Beruflich Dokumente
Kultur Dokumente
CHAPTER 7
ACIDS AND BASES
Arrhenius Theory
A base defined as a
chemical substance
that can neutralise an
acid to produce a
salt and water.
An acid is a chemical
compound that
produces hydrogen ions,
H+ or hydroxonium ions
H3O+ when dissolve in
water.
An alkali is defined as
a chemical
compound that
dissolve in water to
produce hydroxide
ions, OH- .
Example
HCl (g)
H2O
NaOH(s)
H2O
Na+(aq) + OH-(aq)
130
BASICITY OF AN ACID
Is the number of ionisable hydrogen atoms per molecule of an
acid.
Monoprotic Acid
Diprotic Acid
Triprotic Acid
131
STRONG ACID
WEAK ACID
WEAK ALKALI
132
pH Value
Conduct
electricity
Litmus paper
ALKALI
Litmus paper
pH Value
ACID
Taste
Corrosive
Corrosive
Taste
Conduct
electricity
133
134
dm3
Grams per
( g dm-3)
*known as Molarity
Concentration
Unit Conversion
Grams per
dm3 ( g dm-3)
molar mass
molar mass
Example
1. The molarity of a bottle of nitric acid, HNO3 solution is 2.0 mol dm-3.
What is the concentration of the solution in g dm-3?
[RAM: H, 1 ; N, 14 ; O , 16]
135
1.
2.
A 250 cm3 nitric acid solution contains 0.4 moles. Calculate the
molarity of the nitric acid.
136
3.
4.
5.
6.
137
7.
8.
138
9.
Stock solution
Add water
Dilute solution
139
Exercise
1.
Find the volume of 2.0 mol dm-3 sulphuric acid, H2SO4 needed to
prepare 100 cm3 of 1.0 mol dm-3 sulphuric acid, H2SO4.
2.
b)
140
3.
4.
5.
141
Neutralisation
Acid-base titration
Reaction of an acid
and a base that
produce salt and
water.
Acid-base indicator is
used to detect the end
of titration.
Eg: methyl orange,
phenolphthalein and
litmus.
An acid of known
concentration is
carefully delivered from
burette to completely
neutralise a known
volume of an alkali in a
conical flask.
Titration using
phenolphthalein
142
NEUTRALISATION
ACID-BASE
TITRATION
143
Example
1.
Acid-base Indicator
Indicator
Colour in
alkalis
Colour in neutral
solution
Colour in
acids
Methyl orange
phenolphthalein
litmus
product
which,
A = acid
a = no of mole of acid
B = base
b = no of mole of base
MAVA = a
Therefore
and
MAVA
MBVB
MBVB = b
a
b
Exercise
1.
145
2.
What is the volume of 0.5 mol dm-3 sulphuric acid, H2SO4 needed
to neutralize 25.0 cm3 of 0.8 mol dm-3 ammonia, NH3 solution?
3.
146
4.
5.
147