Beruflich Dokumente
Kultur Dokumente
[*]
[**]
COMMUNICATION
DOI: 10.1002/adma.200702304
1679
COMMUNICATION
1680
www.advmat.de
COMMUNICATION
www.advmat.de
1681
COMMUNICATION
Experimental
The polymers that we have used in the work reported in this paper
are poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) from H.C. Starck; regioregular poly(3-hexylthiophene)
(P3HT) from American Dye Source; poly[(9,9-dioctylfluorene)-cobenzothiadiazole] (F8BT), a blend of 95 wt% poly(9,9-dioctylfluorene)
(PFO) and 5 wt% F8BT (5BTF8), and proprietary red, green and blue
emission LumationTM series polyfluorenes from the Sumitomo
Chemical Co., Ltd. In addition we have used the soluble fullerene
[6,6]-phenyl C61-butyric acid methyl ester (PCBM) and glycerol from
SigmaAldrich. Solutions (10 mg ml1) of 5BTF8 and red, green and
blue LumationTM polymers were prepared in chlorobenzene. P3HT
was dissolved (20 mg ml1) in chlorobenzene. Chlorobenzene blend
solutions comprising P3HT (20 mg ml1) with PCBM (20 mg ml1),
and F8BT (20 mg ml1) with PCBM (20 mg ml1) were also prepared.
Glycerol solutions (500 mg ml1) were prepared in water or
isopropanol. Layers of polymer and polymer/polymer or polymer/
PCBM blends were deposited by spin-coating on flat PDMS blocks.
Thicknesses were typically of order 100 nm for PCBM:P3HT blends,
45 nm for F8BT:PCBM blends, 15 nm for P3HT, and 20 nm for the red,
blue and green LumationTM polymers and the 5BTF8 blend. The
EB/HTL[a]
CGL[b]
HB/ETL[c]
Cathode
N/A
P3HT (15 nm)
P3HT (15 nm)
N/A
N/A
F8BT:PCBM (45 nm)
LiF/Al
LiF/Al
LiF/Al
[a]Electron Blocking/Hole Transport Layer. [b]Charge Generation Layer. [c]Hole Blocking/Electron Transport Layer.
1682
www.advmat.de
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
www.advmat.de
COMMUNICATION
1683