within a short
time.
Detectors are installed to detect and raise an alarm / alert.
Operating people should be educated on the results of Risk Analysis and prepare suitable action
plan to reduce the hazards under such situations.
All the personnel working inside the factory should be trained in various aspects of emergency
situations. Training program should be laid down for new employees and refresher training program
for the continuing employees.
Emergency Response Plan should be updated based on the risk analysis carried out for various
scenarios of the factory. Periodical drills to carry out to attack the situations cited.
Electrical continuity for the earthling of hydrocarbon tanks and pipelines should be ensured and
recorded at regular intervals to minimize static charge collection.
Personnel protective equipment should be placed and audited to make use during the emergency.
========================================================
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Mutual Aid:
In the major emergency situation, recourses over and above those available at the works will be needs.
As the fire brigade reinforcement are relatively nowhere in our area, we may require additional sources
of extra supplies of firefighting equipment, breathing apparatus, manpower, ambulance and medical
Facilities. By our request at time of major emergency situation, the above-mentioned additional sources
of extra Supplies can be provided by the Mutual aid neighborhood plants.
S.No
Name of the
Company with
Location
XXXX PHARMA
1.
LIMITED
1.
Chemical Division,
Mekaguda
Distance
Away
from
XXXX
Contact Person
Designation
Contact Phone
No:
Executive
Vice President
CES
9866005215
--
Mr. P.S.R.K.
Prasad
--
Mr. Prakash .B
DGM- EHS
8790560899
10 Km
Mr. Sekhar
Kumar
Sr. Manger
Plant
9490958127
13 Km
Mr. Badi
9848051530
5.
HBL KNIFE Power
4.
Systems Ltd
08 Km
Executive
Director
9394403020
6.
Anus Laboratory,
5.
Chilakammary
14 Km
Mr. E. Bhaskar
Rao
Plant Manger
9849201118
7.
Actus Pharma
6.
Limited, Kothur
9 Km
Plant
Manager
9948320730
XXXX PHARMA
2.
LIMITED
2
Chemical Division,
Mekaguda
3. Indian Oil
2. Corporation Limited,
Kothur
4. OCV
3. Reinforcements,
Thimmapur
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Phone
1.
040 101
040 24600009
040 23260091
2.
08542 - 242299
3.
040 27842306
4.
040 24460722
5.
040 24553230
Responsibility
08458-251821
7.
08458-253687
8.
9.
10.
11.
Gandhi Hospital,
12.
13.
Provision of ambulance
for transport of casualties
and medical treatment of
casualties
040 23607777
040 23320332
040 23318120
040 23319999
040 27713333
040 27702222
040 24600122
040 23701232
040 23701233
08458-257233
15.
08458-252333
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S.No
NAME
Mobile Number
9866005215
Dr. D. Lingarao
9866005214
9866005196
N. Satya Narayana
9949533374
B. Prakash
8790560899
9849735219
P. Chiranjeevi Rao
9848196822
M. Nageswara Rao
9550240469
M. Prasada Rao
9490792732
10
K. Srinivas
9441803839
11
Dr Nandur
9985117079
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FIRE HYDRANT PUMP DETAILS: Fire hydrant water storage capacity: 600m3
1
========================================================
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8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
Water Monitor
Fire Escape Hydrant
Hose reel
Fire extinguisher
Fire extinguisher ( spare)
Deluge Valve with water sprinkler
CI alarm valve with water sprinkler
Foam monitor
Water monitor
Foam stock
Fire Suit
SCBA sets
5x Foam gun
Jet nozzles
Revolving nozzles
Water curtain nozzle
Jet and spray nozzle
Foam making nozzle
Foam solution
DCP Powder
SCBA sets
Chemical Cartridge masks
Normal fighting suits
Life jackets
Fall arrestor
Safety Net
Grip Ladder
PVC aprons
Nomax fire suit
Aluminized fire suit
5 Nos
7 Nos
37 Nos
412 Nos
20 Nos
11 Nos for 57 tanks
3 Nos
5Nos
5Nos
4200 Lts
4Nos
7Nos
20 Nos
57 Nos
1 No
2 No
10 No
20 Nos
4300 lts
600 kgs
6 Nos
66 Nos
6 Nos
4 Nos
10 Nos
12 Nos
6 Nos
15 Nos
03 nos
01 no
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DCP in Kgs
Location
R&D
QCD
QA
P&A
Canteen
Ambulance
Medicare
Security
gate
Quarters
Service-I
Service-II
N2 plant
DM plant
Compresso
r RM
Ice plant
Boiler
Power
House
Ware
house-I
Ware
house-II
WH-III
Ware
house-IV
Solvent
yard
ECC
Safety
Fabrication
yard
10
22.5
No of Fire Extinguishers
CO2 in Kgs
FOAM in Ltrs
150
2
1
2
1
2
4.5
1
3
50
150
Halatron
Kg
2
5
5
2
5
3
1
1
1
1
2
1
1
1
1
1
1
2
6
6
15
14
6
2
1
1
1
2
17
1
1
4
3
2
1
1
2
1
1
Total
2
17
5
2
5
1
1
1
1
2
1
2
8
3
6
Page 86 of 88
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Kilo Lab
Pilot Plant
PB-I
PB-II
PB-III
PB-IV
PB-V
PB-VI
PB-VII
MPB-A
MPB-B
MPB-C
MPB-D
MPB-E
MPB-F
MPB-G
MPB-J
ETP
RO plant
SRP
Incinerator
MPB-CKL
MPBServices
5
5
2
1
1
1
5
3
4
5
7
7
4
1
1
5
5
1
1
2
1
2
1
4
5
7
1
1
2
2
16
16
2
1
1
2
1
2
2
1
1
1
2
2
2
5
8
6
2
1
1
1
3
1
1
3
2
3
1
1
1
1
5
2
1
1
2
1
17
27
22
10
4
6
9
10
13
20
11
7
3
6
27
27
6
6
34
33
21
5
4
2
6
5
18
5
412
Page 87 of 88
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LIST OF ABBREVIATIONS
CES
ECC
EPRP
ERT
ETP
EVP
FLP
HOD
HSD
IDLH
KL
LEL
MPPB
MSDS
PB
PEL
PP
PPE
PPM
PVC
SCBA
STEL
TLV
UEL
VP
MCP
PAS
DCP
Page 88 of 88
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